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Calcium Chloride, Calcium Dichloride, Calcium Chloride Hydrate, 10043-52-4, 22691-02-7, 10035-04-8, 25094-02-4, 7774-34-7

Calcium Chloride, Calcium Dichloride, Calcium Chloride Hydrate, 10043-52-4, 22691-02-7, 10035-04-8, 25094-02-4, 7774-34-7

CALCIUM CHLORIDE – KALSIYUM KLORÜR

CAS Number: 10043-52-4 (Anhydrous), 22691-02-7 (Monohydrate), 10035-04-8 (Dihydrate), 25094-02-4 (Tetrahydroate), 7774-34-7 (Hexahydrate)
EC Number (EINECS): 233-140-8 (Anhydrous)
Molecular Formula: CaCl₂ (Anhydrous), CaCl₂·H₂O (Monohydrate), CaCl₂·2H₂O (Dihydrate), CaCl₂·6H₂O (Hexahydrate)
Molecular Weight: 110.98 g/mol (Anhydrous), 128.99 g/mol (Monohydrate), 147.01 g/mol (Dihydrate), 219.08 g/mol (Hexahydrate)
E Number: E509

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Chemical Name (IUPAC) Calcium chloride
Other Names Calcium Chloride, Calcium Dichloride, Calcium Chloride Hydrate
Chemical Formula (Anhydrous) CaCl₂
Chemical Formula (Hexahydrate) CaCl₂·6H₂O
Molecular Weight (Anhydrous) 110.98 g/mol
Molecular Weight (Hexahydrate) 219.08 g/mol
CAS Number (Anhydrous) 10043-52-4
CAS Number (Monohydrate) 22691-02-7
CAS Number (Dihydrate) 10035-04-8
CAS Number (Tetrahydroate) 25094-02-4
CAS Number (Hexahydrate) 7774-34-7
EC Number (EINECS) 233-140-8
E Number E509 (Food additive)
Chemical Class Inorganic calcium salt (chloride)
Appearance White, crystalline powder, flakes or granules
Odor Odorless
Physical State (20°C) Solid (powder, flakes or granules)
Hygroscopicity Highly hygroscopic (absorbs moisture)

SECTION 2: FORMS OF CALCIUM CHLORIDE

Form CAS Number Formula Molecular Weight Description
Anhydrous 10043-52-4 CaCl₂ 110.98 g/mol Most hygroscopic; used as industrial desiccant
Monohydrate 22691-02-7 CaCl₂·H₂O 128.99 g/mol Used in specialty chemical synthesis
Dihydrate 10035-04-8 CaCl₂·2H₂O 147.01 g/mol Food additive, pharmaceutical, animal feed
Tetrahydroate 25094-02-4 CaCl₂·4H₂O 182.99 g/mol Specialty chemical applications
Hexahydrate 7774-34-7 CaCl₂·6H₂O 219.08 g/mol Agriculture, food, pharmaceutical, cooling baths

SECTION 3: PHYSICAL PROPERTIES

Property Anhydrous (10043-52-4) Hexahydrate (7774-34-7)
Appearance White, hygroscopic crystals White crystalline powder
Molecular Weight 110.98 g/mol 219.08 g/mol
Density (20°C) 2.15 g/cm³ 1.71 g/cm³
Melting Point 772 °C 30 °C (loses water)
Boiling Point ~1600 °C 100 °C (loses water)
Solubility in Water (20°C) Highly soluble (~745 g/L) Highly soluble
Solubility in Ethanol Soluble Soluble
pH (5% solution) 6.0 – 8.5 6.0 – 8.5
Hygroscopicity Very high High

SECTION 4: CHEMICAL PROPERTIES

Property Information
Chemical Formula (Anhydrous) CaCl₂
Chemical Formula (Hexahydrate) CaCl₂·6H₂O
Molecular Weight (Anhydrous) 110.98 g/mol
Chemical Class Inorganic calcium salt (chloride)
Structure Calcium ion and chloride anions
Calcium Content (Anhydrous) ~36.1%
Calcium Content (Hexahydrate) ~18.3%
pH (5% solution) 6.0 – 8.5
Stability Stable under normal storage conditions
Hygroscopicity Highly hygroscopic
Deliquescent Deliquescent (absorbs moisture and dissolves)
Incompatible Materials Strong acids, strong oxidizing agents

SECTION 5: APPLICATION AREAS

5.1. Food Industry (E509)

Application Function
Food Additive Firming agent, calcium source
Cheese Production Coagulant (milk curdling)
Canned Vegetables Firming agent (maintains crispness)
Pickles Firming agent
Tofu Production Coagulant
Dietary Supplements Calcium source
Sports Drinks Electrolyte source
Fruit Juices Calcium fortification

5.2. Industrial Applications

Application Function
Desiccant / Drying Agent Dries gases and liquids
Road Deicing Melts ice and snow
Dust Control Reduces dust on unpaved roads
Concrete Accelerator Speeds up concrete setting
Textile Industry As auxiliary agent
Detergent Industry As processing aid
Petroleum Industry Drilling mud additive
Refrigeration/Cooling Baths Mix with ice to achieve temperatures below -50°C

5.3. Agricultural Applications

Application Function
Fertilizer Calcium source for plants
Soil Conditioner Improves soil structure
Animal Feed Calcium supplementation
Silage Additive Preserves animal feed

5.4. Pharmaceutical Applications

Application Function
Calcium Supplements Calcium source
Intravenous Solutions Calcium replacement therapy
Drug Formulations Excipient
Electrolyte Solutions Electrolyte source

SECTION 6: QUALITY SPECIFICATIONS (FOOD/PHARMACEUTICAL GRADE)

Parameter Specification (USP / Ph. Eur. / FCC)
Appearance White, crystalline powder or flakes
Identification Positive (Calcium and Chloride tests)
Assay (CaCl₂·2H₂O) 99.0 – 103.0%
Assay (CaCl₂) 93.0 – 100.5%
pH (5% solution) 6.0 – 8.5
Loss on Drying (Dihydrate) 18.0 – 26.0%
Alkalinity ≤ 0.05% (as Ca(OH)₂)
Chlorides ≤ 0.01%
Sulfates (SO₄) ≤ 0.02%
Heavy Metals (as Pb) ≤ 10 ppm
Lead (Pb) ≤ 2 ppm
Arsenic (As) ≤ 3 ppm
Mercury (Hg) ≤ 1 ppm
Barium (Ba) ≤ 0.01%
Iron (Fe) ≤ 0.001%
Magnesium (Mg) ≤ 0.5%
Water Insoluble ≤ 0.1%

SECTION 7: MICROBIOLOGICAL SPECIFICATIONS

Parameter Specification
Total Aerobic Mesophilic Bacteria ≤ 1,000 CFU/g
Yeast and Mold ≤ 100 CFU/g
Salmonella spp. Negative in 25g
Escherichia coli Negative in 10g

SECTION 8: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool (15-25°C), dry, well-ventilated area
Container Requirements Tightly closed, original packaging (very hygroscopic)
Protect From Moisture (hygroscopic/deliquescent), strong acids, strong oxidizing agents
Shelf Life 36-60 months (unopened original packaging)
Stability Note Highly hygroscopic; absorbs moisture and dissolves; store in airtight containers

SECTION 9: PACKAGING OPTIONS

Packaging Type Quantity Material
PE-lined kraft paper bag 25 kg Kraft paper + PE
Plastic pail 20-25 kg HDPE
Fiber drum 25-50 kg HDPE + PE
Big-Bag 500-1000 kg Polypropylene (with PE liner)

SECTION 10: SAFETY AND HEALTH INFORMATION

GHS Classification (Bulk Powder)

Hazard Class Category
Eye Irritation Category 2A (H319)
Skin Irritation Category 2 (H315)
Signal Word Warning

Hazard Statements (H-Codes)

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation

Precautionary Statements (P-Codes)

Code Statement
P261 Avoid breathing dust
P280 Wear protective gloves/eye protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes; remove contact lenses if present and easy to do; continue rinsing

SECTION 11: TOXICOLOGICAL INFORMATION

Parameter Value
Oral LD50 (Rat) ~1,000 mg/kg
Skin Irritation Irritant
Eye Irritation Irritant
Carcinogenicity Not classified
Mutagenicity Negative in standard tests
FDA GRAS 21 CFR 184.1193

SECTION 12: FIRST AID MEASURES

Exposure Route Action
Inhalation Move to fresh air. If respiratory irritation persists, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. Seek medical attention.

SECTION 13: REGULATORY STATUS

Region / Authority Status
European Union Approved as E509
USA (FDA) GRAS (21 CFR 184.1193)
Turkey Approved (Turkish Food Codex)
JECFA (FAO/WHO) Approved; ADI: Not specified
Codex Alimentarius Approved (INS 509)
USP Monograph available
Ph. Eur. Monograph available

SECTION 14: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous goods)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No

SECTION 15: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Non-combustible (inorganic salt)
Suitable Extinguishing Media Water spray (mist), CO₂, dry chemical powder
Specific Hazards When heated, emits chlorine gas
Decomposition Products HCl, Cl₂, CaO
Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing

SECTION 16: ACCIDENTAL SPILLAGE AND CLEANUP

Parameter Information
Personal Protection Nitrile gloves, protective goggles, dust mask (N95)
Cleaning Methods Sweep or vacuum; avoid dust generation
Environmental Precautions Prevent entry into drains, soil, and surface waters
Waste Disposal According to local regulations; landfilling at licensed facilities

SECTION 17: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Kalsiyum Klorür, Kalsiyum Klorür Heksahidrat, Antarktisit
English Names Calcium Chloride, Calcium Dichloride, Calcium Chloride Hydrate
Chemical Names Calcium(II) Chloride, Dichlorocalcium Hydrate
E Number E509
CAS (Anhydrous) 10043-52-4
CAS (Monohydrate) 22691-02-7
CAS (Dihydrate) 10035-04-8
CAS (Hexahydrate) 7774-34-7
EC Number 233-140-8

SECTION 18: SUMMARY AND CRITICAL NOTES

Product Summary

Parameter Value
Product Calcium Chloride
CAS Number (Anhydrous) 10043-52-4
CAS Number (Hexahydrate) 7774-34-7
E Number E509
Appearance White, crystalline powder or flakes
Molecular Weight 110.98 g/mol (Anhydrous)
Primary Function Desiccant, food additive, deicer
GRAS Yes

Critical Notes

  1. Multiple Forms: Available as anhydrous (10043-52-4), monohydrate (22691-02-7), dihydrate (10035-04-8), and hexahydrate (7774-34-7).

  2. Highly Hygroscopic: Anhydrous form is very hygroscopic and deliquescent; absorbs moisture and dissolves in it.

  3. Desiccant: Anhydrous form used as industrial drying agent for gases and liquids.

  4. Food Additive (E509): Used as firming agent and calcium source in food products.

  5. Road Deicing: Widely used for melting ice and snow on roads.

  6. Concrete Accelerator: Speeds up concrete setting time.

  7. Cooling Baths: Hexahydrate mixed with ice achieves temperatures below -50°C.

  8. Highly Soluble: All forms are highly soluble in water.

  9. FDA GRAS: Approved as GRAS by FDA (21 CFR 184.1193).

  10. Regulatory Status: Approved in EU (E509), FDA, JECFA, and Turkish Food Codex.

IMPORTANT DECLARATION: This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is responsible for determining the product's suitability for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, use, transport, waste, and regulatory compliance information, refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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