Do you have questions? Let's talk! Get in Contact
info@betakim.com.tr

Ribbed Smoked Sheet, Naturel Rubber Sheet, Air Dried Sheet, ADS, RSS, RSS-1, RSS-2, RSS-3, RSS-4, RSS-5, 9006-04-6

Ribbed Smoked Sheet, Naturel Rubber Sheet, Air Dried Sheet, ADS, RSS, RSS-1, RSS-2, RSS-3, RSS-4, RSS-5, 9006-04-6

RIBBED SMOKED SHEETS (RSS)

Ribbed Smoked Sheets / RSS / RSS-1 / RSS-2 / RSS-3 / RSS-4 / RSS-5 / Natural Rubber Sheet
CAS Number: 9006-04-6
EINECS: 232-674-7

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Product Name Ribbed Smoked Sheets (RSS)
Other Names Natural Rubber Sheet, Smoked Sheets, Rubber Sheets, ADS (Air Dried Sheets)
CAS Number 9006-04-6
EINECS 232-674-7
Chemical Formula (C₅H₈)ₙ
Molecular Weight Variable (depends on degree of polymerization)
Chemical Class Natural rubber (polyisoprene)
Appearance Amber to dark brown translucent sheets
Odor Characteristic smoky odor
Density 0.92 - 0.94 g/cm³
Melting Point 180 - 220°C
Water Solubility Insoluble
Organic Solvent Solubility Soluble in toluene, benzene, chloroform, and other organic solvents
Glass Transition Temperature (Tg) ~ -70°C

Ribbed Smoked Sheets (RSS) are one of the oldest and most traditional forms of natural rubber. Produced from the latex of the Hevea brasiliensis tree, RSS is made by coagulating the latex, passing it through ribbed rollers to create a textured surface, and then smoke-drying the sheets in specially designed smokehouses. The smoking process not only dries the sheets but also preserves them, giving RSS its characteristic amber to dark brown color, distinctive smoky odor, and excellent aging resistance. RSS grades are classified based on visual quality, cleanliness, and physical properties. Historically, RSS was the dominant form of natural rubber in international trade, and it remains widely used in tire manufacturing, industrial products, footwear, and consumer goods.

2. RSS GRADES AND CLASSIFICATION SYSTEM

RSS grades are classified based on visual quality, cleanliness, and physical properties. The grading is primarily determined by visual inspection of the sheets, considering factors such as color, uniformity, presence of bubbles, and contamination. Higher grades (RSS-1, RSS-2, RSS-3) are used in premium applications, while lower grades (RSS-4, RSS-5) are used in general-purpose products.

Grade Quality Level Color Characteristics Primary Applications
RSS-1 Highest Quality Pale amber to light brown Very clean, uniform, no bubbles or specks Medical products, pharmaceuticals, engineering products, premium tires
RSS-2 Very High Quality Amber Very few bubbles, good uniformity High-quality tires, automotive parts, premium industrial products
RSS-3 High Quality Amber to light brown Moderate bubbles, acceptable for most uses Radial tires, high-quality rubber products, technical goods
RSS-4 Standard Quality Amber to dark brown Some bubbles, minor specks Automobile tires, retreading materials, general rubber products
RSS-5 Lower Quality Dark brown More bubbles, specks, less uniform General tires, rubber sheets, floor coverings, mats

Grade Definitions:

  • RSS-1 (Highest Quality): The highest grade of RSS with very clean, uniform sheets. No bubbles, specks, or contamination. Used in medical, pharmaceutical, and engineering applications requiring the highest purity and consistency.

  • RSS-2 (Very High Quality): Very high quality with very few bubbles and good uniformity. Used in high-quality tires and premium industrial products.

  • RSS-3 (High Quality): High quality with moderate bubbles, acceptable for most high-performance applications. Preferred for radial tires and technical rubber goods.

  • RSS-4 (Standard Quality): Standard quality with some bubbles and minor specks. Used in automobile tires, retreading materials, and general rubber products.

  • RSS-5 (Lower Quality): Lower quality with more bubbles, specks, and less uniformity. Used in general tires, rubber sheets, floor coverings, and mats.

3. TECHNICAL SPECIFICATIONS

Typical Quality Parameters by Grade:

Parameter Unit RSS-1 RSS-2 RSS-3 RSS-4 RSS-5
Dirt Content (max) % wt 0.03 0.03 0.05 0.08 0.16
Ash Content (max) % wt 0.40 0.40 0.50 0.60 0.75
Nitrogen Content (max) % wt 0.60 0.60 0.60 0.60 0.60
Volatile Matter (max) % wt 0.80 0.80 0.80 0.80 0.80
Initial Plasticity (Po, min) - 35 33 30 30 28
PRI (min) - 60 60 55 50 45
Mooney Viscosity (ML 1+4 at 100°C) MU Variable Variable Variable Variable Variable

Note: RSS grades are primarily classified by visual inspection rather than chemical analysis. The above specifications are typical values for reference.

4. COMPARISON OF RSS GRADES

Property RSS-1 RSS-2 RSS-3 RSS-4 RSS-5
Quality Level Highest Very High High Standard Lower
Color Pale amber to light brown Amber Amber to light brown Amber to dark brown Dark brown
Bubbles None Very few Moderate Some More
Specks/Contamination None None Minor Minor specks Specks present
Uniformity Excellent Very Good Good Moderate Fair
Primary Applications Medical, pharmaceutical, engineering, premium tires High-quality tires, automotive parts Radial tires, technical goods Automobile tires, retreading General tires, mats, floor coverings

5. PRODUCTION PROCESS

RSS is produced from natural rubber latex through a traditional process that has been refined over decades.

Production Steps:

  1. Latex Collection: Latex is tapped from Hevea brasiliensis trees and collected in cups.

  2. Coagulation: The latex is coagulated using formic acid or acetic acid to form a solid coagulum.

  3. Sheeting: The coagulum is passed through a series of ribbed rollers to form thin, uniform sheets with a characteristic ribbed (grooved) surface pattern. The ribbed texture increases the surface area for more efficient drying.

  4. Drying: The ribbed sheets are hung in smokehouses where they are dried and smoked at controlled temperatures (typically 40-50°C) for several days. The smoking process gives RSS its characteristic amber color, smoky odor, and excellent aging resistance.

  5. Grading: The dried sheets are visually inspected and graded according to quality standards (RSS-1 to RSS-5). The grading considers color, uniformity, presence of bubbles, specks, and contamination.

  6. Baling: The graded sheets are folded and compressed into bales for packaging and shipping.

6. PHYSICAL PROPERTIES

Property Value
Density 0.92 - 0.94 g/cm³
Glass Transition Temperature ~ -70°C
Mooney Viscosity (ML 1+4 at 100°C) Variable (50-65 MU typical)
Color Amber to dark brown (higher grades are lighter)
Odor Characteristic smoky odor
Texture Ribbed/grooved surface

7. CHEMICAL PROPERTIES AND REACTIONS

Natural rubber (polyisoprene) has a hydrocarbon backbone with unsaturated double bonds, making it susceptible to oxidation, vulcanization, and addition reactions.

Vulcanization: Sulfur cross-linking with accelerators to improve strength, elasticity, and heat resistance.

Oxidation: Reacts with oxygen, especially when heated, causing chain scission and hardening. PRI measures resistance to this. RSS has good aging resistance due to the natural antioxidants present in the rubber and the smoking process.

Ozone Resistance: RSS has poor resistance to ozone; requires antioxidants/antiozonants in formulations.

Addition Reactions: The double bonds can undergo halogenation, hydrogenation, and epoxidation.

8. ADVANTAGES OF RSS

Advantage Description
Excellent Aging Resistance The smoking process provides natural antioxidants, giving RSS superior aging resistance compared to some other natural rubber forms.
High Tensile Strength RSS exhibits excellent tensile strength and tear resistance.
Good Processability Consistent quality and uniform texture make RSS easy to process in rubber compounding.
Traditional and Well-Known RSS is a well-established grade with decades of proven performance in various applications.
Widely Available RSS is produced in several countries (Thailand, Indonesia, Malaysia, Vietnam, Sri Lanka) and is readily available in international markets.
Good Electrical Insulation Natural rubber has excellent electrical insulation properties.

9. APPLICATIONS AND INDUSTRIAL USES

9.1. Tire Industry (Largest Application)

Application Recommended Grade
Passenger Car Tires - Tread RSS-1, RSS-3
Truck and Bus Tires RSS-3, RSS-4
OTR (Mining/Construction) Tires RSS-4, RSS-5
Retreading RSS-3, RSS-4
Tire Sidewalls RSS-3

9.2. Medical and Pharmaceutical Products

Application Recommended Grade
Surgical Gloves RSS-1
Catheters RSS-1
Medical Tubing RSS-1
Pharmaceutical Stoppers RSS-1

9.3. Automotive and Industrial Rubber Products

Application Recommended Grade
Automotive Seals and Gaskets RSS-1, RSS-2
Hoses and Tubing RSS-3, RSS-4
Conveyor Belts RSS-3, RSS-4
V-Belts and Drive Belts RSS-2, RSS-3
Anti-Vibration Mounts RSS-2, RSS-3
Rubber Rollers RSS-1, RSS-2

9.4. Footwear and Consumer Goods

Application Recommended Grade
Shoe Soles RSS-3, RSS-4
Athletic Footwear RSS-2, RSS-3
Rubber Bands RSS-3
Floor Mats RSS-4, RSS-5
Rubber Sheets RSS-4, RSS-5
Floor Coverings RSS-5

9.5. Engineering and Technical Products

Application Recommended Grade
Engineering Components RSS-1
Vibration Dampers RSS-2, RSS-3
Gaskets RSS-1, RSS-2

10. COMPARISON WITH OTHER NATURAL RUBBER GRADES

Property RSS-3 SMR-10 SVR-10 STR-10
Origin Thailand/Malaysia Malaysia Vietnam Thailand
Grading Method Visual Inspection Technical Specifications Technical Specifications Technical Specifications
Color Amber Light to variable Light to variable Light to variable
Odor Smoky Natural Natural Natural
Dirt Content Variable 0.08% 0.08% 0.08%
Ash Content Variable 0.60% 0.60% 0.60%
PRI 55 (min) 50 (min) 50 (min) 50 (min)
Consistency Less consistent (visual grading) Highly consistent Highly consistent Highly consistent
Primary Use Tires, general products Tires, industrial products Tires, industrial products Tires, industrial products

11. PACKAGING AND SHIPPING

Packaging Option Details
Sheet Size ~1.2 m x 0.6 m (standard)
Bale Weight 33.33 kg or 35 kg
Bale Dimensions ~70 cm x 35 cm x 18 cm
Pallet Configuration 36 bales/pallet = 1.26 MT
Pallet Type Wooden pallet, shrink-wrapped
Container Capacity (20-ft) 16 pallets = 20.16 MT
Container Type Standard 20-ft container

12. STORAGE AND HANDLING

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; away from direct sunlight
Recommended Temperature Below 30°C
Humidity Avoid high humidity to prevent mold growth and surface stickiness
Shelf Life 12-24 months under proper storage conditions
Handling Avoid contamination with oils, solvents, and dirt
Protection Keep bales covered and protected from moisture and dust
Stacking Maximum 4-5 pallets high for stable storage

13. SAFETY AND HEALTH INFORMATION

Parameter Information
Toxicity Non-toxic
Skin Irritation Non-irritant
Eye Irritation Mild irritant (dust)
Inhalation May cause respiratory irritation (dust)
Flammability Combustible (can burn)
Fire Extinguishing Media Water spray, foam, CO₂, dry chemical powder
Special Hazards Burning produces toxic fumes (CO, CO₂, SO₂)

14. FIRST AID MEASURES

Exposure Route Action
Inhalation Move person to fresh air. If irritation persists, seek medical attention.
Skin Contact Wash with soap and water. Remove contaminated clothing.
Eye Contact Rinse with plenty of water for at least 15 minutes. Seek medical attention if irritation persists.
Ingestion Rinse mouth. Do NOT induce vomiting. Seek medical attention if large amounts are swallowed.

15. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; requires registration
USA (TSCA) Listed
Canada (DSL) Listed
Australia (AICS) Listed
Japan (ENCS) Listed
Korea (KECL) Listed
China (IECSC) Listed

Regulatory Status:

Status Information
HS Code 40012100 (Smoked Sheets)
CAS Number 9006-04-6
EINECS 232-674-7
IARC Classification Not classified
WGK Germany 1 (slight hazard to water)

16. OTHER NAMES AND DATABASE IDENTIFIERS

Category Names / Identifiers
Product Names Ribbed Smoked Sheets, RSS, Smoked Sheets, Natural Rubber Sheet, Rubber Sheets
Grade Names RSS-1, RSS-2, RSS-3, RSS-4, RSS-5
Common Names Smoked Rubber, Sheet Rubber, NR
Country Equivalents RSS (Thailand, Malaysia, Indonesia, Vietnam, Sri Lanka)
Alternative Forms ADS (Air Dried Sheets), Sun Dried Sheets

Database Identifiers:

Database Identifier
CAS 9006-04-6
EINECS 232-674-7
HS Code 40012100

17. PRODUCING COUNTRIES

RSS is produced in several countries in Southeast Asia and other regions where Hevea brasiliensis is cultivated:

Country Notable Features
Thailand Largest producer of RSS; known for consistent quality
Indonesia Major producer; produces significant volumes
Malaysia Traditional producer; high-quality grades available
Vietnam Growing producer; RSS grades increasingly available
Sri Lanka Smaller producer; known for high-grade RSS
India Produces RSS for domestic consumption

18. HISTORY AND TRADITION

RSS has been produced for over a century and was historically the dominant form of natural rubber in international trade. The smoking process was developed to preserve the rubber sheets during long ocean voyages from Southeast Asia to Europe and America. The distinctive ribbed pattern on the sheets is created by passing the coagulated rubber through ribbed rollers, which increases the surface area for more efficient drying and smoking. The smoking process not only dries the sheets but also imparts antioxidant properties to the rubber, giving RSS its characteristic amber color and excellent aging resistance. Today, RSS remains an important grade in the natural rubber market, particularly for applications requiring high quality and traditional processing characteristics.

19. INDUSTRY SUITABILITY TABLE

Industry Applications Recommended Grades Suitability
Tire Industry Passenger, truck, OTR tires RSS-1, RSS-3, RSS-4 High
Medical/Pharmaceutical Gloves, catheters, stoppers RSS-1 High
Automotive Parts Seals, hoses, mounts RSS-1, RSS-2, RSS-3 High
Footwear Shoe soles, sports shoes RSS-2, RSS-3, RSS-4 High
Industrial Products Conveyor belts, rollers RSS-3, RSS-4 High
Engineering Gaskets, components RSS-1, RSS-2 High
Consumer Goods Rubber bands, floor mats RSS-3, RSS-4, RSS-5 High

20. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Ribbed Smoked Sheets (RSS) are one of the oldest and most traditional forms of natural rubber, produced by coagulating latex, sheeting it through ribbed rollers, and smoke-drying the sheets. RSS grades are classified based on visual quality: RSS-1 (highest quality), RSS-2 (very high quality), RSS-3 (high quality), RSS-4 (standard quality), and RSS-5 (lower quality). RSS exhibits excellent aging resistance, high tensile strength, and good processability. It is used in tires, medical products, automotive parts, footwear, industrial products, and consumer goods. RSS is produced primarily in Thailand, Indonesia, Malaysia, Vietnam, and Sri Lanka. Packaging: 33.33 kg or 35 kg bales, 36 bales/pallet (1.26 MT), 16 pallets/20-ft container (20.16 MT). RSS is non-toxic, combustible, and requires storage in cool, dry conditions. HS Code: 40012100.

Key Properties:

Property Value
Appearance Amber to dark brown translucent sheets
CAS Number 9006-04-6
Density 0.92 - 0.94 g/cm³
Primary Grades RSS-1, RSS-2, RSS-3, RSS-4, RSS-5
Primary Use Tires, medical products, automotive parts, footwear

Major Application Areas:

Industry Applications
Tire Industry Passenger, truck, OTR tires
Medical/Pharmaceutical Gloves, catheters, stoppers
Automotive Parts Seals, hoses, mounts
Footwear Shoe soles
Industrial Products Conveyor belts, rollers
Engineering Gaskets, components
Consumer Goods Rubber bands, mats

Key Safety Points:

  • NON-TOXIC: Generally safe for handling

  • COMBUSTIBLE: Can burn; keep away from ignition sources

  • STORAGE: Store in cool, dry, well-ventilated area; avoid direct sunlight and high humidity

  • PPE RECOMMENDED: Dust mask, safety goggles, protective gloves (for handling)

  • PROTECT: Keep away from oils, solvents, and contaminants

CRITICAL WARNINGS:

  • RSS grades are classified primarily by visual inspection rather than chemical analysis. Higher grades (RSS-1, RSS-2) have better quality and uniformity.

  • RSS-1 is the highest quality grade, used in medical, pharmaceutical, and engineering applications requiring the highest purity and consistency.

  • RSS-3 is the most widely used grade for radial tires and high-quality rubber products.

  • RSS-4 and RSS-5 are lower quality grades used in general tires and industrial applications.

  • The smoking process gives RSS its characteristic amber color, smoky odor, and excellent aging resistance due to natural antioxidants.

  • RSS has poor resistance to ozone and requires antioxidants/antiozonants in formulations.

  • Store away from direct sunlight and heat sources to prevent degradation and maintain quality.

  • Contamination with oils or solvents can significantly affect rubber performance.

  • RSS is a traditional grade with a long history of proven performance in various applications.

  • Produced primarily in Thailand, Indonesia, Malaysia, Vietnam, and Sri Lanka.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific application and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

Documents

Do you have questions? Let us help!

Effective Business Solutions? — Get in Contact
Scroll