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Manganese Sulfate, Manganese Sulphate Monohydrate, Anhydrous Manganese Sulfate, Manganese Sulfate Tetrahydrate, 7785-87-7, 10034-96-5, 10101-68-5

Manganese Sulfate, Manganese Sulphate Monohydrate, Anhydrous Manganese Sulfate, Manganese Sulfate Tetrahydrate, 7785-87-7, 10034-96-5, 10101-68-5

🔹 CAS Numbers for Manganese Sulfate

Here are the main variants:

Form Chemical Formula CAS Number Molar Mass
Anhydrous manganese sulfate MnSO₄ 7785-87-7 151.00 g/mol
Monohydrate MnSO₄·H₂O 10034-96-5 169.02 g/mol
Tetrahydrate MnSO₄·4H₂O 10101-68-5 223.07 g/mol
Heptahydrate MnSO₄·7H₂O (less common, sometimes listed) 277.11 g/mol

🔹 Notes

  • EC Number: 232-089-9 (covers manganese sulfate in general).

  • Hydrated forms are the most common in commerce, especially monohydrate (MnSO₄·H₂O), widely used in fertilizers and feed additives.

  • The anhydrous form is less common but used in laboratory and industrial processes.

  • CAS numbers differ because each hydration state is considered a distinct chemical substance.

Summary: Manganese sulfate has multiple CAS numbers depending on hydration: 7785-87-7 (anhydrous), 10034-96-5 (monohydrate), and 10101-68-5 (tetrahydrate). The monohydrate is the most widely used industrial form

Manganese Sulfate (MnSO₄) 

Here’s a clear English version of the information you shared, with technical corrections included:

🔹 Basic Information

  • Chemical Formula: MnSO₄

  • CAS Number: 7785-87-7

  • Oxidation State of Mn: +2

  • Molar Mass:

    • Anhydrous: 151.00 g/mol

    • Monohydrate: 169.02 g/mol

  • Appearance: White to pale pink crystalline solid (color depends on hydration and purity)

🔹 Physical & Chemical Properties

  • Density: ~3.25 g/cm³ (not g/mol)

  • Solubility:

    • Highly soluble in water

    • Slightly soluble in methanol

  • Thermal Behavior:

    • Hydrate loses water at ~100–125 °C

    • Anhydrous salt decomposes at ~700–850 °C, forming manganese oxides and sulfur oxides

  • Stability: Hygroscopic; commonly found as monohydrate (MnSO₄·H₂O)

🔹 Synonyms

  • Manganese(II) sulfate

  • Manganese sulfate monohydrate

  • Anhydrous manganese sulfate

  • MnSO₄

  • Note: “Sulfuric acid magnesium salt” is incorrect; the correct term is “sulfuric acid manganese salt.”

🔹 Applications

  • Agriculture:

    • Used in fertilizers to correct manganese deficiency, especially in alkaline soils (high pH).

    • Foliar application is more effective than soil application because high pH reduces manganese uptake.

    • Often combined with acidic fertilizers to improve absorption.

  • Animal Nutrition:

    • Manganese is essential for enzyme activity and bone development.

    • Supplements containing MnSO₄ are added to feed to prevent deficiency.

    • Dosage must be determined by veterinary or nutritional experts.

  • Metallurgy:

    • Manganese is critical in steelmaking and alloy production.

    • However, ferromanganese alloys are typically used, not MnSO₄ directly.

    • Manganese improves hardness, toughness, and corrosion resistance in aluminum and magnesium alloys.

  • Battery Industry:

    • Precursor for lithium-ion battery cathode materials (NMC/NMN).

    • Improves performance in lead-acid batteries by enhancing electrolyte properties.

  • Water Treatment:

    • Manganese compounds are sometimes used in water treatment, but MnSO₄ is not a primary chemical for municipal water purification.

🔹 Safety & Handling

  • Store in a dry environment to prevent clumping.

  • Avoid inhalation of dust; use protective equipment.

  • Follow local regulations and Safety Data Sheet (SDS) guidelines.

Summary: Manganese sulfate is a versatile compound widely used in fertilizers, animal feed, metallurgy, and battery production. Its main role is to supply manganese in a soluble form, correcting deficiencies in plants and animals, and serving as a precursor in industrial processes.

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