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Standard Malaysian Rubber, SMR, SMR-3L, SMR-10, SMR-20, SMR-CV, SMR L, SMR 5, SMR 10, SMR 20, 9006-04-6

Standard Malaysian Rubber, SMR, SMR-3L, SMR-10, SMR-20, SMR-CV, SMR L, SMR 5, SMR 10, SMR 20, 9006-04-6

STANDARD MALAYSIAN RUBBER (SMR)

Standard Malaysian Rubber / SMR / TSR / Technically Specified Rubber / SMR CV / SMR-L / SMR-3L / SMR-5 / SMR-10 / SMR-20
CAS Number: 9006-04-6
EINECS: 232-674-7

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Product Name Standard Malaysian Rubber (SMR)
Other Names TSR (Technically Specified Rubber), Malaysian Rubber, Natural Rubber (NR)
CAS Number 9006-04-6
EINECS 232-674-7
Chemical Formula (C₅H₈)ₙ
Molecular Weight Variable (depends on degree of polymerization)
Chemical Class Natural rubber (polyisoprene)
Appearance White to pale yellow solid block (bale)
Odor Characteristic rubber odor
Density 0.92 - 0.94 g/cm³
Melting Point 180 - 220°C
Water Solubility Insoluble
Organic Solvent Solubility Soluble in toluene, benzene, chloroform, and other organic solvents
Glass Transition Temperature (Tg) ~ -70°C

Standard Malaysian Rubber (SMR) is a technically specified natural rubber produced in Malaysia according to international standards (ISO 2000:2014, SMR Bulletin). The naming convention follows the TSR (Technically Specified Rubber) system: SMR stands for Standard Malaysian Rubber, indicating the country of origin. SMR grades are classified based on dirt content, ash content, nitrogen content, volatile matter, plasticity, and Plasticity Retention Index (PRI). The rubber is derived from the latex of the Hevea brasiliensis tree, which is native to the Amazon but widely cultivated in Southeast Asia. Malaysia was historically the world's largest natural rubber producer and remains one of the leading producers of high-quality SMR grades. SMR is widely used in tire manufacturing, automotive parts, footwear, industrial rubber products, and consumer goods.

2. SMR GRADES AND CLASSIFICATION SYSTEM

SMR grades are classified according to technical specifications, including cleanliness (dirt content), ash content, nitrogen content, volatile matter, initial plasticity (Po), and Plasticity Retention Index (PRI). The grades range from premium high-quality grades to standard industrial grades.

Grade Description Primary Applications
SMR CV Constant Viscosity (50, 60, 70) Adhesives, bands, sports racket surfaces, tire sidewalls, premium applications
SMR-L Light-colored, high quality Light-colored rubber products, medical applications, high-end consumer goods
SMR-3L Low dirt and ash; high quality Premium tires, automotive seals, high-performance products
SMR-5 Medium quality General tires, automotive parts, industrial goods
SMR-10 Medium quality; general purpose Tires, conveyor belts, industrial rubber products
SMR-20 Standard quality; most common grade Cost-effective tires, industrial products, general rubber goods

Grade Definitions:

  • SMR CV (Constant Viscosity): Grades with controlled Mooney viscosity (SMR CV50, CV60, CV70). Provide consistent processing behavior for automated and high-volume production.

  • SMR-L (Latex Grade): Made from high-quality latex with low dirt and ash content. Light in color, suitable for light-colored products.

  • SMR-3L: High-quality grade with very low dirt (0.03%) and ash (0.50%) content. Used in premium tire applications.

  • SMR-5: Medium quality grade with low dirt (0.05%) and ash (0.60%) content.

  • SMR-10: Medium quality grade with dirt content (0.08%) and ash content (0.60%).

  • SMR-20: Standard quality grade with higher dirt (0.16%) and ash (1.00%) content. Most commonly used grade worldwide for general tire and industrial applications.

3. TECHNICAL SPECIFICATIONS (ISO 2000:2014 / SMR BULLETIN)

Detailed Quality Parameters by Grade:

Parameter Unit SMR CV SMR-L SMR-3L SMR-5 SMR-10 SMR-20
Dirt Content (max) % wt 0.02 0.02 0.03 0.05 0.08 0.16
Ash Content (max) % wt 0.40 0.40 0.50 0.60 0.60 1.00
Nitrogen Content (max) % wt 0.60 0.60 0.60 0.60 0.60 0.60
Volatile Matter (max) % wt 0.80 0.80 0.80 0.80 0.80 0.80
Initial Plasticity (Po, min) - 35 35 35 35 30 30
PRI (min) - 60 60 60 60 50 40
Mooney Viscosity (ML 1+4 at 100°C) MU 50/60/70 ± 5 - - - - -
Lovibond Color (max) - 4.0 4.0 6.0 6.0 - -

Explanation of Key Parameters:

  1. Dirt Content: Impurities such as sand, bark, and foreign matter. Lower is better for premium applications.

  2. Ash Content: Inorganic residue after combustion. Indicates mineral contamination.

  3. Nitrogen Content: Protein content indicator. Higher nitrogen may affect aging resistance.

  4. Volatile Matter: Moisture and volatiles. High levels can cause porosity in finished products.

  5. Initial Plasticity (Po): Measure of raw rubber's ability to deform. Higher values indicate better processability.

  6. PRI (Plasticity Retention Index): Resistance to oxidation and aging. Higher PRI = better durability.

  7. Mooney Viscosity: Resistance to flow. CV grades have controlled values (50, 60, or 70 MU).

4. COMPARISON OF SMR GRADES

Property SMR CV SMR-3L SMR-10 SMR-20
Grade Type Constant Viscosity High Quality Medium Quality Standard Quality
Dirt Content Very Low (0.02%) Very Low (0.03%) Low (0.08%) Medium (0.16%)
Ash Content Very Low (0.40%) Very Low (0.50%) Low (0.60%) Medium (1.00%)
PRI Excellent (60) Good (60) Good (50) Moderate (40)
Color Light Bright Variable Darker
Viscosity Control Yes (50/60/70 ± 5) No No No
Primary Applications Premium products, adhesives, bands Premium tires, seals, high-performance products General tires, conveyor belts, industrial goods Most common grade; cost-effective tires, industrial products

5. CHEMICAL PROPERTIES AND REACTIONS

Natural rubber (polyisoprene) has a hydrocarbon backbone with unsaturated double bonds, making it susceptible to oxidation, vulcanization, and addition reactions.

Vulcanization: Sulfur cross-linking with accelerators to improve strength, elasticity, and heat resistance.

Oxidation: Reacts with oxygen, especially when heated, causing chain scission and hardening. PRI measures resistance to this.

Ozone Resistance: SMR has poor resistance to ozone; requires antioxidants/antiozonants in formulations.

Addition Reactions: The double bonds can undergo halogenation, hydrogenation, and epoxidation.

6. PHYSICAL PROPERTIES

Property Value
Density 0.92 - 0.94 g/cm³
Glass Transition Temperature ~ -70°C
Mooney Viscosity (ML 1+4 at 100°C) 50-70 MU (grade-dependent)
Color White to pale yellow (higher grades are lighter)
Odor Characteristic rubber odor

7. APPLICATIONS AND INDUSTRIAL USES

7.1. Tire Industry (Largest Application)

Application Recommended Grade
Passenger Car Tires - Tread SMR-3L, SMR CV
Truck and Bus Tires SMR-10
OTR (Mining/Construction) Tires SMR-20
Tire Sidewalls SMR CV grades
Retreading SMR-3L, SMR-10

7.2. Automotive and Industrial Rubber Products

Application Recommended Grade
Automotive Seals and Gaskets SMR-3L, SMR CV
Hoses and Tubing SMR-10, SMR-20
Conveyor Belts SMR-10
V-Belts and Drive Belts SMR CV grades
Anti-Vibration Mounts SMR CV grades
Rubber Rollers SMR-3L

7.3. Consumer Goods and Other Applications

Application Recommended Grade
Shoe Soles SMR-10
Athletic Footwear SMR-3L
Rubber Bands SMR CV grades
Adhesive Tapes SMR CV grades
Medical Rubber Products SMR-L
Light-colored Products SMR-L, SMR-3L
Condoms SMR-L
Hot Water Bottles SMR-3L, SMR-10
Balloons SMR-3L, SMR CV
Rubber Boots SMR-10, SMR-20

8. PACKAGING AND SHIPPING

Packaging Option Details
Bale Weight 35 kg
Pallet Configuration 36 bales/pallet = 1.26 MT (1,260 kg)
Pallet Type Wooden pallet, shrink-wrapped
Container Capacity (20-ft) 16 pallets = 20.16 MT
Container Type Standard 20-ft container

9. STORAGE AND HANDLING

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; away from direct sunlight
Recommended Temperature Below 30°C
Humidity Avoid high humidity to prevent mold growth
Shelf Life 12-24 months under proper storage conditions
Handling Avoid contamination with oils, solvents, and dirt
Protection Keep bales covered and protected from moisture and dust
Stacking Maximum 4-5 pallets high for stable storage

10. SAFETY AND HEALTH INFORMATION

Parameter Information
Toxicity Non-toxic
Skin Irritation Non-irritant
Eye Irritation Mild irritant (dust)
Inhalation May cause respiratory irritation (dust)
Flammability Combustible (can burn)
Fire Extinguishing Media Water spray, foam, CO₂, dry chemical powder
Special Hazards Burning produces toxic fumes (CO, CO₂, SO₂)

11. FIRST AID MEASURES

Exposure Route Action
Inhalation Move person to fresh air. If irritation persists, seek medical attention.
Skin Contact Wash with soap and water. Remove contaminated clothing.
Eye Contact Rinse with plenty of water for at least 15 minutes. Seek medical attention if irritation persists.
Ingestion Rinse mouth. Do NOT induce vomiting. Seek medical attention if large amounts are swallowed.

12. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; requires registration
USA (TSCA) Listed
Canada (DSL) Listed
Australia (AICS) Listed
Japan (ENCS) Listed
Korea (KECL) Listed
China (IECSC) Listed

Regulatory Status:

Status Information
HS Code 40012200 (Technically Specified Natural Rubber)
CAS Number 9006-04-6
EINECS 232-674-7
IARC Classification Not classified
WGK Germany 1 (slight hazard to water)

13. OTHER NAMES AND DATABASE IDENTIFIERS

Category Names / Identifiers
Product Names Standard Malaysian Rubber, SMR, Malaysian Rubber, Natural Rubber
Grade Names SMR CV, SMR-L, SMR-3L, SMR-5, SMR-10, SMR-20
Common Names TSR (Technically Specified Rubber), NR
Country Equivalents SMR (Malaysia), SVR (Vietnam), STR (Thailand), SIR (Indonesia)

Database Identifiers:

Database Identifier
CAS 9006-04-6
EINECS 232-674-7
HS Code 40012200

14. COMPARISON WITH OTHER NATURAL RUBBER GRADES

Grade Origin Characteristics Equivalence
SMR-3L Malaysia Low dirt, high quality Comparable to SVR 3L / STR 5L
SMR-10 Malaysia Medium quality Comparable to SVR 10 / STR 10
SMR-20 Malaysia Standard quality Comparable to SVR 20 / STR 20
SMR CV Malaysia Constant viscosity Comparable to SVR CV / STR CV
STR 20 Thailand Standard TSR Comparable to SMR 20
SVR 20 Vietnam Standard TSR Comparable to SMR 20
RSS 3 Thailand Ribbed smoked sheet Visual grade, high quality

TSR Naming Convention: The letters indicate country of origin (SMR = Malaysia, SIR = Indonesia, STR = Thailand, SVR = Vietnam), and the number/letters indicate the grade.

15. HS CODE AND CUSTOMS INFORMATION

Grade Material HS Code
Cup Lump Grade (SMR-10, 20) 4001.2210 / 4001.2220
Latex Grade (SMR-L, CV) 4001.2230 / 4001.2240

16. ADVANTAGES OF SMR

Advantage Description
Technically Specified Consistent quality determined by scientific analysis
Consistent Quality Standardized specifications ensure batch-to-batch consistency
Wide Range of Grades Grades from premium (SMR-3L) to cost-effective (SMR-20)
Good Mechanical Properties High tensile strength, elasticity, and abrasion resistance
Easy Processing Stable characteristics for compounding and blending
Global Acceptance Widely recognized and accepted in international markets

17. LIMITATIONS

Limitation Description
Poor Ozone Resistance Requires antioxidants/antiozonants in formulations
Oxidative Aging Susceptible to oxidation at high temperatures; PRI indicates resistance
Moisture Sensitivity Requires proper storage to prevent mold growth
Color Variation Lower grades have darker color; affects light-colored products

18. INDUSTRY SUITABILITY TABLE

Industry Applications Recommended Grades Suitability
Tire Industry Passenger, truck, OTR tires SMR-3L, SMR-10, SMR-20, SMR CV High
Automotive Parts Seals, hoses, mounts, belts SMR-3L, SMR CV High
Footwear Shoe soles, sports shoes SMR-10, SMR-3L High
Industrial Products Conveyor belts, rollers SMR-10, SMR-20 High
Medical Products Gloves, catheters SMR-L High
Adhesives and Tapes Rubber bands, PSA tapes SMR CV High
Sports Equipment Racket surfaces SMR CV High
Light-colored Products Premium consumer goods SMR-L, SMR-3L High

19. HISTORY AND ORIGIN

Malaysia has been one of the world's leading natural rubber producers since the early 20th century. The Hevea brasiliensis tree, native to the Amazon, was introduced to Southeast Asia in the late 19th century. The first rubber trees were planted in Malaysia in 1877, and by the early 1900s, Malaysia had become the world's largest rubber producer. The SMR (Standard Malaysian Rubber) grading system was established in 1965 to ensure consistent quality for international markets. Today, Malaysia remains a major producer of high-quality natural rubber, particularly the SMR-20 grade, which is the most widely traded natural rubber grade globally.

20. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Standard Malaysian Rubber (SMR) is a technically specified natural rubber produced in Malaysia according to international standards. The main grades are SMR CV (Constant Viscosity), SMR-L (Light-colored), SMR-3L (High Quality), SMR-5 (Medium Quality), SMR-10 (Medium Quality), and SMR-20 (Standard Quality). Specifications vary by grade: dirt content (0.02-0.16%), ash content (0.40-1.00%), nitrogen content (≤0.60%), volatile matter (≤0.80%), Po (30-35), PRI (40-60), and Mooney viscosity (50-70 MU for CV grades). SMR is used in tires, automotive parts, footwear, conveyor belts, adhesives, medical products, and consumer goods. Packaging: 35 kg bales, 36 bales/pallet (1.26 MT), 16 pallets/20-ft container (20.16 MT). SMR is non-toxic, combustible, and requires storage in cool, dry conditions. HS Code: 40012200.

Key Properties:

Property Value
Appearance White to pale yellow solid block
CAS Number 9006-04-6
Density 0.92 - 0.94 g/cm³
Primary Grades SMR CV, SMR-L, SMR-3L, SMR-5, SMR-10, SMR-20
Primary Use Tires, automotive parts, industrial products

Major Application Areas:

Industry Applications
Tire Industry Passenger, truck, OTR tires
Automotive Parts Seals, hoses, mounts, belts
Footwear Shoe soles
Industrial Products Conveyor belts, rollers
Medical Products Gloves, catheters
Adhesives Rubber bands, tape adhesives

Key Safety Points:

  • NON-TOXIC: Generally safe for handling

  • COMBUSTIBLE: Can burn; keep away from ignition sources

  • STORAGE: Store in cool, dry, well-ventilated area; avoid direct sunlight and high humidity

  • PPE RECOMMENDED: Dust mask, safety goggles, protective gloves (for handling)

  • PROTECT: Keep away from oils, solvents, and contaminants

CRITICAL WARNINGS:

  • SMR grades are classified by technical specifications rather than visual inspection, ensuring consistent quality.

  • SMR CV grades have controlled Mooney viscosity (50, 60, or 70 ± 5) for consistent processing.

  • SMR-3L is the highest quality grade with very low dirt and ash content, used in premium applications.

  • SMR-20 is the most common grade worldwide, used in tire manufacturing and general industrial applications.

  • PRI indicates aging resistance; higher values (60) indicate better durability.

  • Store away from direct sunlight and heat sources to prevent degradation and maintain quality.

  • Contamination with oils or solvents can significantly affect rubber performance.

  • Malaysia was historically the world's largest rubber producer and remains a key supplier of high-quality SMR grades.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific application and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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