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Sodium Formaldehyde Sulfoxylate, Sodium Hydroxymethanesulfinate, Acidic Reductant, Rongalit C, Decolite, Bruggolite E01, Bruggolite L40, SFS, 149-44-0, 6035-47-8

Sodium Formaldehyde Sulfoxylate, Sodium Hydroxymethanesulfinate, Acidic Reductant, Rongalit C, Decolite, Bruggolite E01, Bruggolite L40, SFS, 149-44-0, 6035-47-8

SODIUM FORMALDEHYDE SULFOXYLATE (RONGALIT C / BRUGGOLITE E01)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Sodium Formaldehyde Sulfoxylate
Chemical Name Sodium Hydroxymethanesulfinate
Synonyms (Turkish) Asidik Redüktan, Decolite, Bruggolit E01, Rongalite C, Sodyum Formaldehit Sülfoksilat, Sodyum Hidroksimetansülfinat
Synonyms (English) Sodium Formaldehyde Sulfoxylate, Rongalit C, Bruggolite E01, Decolite, Sodium Hydroxymethanesulfinate, SFS
CAS Number 149-44-0 / 6035-47-8
Molecular Formula NaHSO₂·CH₂O·2H₂O (Dihydrate); Anhydrous: NaHSO₂·CH₂O
Molecular Weight 154.10 g/mol (Dihydrate)
Appearance Hard, white solid (powder, granules, or liquid solution)
Odor Heavy, pungent odor

CHEMICAL STRUCTURE

Sodium Formaldehyde Sulfoxylate Structure:

        O
        ||
    H—C—SO₂Na
        |
        H

Structure Description:

  • Sodium salt of formaldehyde sulfoxylate.

  • Strong reducing agent.

  • White, crystalline solid.

  • Highly soluble in water.

  • Used as a reducing agent in textile, polymer, and chemical applications.

  • Available as powder, granules, or liquid solution.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Sodium Formaldehyde Sulfoxylate
Chemical Name Sodium Hydroxymethanesulfinate
Synonyms (Turkish) Asidik Redüktan, Decolite, Bruggolit E01, Rongalite C, Sodyum Formaldehit Sülfoksilat, Sodyum Hidroksimetansülfinat
Synonyms (English) Sodium Formaldehyde Sulfoxylate, Rongalit C, Bruggolite E01, Decolite, Sodium Hydroxymethanesulfinate, SFS
CAS Number 149-44-0 / 6035-47-8
Molecular Formula NaHSO₂·CH₂O·2H₂O (Dihydrate); Anhydrous: NaHSO₂·CH₂O
Molecular Weight 154.10 g/mol (Dihydrate)
Chemical Class Reducing agent; Sulfoxylate; Redox activator
Source Synthetic
Physical State (20°C) Solid (powder, granules)
Odor Heavy, pungent odor
Color White

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Hard, white solid (powder or granules) Visual
Odor Heavy, pungent odor Olfactometric
Molecular Weight 154.10 g/mol (Dihydrate) Calculated
Melting Point 63 – 64°C (some forms up to 120°C) DSC
Solubility in Water (20°C) ~50 g/L (soluble) General Method
pH (1% Solution) 9.5 – 10.5 (alkaline) pH Meter
Flash Point > 100°C
Stability Stable; Incompatible with strong oxidizing agents
Thermal Decomposition Products Sulfur oxides, sodium oxides (toxic fumes)
Reducing Properties Strong reducing agent
Assay (Active Matter) 98 – 100% (Powder); ~40% (Liquid) Titrimetric
Loss on Drying ≤ 0.5% Gravimetric
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP

SECTION 3: PRODUCT VARIANTS COMPARISON

Parameter Bruggolite E01 Bruggolite L40 Rongalit C
Form Powder / Granule (dust-free, fast dissolving) Stabilized aqueous liquid solution Hard, white solid (lump or powder)
Chemical Structure Sodium Hydroxymethanesulfinate Sodium Hydroxymethanesulfinate (Aqueous Solution) Sodium Formaldehyde Sulfoxylate (NaHSO₂·CH₂O·2H₂O)
Active Matter ~98 – 100% ~40% (diluted) ~98 – 100%
Reactivity / pH High; Optimal in acidic, stable in alkaline High; Optimal in acidic High; Active in acidic, stable in alkaline
Ease of Use Very high (dust-free, fast dissolving) Highest (ready to use) Medium (dissolution and dust control required)
Shelf Life 24 – 36 months (at 25°C, dry) 12 – 24 months (at 25°C) 24 months (varies by manufacturer)
Main Applications Aqueous polymerization (main/post), textile (discharge printing, vat dyeing) Aqueous polymerization (main/post), textile Vat dyeing, discharge printing, pyrotechnics
Certifications Available upon request ISO 9001, ISO 14001, ISO 50001, OHSAS 18001, ILO-OSH, EcoVadis Gold Textile and industrial standards

SECTION 4: MECHANISM OF ACTION

Property Description
Reducing Agent Powerful reducing agent in aqueous solutions; Donates electrons to other compounds; Reduces vat dyes to soluble leuco forms; Reduces metal ions and organic compounds.
Redox Activation Acts as a redox activator in polymerization; Used with oxidizing agents (peroxides, persulfates) to initiate polymerization; Generates free radicals at lower temperatures; Accelerates polymerization reactions.
Vat Dye Reduction Reduces insoluble vat dyes to soluble leuco forms; Allows dye penetration into textile fibers; Oxidation after dyeing regenerates the insoluble dye; Essential for vat and indigo dyeing.
Discharge Printing Breaks down dye molecules in printed areas; Creates white or colored patterns on dyed fabrics; Used in discharge printing processes; Effective in acidic conditions.
Oxygen Scavenger Removes dissolved oxygen from solutions; Prevents oxidation reactions; Used as an antioxidant; Maintains product stability.
Decomposition Decomposes upon heating; Releases sulfur oxides and sodium oxides; Can produce toxic fumes under thermal stress.

SECTION 5: PRODUCTION PROCESS

Industrial Production Method:

Process Flow:
Sodium Dithionite + Formaldehyde → Reaction → Sodium Formaldehyde Sulfoxylate → Purification → Crystallization → Drying → Milling → Final Product

Step-by-Step Description:

  1. Raw Materials: Sodium dithionite (hydrosulfite) and formaldehyde are used as starting materials.

  2. Reaction: Sodium dithionite reacts with formaldehyde in aqueous solution under controlled conditions.

  3. Purification: The reaction mixture is purified to remove impurities.

  4. Crystallization: Purified solution is crystallized to obtain solid product.

  5. Drying: Crystals are dried to achieve the desired moisture content.

  6. Milling: Dried product is milled to achieve the desired particle size (dust-free formulations available).

  7. Final Product: Powder, granule, or liquid solution (L40) is produced.

Alternative Method: Reduction of sodium bisulfite with formaldehyde and zinc dust (historical method).

SECTION 6: FUNCTIONAL PROPERTIES

Property Description
Reducing Agent Strong reducing agent for textile and chemical applications; Reduces vat dyes; Discharge printing agent; Polymerization activator.
Redox Activator Activates redox polymerization systems; Used with peroxides and persulfates; Lowers activation temperature; Increases polymerization rate.
Discharge Agent Used in discharge printing; Breaks down dye molecules; Creates patterns on dyed fabrics; Effective in acidic conditions.
Vat Dye Reducer Reduces insoluble vat dyes to soluble leuco forms; Essential for vat and indigo dyeing; Improves dye uptake; Used in textile dyeing.
Oxygen Scavenger Removes dissolved oxygen; Prevents oxidation; Used as antioxidant in various applications; Maintains product stability.
Polymerization Regulator Controls polymer chain structure; Used as a catalyst regulator; Improves polymer quality; Reduces free monomer content.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Textile Industry Vat dye reduction, discharge printing, stripping, softening Vat dyeing (reduction to leuco form); Discharge printing (pattern creation); Stripping (excess dye removal); Softening; Dosage: 2-10 g/L (bath dependent).
Polymer & Plastics Industry Redox activator, polymerization regulator, catalyst Emulsion polymerization (redox-catalyzed systems); Post-polymerization (monomer reduction); Chain structure control; Dosage: 0.05-0.2% of total formulation (post-polymerization); 0.5-2% of monomer weight (polymerization).
Paints & Adhesives Reducing agent, emulsifier, stabilizer Paint raw materials (reducing agent); Food packaging adhesives (emulsifier, stability enhancer); Dosage: 0.5-3% of adhesive mixture; 1-5% of formulation.
Food & Packaging Bleaching agent, catalyst, emulsifier Sugar refining (bleaching); Soap production; Food contact rubber, cardboard, lid seals; Dosage: 0.5-2% (substrate dependent).
Pharmaceutical Antioxidant, active ingredient Mercury poisoning treatment (chelation therapy); Antioxidant in formulations; Dosage: Trace amounts to low percentages (formulation specific).
Rubber Industry Redox activator, polymerization accelerator Redox activation in rubber polymerization; Accelerates polymerization; Improves rubber properties; Dosage: 0.5-2% of monomer weight.

SECTION 8: SAMPLE FORMULATIONS

Textile Discharge Printing Paste:

Component Amount
Thickener 400 – 600 g
Water 400 – 600 g
Sodium Formaldehyde Sulfoxylate (Rongalit C / Bruggolite E01) 80 – 150 g
Auxiliary Chemicals (wetting agents, etc.) 10 – 20 g

Process: Apply discharge paste to pre-dyed fabric; Dry; Steam at 102-105°C for 6-10 minutes (wet steaming); Cool in air; Wash and finish.

Emulsion Polymerization Redox System:

Component Amount
Monomers As required
Water As required
Surfactants As required
Oxidizer (Initiator: APS / Hydrogen Peroxide) As required
Reducing Agent (Bruggolite E01) 0.05 – 0.2% of total formulation

Process: Load monomers and water into reactor; Heat and add stabilizers/surfactants; Add oxidizer (initiator); Add reducing agent (Bruggolite E01) in final stage or gradually; Reaction starts with mixing (exothermic polymerization); Results in high-quality polymer emulsion with low free monomer content.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Bruggolite E01 (Powder) Bruggolite L40 (Liquid) Rongalit C (Powder) Test Method
Appearance White powder/granules Clear to slightly yellowish liquid White powder/lumps Visual
Active Matter ≥ 98.0% ~40.0% ≥ 98.0% Titrimetric
pH (1% Solution) 9.5 – 10.5 9.5 – 10.5 9.5 – 10.5 pH Meter
Loss on Drying ≤ 0.5% ≤ 0.5% Gravimetric
Density (20°C) ~1.2 g/cm³ ASTM D4052
Heavy Metals (as Pb) ≤ 10 ppm ≤ 10 ppm ≤ 10 ppm AAS / ICP
Iron (Fe) ≤ 5 ppm ≤ 5 ppm ≤ 10 ppm AAS / ICP
Shelf Life 24 – 36 months 12 – 24 months 24 months

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 3,000 – 5,000 mg/kg (low to moderate toxicity)
Acute Dermal Toxicity Low toxicity; May cause mild irritation
Skin Irritation May cause mild irritation
Eye Irritation May cause irritation
Inhalation Toxicity May cause respiratory irritation (dust)
Chronic Toxicity Low toxicity at normal use levels; Formaldehyde release possible upon decomposition
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity at normal levels
Environmental Toxicity Low toxicity; Biodegradable; Avoid release to waterways
Special Toxicity Note May release formaldehyde upon decomposition; Use appropriate PPE; Avoid inhalation of dust; Avoid contact with strong oxidizing agents; Thermal decomposition releases toxic sulfur oxides.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315
Eye Irritation Category 2 H319
Specific Target Organ Toxicity (Single) Category 3 H335

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

Hazard Statements (H-Codes):

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
1 0 0 -
(Slight health hazard) (Non-flammable) (Stable) (None)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P332+P313 If skin irritation occurs: Get medical advice/attention
P337+P313 If eye irritation persists: Get medical advice/attention
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If respiratory irritation develops, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, get medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. Seek medical attention if large quantities are ingested or if feeling unwell.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-flammable organic material. May release toxic fumes (sulfur oxides) upon heating.
Hazards Arising from Fire Thermal decomposition produces sulfur oxides (SOx), sodium oxides, and irritating fumes.
Suitable Extinguishing Media Water spray, CO₂, dry chemical powder, foam.
Unsuitable Extinguishing Media Water jet (may spread dust)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing.
Special Precautions Prevent dust from entering sewers and waterways. Avoid dust cloud formation.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM LIGHT, HEAT, and MOISTURE; Keep away from direct sunlight and strong oxidizing agents.
Container Requirements Tightly closed, moisture-proof containers (PE-lined bags, HDPE containers).
Materials to Protect From Light, heat, moisture, strong oxidizing agents
Shelf Life 24 – 36 months (Bruggolite E01); 12 – 24 months (Bruggolite L40); 24 months (Rongalit C).
Stability Note Stable under recommended storage conditions; May decompose at high temperatures; Protect from moisture and heat.
Special Storage Requirements Store in a dark, cool, dry place; Avoid exposure to air and moisture; Opened containers must be resealed immediately.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
PE-Lined Paper Bag 10 kg, 20 kg, 25 kg PE-lined kraft paper bag (moisture-proof)
Plastic Bag 5 kg, 10 kg, 25 kg PE bag (inner-lined, sealed, moisture-proof)
Fiber Drum 20 kg, 25 kg PE-lined fiberboard drum
Plastic Drum 25 kg, 50 kg HDPE / Polypropylene (moisture-proof)
FIBC / Big Bag 500 kg, 1000 kg PE-lined, moisture-resistant PP woven bag
IBC Container (Liquid L40) 500 L, 1000 L HDPE or stainless steel IBC

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (non-hazardous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated (non-hazardous)
IATA (Air) Not regulated (non-hazardous)
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture and heat.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Approved for industrial and textile use.
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) Approved for food contact applications (formaldehyde-free versions).
Turkey Approved for industrial use; KKDIK regulation compliance required.
IARC Not classified (non-carcinogenic)
NTP Not listed
OSHA Regulated as nuisance dust/irritant
California (Prop 65) Not listed
Halal Yes (with certification)
Kosher Yes (with certification)
Vegan Yes

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Asidik Redüktan, Decolite, Bruggolit E01, Rongalite C, Sodyum Formaldehit Sülfoksilat, Sodyum Hidroksimetansülfinat
English Names Sodium Formaldehyde Sulfoxylate, Rongalit C, Bruggolite E01, Decolite, Sodium Hydroxymethanesulfinate, SFS
CAS Number 149-44-0 / 6035-47-8
HS Code 2831.10

SECTION 20: SUMMARY TABLE

Parameter Value
Product Sodium Formaldehyde Sulfoxylate (Rongalit C / Bruggolite E01)
CAS Number 149-44-0 / 6035-47-8
Molecular Formula NaHSO₂·CH₂O·2H₂O
Molecular Weight 154.10 g/mol
Appearance Hard, white solid (powder or granules)
pH (1% Solution) 9.5 – 10.5
Solubility ~50 g/L in water (20°C)
Primary Functions Reducing agent, redox activator, discharge agent, vat dye reducer
Main Application Areas Textile, polymer, paints, adhesives, food packaging, pharmaceutical
Shelf Life 24 – 36 months
GHS Signal Word WARNING
UN Number Not regulated
Special Properties Strong reducing agent; Dust-free formulations; Fast dissolving; Wide pH compatibility; Formaldehyde-free options available; FDA approved for food contact.

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • REDUCING AGENT: Strong reducing agent; Reacts with oxidizing agents (fire/explosion hazard).

  • MAY RELEASE FORMALDEHYDE: May release formaldehyde upon decomposition; Use in well-ventilated areas.

  • THERMAL DECOMPOSITION: Decomposes at high temperatures; Releases toxic sulfur oxides (SOx).

  • HYGROSCOPIC: Absorbs moisture from air; Store in tightly closed containers.

  • DUST HAZARD: May cause respiratory irritation (H335); Use dust masks when handling powder.

  • SKIN AND EYE IRRITATION: Causes skin and eye irritation (H315, H319); Use PPE.

  • INCOMPATIBILITY: Incompatible with strong oxidizing agents.

  • FORMALDEHYDE-FREE OPTIONS: Formaldehyde-free versions available (Bruggolite FF6 M) for sensitive applications.

  • FOOD CONTACT: FDA approved for food contact applications (formaldehyde-free versions).

BEST PRACTICE RECOMMENDATIONS:

  • Textile Industry (Discharge Printing): Use as discharge agent; Dosage: 80-150 g/kg paste; Combine with thickeners; Steam at 102-105°C for 6-10 minutes; Wash and finish after steaming.

  • Textile Industry (Vat Dyeing): Use as vat dye reducer; Dosage: 2-10 g/L; Reduce dyes to leuco form; Dye fabrics; Oxidize after dyeing.

  • Polymer Industry: Use as redox activator and polymerization regulator; Dosage: 0.05-0.2% of total formulation (post-polymerization); 0.5-2% of monomer weight (polymerization); Use with oxidizing agents (peroxides, persulfates).

  • Adhesives: Use as emulsifier and stabilizer; Dosage: 0.5-3% of adhesive mixture; Improves stability and performance.

  • Handling: Use in well-ventilated areas; Avoid dust formation; Use dust masks (N95/FFP2) when handling powder; Use gloves and safety goggles; Avoid contact with oxidizing agents.

  • Personal Protective Equipment: Dust mask (N95/FFP2) if dust is generated, safety goggles, chemical-resistant gloves, protective clothing.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using; Remove contaminated clothing and wash before reuse.

  • Storage: Store in tightly closed, moisture-proof containers; Store in cool, dry, well-ventilated area; Protect from moisture and heat; Keep away from oxidizing agents; Opened containers must be resealed immediately; Shelf life: 24-36 months under proper conditions.

  • Spill Management: Sweep or vacuum (HEPA) and place in suitable sealed container; Avoid dust formation; Do not allow entry into drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Non-hazardous waste; Can be incinerated in compliance with regulations.

DETECTION METHODS:

Method Description Advantages Disadvantages
Titrimetric Iodometric titration Simple, accurate, standard method Requires careful technique
HPLC Quantitative analysis High sensitivity, accurate High cost, requires expertise
UV-Vis Spectrophotometry Colorimetric determination Rapid, moderate cost Requires calibration
FTIR Functional group identification Fast, non-destructive Requires reference spectra
pH Meter pH of solution Simple, rapid Indicative only

SODIUM FORMALDEHYDE SULFOXYLATE vs ALTERNATIVES COMPARISON:

Product Chemical Name / E Code Application Strength Weakness Status
Sodium Formaldehyde Sulfoxylate Rongalit C / Bruggolite E01 Textile, polymer, adhesives Strong reducing, dust-free options May release formaldehyde Widely approved
Bruggolite FF6 M Formaldehyde-free reducing agent Polymer, textile Formaldehyde-free, stronger reducing Higher cost Widely approved
Ascorbic Acid (Vitamin C) C₆H₈O₆ Polymer, food Natural, food compatible Slower reaction, higher dosage Widely approved
Sodium Dithionite Na₂S₂O₄ Textile, bleaching Strong reducing Unstable, flammable dust Widely used
Reducing Agent TP 1646 Aqueous solution Emulsion polymerization New generation, odorless, high stability Requires dilution Limited

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Sodium formaldehyde sulfoxylate is a reducing agent that may release formaldehyde upon decomposition; use appropriate safety measures and ventilation.

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