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Rapeseed Oil, Canola Oil, 8002-13-9

Rapeseed Oil, Canola Oil, 8002-13-9

RAPESEED OIL / CANOLA OIL

Kolza Yağı / Kanola Yağı

CAS Number: 8002-13-9

EC Number: 232-299-0

1. IDENTIFICATION

Property Information
Product Name Rapeseed Oil / Canola Oil
Botanical Sources Brassica napusBrassica rapaBrassica campestris
CAS Number 8002-13-9
EINECS Number 232-299-0
Molecular Formula Not applicable (triglyceride mixture)
Appearance Very light yellow to pale amber clear liquid
Odor Odorless or nearly odorless (refined)
Taste Neutral, bland taste (refined)

Other Names / Synonyms:

  • AKOREX L

  • LIPEX CANOLA-U

  • BRASSICA NAPUS OIL

  • Cold Pressed Canola Oil

  • HIGH ERUCIC ACID RAPESEED OIL (HEAR)

  • BRASSICA CAMPESTRIS (RAPESEED) SEED OIL

  • BRASSICA RAPA OIL

  • Rapiska / Rapitsa (Turkish common names)

2. RAPESEED OIL vs CANOLA OIL: KEY DIFFERENCES

Parameter Traditional Rapeseed Oil Canola Oil (Low Erucic Acid)
Erucic Acid (C22:1) Content 30-60% < 2% (typically < 0.5-1%)
Glucosinolate Content High (60-100 μmol/g) Low (< 30 μmol/g)
Toxicity Concerns Potential health risks Generally recognized as safe
Food Grade Not suitable for human consumption Yes, widely used
Primary Use Industrial (lubricants, biodiesel) Food, cooking oil
Genetic Modification Conventional (wild type) Conventional breeding / Non-GMO varieties available

Key Historical Note: In 1979, traditional rapeseed cultivation was banned in many countries due to erucic acid and glucosinolate toxicity concerns. Canadian plant breeders developed "Canola" (Canadian Oil, Low Acid) – a low-erucic acid, low-glucosinolate variety that is safe for human consumption.

3. PHYSICAL & CHEMICAL PROPERTIES

Property Rapeseed Oil (Traditional) Canola Oil (Low Erucic)
Physical State (20°C) Liquid Liquid
Appearance Pale yellow to amber Very light yellow, clear
Density (20°C) 0.910 – 0.925 g/mL 0.914 – 0.920 g/mL
Refractive Index (20°C) 1.470 – 1.476 1.472 – 1.476
Melting Point -10°C to -5°C -10°C to -5°C
Smoke Point (Refined) 190-210°C (374-410°F) 200-230°C (392-446°F)
Flash Point >110°C (>230°F) >110°C (>230°F)
Iodine Value 94 – 120 110 – 126
Saponification Value 170 – 190 182 – 193
Acid Value (Refined) ≤ 0.2 mg KOH/g ≤ 0.2 mg KOH/g

4. TYPICAL FATTY ACID COMPOSITION

Fatty Acid Common Name Traditional Rapeseed Oil (%) Canola Oil (%)
C16:0 Palmitic acid 2.5 – 7.0 3.0 – 6.0
C18:0 Stearic acid 0.5 – 3.0 1.0 – 3.0
C18:1 Oleic acid (Omega-9) 14 – 35 55 – 70
C18:2 Linoleic acid (Omega-6) 15 – 35 15 – 30
C18:3 α-Linolenic acid (Omega-3) 5 – 12 7 – 12
C20:1 Gadoleic acid 1 – 15 < 2
C22:1 Erucic acid 30 – 60 < 2 (typically < 0.5-1)
C20:0 Arachidic acid < 1 < 1

Key Feature: Canola oil is characterized by:

  • Low saturated fat (~7%) – lower than olive oil (15%) and sunflower oil (12%)

  • High monounsaturated fat (oleic acid – 55-70%)

  • Excellent source of Omega-3 (α-linolenic acid)

  • No trans fats (unless partially hydrogenated)

5. PRODUCTION PROCESS

Stage Description
1. Seed Cleaning Rapeseed/Canola seeds are cleaned to remove foreign matter
2. Seed Conditioning Seeds are heated to optimize oil extraction
3. Flaking Seeds are rolled into thin flakes
4. Cooking Flakes are cooked to break oil cells
5. Pressing (Mechanical) Oil is expelled using screw press (expeller)
6. Solvent Extraction Remaining oil is extracted using hexane (higher yield)
7. Crude Oil Crude rapeseed/canola oil is obtained
8. Refining (RBD Process) Degumming: Removal of phospholipids; Neutralization: Removal of free fatty acids; Bleaching: Removal of pigments using bleaching earth; Deodorization: Steam distillation under vacuum to remove odors
9. Finished Oil Refined, Bleached, Deodorized (RBD) Canola Oil

Yield: Approximately 450 grams of oil per 1 kg of rapeseed seeds.

6. GRADES & TYPES

Grade Description Applications
Crude Rapeseed Oil Unrefined, high erucic acid Industrial (biodiesel, lubricants)
Refined Rapeseed Oil (HEAR) High erucic acid – refined Industrial lubricants, plasticizers
Crude Canola Oil Unrefined, low erucic acid Further refining
Refined Canola Oil (RBD) Fully refined – neutral taste Cooking oil, food industry
Winterized Canola Oil Cold-filtered Salad dressings (remains clear at low temperatures)
Expeller-Pressed Canola Oil Mechanically pressed, no solvents Premium food grade
Cold-Pressed Canola Oil Low-temperature extraction Specialty food, cosmetics
Organic Canola Oil USDA/EU organic certified Health food, natural cosmetics
Non-GMO Canola Oil From non-genetically modified seeds Specialized food applications

7. APPLICATIONS

7.1. Food Industry (Primary for Canola)

Application Function
Cooking Oil High smoke point, neutral taste – frying, sautéing, baking
Salad Dressings & Mayonnaise Base oil for emulsions
Margarine & Shortening Hydrogenated or interesterified canola oil
Bakery Products Moisture, texture, shelf-life extension
Processed Foods Ingredient in sauces, marinades, snacks
Bread & Baked Goods Used in commercial baking
Canned Foods Packing medium

7.2. Industrial Applications

Application Function Oil Type
Biodiesel Production Primary feedstock (rapeseed methyl ester) HEAR / Traditional
Bio-lubricants Biodegradable lubricants for machinery HEAR / Refined
Soap Manufacturing Saponification Technical grade
Paints & Varnishes Drying oil component High erucic
Printing Inks Ink vehicle (especially newspaper ink) Refined
Plasticizers Epoxidized rapeseed oil High erucic
Synthetic Rubber Processing aid Refined
Candles Natural wax component Hydrogenated

7.3. Cosmetics & Personal Care

Application Function
Skin Care Products Emollient, moisturizer in creams, lotions
Lipsticks & Lip Balms Base oil, texture enhancer
Hair Care Products Conditioning agent, shine enhancer
Body Oils Carrier oil
Soap Base For specialty soaps

7.4. Animal Feed (Rapeseed Meal)

Application Function
Cattle Feed High-protein meal (35-40% protein)
Poultry Feed Protein supplement (limited due to glucosinolates – canola meal preferred)
Swine Feed Protein source
Aquaculture Feed Fish feed component

Note: Traditional rapeseed meal has high glucosinolate content and is less suitable for monogastric animals. Canola meal is preferred for animal nutrition.

8. NUTRITIONAL INFORMATION (per 1 tbsp / 14 g Canola Oil)

Nutrient Amount
Calories 120 kcal
Total Fat 14 g
– Saturated Fat 1 g (7%)
– Monounsaturated Fat 8 g (57%)
– Polyunsaturated Fat 4 g (29%)
– Trans Fat 0 g
Vitamin E 2.4 mg (16% DV)
Vitamin K 10 µg (12% DV)

9. HEALTH BENEFITS (Canola Oil)

Benefit Mechanism
Heart Health Low saturated fat (7%) – helps reduce LDL cholesterol when substituted for saturated fats
Omega-3 Rich Good source of α-linolenic acid (ALA) – supports brain and nerve function
Vitamin E Antioxidant – protects cells from oxidative damage
High Smoke Point Suitable for high-heat cooking (200-230°C) – less degradation
Vitamin K Supports bone health and blood clotting
Neutral Taste Does not overpower other food flavors

10. HEALTH RISKS & CONCERNS

Risk Associated Oil Explanation
Erucic Acid Toxicity Traditional Rapeseed Oil High erucic acid (30-60%) – linked to heart damage, kidney/adrenal issues in animal studies
Glucosinolates Traditional Rapeseed Oil Anti-nutritional compounds – may cause goiter, liver damage
Trans Fats Partially Hydrogenated Canola Oil Hydrogenation creates trans fats – associated with heart disease
Omega-6/Omega-3 Ratio Canola Oil (acceptable ratio) Ratio ~2:1 – considered balanced
GMO Concerns Conventional Canola (80-90% GMO) Most canola grown in North America is genetically modified. Non-GMO varieties available.

Key Warnings:

  • Traditional rapeseed oil (high erucic acid) is NOT suitable for human consumption

  • Canola oil is safe for human consumption (GRAS approved)

  • Overconsumption of any oil may contribute to weight gain and cardiovascular issues

11. CULTIVATION & PRODUCTION COUNTRIES

Region Countries Production Focus
Europe Germany, France, Poland, UK, Turkey (Trakya, Marmara, Mediterranean) Food grade, biodiesel
North America Canada (largest producer), USA Canola oil (low erucic)
Asia China, India, Pakistan Traditional rapeseed, canola

Turkey Cultivation Regions:

  • Trakya Region (first introduced)

  • South Marmara

  • Southeastern Anatolia

  • Mediterranean / Çukurova

  • Aegean

  • Central Anatolia

  • Black Sea

12. RAPESEED MEAL (By-Product)

Parameter Traditional Rapeseed Meal Canola Meal
Protein Content 30-35% 35-40%
Glucosinolate Content High (60-100 μmol/g) Low (< 30 μmol/g)
Animal Feed Suitability Limited (ruminants only) Excellent (all livestock)
Primary Use Cattle feed, fertilizer Poultry, swine, cattle, aquaculture feed

13. STORAGE & HANDLING

Parameter Information
Storage Conditions Cool, dry, dark place; 2-8°C recommended
Protect From Light, heat, oxygen, moisture
Container Requirements Tightly closed, food-grade containers (stainless steel, HDPE, glass)
Shelf Life (RBD Canola) 12-24 months (with antioxidants)
Oxidation Prevention Store under nitrogen; add antioxidants (tocopherols, TBHQ, citric acid)
Packaging Options 20 L jerry cans, 200 L drums, 1000 kg IBC, flexibag, bulk tanker

14. SAFETY & REGULATORY INFORMATION

Parameter Canola Oil (Low Erucic) Traditional Rapeseed Oil
FDA Status (US) GRAS (21 CFR 184.1555) Not GRAS for food
EU Status Approved food ingredient Restricted (erucic acid limits)
Turkey Status Approved (TGK compliant) Not for human consumption
Maximum Erucic Acid (Food) < 2% (EU: < 0.5-1% for infant formula)
TSCA Listed Listed
HS Code (Crude) 1514110000 1514110000
HS Code (Refined) 1514199000 1514199000

15. OTHER NAMES & SYNONYMS

Name Description
Rapeseed Oil Traditional name (high erucic)
Canola Oil Low erucic, low glucosinolate variety
Kolza Yağı Turkish name
Kanola Yağı Turkish name for canola
Rapiska / Rapitsa Turkish common names
Akorex L Trade name
Lipex Canola-U Trade name
HEAR Oil High Erucic Acid Rapeseed Oil
LEAR Oil Low Erucic Acid Rapeseed Oil (Canola)
Brassica Oil Botanical name

Database Identifiers:

  • CAS: 8002-13-9

  • EC: 232-299-0

  • MDL: MFCD00132441

16. SUMMARY

Rapeseed Oil / Canola Oil (CAS 8002-13-9) is a vegetable oil derived from Brassica species seeds. Traditional rapeseed oil contains high levels of erucic acid (30-60%) and glucosinolates, making it unsuitable for human consumption. Canola oil (Canadian Oil, Low Acid) is a specially bred variety with <2% erucic acid and low glucosinolates, safe for human consumption.

Key Differences:

Feature Traditional Rapeseed Oil Canola Oil
Erucic Acid 30-60% < 2%
Glucosinolates High Low
Food Safety Not for human consumption Safe (GRAS)
Primary Use Industrial (biodiesel, lubricants) Food (cooking oil)

Canola Oil Key Features:

Feature Description
Low Saturated Fat Only 7% – lower than olive oil (15%)
High Monounsaturated Fat 55-70% oleic acid
Omega-3 Source Rich in α-linolenic acid (7-12%)
High Smoke Point 200-230°C (392-446°F)
Neutral Taste Does not affect food flavor

Main Application Areas:

Sector Applications
Food Industry Cooking oil, salad dressings, margarine, baking
Industrial Biodiesel, lubricants, soaps, inks, plastics
Cosmetics Emollient, skin/hair care, lipsticks
Animal Feed High-protein meal (canola meal)

17. IMPORTANT NOTES

  1. Traditional vs. Canola: Traditional rapeseed oil (high erucic acid) is NOT safe for human consumption. Only low erucic acid varieties (Canola) should be used for food.

  2. Erucic Acid Limits: EU regulations limit erucic acid in edible oils to <2% (and <0.5-1% for infant formula). Canola oil meets these standards.

  3. 1979 Ban: In 1979, traditional rapeseed cultivation was banned in many countries due to toxicity concerns (erucic acid and glucosinolates). Modern canola varieties were developed through conventional breeding.

  4. GMO Status: Approximately 80-90% of canola grown in North America is genetically modified (herbicide-resistant). Non-GMO and organic canola oil is available from specialty suppliers.

  5. High Smoke Point: Refined canola oil has a smoke point of 200-230°C (392-446°F), making it suitable for frying and high-heat cooking.

  6. Cold Stability: Non-winterized canola oil may become cloudy at refrigerator temperatures. Use winterized grade for salad dressings and cold applications.

  7. Omega-3/Omega-6 Balance: Canola oil has an Omega-6:Omega-3 ratio of approximately 2:1, which is considered healthy and balanced.

  8. Sustainable Source: Rapeseed/canola is a sustainable oil crop with high yield per hectare and lower water requirements compared to many other oilseeds.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS) provided by the manufacturer/supplier. The health claims described are based on research but may vary by jurisdiction. Traditional rapeseed oil (high erucic acid) should not be used for human consumption.

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