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Sorbitan Tristearate, Sorbitan Trioctadecanoate, Anhydrosorbitan Tristearate, STS, Span 65, E492, 26658-19-5

Sorbitan Tristearate, Sorbitan Trioctadecanoate, Anhydrosorbitan Tristearate, STS, Span 65, E492, 26658-19-5

SORBITAN TRISTEARATE (SORBITAN TRISTEARATE / SPAN 65 / E492)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Sorbitan Tristearate / Sorbitan Tristearate
Other Technical Names Sorbitan Trioctadecanoate, Anhydrosorbitan Tristearate, STS, Span 65
CAS Number 26658-19-5
EC Number 247-891-4
Chemical Formula C₆₀H₁₁₄O₈
Molecular Weight 963.55 g/mol
E Code E492
Product Family Sorbitan Ester (Span Series)
Appearance Light cream to tan, waxy solid

CHEMICAL STRUCTURE

    Sorbitan Tristearate (Span 65)
    
    Anhydrosorbitol Core
    Esterified with Three Stearic Acid (C₁₇H₃₅COOH) Molecules
    
                  C₁₇H₃₅COO
                       |
         CH₂-OOC-C₁₇H₃₅
         |              |
         O              CH-OOC-C₁₇H₃₅
         |              |
    CH₂-O-C-CH₂         CH
         |              |
        CHOH            CH₂OH
         |
        CH₂OH
    
    Sorbitol Derivative
    Esterified with Three Stearic Acid Molecules
    Non-Ionic Surfactant
    Waxy Solid Form
    Food and Cosmetic Emulsifier

Molecular Formula: C₆₀H₁₁₄O₈
Chemical Class: Sorbitan Ester (Non-Ionic Surfactant)
HLB Value: ~2.1 (Low HLB → W/O emulsions)
Physical Form: Waxy solid
Color: Light cream to tan

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Sorbitan Tristearate / Sorbitan Tristearate
Other Technical Names (English) Sorbitan Tristearate, Sorbitan Trioctadecanoate, Anhydrosorbitan Tristearate, STS, Span 65
Other Technical Names (Turkish) Sorbitan Tristearat, Sorbitan Trioktadekanoat, STS, Span 65
Other Technical Names (German) Sorbitantristearat, Span 65
Other Technical Names (French) Tristéarate de Sorbitan, Span 65
Other Technical Names (Spanish) Triestearato de Sorbitán, Span 65
CAS Number 26658-19-5
EC Number 247-891-4
E Code E492
Chemical Formula C₆₀H₁₁₄O₈
Molecular Weight 963.55 g/mol
Chemical Class Sorbitan Ester (Non-Ionic Surfactant)
HLB Value ~2.1 (Low HLB)
Appearance Light cream to tan, waxy solid
Odor Characteristic, slight fatty
Color Light cream - tan
Physical State Waxy solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Light cream to tan, waxy solid Visual
Chemical Formula C₆₀H₁₁₄O₈ -
Molecular Weight 963.55 g/mol Calculated
HLB Value ~2.1 Low HLB → W/O emulsions
Melting Point ~55-57°C -
Density ~0.98-1.0 g/cm³ -
Solubility Soluble in oils; Dispersible in water (insoluble) -
Acid Value ≤ 15 -
Saponification Value 145-165 -
Hydroxyl Value 175-205 -
Ash Content ≤ 0.5% -
Water Content ≤ 2.0% -
Iodine Value ≤ 2 -

SECTION 3: FUNCTIONAL PROPERTIES

Property Explanation
Non-Ionic Surfactant Reduces surface tension, providing stability in oil-water systems.
Emulsifier Ensures homogeneous mixing of oil and water phases. Ideal for W/O (water-in-oil) emulsions.
Stabilizer Prevents emulsion breakdown. Extends product shelf life.
Dispersing Agent Helps uniform distribution of particles in aerosol sprays and food systems.
Anti-Bloom Agent Prevents fat crystallization (bloom) on chocolate surfaces.
Viscosity Regulator Controls product consistency and texture.

SECTION 4: APPLICATION AREAS

4.1 Food Industry

Application Area Function Explanation
Chocolate Anti-bloom agent, emulsifier Prevents fat crystallization, provides glossy appearance
Margarine Emulsifier, stabilizer Keeps water and oil phases stable
Confectionery Dispersing agent Ensures homogeneous distribution of sugar and fat
Bakery Products Emulsifier Improves dough structure, extends shelf life
Ice Cream Stabilizer Prevents ice crystallization, provides creamy texture
Creams and Fillings Emulsifier, stabilizer Provides homogeneous structure, prevents separation

4.2 Cosmetics and Personal Care

Application Area Function Explanation
Creams and Lotions Emulsifier Forms W/O emulsions, thickening agent
Sunscreens Dispersing agent Ensures homogeneous distribution of UV filters
Makeup Products Emulsifier, stabilizer Improves pigment distribution
Body Lotions Emollient Provides skin smoothness

4.3 Industrial Applications

Application Area Function Explanation
Aerosol Sprays Dispersing agent Ensures uniform distribution of particles
Plastics and Coatings Additive Improves surface properties
Pharmaceutical Emulsifier Used in ointments and suspensions

SECTION 5: SPAN SERIES COMPARISON TABLE

Product (Span) Chemical Name HLB Value Physical Form Function E Code (EU) Industry Suitability
Span 20 Sorbitan Monolaurate ~8.6 Amber liquid O/W emulsifier, dispersant E493 Food (confectionery, bakery), cosmetics (lotions, creams), pharmaceutical suspensions
Span 40 Sorbitan Monopalmitate ~6.7 Waxy solid W/O emulsifier, stabilizer E494 Food (margarine, fatty products), cosmetics
Span 60 Sorbitan Monostearate ~4.7 Waxy solid Strong W/O emulsifier, stabilizer E491 Food (chocolate, margarine), pharmaceutical ointments, cosmetics
Span 65 Sorbitan Tristearate ~2.1 Waxy solid W/O emulsifier, anti-bloom agent E492 Food (chocolate, margarine), cosmetics
Span 80 Sorbitan Monooleate ~4.3 Viscous liquid W/O emulsifier, dispersant E495 Food, pharmaceutical capsules, cosmetics (sunscreen, lotions)
Span 85 Sorbitan Trioleate ~1.8 Viscous liquid W/O emulsifier, dispersant (No E code) Industrial (lubricants, coatings), limited cosmetics

SECTION 6: TECHNICAL SPECIFICATIONS

Parameter Specification Test Method
Appearance Light cream to tan waxy solid Visual
Acid Value ≤ 15 -
Saponification Value 145-165 -
Hydroxyl Value 175-205 -
Iodine Value ≤ 2 -
Ash Content ≤ 0.5% -
Water Content ≤ 2.0% -
Heavy Metals ≤ 10 ppm AAS / ICP
Arsenic ≤ 2 ppm AAS / ICP
Lead ≤ 2 ppm AAS / ICP
Mercury ≤ 1 ppm AAS / ICP

SECTION 7: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Skin Irritation Low irritant
Eye Irritation May be slightly irritating
Chronic Toxicity High doses may cause mild effects on digestive system
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Digestive system (at high doses)
Special Toxicity Note Considered safe as food additive by EFSA and FDA (within established limits)

SECTION 8: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Generally not classified as hazardous - -

Note: Considered safe as food additive. No health risks under normal use conditions.

Signal Word: Signal word not required

Hazard Pictograms: May not be required

SECTION 9: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Protect from direct sunlight
Container Requirements Keep in original packaging, tightly closed
Materials to Protect From Light, moisture, strong oxidizing agents
Shelf Life 2-3 years (under proper storage conditions)
Stability Note Stable under normal conditions; May decompose at high temperatures

SECTION 10: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE
Plastic Bucket 5-25 kg HDPE
Multi-layer Bag 25 kg PE lined kraft
Carton Box 25 kg Cardboard

SECTION 11: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature

SECTION 12: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Sorbitan Tristearat, Sorbitan Trioktadekanoat, STS, Span 65
English Names Sorbitan Tristearate, Sorbitan Trioctadecanoate, Anhydrosorbitan Tristearate, STS, Span 65
Trade Names Span 65, Alkest, Canarcel
E Code E492
Chemical Names Sorbitan trioctadecanoate; Sorbitan tristearate
CAS Number 26658-19-5
EC Number 247-891-4

SECTION 13: SUMMARY TABLE

Parameter Value
Product Sorbitan Tristearate / Span 65
CAS Number 26658-19-5
EC Number 247-891-4
E Code E492
Chemical Formula C₆₀H₁₁₄O₈
Molecular Weight 963.55 g/mol
Appearance Light cream to tan waxy solid
HLB Value ~2.1
Melting Point ~55-57°C
Primary Function Non-ionic surfactant; Emulsifier; Stabilizer
Main Applications Food (chocolate, margarine), cosmetics, industrial
Shelf Life 2-3 years
GHS Signal Word Signal word not required
UN Number Not regulated
Special Features Approved as food additive (E492); W/O emulsifier; Anti-bloom agent

SECTION 14: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Considered safe as food additive by EFSA and FDA (within established limits).

  2. High doses may cause mild effects on the digestive system.

  3. Usage amount is limited according to product type and country regulations.

  4. Low HLB value (~2.1) makes it ideal for W/O emulsions.

  5. Anti-bloom agent prevents fat crystallization on chocolate surfaces.

  6. No health risks under normal use conditions.

BEST PRACTICE RECOMMENDATIONS:

7. Chocolate Production:
Use as anti-bloom agent and emulsifier. Prevents fat crystallization, provides glossy appearance.

8. Margarine Production:
Use as emulsifier and stabilizer. Keeps water and oil phases stable.

9. Cosmetic Formulations:
Use to form W/O emulsions. Use as thickening agent in creams and lotions.

10. Aerosol Sprays:
Use as dispersing agent. Ensures uniform distribution of particles.

11. Use:
Usage amount should be adjusted according to product type and country regulations.

12. Storage:
Store in cool, dry and well-ventilated areas. Protect from direct sunlight.

APPLICATION RECOMMENDATIONS AND LIMITATIONS:

Application Maximum Usage Level Explanation
Chocolate 0.1-0.3% As anti-bloom agent
Margarine 0.2-0.5% As emulsifier
Confectionery 0.5-1.0% As dispersing agent
Cosmetics 1.0-5.0% Depends on formulation
Bakery Products 0.2-0.5% Improves dough structure

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature 15-25°C
Humidity <60% relative humidity
Container Tightly closed
Location Cool, dry, well-ventilated area

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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