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Sunflower Oil, Sunflower Seed Oil, Gina Glyceride, Helianthus Annuus Oil, 8001-21-6

Sunflower Oil, Sunflower Seed Oil, Gina Glyceride, Helianthus Annuus Oil, 8001-21-6

SUNFLOWER OIL 

Ayçiçek Yağı / Sunflower Seed Oil

CAS Number: 8001-21-6

EC Number: 232-273-9

1. IDENTIFICATION

Property Information
Product Name Sunflower Oil (Refined)
Botanical Source Helianthus annuus (Sunflower plant seeds)
CAS Number 8001-21-6
EINECS Number 232-273-9
Molecular Formula Not applicable (triglyceride mixture)
Appearance Light yellow to pale amber clear liquid
Odor Almost odorless; very faint characteristic fatty/nutty aroma
Taste Mild, light taste

2. GRADES & TYPES OF SUNFLOWER OIL

Grade Description Key Characteristics Applications
Crude Sunflower Oil Unrefined oil from pressing/extraction Darker color, stronger odor, higher free fatty acids Further refining, industrial
Refined Sunflower Oil (Standard) Fully refined (degummed, neutralized, bleached, deodorized) Light yellow, neutral taste, versatile General cooking, frying, baking
High Oleic Sunflower Oil (HOSO) High oleic acid content (75-90%) Very high heat stability, longer fry life Deep frying, industrial frying, spray oils
Mid Oleic Sunflower Oil (NuSun) Mid oleic acid content (55-75%) Balanced profile, good stability Commercial frying, packaged foods
Linoleic Sunflower Oil (Standard) High linoleic acid content (50-70%) Standard profile, good for cold applications Salad dressings, margarine
Cold Pressed Sunflower Oil Mechanical pressing without heat Light yellow, retains natural flavor Premium food, cosmetics
Organic Sunflower Oil USDA/EU organic certified Non-GMO, no synthetic pesticides Health food, natural cosmetics
Winterized Sunflower Oil Cold-filtered Remains clear at refrigerator temperatures Salad dressings, clear products

3. PHYSICAL & CHEMICAL PROPERTIES

Property Standard Sunflower Oil High Oleic Sunflower Oil
Physical State (20°C) Liquid Liquid
Appearance Light yellow, clear Light yellow, clear
Density (20°C) 0.918 – 0.923 g/mL 0.914 – 0.920 g/mL
Refractive Index (20°C) 1.472 – 1.476 1.467 – 1.471
Melting Point -18°C to -16°C -15°C to -10°C
Smoke Point (Refined) 210-227°C (410-440°F) 230-240°C (446-464°F)
Flash Point >110°C (>230°F) >110°C (>230°F)
Fire Point >330°C (>626°F) >340°C (>644°F)
Iodine Value 118 – 141 78 – 90
Saponification Value 188 – 194 185 – 192
Acid Value (Refined) ≤ 0.2 mg KOH/g ≤ 0.2 mg KOH/g
Peroxide Value ≤ 10 mEq/kg ≤ 10 mEq/kg
Unsaponifiable Matter ≤ 1.5% ≤ 1.5%
Moisture & Volatiles ≤ 0.1% ≤ 0.1%

4. TYPICAL FATTY ACID COMPOSITION

Fatty Acid Common Name Standard Sunflower Oil (%) High Oleic Sunflower Oil (%) Mid Oleic (NuSun) (%)
C16:0 Palmitic acid 5.0 – 7.6 3.0 – 6.0 4.0 – 6.0
C18:0 Stearic acid 2.5 – 6.0 2.0 – 5.0 3.0 – 5.0
C18:1 Oleic acid (Omega-9) 14 – 40 75 – 90 55 – 75
C18:2 Linoleic acid (Omega-6) 48 – 74 2 – 17 15 – 35
C18:3 α-Linolenic acid (Omega-3) < 0.3 < 0.3 < 0.3
C20:0 Arachidic acid 0.2 – 0.5 0.2 – 0.5 0.2 – 0.5
C22:0 Behenic acid 0.5 – 1.0 0.5 – 1.0 0.5 – 1.0
C24:0 Lignoceric acid < 0.5 < 0.5 < 0.5

Key Features by Type:

Type Oleic Acid Linoleic Acid Heat Stability Best For
High Oleic 75-90% 2-17% Excellent Deep frying, high-heat cooking
Mid Oleic (NuSun) 55-75% 15-35% Good Commercial frying, packaged foods
Standard (Linoleic) 14-40% 48-74% Moderate Salad dressings, light sautéing

5. VITAMIN & NUTRITIONAL CONTENT

Nutrient Amount (per 100g) % Daily Value
Vitamin E (Tocopherols) 40 – 60 mg 270-400%
Vitamin K 5 – 10 µg 6-12%
Total Fat 100 g
– Saturated Fat 10-12 g
– Monounsaturated Fat 20-80 g (varies by type)
– Polyunsaturated Fat 10-70 g (varies by type)
– Trans Fat 0 g
Cholesterol 0 mg
Calories 884 kcal

Note: Sunflower oil is one of the richest natural sources of Vitamin E (tocopherols). The high vitamin E content acts as a natural antioxidant, improving storage stability.

6. PRODUCTION PROCESS

Stage Description
1. Seed Cleaning Sunflower seeds are cleaned to remove foreign matter (stones, dust, husks)
2. Dehulling Seeds are dehulled to remove the outer shell (optional, depending on oil content)
3. Conditioning Seeds are heated to 60-80°C to optimize oil extraction
4. Flaking Seeds are rolled into thin flakes to rupture oil cells
5. Cooking Flakes are cooked at 90-120°C
6. Pressing (Mechanical) Oil is expelled using a screw press (expeller) – yields ~70-75% of oil
7. Solvent Extraction Remaining oil is extracted from press cake using hexane – yields additional 10-15%
8. Crude Oil Crude sunflower oil is obtained
9. Refining (RBD Process) Degumming: Removal of phospholipids (gums) using water/acid; Neutralization: Removal of free fatty acids using caustic soda; Bleaching: Removal of pigments (chlorophyll, carotenoids) using bleaching earth; Deodorization: Steam distillation under vacuum (180-260°C) to remove odors and free fatty acids
10. Winterization (Optional) Oil is cooled to 4-10°C and filtered to remove high-melting waxes and triglycerides – ensures clarity at low temperatures
11. Finished Oil Refined, Bleached, Deodorized (RBD) Sunflower Oil is packaged

Yield: Approximately 350-450 grams of oil per 1 kg of sunflower seeds (depending on seed quality and extraction method).

Cold Pressed Production (Alternative):

  • Mechanical pressing at temperatures below 50°C

  • No solvents or chemical refining

  • Retains natural flavor, color, and nutrients

  • Lower yield, premium product

7. APPLICATIONS

7.1. Food Industry (Primary Use – >80%)

Application Function Preferred Type
Cooking Oil All-purpose cooking, sautéing Standard or High Oleic
Deep Frying High heat stability, long fry life High Oleic
Salad Dressings & Mayonnaise Neutral taste, good emulsion stability Standard (winterized)
Margarine & Shortening Base oil for spreads Hydrogenated or blended
Bakery Products Provides moisture and texture Standard
Snack Foods Spray oil for chips, crackers High Oleic
Sauces & Marinades Carrier oil for flavors Standard
Infused Oils Herb/garlic infused oils Standard

7.2. Industrial Applications

Application Function Oil Type
Biodiesel Production Feedstock for methyl esters Crude or waste oil
Paint & Coatings Drying oil component (semi-drying) Standard (high linoleic)
Soap Manufacturing Saponification Technical grade
Lubricants Bio-based lubricants High oleic
Printing Inks Ink vehicle Standard
Plasticizers Epoxidized sunflower oil High oleic
Cosmetics Carrier oil, emollient Refined or cold pressed

7.3. Pharmaceutical Industry

Application Function
Excipient Carrier oil for oil-soluble drugs
Vitamin Carrier For Vitamin E, D, A formulations
Topical Preparations Base for ointments and creams
Softgel Capsules Fill material for softgels

7.4. Cosmetics & Personal Care

Application Function
Skin Care Emollient, moisturizer, non-comedogenic
Hair Care Conditioning agent, shine enhancer
Lip Balms & Lipsticks Base oil, texture enhancer
Massage Oils Carrier oil
Soap Base For natural soaps

8. HIGH OLEIC SUNFLOWER OIL ADVANTAGES

Advantage Description
High Heat Stability Smoke point 230-240°C (446-464°F) – excellent for deep frying
Long Fry Life Resists polymerization and oxidation – longer oil change intervals
Low Linoleic Acid Low reactivity with oxygen – less rancidity
No Trans Fats Naturally trans fat-free (unless partially hydrogenated)
Neutral Flavor Does not transfer flavor to fried foods
Good Shelf Life 12-24 months with proper storage

9. NUTRITIONAL & HEALTH INFORMATION

Health Benefits

Benefit Mechanism
Heart Health High in unsaturated fats; may help lower LDL cholesterol
Vitamin E Rich Powerful antioxidant – protects cells from oxidative damage
Skin Health Emollient properties; vitamin E supports skin barrier
No Cholesterol Naturally cholesterol-free
Low Saturated Fat Only 10-12% saturated fat – lower than palm and coconut oil

Health Considerations

Consideration Information
Omega-6 Content Standard sunflower oil is high in Omega-6 (48-74%) – excessive intake may promote inflammation. High oleic variety has lower Omega-6.
Omega-3 Deficiency Very low in Omega-3 (α-linolenic acid) – should be balanced with Omega-3 sources (flax, fish oil).
Trans Fats Refined sunflower oil contains no trans fats. Partially hydrogenated versions may contain trans fats.
Calorie Density 884 kcal/100g – use in moderation for weight management.

10. STORAGE & HANDLING

Parameter Information
Storage Conditions Cool, dry, dark place; 10-25°C recommended
Protect From Light, heat, oxygen, moisture
Container Requirements Tightly closed, food-grade containers (stainless steel, HDPE, PET, glass, lined drums)
Shelf Life (RBD Oil) 12-24 months (with added antioxidants)
Shelf Life (High Oleic) 18-24 months (more stable)
Oxidation Prevention Store under nitrogen blanket; antioxidants (tocopherols, TBHQ, citric acid) added
Packaging Options 1 L – 5 L PET bottles (retail), 20 L jerry cans, 200 L drums, 1000 kg IBC, flexibag, bulk tanker

Storage Stability by Type:

Type Oxidative Stability (Rancimat @ 110°C)
High Oleic 20-25 hours
Mid Oleic (NuSun) 10-15 hours
Standard (Linoleic) 5-8 hours

11. SAFETY & REGULATORY INFORMATION

Parameter Information
FDA Status (US) GRAS (Generally Recognized as Safe) – 21 CFR 184.1472
EU Status Approved food ingredient
Turkey Status Compliant with Turkish Food Codex (TGK) Edible Oils Regulation
Allergen Status Not a major allergen; refined oil contains no detectable protein
GMO Status Non-GMO varieties available; conventional may be GMO (rare)
TSCA Listed
HS Code (Crude) 1512110000
HS Code (Refined) 1512199000
HS Code (High Oleic) 1512199010

12. COMPARISON WITH OTHER VEGETABLE OILS (per 100g)

Oil Type Saturated Fat Monounsaturated (Oleic) Polyunsaturated (Linoleic) Omega-3 (ALA) Smoke Point
Sunflower (Standard) 10-12% 14-40% 48-74% <0.3% 210-227°C
Sunflower (High Oleic) 9-11% 75-90% 2-17% <0.3% 230-240°C
Olive Oil 14-15% 71-80% 5-10% 0.8% 190-210°C
Canola Oil 7% 55-70% 15-30% 7-12% 200-230°C
Soybean Oil 15% 17-30% 48-58% 5-11% 230-238°C
Palm Oil 49% 37-40% 9-11% <0.3% 230-240°C
Coconut Oil 87% 6-8% 1-2% 0% 175-200°C

13. PRODUCTION STATISTICS

Parameter Data
Global Production (2023) ~20-22 million metric tons
Top Producers Ukraine, Russia, Argentina, Turkey, EU (Romania, Bulgaria, Hungary)
World Ranking 4th most produced vegetable oil (after palm, soybean, canola)
Turkey Production Major producer; Trakya, Marmara, Aegean, Central Anatolia regions
Yield per Hectare ~1.5 – 2.5 tons of seed (0.5-1.0 tons of oil)

14. BY-PRODUCTS & DERIVATIVES

By-Product Source Applications
Sunflower Meal Press cake after oil extraction Animal feed (high protein, 25-35%)
Sunflower Lecithin Degumming process Emulsifier in food, cosmetics
Sunflower Oil Fatty Acids Refining by-product Soap, detergents, surfactants
Distilled Fatty Acids Deodorizer distillate Industrial applications
Gums (Phospholipids) Degumming Lecithin production
Waxes Winterization process Cosmetics, coatings

15. OTHER NAMES & SYNONYMS

Name Description
Sunflower Oil Standard English name
Ayçiçek Yağı Turkish name
Sunflower Seed Oil Full name
Refined Sunflower Oil Process-based name
High Oleic Sunflower Oil (HOSO) High stability variety
Mid Oleic Sunflower Oil (NuSun) Mid stability variety
Helianthus annuus Seed Oil INCI name for cosmetics

Database Identifiers:

  • CAS: 8001-21-6

  • EC: 232-273-9

  • MDL: MFCD00132473

  • INCI: Helianthus Annuus (Sunflower) Seed Oil

16. SUMMARY

Sunflower Oil (CAS 8001-21-6) is a vegetable oil extracted from the seeds of the sunflower plant (Helianthus annuus). It is one of the four most produced vegetable oils globally and is valued for its light color, mild taste, and versatility.

Key Features by Type:

Type Key Feature Best For
Standard (Linoleic) High linoleic acid (48-74%), rich in Vitamin E General cooking, salad dressings
High Oleic (HOSO) High oleic acid (75-90%), excellent heat stability Deep frying, industrial frying
Mid Oleic (NuSun) Balanced profile (55-75% oleic) Commercial frying, packaged foods

Main Application Areas:

Sector Applications
Food Industry Cooking oil, frying oil, salad dressings, margarine, bakery
Industrial Biodiesel, paints, soaps, lubricants, printing inks
Pharmaceuticals Excipient, vitamin carrier, softgel fill
Cosmetics Emollient, carrier oil, skin/hair care

17. IMPORTANT NOTES

  1. High Oleic vs Standard: The fatty acid composition varies significantly between types. High oleic sunflower oil (75-90% oleic acid) has much higher heat stability and longer fry life than standard sunflower oil (14-40% oleic acid). Always specify the required type for your application.

  2. Vitamin E Source: Sunflower oil is one of the richest natural sources of Vitamin E (tocopherols) – 40-60 mg per 100g. This natural antioxidant improves oxidative stability.

  3. Cold Pressed vs Refined: Cold pressed sunflower oil retains more natural flavor, color, and nutrients but has a shorter shelf life and lower smoke point. Refined oil is more stable and suitable for high-heat cooking.

  4. Winterization: For applications requiring clarity at refrigerator temperatures (e.g., salad dressings), use winterized sunflower oil. Non-winterized oil may become cloudy at low temperatures due to wax crystallization.

  5. Omega-6 Content: Standard sunflower oil is very high in Omega-6 linoleic acid (48-74%) and very low in Omega-3. For health-conscious applications, consider high oleic varieties which have lower Omega-6.

  6. GMO Status: Sunflower oil is generally non-GMO, as no genetically modified sunflower varieties are commercially grown. However, verify with supplier for non-GMO certification if required.

  7. Allergen Information: Refined sunflower oil is highly refined and contains no detectable protein. It is generally considered safe for individuals with seed allergies, but caution is advised for cold pressed oils.

  8. **Storage: Due to high polyunsaturated fat content (especially standard variety), protect from light, heat, and oxygen. High oleic variety has significantly better oxidative stability.

  9. **Biodiesel Use: In 2007, approximately 10% of EU sunflower oil production was used as ecological fuel (biodiesel). This application continues to grow.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS) provided by the manufacturer/supplier.

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