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Beeswax, Bee Wax, Cera Alba White, Cera Flava Yellow, Refined Beeswax, Bleached Beeswax, Natural Beeswax, E901, 8012-89-3, 8006-40-4

Beeswax, Bee Wax, Cera Alba White, Cera Flava Yellow, Refined Beeswax, Bleached Beeswax, Natural Beeswax, E901, 8012-89-3, 8006-40-4

BEESWAX (NATURAL BEE WAX PELLET)

Beeswax / Bee Wax / Cera Alba (White) / Cera Flava (Yellow) / E901
CAS Numbers: 8012-89-3 (Refined, White/Yellow Pellet); 8006-40-4 (Crude)
EC Number: 232-383-7
E Number: E901
INCI: Cera Alba (White), Cera Flava (Yellow)
Source: Apis mellifera (Honey Bee)

SECTION 1: PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Beeswax (Natural Bee Wax Pellet)
Other Names Bee Wax, Cera Alba (White Beeswax), Cera Flava (Yellow Beeswax), E901
CAS Number (Refined) 8012-89-3
CAS Number (Crude) 8006-40-4
EC Number (EINECS) 232-383-7
E Number (Food) E901
INCI Name Cera Alba (White), Cera Flava (Yellow)
Source Apis mellifera (Honey Bee)
Chemical Class Natural wax (complex mixture of esters, hydrocarbons, fatty acids, and alcohols)
Appearance White to yellow pellets or brownish crude form
Odor Slight, sweet, honey-like (more pronounced in crude form)
Physical State (20°C) Solid

Beeswax is a natural wax produced by honey bees of the genus Apis. It is a complex mixture of long-chain esters, hydrocarbons, free fatty acids, and fatty alcohols. It is widely used in cosmetics, pharmaceuticals, food (as E901), candles, and polishes due to its excellent film-forming, emulsifying, and structuring properties.

SECTION 2: SYNONYMS AND OTHER NAMES

Type Name
Common Names Beeswax, Bee Wax, White Wax, Yellow Wax
INCI Names Cera Alba (White), Cera Flava (Yellow)
Food Additive Code E901
CAS (Refined) 8012-89-3
CAS (Crude) 8006-40-4
EC Number 232-383-7
HS Code 1521.90

SECTION 3: CHEMICAL STRUCTURE

3.1. General Composition

Beeswax is a complex mixture of over 300 different compounds. The main components are:

Component Group Typical Ratio (%)
Hydrocarbons (especially C21-C33 alkanes) ~14%
Monoesters (e.g., ceryl palmitate, myricyl palmitate) ~35%
Diesters and Hydroxyesters ~14%
Free Fatty Acids (e.g., palmitic acid, cerotic acid) ~12%
Fatty Alcohols (ceryl, myricyl alcohols) ~10%
Other (minerals, water, polyphenols) ~15%

3.2. Key Structural Features

Feature Description
Primary Components Esters, hydrocarbons, free fatty acids, fatty alcohols
Typical Ester Myricyl palmitate (C₄₆H₉₂O₂)
Typical Hydrocarbon Heptacosane (C₂₇H₅₆)
Typical Fatty Acid Palmitic acid (C₁₆H₃₂O₂)
Typical Fatty Alcohol Ceryl alcohol (C₂₆H₅₄O)
Molecular Weight Range 300 – 1,200 g/mol

Simplified Structural Representation (Myricyl Palmitate - Main Ester):

CH₃-(CH₂)₁₄-COO-(CH₂)₂₉-CH₃

SECTION 4: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Range Description
Appearance White/yellow pellets or brownish crude form Refined white or yellow; crude form is pigmented
Odor Slight, sweet, honey-like More pronounced in crude form
Density (25°C) 0.95 – 0.96 g/cm³ Lighter than water
Melting Point 61 – 65°C (142 – 149°F) Narrow melting range – high thermal stability
Water Solubility Insoluble -
Solubility in Organic Solvents Soluble in oils, chloroform, benzene, hot ethanol, acetone -
Saponification Value 87 – 104 mg KOH/g Indicator of ester and free acid content
Iodine Value 8 – 12 Degree of unsaturation (low)
Acid Value 17 – 24 mg KOH/g Free fatty acid content
Saponification Value (European type) 3 – 5 -
Saponification Value (Oriental type) 8 – 9 -
Refractive Index (75°C) 1.441 – 1.445 -
Flash Point >250°C (>482°F) Not flammable (burns as a wax)
Melting Point (Crude) 62 – 65°C -
Melting Point (Refined White) 61 – 64°C -

SECTION 5: COMPARISON WITH ALTERNATIVE WAXES

Property Beeswax Candelilla Wax Carnauba Wax Soy Wax Paraffin Wax
Source Animal (bees) Vegetable Vegetable Vegetable Synthetic (petroleum)
Melting Point 61-65°C 67-79°C 81-86°C 49-56°C 46-68°C
Hardness Medium (flexible) High (hard, brittle) Very high (very hard) Low (soft) Low-medium
Gloss High Medium-high Very high Medium Low
Emulsifiability Medium (good) Good Poor Good Very poor
Vegan Suitability No Yes Yes Yes Yes (vegan)
Food Approval (EU) E901 E902 E903 Not approved E905
Biodegradability High High High High Low
Odor Sweet, honey-like Slight vegetable Slight Neutral Neutral
Cost High Very high Very high Medium Low

SECTION 6: ADVANTAGES AND DISADVANTAGES

Advantages of Beeswax:

  • Natural and renewable source

  • Excellent structuring and stabilizing properties

  • Hypoallergenic – skin-friendly

  • Natural antibacterial properties (propolis residues)

  • Sharp melting point (61-65°C) – very fast transition to liquid

  • Good emulsifying properties

  • Compatible with other waxes

Disadvantages of Beeswax:

  • Animal-derived – not suitable for vegan products

  • High cost (compared to vegetable waxes and synthetics)

  • High risk of adulteration – often mixed with paraffin or stearic acid

  • Alias risk – CAS number must be fixed in ERP systems to avoid confusion

  • Can develop mold if stored in humid conditions

  • May cause allergic reactions in propolis-sensitive individuals

SECTION 7: REFINING PROCESS AND GRADES

Grade Characteristics Purity Color Applications
Crude Beeswax Pigmented, strong aroma, particulate 90-95% Dark yellow / brown Candles, industrial (not suitable for cosmetics)
Yellow Beeswax (Cera Flava) Physical refining (filtration, washing) 97-99% Yellow Cosmetics, pharmaceuticals, food
White Beeswax (Cera Alba) Chemical bleaching (chromic acid or hydrogen peroxide) 99%+ White / cream High-quality cosmetics, pharmaceuticals, food
Beeswax Pellet (Micronized) Ground, granulated 99%+ White Easy dosing, rapid melting

Bleaching Methods:

  • Traditional: Chromic acid (H₂CrO₄) bleaching

  • Modern: Hydrogen peroxide (H₂O₂) bleaching (more environmentally friendly)

SECTION 8: APPLICATIONS AND INDUSTRIAL USES

8.1. Cosmetics and Personal Care

Application Function Typical Usage
Lip Balms Structuring agent, hardness, film former 20-40%
Creams and Lotions Emulsifier (auxiliary), thickener 3-8%
Mascara Thickener, film former 5-15%
Lipstick Structuring agent, gloss 10-15%
Hair Care Products Conditioning agent, thickener 1-5%
Deodorants Structuring agent (solid sticks) 5-15%

8.2. Pharmaceutical Industry

Application Function Typical Usage
Ointments Consistency agent, skin barrier 5-25%
Emulsions Emulsifier (auxiliary), thickener 5-20%
Tablet Coatings Coating agent 1-5%
Wound Dressings Barrier layer 5-15%

8.3. Food Industry (E901)

Application Function Typical Usage
Fruit Coating Moisture barrier, gloss 0.5-2.0% (emulsion)
Confectionery Gloss, anti-sticking Trace amounts
Chewing Gum Viscosity regulator, plasticizer 1-5%
Cheese Coating Protection, moisture barrier Trace amounts
Biscuit and Coffee Bean Coating Protection, gloss Trace amounts

8.4. Candle Making

Application Function Typical Usage
Traditional Candles Wax base 30-100%
Decorative Candles Hardness, gloss 30-100%
Religious Candles Wax base 30-100%

8.5. Polishes and Coatings

Application Function Typical Usage
Furniture Polish Gloss, protection 20-30%
Shoe Polish Gloss, water repellency 10-25%
Leather Conditioner Softening, protection 5-15%
Wood Finish Protection, gloss 5-20%

8.6. Other Applications

Application Function
Packaging Natural barrier coatings
Plastics / PVC Not suitable
Detergents Rare (some natural soaps)

SECTION 9: FORMULATION EXAMPLES

9.1. Lip Balm (Moisturizing, Protective)

Component Function Concentration (% w/w)
Beeswax (White or Yellow) Structuring agent, hardness, film former 20-40%
Shea Butter / Coconut Oil Moisturizer, emollient 20-30%
Jojoba Oil / Almond Oil Emollient, absorption aid 10-20%
Lanolin (optional) Humectant, emollient 5-10%
Candelilla Wax (optional, vegan alternative) Hardness enhancer 0-10%
Vitamin E (Tocopherol) Antioxidant, preservative 0.5-1.0%
Flavor / Essential Oil Odor, taste 0.5-2.0%

Process: Melt all ingredients at 65-70°C, mix, pour into molds.

9.2. Natural Skin Cream (Emulsion, Oil-in-Water)

Component Function Concentration (% w/w)
Beeswax Emulsifier (auxiliary), thickener 3-8%
Almond Oil / Olive Oil Emollient 10-20%
Vegetable Emulsifier (e.g., Glyceryl Stearate) Primary emulsifier 2-5%
Water Liquid phase 60-80%
Glycerin Humectant 3-5%
Preservative Microbial stability 0.5-1.0%
Essential Oil Odor 0.5-1.0%

Process: Heat oil phase (beeswax + oils + emulsifier) to 70°C. Heat water phase to 70°C. Slowly add water phase to oil phase with high-shear mixing. Continue mixing while cooling.

9.3. Fruit Coating (Apples, Pears, Citrus)

Component Function Concentration (% w/w)
Beeswax (E901, Food Grade) Moisture barrier, gloss 0.5-2.0%
Water Carrier 70-95%
Emulsifier (e.g., Lecithin, Polysorbate 60) Dispersing aid 0.5-1.0%
Sugar / Glucose Syrup (optional) Gloss, taste 1-5%
Preservative (Citric Acid or Potassium Sorbate) Microbial stability 0.1-0.3%

Process: Prepare emulsion at room temperature (or emulsify melted wax into hot water). Spray or dip fruits, dry.

9.4. Chewing Gum Base

Component Function Concentration (% w/w)
Beeswax Viscosity regulator, plasticizer 1-5%
Gum Base (Polyvinyl Acetate, etc.) Structure, elasticity 20-30%
Sugar / Glucose Syrup Sweetness, texture 60-70%
Flavor Taste 1-2%
Glycerin Humectant 0.5-1.0%

9.5. Furniture Polish (Natural)

Component Function Concentration (% w/w)
Beeswax Gloss, protection 20-30%
Carnauba Wax Hardness, high gloss 5-15%
Turpentine / Orange Oil Solvent, spreading aid 40-60%
Olive Oil / Coconut Oil Emollient, spreading 5-15%

Process: Melt waxes at 70°C, add oils, mix while cooling. Achieve paste consistency at room temperature.

SECTION 10: PROCESSING GUIDELINES

Application Method Temperature Notes
Cosmetics / Pharmaceuticals Melting + mixing 65-75°C Melt directly, mix, pour into molds
Food Coating Emulsion (spray/dip) Room temperature or 50-60°C Emulsify in water or apply melted
Candle Making Melting + pouring 70-80°C Additives for odor and color
Polish (Solid) Melting + cooling 70-80°C Solvent may be added (paste consistency)
Emulsion Preparation Melted + water + surfactant 70-75°C (both phases) High-shear mixing (rotor-stator)

Important Processing Notes:

  • Melting point is very sharp – solid below 61°C, fully fluid above 65°C

  • Do not place directly over high heat (can ignite) – use water bath or indirect heating

  • Shrinkage is high upon cooling – leave allowance for mold shrinkage

  • Mixes well with other waxes (carnauba, paraffin)

SECTION 11: REGULATORY STATUS AND FOOD CONTACT

Regulation Scope Status
EU (EFSA) Food additive E901 Approved, specifications established
FDA 21 CFR 184.1848 Direct food additive (GRAS) Approved (fruit coating, confectionery)
FDA 21 CFR 175.105 Adhesives (indirect food contact) Approved
FDA 21 CFR 175.300 Coatings (indirect food contact) Approved
EU Cosmetics Regulation Cosmetic ingredient (INCI Cera Alba/Flava) Approved, no restrictions
Pharmacopoeia (USP, Ph. Eur., JP) Pharmaceutical grade Monographs available
REACH (EU) Chemical registration Registered, no restrictions
Halal / Kosher Religious certification Possible (generally considered Halal/Kosher)
Vegan Animal source NOT suitable

Food Coating Labeling Requirement:

  • Waxed fruits must be labeled as "waxed"

  • Must be listed as E901 in the ingredient list

SECTION 12: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 5,000 mg/kg (low toxicity)
Acute Dermal Toxicity Low
Skin Irritation Not classified (hypoallergenic)
Eye Irritation Mechanical irritant (dust or particulate form)
Inhalation (Molten Vapor) No risk under normal use
Allergic Reactions Rare (sensitivity in propolis-allergic individuals)
Ingestion (Large Amount) Not digested; risk of intestinal blockage (very low)
Carcinogenicity Not classified
Mutagenicity Negative

SECTION 13: GHS CLASSIFICATION

GHS Classification (Not Classified as Hazardous for Food/Pharma Grade):

Hazard Class Category H-Statement
Not classified as hazardous - -

Signal Word: None (not classified as hazardous)

Hazard Pictograms: None

Hazard Statements (H-Codes): None

SECTION 14: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P501 Dispose of contents/container in accordance with local regulations.

SECTION 15: FIRST AID MEASURES

Route of Exposure Action to Be Taken
Skin Contact (Molten) Cool immediately under cold water. DO NOT peel off adhered wax (skin may tear) – wait until it softens.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. Seek medical attention.
Ingestion Seek medical attention (generally no intervention required).
General Note If symptoms persist, always consult a healthcare facility.

SECTION 16: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Flammable solid (burns as a wax).
Suitable Extinguishing Media Water spray, CO₂, dry chemical powder, foam.
Special Hazards Thermal decomposition produces carbon monoxide and carbon dioxide.
Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing.

SECTION 17: ACCIDENTAL RELEASE MEASURES

Parameter Information
Personal Protection Protective goggles, gloves, coverall.
Ventilation Increase ventilation; use local exhaust in confined spaces.
Containment Collect dry using vacuum or careful sweeping.
Cleaning Methods Collect dry. Avoid washing with water (solid).
Environmental Precautions Prevent entry into drains, sewers, and water bodies.
Waste Disposal Dispose of in accordance with local regulations.

SECTION 18: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool (10-25°C), dry place, protected from direct sunlight.
Humidity Below 60% RH (dry) – mold risk if moisture is absorbed.
Container Requirements Airtight containers (cardboard, plastic, metal).
Compatible Materials Polyethylene, polypropylene, stainless steel, glass.
Shelf Life 3-5 years (under proper storage).
Stability Issues Light and prolonged temperature exposure may cause color fading; decomposition begins >70°C.
Mold Risk High (in humid environments) – storage must be dry.

SECTION 19: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Pail 10-25 kg HDPE
Fiber Drum 25 kg Cardboard / Plastic
Big-Bag 500 – 1000 kg Polypropylene
Small Containers 1 kg, 5 kg Plastic / Kraft paper

SECTION 20: TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not classified as dangerous goods)
Hazard Class Not classified as hazardous for transport
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; protect from heat and moisture.

SECTION 21: REGULATORY INFORMATION

Region / Authority Status
European Union (REACH) Registered; approved as food additive E901.
USA (FDA) GRAS (21 CFR 184.1848).
Turkey Approved as food additive; regulated by Turkish Food Codex.
EFSA Approved as food additive E901.
USP / Ph. Eur. Monographed for pharmaceutical use.
Halal / Kosher Can be certified upon request.
Vegan NOT suitable (animal-derived).

SECTION 22: ENVIRONMENTAL INFORMATION

Parameter Information
Aquatic Toxicity Low toxicity to aquatic organisms.
Biodegradability Readily biodegradable.
Bioaccumulation Low potential.
Waste Disposal Dispose of in accordance with local regulations. Incineration is recommended for contaminated materials.

SECTION 23: FREQUENTLY ASKED QUESTIONS (FAQ)

Q1: Is beeswax vegan?
A: No. Beeswax is an animal-derived product from honey bees (Apis mellifera). It cannot be used in vegan products. Alternatives: Candelilla wax, carnauba wax, soy wax.

Q2: Is beeswax safe as a food coating?
A: Yes. It is approved by the EU (E901) and FDA (GRAS). It is used on fruits, confectionery, cheeses, and chewing gum. However, waxed fruits must be labeled as "waxed."

Q3: What is the difference between white and yellow beeswax?
A: Yellow beeswax (Cera Flava) is physically refined (filtering, washing) and retains its natural yellow color and honey-like odor. White beeswax (Cera Alba) is chemically bleached (chromic acid or hydrogen peroxide) and is more pure, odorless, and colorless. White beeswax is preferred in high-quality cosmetics and pharmaceuticals.

Q4: Does beeswax cause acne?
A: Generally no. Beeswax is not comedogenic (pore-clogging) (comedogenic rating 0-2). However, in some formulations with other oils, it may contribute to pore blockage. Patch testing is recommended for sensitive skin.

Q5: How much honey do bees consume to produce 1 kg of beeswax?
A: Approximately 10 kg of honey. Bees metabolize honey sugars in their bodies to secrete wax from their wax glands. This is why beeswax is about 10 times more valuable than honey.

Q6: Does beeswax burn when melted? What is the safe melting method?
A: It can ignite if placed directly over high heat. Safe melting methods:

  • Water bath (double boiler): Place beeswax in a metal container, set over hot water.

  • Wax melter: Electric or double-walled melter.

  • Slow cooker: Low setting. Never leave directly on the stove. Melting point is 65°C – it does not ignite at this temperature, but above 200°C it may vaporize and ignite.

Q7: How can I prevent beeswax from molding during storage?
A: Store in a dry environment (below 60% RH), use airtight containers, keep away from direct sunlight and heat sources. Shelf life is 3-5 years – discard if color fades or moldy odor appears.

Q8: Can beeswax be mixed with paraffin wax?
A: Yes. Paraffin makes beeswax softer and cheaper. However, this is considered adulteration and is usually not declared on the label. If you want pure beeswax, request melting point (DSC) and GC analysis from your supplier.

Q9: Why is beeswax used in lip balm?
A: It provides structure (keeps lip balm solid), acts as a protective barrier against wind and cold, is not occlusive (does not trap moisture), and has natural antibacterial properties (due to propolis residues).

Q10: What are the non-food uses of beeswax?
A: Candle making (traditional, decorative, religious), leather care (shoe polish, leather cream), wood care (furniture polish, wood protector), dentistry (dental impression waxes), art (wax sculptures, encaustic painting), fishing line (water-repellent coating), thread and sewing (thread waxing).

SECTION 24: QUICK REFERENCE TABLE

Property Value
CAS Number (Refined) 8012-89-3
CAS Number (Crude) 8006-40-4
EC Number 232-383-7
E Number E901
Appearance White to yellow pellets or brownish crude
Odor Slight, sweet, honey-like
Density (25°C) 0.95 – 0.96 g/cm³
Melting Point 61 – 65°C
Saponification Value 87 – 104 mg KOH/g
Acid Value 17 – 24 mg KOH/g
Iodine Value 8 – 12
Primary Uses Cosmetics, pharmaceuticals, food (E901), candles, polishes
Shelf Life 3-5 years
UN Number Not applicable
GHS Signal Word None (not classified as hazardous)

SECTION 25: CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Vegan Not Suitable: Beeswax is an animal-derived product from honey bees. It is not suitable for vegan products.

  2. Adulteration Risk: Pure beeswax is often adulterated with paraffin, stearic acid, or other waxes. Request GC or FTIR analysis reports from suppliers to verify purity.

  3. Melting Point Sharpness: Beeswax has a very sharp melting point (61-65°C). Solid below 61°C, fully fluid above 65°C. This is a key quality indicator.

  4. Mold Risk: Beeswax can develop mold if stored in humid conditions. Store in a dry environment (below 60% RH) with airtight containers.

  5. Heat Sensitivity: Do not heat above 70°C unnecessarily. Prolonged heating above 70°C may cause color fading and degradation.

  6. Direct Flame: Do not melt beeswax directly over an open flame – it can ignite. Use a water bath, wax melter, or slow cooker.

  7. Allergic Reactions: Rare, but possible in individuals sensitive to propolis (bee products). Patch testing is recommended for topical applications.

  8. Shrinkage: Beeswax shrinks significantly upon cooling (3-5%). Allow for mold shrinkage in candle and casting applications.

BEST PRACTICE RECOMMENDATIONS:

  • Storage: Store in a cool (10-25°C), dry place (below 60% RH), in airtight containers. Protect from direct sunlight and heat sources.

  • Melting: Use a water bath (double boiler), wax melter, or slow cooker. Do not exceed 70°C unnecessarily. Never melt directly over an open flame.

  • Filtering: If using crude beeswax, filter through cheesecloth or a fine mesh filter to remove debris and impurities.

  • Compatibility: Beeswax mixes well with other waxes (carnauba, paraffin, candelilla). Adjust ratio based on desired hardness and melting point.

  • Quality Control: Test for melting point (DSC), saponification value, acid value, and iodine value to verify purity. Request GC or FTIR analysis from suppliers.

  • Labeling: For food applications, label as E901. For cosmetics, use INCI names Cera Alba (white) or Cera Flava (yellow).

  • Waste Management: Dispose of waste in accordance with local regulations. Incineration is recommended for contaminated materials.

LEGAL DISCLAIMER:

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Beeswax is a natural product and its properties may vary slightly depending on source and refining process.

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