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Dimeric acid, Dimer Acid, Dimerized Fatty Acid, Dimeric Carboxylic Acid, Dimeric Fatty Acid, 61788-89-4

Dimeric acid, Dimer Acid, Dimerized Fatty Acid, Dimeric Carboxylic Acid, Dimeric Fatty Acid, 61788-89-4

Dimer Acid 

1. Product Identity

Property Details
Product Name Dimer Acid
CAS Number 61788-89-4
EINECS Number 500-148-0
Molecular Formula C₃₆H₆₄O₄
Molecular Weight 560.91 g/mol
Chemical Name Dimerized fatty acids

2. Synonyms and Other Names

Name Description
Dimerized fatty acids Common chemical description
Dimeric acid Short technical name
Dimeric fatty acids Plural form
Dimeric carboxylic acids Functional group description
Dimeric fatty acid Singular form
Dimer acid Most common trade name

3. Physical and Chemical Properties

Property Value
Appearance Light yellow, transparent, viscous liquid
Density 0.931 g/cm³
Boiling Point 667.7°C at 760 mmHg
Flash Point 371.6°C
Vapor Pressure 0-0.029 Pa at 25°C
Solubility Insoluble in water; soluble in ether, ethanol, acetone, chloroform, benzene, and petroleum-based solvents
Low Temperature Behavior Does not crystallize at -20°C
High Temperature Behavior Does not evaporate or gel at 250°C
Heat Stability Color may darken when heated
Metal Sensitivity Color degradation accelerates when exposed to copper and iron ions

4. Product Description

Dimer acids are dicarboxylic acids obtained from the dimerization of unsaturated fatty acids (typically oleic acid or linoleic acid). They are formed by the chemical combination of two fatty acid molecules. Due to their unique structure, they are high molecular weight, thermally stable, viscous liquids soluble in various solvents.

Key Characteristics:

  • High molecular weight dicarboxylic acid

  • Viscous liquid form

  • Wide solvent compatibility

  • Thermal stability

  • Remains liquid at low temperatures

5. Production Process

Dimer acids are produced by thermal or catalytic dimerization of unsaturated fatty acids (typically derived from tall oil, soybean oil, or sunflower oil). During this process, two fatty acid molecules chemically combine to form larger molecular structures. The reaction yields a mixture of monomer, dimer, and trimer acids, with the dimer fraction being purified and separated.

6. Applications and Uses

6.1. Polyamide Resins

Application Function
Coatings Binder in high-performance coatings
Adhesives Main component in polyamide-based adhesives
Engineering Plastics Monomer in polyamide resin production

6.2. Hot Melt Adhesives

Application Function
Packaging Industry Carton and package bonding
Book Binding Book spine adhesion
Furniture Assembly Wood joining applications
Shoe Industry Sole and upper bonding

6.3. Alkyd Resins

Application Function
Paint Industry In alkyd resin-based paints
Coating Industry In industrial coatings
Surface Coatings In protective and decorative coatings

6.4. Surfactants

Application Function
Detergents Surface-active component in cleaning products
Cosmetics Emulsifier and surfactant
Personal Care Products In shampoos, soaps, and lotions

6.5. Fuel Additives

Application Function
Engine Performance Improves fuel efficiency
Emission Reduction Reduces exhaust emissions
Injection Systems Injector cleaning and protection

6.6. Lubricants

Application Function
Industrial Lubricants Friction reduction in machinery and equipment
Automotive Lubricants In engine oils and transmission fluids
Metalworking Fluids In cutting and forming operations

6.7. Other Applications

Application Function
Epoxy Resins Modifying additive
Polyester Resins Flexibility and impact resistance enhancer
Corrosion Inhibitors In metal protection applications
Inks Resin component in printing inks

7. Industrial Importance

Dimer acids are highly valued in industry for the following properties:

Property Industrial Advantage
High Molecular Weight Good mechanical properties in polymers
Dual Functional Group Chain extension and cross-linking capability
Hydrophobic Structure In applications requiring water resistance
Flexibility Imparts flexibility to polymers
Thermal Stability In high-temperature applications
Solvent Compatibility Ease of use in various formulations

8. Safety and Storage

Parameter Details
Storage Conditions Store in cool, dry, well-ventilated area
Temperature Store at room temperature, avoid excessive heat
Metal Contact Avoid contact with metals such as copper and iron (risk of color degradation)
Shelf Life 2-3 years under proper conditions
Handling Follow standard chemical handling procedures
Eye Contact In case of contact, rinse thoroughly with water
Skin Contact Avoid prolonged contact

9. Quality Parameters

Parameter Typical Value
Acid Value 190-200 mg KOH/g
Saponification Value 195-205 mg KOH/g
Iodine Value Low (saturated structure)
Color (Gardner) Maximum 8-10
Monomer Content <1%
Dimer Content >75-95% (depending on purity)
Trimer Content <5-20% (depending on purity)
Viscosity (25°C) 5000-10000 cP

10. Summary

Dimer Acid (CAS: 61788-89-4, EINECS: 500-148-0) is a high molecular weight dicarboxylic acid obtained from the dimerization of unsaturated fatty acids. It is a light yellow, transparent, viscous liquid with molecular formula C₃₆H₆₄O₄ and molecular weight 560.91 g/mol.

Key Physical Properties:

  • Density: 0.931 g/cm³

  • Boiling point: 667.7°C

  • Flash point: 371.6°C

  • Does not crystallize at low temperatures (-20°C)

  • Does not evaporate or gel at high temperatures (250°C)

Solubility: Insoluble in water; soluble in ether, ethanol, acetone, chloroform, benzene, and petroleum-based solvents.

Main Application Areas:

  • Polyamide Resins: Coatings, adhesives, and engineering plastics

  • Hot Melt Adhesives: Packaging, book binding, furniture assembly

  • Alkyd Resins: Paint and coating industry

  • Surfactants: Detergents, cosmetics, and personal care products

  • Fuel Additives: Engine performance enhancement, emission reduction

  • Lubricants: Industrial and automotive lubricants

Important Note: Color degradation accelerates when exposed to copper and iron ions. Therefore, contact with these metals should be avoided during storage and use.

Dimer acids are critical components in many industrial applications due to their versatile chemical structure and superior physical properties. They are used across a wide spectrum, from polymers to adhesives, coatings to lubricants.

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