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Zinc Dimethyl Dithiocarbamate, Accelerator ZDMC, PZ-80, Rubber Accelerant ZDMC,  ZDMC, ZDMC-80, ZDMC80, 137-30-4

Zinc Dimethyl Dithiocarbamate, Accelerator ZDMC, PZ-80, Rubber Accelerant ZDMC,  ZDMC, ZDMC-80, ZDMC80, 137-30-4

ZDMC (Zinc Dimethyldithiocarbamate)

CAS No: 137-30-4 Chemical Formula: C₆H₁₂N₂S₄Zn Appearance: White to creamy powder or granules Packaging Type: Typically 25 kg bags or PD masterbatch form

Technical Specifications

Property Value / Description
Active Content (%) ~80 (in masterbatch form)
Melting Point > 180 °C
Nitrosamine Risk Low
Dispersion High (in PD form)
Toxicity Low

Application Areas

Sector Description
Latex Products Enables fast curing at low temperatures in gloves, catheters, balloons.
Natural Rubber Used as a secondary accelerator for rapid vulcanization.
Synthetic Rubber Plays a supporting role in SBR, NBR systems.
Agrochemicals Used in certain fungicide formulations.
Adhesives Applied in specialized "Medicine Glue" formulations.

Advantages

  • Effective at low temperatures: Ideal for latex systems requiring fast curing.

  • Clean formulation: Nitrosamine-free, preferred in medical-grade products.

  • High dispersion: PD form ensures homogeneous mixing.

  • High efficiency at low dosage: Works well as a secondary accelerator.

Precautions

  • May degrade at high temperatures — process temperature must be controlled.

  • Can react with metal ions — stability testing in formulations is recommended.

ZDMC vs TBBS Sectoral Suitability Table

Sector ZDMC Suitability TBBS Suitability Notes
Natural Rubber ✅ High ✅ Medium ZDMC acts fast at low temp; TBBS offers delayed vulcanization.
Synthetic Rubber (SBR, NBR) ✅ Medium ✅ High TBBS performs strongly in SBR/NBR systems.
Latex Systems ✅ High ❌ Not suitable ZDMC preferred for low nitrosamine risk.
Automotive Tires ❌ Low ✅ High TBBS provides superior mechanical strength.
Medical Products ✅ High ❌ Not suitable ZDMC ideal for low toxicity and fast curing.
General Industrial Rubber ✅ Medium ✅ High Both usable depending on formulation.
Agrochemicals ✅ (as fungicide) ZDMC used in some pesticide blends.
Fire Hose, Gaskets etc. ✅ Medium ✅ High TBBS preferred for durability; ZDMC as secondary accelerator.

Mandatory Use Cases for ZDMC

Justification Type Description
Nitrosamine Risk ZDMC is nitrosamine-free, making it mandatory in medical and food-contact rubber.
Low-Temperature Curing Essential in latex systems requiring fast vulcanization at low temperatures.
High Dispersion (PD Form) PD form ensures process stability and is standardized in some production lines.
Regulatory Compliance EU and FDA regulations mandate nitrosamine-free accelerators in specific applications.
Medical & Hygiene Products Required by certification and customer specs in sensitive applications.
Medicine Glue Formulations The only suitable accelerator in certain adhesive systems — no alternatives.

Limitations of Alternatives

ZDEC, ZDBC, ZMBT may be used in some systems, but:

  • Curing speed is lower

  • Nitrosamine risk is higher

  • Dispersion and process compatibility are limited

Sectoral Suitability Matrix

(✅: Suitable, ⚠️: Limited, ❌: Not Suitable)

Application Area / Product → ZDEC ZDBC ZMBT TBBS
Natural Rubber
Synthetic Rubber (SBR, NBR, EPDM)
Latex Systems ⚠️
Automotive Tires ⚠️
Medical Products ⚠️
Technical Rubber (Gaskets, Hoses) ⚠️
Agrochemicals ⚠️ ⚠️

Technical Notes Summary

  • ZDEC: Ultra-fast curing, ideal for low-temp systems. Low nitrosamine risk.

  • ZDBC: Good aging resistance, slower curing.

  • ZMBT: Broad curing range, versatile in technical rubber.

  • TBBS: Delayed vulcanization, high mechanical strength — essential in automotive.

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