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Send EmailStandard Malaysian Rubber, SMR, SMR-3L, SMR-10, SMR-20, SMR-CV, SMR L, SMR 5, SMR 10, SMR 20, 9006-04-6
Standard Malaysian Rubber / SMR / TSR / Technically Specified Rubber / SMR CV / SMR-L / SMR-3L / SMR-5 / SMR-10 / SMR-20
CAS Number: 9006-04-6
EINECS: 232-674-7
| Parameter | Description |
|---|---|
| Product Name | Standard Malaysian Rubber (SMR) |
| Other Names | TSR (Technically Specified Rubber), Malaysian Rubber, Natural Rubber (NR) |
| CAS Number | 9006-04-6 |
| EINECS | 232-674-7 |
| Chemical Formula | (C₅H₈)ₙ |
| Molecular Weight | Variable (depends on degree of polymerization) |
| Chemical Class | Natural rubber (polyisoprene) |
| Appearance | White to pale yellow solid block (bale) |
| Odor | Characteristic rubber odor |
| Density | 0.92 - 0.94 g/cm³ |
| Melting Point | 180 - 220°C |
| Water Solubility | Insoluble |
| Organic Solvent Solubility | Soluble in toluene, benzene, chloroform, and other organic solvents |
| Glass Transition Temperature (Tg) | ~ -70°C |
Standard Malaysian Rubber (SMR) is a technically specified natural rubber produced in Malaysia according to international standards (ISO 2000:2014, SMR Bulletin). The naming convention follows the TSR (Technically Specified Rubber) system: SMR stands for Standard Malaysian Rubber, indicating the country of origin. SMR grades are classified based on dirt content, ash content, nitrogen content, volatile matter, plasticity, and Plasticity Retention Index (PRI). The rubber is derived from the latex of the Hevea brasiliensis tree, which is native to the Amazon but widely cultivated in Southeast Asia. Malaysia was historically the world's largest natural rubber producer and remains one of the leading producers of high-quality SMR grades. SMR is widely used in tire manufacturing, automotive parts, footwear, industrial rubber products, and consumer goods.
SMR grades are classified according to technical specifications, including cleanliness (dirt content), ash content, nitrogen content, volatile matter, initial plasticity (Po), and Plasticity Retention Index (PRI). The grades range from premium high-quality grades to standard industrial grades.
| Grade | Description | Primary Applications |
|---|---|---|
| SMR CV | Constant Viscosity (50, 60, 70) | Adhesives, bands, sports racket surfaces, tire sidewalls, premium applications |
| SMR-L | Light-colored, high quality | Light-colored rubber products, medical applications, high-end consumer goods |
| SMR-3L | Low dirt and ash; high quality | Premium tires, automotive seals, high-performance products |
| SMR-5 | Medium quality | General tires, automotive parts, industrial goods |
| SMR-10 | Medium quality; general purpose | Tires, conveyor belts, industrial rubber products |
| SMR-20 | Standard quality; most common grade | Cost-effective tires, industrial products, general rubber goods |
Grade Definitions:
SMR CV (Constant Viscosity): Grades with controlled Mooney viscosity (SMR CV50, CV60, CV70). Provide consistent processing behavior for automated and high-volume production.
SMR-L (Latex Grade): Made from high-quality latex with low dirt and ash content. Light in color, suitable for light-colored products.
SMR-3L: High-quality grade with very low dirt (0.03%) and ash (0.50%) content. Used in premium tire applications.
SMR-5: Medium quality grade with low dirt (0.05%) and ash (0.60%) content.
SMR-10: Medium quality grade with dirt content (0.08%) and ash content (0.60%).
SMR-20: Standard quality grade with higher dirt (0.16%) and ash (1.00%) content. Most commonly used grade worldwide for general tire and industrial applications.
Detailed Quality Parameters by Grade:
| Parameter | Unit | SMR CV | SMR-L | SMR-3L | SMR-5 | SMR-10 | SMR-20 |
|---|---|---|---|---|---|---|---|
| Dirt Content (max) | % wt | 0.02 | 0.02 | 0.03 | 0.05 | 0.08 | 0.16 |
| Ash Content (max) | % wt | 0.40 | 0.40 | 0.50 | 0.60 | 0.60 | 1.00 |
| Nitrogen Content (max) | % wt | 0.60 | 0.60 | 0.60 | 0.60 | 0.60 | 0.60 |
| Volatile Matter (max) | % wt | 0.80 | 0.80 | 0.80 | 0.80 | 0.80 | 0.80 |
| Initial Plasticity (Po, min) | - | 35 | 35 | 35 | 35 | 30 | 30 |
| PRI (min) | - | 60 | 60 | 60 | 60 | 50 | 40 |
| Mooney Viscosity (ML 1+4 at 100°C) | MU | 50/60/70 ± 5 | - | - | - | - | - |
| Lovibond Color (max) | - | 4.0 | 4.0 | 6.0 | 6.0 | - | - |
Explanation of Key Parameters:
Dirt Content: Impurities such as sand, bark, and foreign matter. Lower is better for premium applications.
Ash Content: Inorganic residue after combustion. Indicates mineral contamination.
Nitrogen Content: Protein content indicator. Higher nitrogen may affect aging resistance.
Volatile Matter: Moisture and volatiles. High levels can cause porosity in finished products.
Initial Plasticity (Po): Measure of raw rubber's ability to deform. Higher values indicate better processability.
PRI (Plasticity Retention Index): Resistance to oxidation and aging. Higher PRI = better durability.
Mooney Viscosity: Resistance to flow. CV grades have controlled values (50, 60, or 70 MU).
| Property | SMR CV | SMR-3L | SMR-10 | SMR-20 |
|---|---|---|---|---|
| Grade Type | Constant Viscosity | High Quality | Medium Quality | Standard Quality |
| Dirt Content | Very Low (0.02%) | Very Low (0.03%) | Low (0.08%) | Medium (0.16%) |
| Ash Content | Very Low (0.40%) | Very Low (0.50%) | Low (0.60%) | Medium (1.00%) |
| PRI | Excellent (60) | Good (60) | Good (50) | Moderate (40) |
| Color | Light | Bright | Variable | Darker |
| Viscosity Control | Yes (50/60/70 ± 5) | No | No | No |
| Primary Applications | Premium products, adhesives, bands | Premium tires, seals, high-performance products | General tires, conveyor belts, industrial goods | Most common grade; cost-effective tires, industrial products |
Natural rubber (polyisoprene) has a hydrocarbon backbone with unsaturated double bonds, making it susceptible to oxidation, vulcanization, and addition reactions.
Vulcanization: Sulfur cross-linking with accelerators to improve strength, elasticity, and heat resistance.
Oxidation: Reacts with oxygen, especially when heated, causing chain scission and hardening. PRI measures resistance to this.
Ozone Resistance: SMR has poor resistance to ozone; requires antioxidants/antiozonants in formulations.
Addition Reactions: The double bonds can undergo halogenation, hydrogenation, and epoxidation.
| Property | Value |
|---|---|
| Density | 0.92 - 0.94 g/cm³ |
| Glass Transition Temperature | ~ -70°C |
| Mooney Viscosity (ML 1+4 at 100°C) | 50-70 MU (grade-dependent) |
| Color | White to pale yellow (higher grades are lighter) |
| Odor | Characteristic rubber odor |
| Application | Recommended Grade |
|---|---|
| Passenger Car Tires - Tread | SMR-3L, SMR CV |
| Truck and Bus Tires | SMR-10 |
| OTR (Mining/Construction) Tires | SMR-20 |
| Tire Sidewalls | SMR CV grades |
| Retreading | SMR-3L, SMR-10 |
| Application | Recommended Grade |
|---|---|
| Automotive Seals and Gaskets | SMR-3L, SMR CV |
| Hoses and Tubing | SMR-10, SMR-20 |
| Conveyor Belts | SMR-10 |
| V-Belts and Drive Belts | SMR CV grades |
| Anti-Vibration Mounts | SMR CV grades |
| Rubber Rollers | SMR-3L |
| Application | Recommended Grade |
|---|---|
| Shoe Soles | SMR-10 |
| Athletic Footwear | SMR-3L |
| Rubber Bands | SMR CV grades |
| Adhesive Tapes | SMR CV grades |
| Medical Rubber Products | SMR-L |
| Light-colored Products | SMR-L, SMR-3L |
| Condoms | SMR-L |
| Hot Water Bottles | SMR-3L, SMR-10 |
| Balloons | SMR-3L, SMR CV |
| Rubber Boots | SMR-10, SMR-20 |
| Packaging Option | Details |
|---|---|
| Bale Weight | 35 kg |
| Pallet Configuration | 36 bales/pallet = 1.26 MT (1,260 kg) |
| Pallet Type | Wooden pallet, shrink-wrapped |
| Container Capacity (20-ft) | 16 pallets = 20.16 MT |
| Container Type | Standard 20-ft container |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area; away from direct sunlight |
| Recommended Temperature | Below 30°C |
| Humidity | Avoid high humidity to prevent mold growth |
| Shelf Life | 12-24 months under proper storage conditions |
| Handling | Avoid contamination with oils, solvents, and dirt |
| Protection | Keep bales covered and protected from moisture and dust |
| Stacking | Maximum 4-5 pallets high for stable storage |
| Parameter | Information |
|---|---|
| Toxicity | Non-toxic |
| Skin Irritation | Non-irritant |
| Eye Irritation | Mild irritant (dust) |
| Inhalation | May cause respiratory irritation (dust) |
| Flammability | Combustible (can burn) |
| Fire Extinguishing Media | Water spray, foam, CO₂, dry chemical powder |
| Special Hazards | Burning produces toxic fumes (CO, CO₂, SO₂) |
| Exposure Route | Action |
|---|---|
| Inhalation | Move person to fresh air. If irritation persists, seek medical attention. |
| Skin Contact | Wash with soap and water. Remove contaminated clothing. |
| Eye Contact | Rinse with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. |
| Ingestion | Rinse mouth. Do NOT induce vomiting. Seek medical attention if large amounts are swallowed. |
| Region | Status |
|---|---|
| EU | REACH registered |
| Turkey (KKDİK) | Mandatory compliance; requires registration |
| USA (TSCA) | Listed |
| Canada (DSL) | Listed |
| Australia (AICS) | Listed |
| Japan (ENCS) | Listed |
| Korea (KECL) | Listed |
| China (IECSC) | Listed |
Regulatory Status:
| Status | Information |
|---|---|
| HS Code | 40012200 (Technically Specified Natural Rubber) |
| CAS Number | 9006-04-6 |
| EINECS | 232-674-7 |
| IARC Classification | Not classified |
| WGK Germany | 1 (slight hazard to water) |
| Category | Names / Identifiers |
|---|---|
| Product Names | Standard Malaysian Rubber, SMR, Malaysian Rubber, Natural Rubber |
| Grade Names | SMR CV, SMR-L, SMR-3L, SMR-5, SMR-10, SMR-20 |
| Common Names | TSR (Technically Specified Rubber), NR |
| Country Equivalents | SMR (Malaysia), SVR (Vietnam), STR (Thailand), SIR (Indonesia) |
Database Identifiers:
| Database | Identifier |
|---|---|
| CAS | 9006-04-6 |
| EINECS | 232-674-7 |
| HS Code | 40012200 |
| Grade | Origin | Characteristics | Equivalence |
|---|---|---|---|
| SMR-3L | Malaysia | Low dirt, high quality | Comparable to SVR 3L / STR 5L |
| SMR-10 | Malaysia | Medium quality | Comparable to SVR 10 / STR 10 |
| SMR-20 | Malaysia | Standard quality | Comparable to SVR 20 / STR 20 |
| SMR CV | Malaysia | Constant viscosity | Comparable to SVR CV / STR CV |
| STR 20 | Thailand | Standard TSR | Comparable to SMR 20 |
| SVR 20 | Vietnam | Standard TSR | Comparable to SMR 20 |
| RSS 3 | Thailand | Ribbed smoked sheet | Visual grade, high quality |
TSR Naming Convention: The letters indicate country of origin (SMR = Malaysia, SIR = Indonesia, STR = Thailand, SVR = Vietnam), and the number/letters indicate the grade.
| Grade Material | HS Code |
|---|---|
| Cup Lump Grade (SMR-10, 20) | 4001.2210 / 4001.2220 |
| Latex Grade (SMR-L, CV) | 4001.2230 / 4001.2240 |
| Advantage | Description |
|---|---|
| Technically Specified | Consistent quality determined by scientific analysis |
| Consistent Quality | Standardized specifications ensure batch-to-batch consistency |
| Wide Range of Grades | Grades from premium (SMR-3L) to cost-effective (SMR-20) |
| Good Mechanical Properties | High tensile strength, elasticity, and abrasion resistance |
| Easy Processing | Stable characteristics for compounding and blending |
| Global Acceptance | Widely recognized and accepted in international markets |
| Limitation | Description |
|---|---|
| Poor Ozone Resistance | Requires antioxidants/antiozonants in formulations |
| Oxidative Aging | Susceptible to oxidation at high temperatures; PRI indicates resistance |
| Moisture Sensitivity | Requires proper storage to prevent mold growth |
| Color Variation | Lower grades have darker color; affects light-colored products |
| Industry | Applications | Recommended Grades | Suitability |
|---|---|---|---|
| Tire Industry | Passenger, truck, OTR tires | SMR-3L, SMR-10, SMR-20, SMR CV | High |
| Automotive Parts | Seals, hoses, mounts, belts | SMR-3L, SMR CV | High |
| Footwear | Shoe soles, sports shoes | SMR-10, SMR-3L | High |
| Industrial Products | Conveyor belts, rollers | SMR-10, SMR-20 | High |
| Medical Products | Gloves, catheters | SMR-L | High |
| Adhesives and Tapes | Rubber bands, PSA tapes | SMR CV | High |
| Sports Equipment | Racket surfaces | SMR CV | High |
| Light-colored Products | Premium consumer goods | SMR-L, SMR-3L | High |
Malaysia has been one of the world's leading natural rubber producers since the early 20th century. The Hevea brasiliensis tree, native to the Amazon, was introduced to Southeast Asia in the late 19th century. The first rubber trees were planted in Malaysia in 1877, and by the early 1900s, Malaysia had become the world's largest rubber producer. The SMR (Standard Malaysian Rubber) grading system was established in 1965 to ensure consistent quality for international markets. Today, Malaysia remains a major producer of high-quality natural rubber, particularly the SMR-20 grade, which is the most widely traded natural rubber grade globally.
SUMMARY:
Standard Malaysian Rubber (SMR) is a technically specified natural rubber produced in Malaysia according to international standards. The main grades are SMR CV (Constant Viscosity), SMR-L (Light-colored), SMR-3L (High Quality), SMR-5 (Medium Quality), SMR-10 (Medium Quality), and SMR-20 (Standard Quality). Specifications vary by grade: dirt content (0.02-0.16%), ash content (0.40-1.00%), nitrogen content (≤0.60%), volatile matter (≤0.80%), Po (30-35), PRI (40-60), and Mooney viscosity (50-70 MU for CV grades). SMR is used in tires, automotive parts, footwear, conveyor belts, adhesives, medical products, and consumer goods. Packaging: 35 kg bales, 36 bales/pallet (1.26 MT), 16 pallets/20-ft container (20.16 MT). SMR is non-toxic, combustible, and requires storage in cool, dry conditions. HS Code: 40012200.
Key Properties:
| Property | Value |
|---|---|
| Appearance | White to pale yellow solid block |
| CAS Number | 9006-04-6 |
| Density | 0.92 - 0.94 g/cm³ |
| Primary Grades | SMR CV, SMR-L, SMR-3L, SMR-5, SMR-10, SMR-20 |
| Primary Use | Tires, automotive parts, industrial products |
Major Application Areas:
| Industry | Applications |
|---|---|
| Tire Industry | Passenger, truck, OTR tires |
| Automotive Parts | Seals, hoses, mounts, belts |
| Footwear | Shoe soles |
| Industrial Products | Conveyor belts, rollers |
| Medical Products | Gloves, catheters |
| Adhesives | Rubber bands, tape adhesives |
Key Safety Points:
NON-TOXIC: Generally safe for handling
COMBUSTIBLE: Can burn; keep away from ignition sources
STORAGE: Store in cool, dry, well-ventilated area; avoid direct sunlight and high humidity
PPE RECOMMENDED: Dust mask, safety goggles, protective gloves (for handling)
PROTECT: Keep away from oils, solvents, and contaminants
CRITICAL WARNINGS:
SMR grades are classified by technical specifications rather than visual inspection, ensuring consistent quality.
SMR CV grades have controlled Mooney viscosity (50, 60, or 70 ± 5) for consistent processing.
SMR-3L is the highest quality grade with very low dirt and ash content, used in premium applications.
SMR-20 is the most common grade worldwide, used in tire manufacturing and general industrial applications.
PRI indicates aging resistance; higher values (60) indicate better durability.
Store away from direct sunlight and heat sources to prevent degradation and maintain quality.
Contamination with oils or solvents can significantly affect rubber performance.
Malaysia was historically the world's largest rubber producer and remains a key supplier of high-quality SMR grades.
Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific application and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.