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GLUCONIC ACID, MALTONIC ACID, GLYCOGENIC ACID, PENTA HYDROXY CAPROIC ACID, Gluconic acid, glyconicacid, Hexonic acid, 526-95-4

GLUCONIC ACID, MALTONIC ACID, GLYCOGENIC ACID, PENTA HYDROXY CAPROIC ACID, Gluconic acid, glyconicacid, Hexonic acid, 526-95-4

CAS: 526-95-4

Molecular Formula: C6H12O7

Names and Identifiers

Name Gluconic acid
Synonyms Hexonic acid
glyconicacid
GLUCONIC ACID
Gluconic acid
MALTONIC ACID
D-Gluconic acid
GLYCOGENIC ACID
Gluconicacidaqsoln
Gluconic Acid Solution
PENTAHYDROXYCAPROIC ACID
D-Gluconic acid solution
2,3,4,5,6-PENTAHYDROXYCAPROIC ACID
Ultra-Mg [as magnesium salt dihydrate]
(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate (non-preferred name)
CAS 526-95-4
EINECS 208-401-4
InChI InChI=1/C6H12O7/c7-1-2(8)3(9)4(10)5(11)6(12)13/h2-5,7-11H,1H2,(H,12,13)/p-1/t2-,3-,4+,5-/m1/s1

 Physico-chemical Properties

Molecular Formula C6H12O7
Molar Mass 196.16
Density 1.23
Melting Point 15 °C
Boling Point 102 °C
Specific Rotation(α) D20 -6.7° (c = 1)
Flash Point 375.1°C
Water Solubility Soluble in water.
Solubility DMSO (Slightly), Methanol (Slightly), Water
Vapor Presure 4.95E-21mmHg at 25°C
Appearance Crystalline Powder or Crystals
Specific Gravity 1.234
Color White to light yellow
Merck 14,4456
BRN 1726055
pKa pK (25°) 3.60
Storage Condition Store below +30°C.
Refractive Index 1.4161
MDL MFCD00004240
Physical and Chemical Properties Slightly acidic crystals. Melting point 131 °c, 50% aqueous solution relative density 1.24(25 °c). Soluble in water, slightly soluble in alcohol, insoluble in ethanol and most organic solvents.
Use Used as protein coagulant and food preservative

Risk and Safety

Risk Codes R36/37/38 - Irritating to eyes, respiratory system and skin.
R34 - Causes burns
Safety Description S37/39 - Wear suitable gloves and eye/face protection
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
UN IDs 3265
WGK Germany -
RTECS LZ5057100
TSCA Yes
HS Code 29181600
Hazard Class 8
Packing Group III

Nature

slightly acidic crystals. Melting point 131 ℃,50% aqueous solution relative density 1. 24 (25 ℃). Soluble in water, slightly soluble in alcohol, insoluble in ethanol and most organic solvents.

Preparation Method

gluconic acid can be produced by glucose oxidation or biological fermentation.

Use

for the production of gluconate such as sodium gluconate, potassium gluconate, calcium gluconate, etc.

Safety

This product is almost non-toxic, non-corrosive, non-irritating odor.

Reference Information

Sugar acid Gluconic acid is also called dextrogluconic acid. Under the action of weak oxidants or enzymes, the aldehyde group in the molecule is oxidized to carboxyl A sugar acid formed. Its 6-phosphate is an intermediate of the oxidative decomposition of glucose in the organism (pentose phosphate pathway). It forms soluble salts with metal ions such as calcium and zinc as nutrients and drugs.
uses calcium salt, ferrous salt, bismuth salt and other salts of gluconic acid can be used as medicine; the metal complexes of this product are widely used in alkaline systems The masking agent for metal ions; aqueous solution is used as a food sour agent; the preparation of sake; bottle washing agent; de-lactis for dairy equipment, etc.
Protein coagulants and food preservatives. Used to produce gluconate such as sodium gluconate, potassium gluconate, calcium gluconate, etc.
Used as protein coagulant and food preservative
Preparation method ① Glucose can be oxidized to produce gluconic acid can be prepared under the action of weak oxidants (such as bromine water); under the action of strong oxidants, in addition to the aldehyde group being oxidized to form a carboxyl group, the primary alcohol group is also oxidized to a carboxyl group to form glucosaric acid.
② citric acid is used as raw material, and aftromycin strain is used for fermentation at 25~30 ℃ at pH = 3.5 or above to obtain .At the same time, oxalic acid is produced. Then use calcium hydroxide to separate and remove oxalic acid.
fig. 2 is a chemical reaction roadmap for preparing gluconic acid from citric acid.
③Glucose is electrolytically oxidized in alkaline solution to produce 
④ calcium gluconate (or sodium) is decomposed with sulfuric acid, refined by ion exchange resin, evaporated and concentrated to obtain 
Production method Gluconic acid can be produced by glucose oxidation or biological fermentation.

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