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Ammonium Hydroxide, Peramine, Ammonia, Ammoniac, Ammonia Water, AZAN, 1336-21-6

Ammonium Hydroxide, Peramine, Ammonia, Ammoniac, Ammonia Water, AZAN, 1336-21-6

Here’s a clear, English summary of the information you provided about Ammonium Hydroxide (CAS 1336-21-6):

🔹 General Information

  • Name: Ammonium Hydroxide

  • Synonyms: Ammonia water, Ammonia solution, Ammoniak, Ammoniac, Ammoniaca, Ammonia concentrate

  • Formula: H₅NO

  • Molar Mass: 35.05 g/mol

  • Identifiers: CAS 1336-21-6, EINECS 215-647-6, InChIKey VHUUQVKOLVNVRT-UHFFFAOYSA-N

🔹 Physical & Chemical Properties

  • Appearance: Colorless liquid, pungent ammonia odor

  • Density: ~0.91 g/mL at 20 °C

  • Melting Point: −77 °C

  • Boiling Point: ~36 °C (solution dependent)

  • Solubility: Miscible with water, alcohol, ether

  • pKa: 9.3 (25 °C)

  • pH: 10.1–11.1 depending on concentration

  • Stability: Stable but incompatible with acids, copper, zinc, aluminium, mercury, alkali metals

  • Explosive Limit: 27% (ammonia-air mixture)

🔹 Safety & Toxicity

  • Hazard Class: 8 (Corrosive)

  • Packing Group: III

  • LD50 (oral, rat): 350 mg/kg

  • OSHA PEL: 35 ppm

  • ACGIH TLV-TWA: 25 ppm

  • Risks: Causes burns (R34), harmful if swallowed (R22), very toxic to aquatic organisms (R50)

  • Precautions: Wear protective clothing, gloves, goggles; avoid release to environment; seek medical help if exposed

🔹 Industrial Uses

  • Electronics: Cleaning and etching silicon wafers (often with H₂O₂ and HF)

  • Chemicals: Production of nitric acid, fertilizers, dyes, plastics, refrigerants

  • Laboratory: Analytical reagent, neutralizer, alkaloid extraction, precipitation of metal hydroxides

  • Other: Used in medicine, detergents, and preparation of ammonium compounds

🔹 Preparation

  • Produced by absorbing ammonia gas into purified water in a gas absorption tower, followed by membrane treatment.

🔹 Storage & Handling

  • Store at 2–8 °C, in a ventilated, dry warehouse, away from acids and incompatible metals.

  • Fire hazard: releases toxic ammonia and nitrogen oxides when heated; extinguish with water.

  • Spontaneous ignition temperature of ammonia: 690 °C.

English synonyms and alternative names for Ammonium Hydroxide (CAS 1336-21-6):

🔹 Synonyms / Other Names 

  • Ammonium hydroxide

  • Ammonia

  • Ammonia water

  • Ammonia concentrate

  • Ammonia solution (JP15)

  • Ammonium hydroxide solution, 1 M in water

  • Ammonium hydroxide solution, volumetric, 5.0N in water

  • Ammonia water (analytical grade)

  • Ammonium hydroxide solution (various concentrations)

🔹 International Variants (translated into English)

  • Amoniak (Polish → Ammonia)

  • Ammoniac (French → Ammonia)

  • Ammoniaca (Italian → Ammonia)

🔹 Less Common / Trade Synonyms

  • AZAN

  • Peramine

  • Nitro-sil

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