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Ferric Oxide, Iron Oxide Anhydrous, Diiron Trioxide, Hematite, R101, E172, 1309-37-1, 1317-60-8, 1332-37-2

Ferric Oxide, Iron Oxide Anhydrous, Diiron Trioxide, Hematite, R101, E172, 1309-37-1, 1317-60-8, 1332-37-2

IRON OXIDE (RED IRON OXIDE) 

CHEMICAL PROFILE AND IDENTIFICATION

Parameter Information
Chemical Name Iron(III) Oxide, Ferric Oxide
CAS Numbers 1309-37-1 (α-Fe₂O₃), 1317-60-8 (Fe₂O₃·H₂O), 1332-37-2 (Iron Oxide)
Molecular Formula Fe₂O₃
Molecular Weight 159.69 g/mol
Appearance Red to brown solid powder
E Number E172
Other Names Pigment Red 101, Pigment Red 102, Hematite, Red Iron Oxide, Colcothar, Rouge, Caput Mortuum, Jeweler's Rouge, Ferric Oxide, Iron Sesquioxide

SECTION 1: PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Appearance Red to brown powder
Odor Odorless
Molecular Weight 159.69 g/mol
Density (20°C) 5.24 g/cm³
Melting Point ~1565°C (decomposes)
Solubility in Water Insoluble
Solubility in Acids Soluble (in HCl)
pH Neutral (aqueous dispersion)
Magnetic Property Paramagnetic (α-Fe₂O₃) / Ferrimagnetic (γ-Fe₂O₃)
Calcination Temperature >500°C
Color Range Red, yellow, brown, black
Specific Surface Area Variable (particle size dependent)
Refractive Index ~2.9
Hardness (Mohs) 5-6
Thermal Stability Stable at high temperatures

SECTION 2: IRON OXIDE TYPES

Compound Formula Color Mineral Name Application
Wüstite FeO Dark grey / black Wüstite Steel production
Hematite α-Fe₂O₃ Red Hematite Pigment, paints, cosmetics
Magnetite Fe₃O₄ Black Magnetite Magnetic materials
Limonite Fe₂O₃·H₂O Yellow / brown Limonite Pigment
Maghemite γ-Fe₂O₃ Brown Maghemite Magnetic recording media
Goethite α-FeOOH Yellow / brown Goethite Pigment

SECTION 3: APPLICATIONS

3.1 Pigment and Paint Industry

Application Description
Pigment (CI 77491) Used as red, yellow, brown, black pigment. Durable, non-toxic, stable to light and chemicals
Paints and Coatings Facade paints, automotive paints, industrial coatings, primer paints
Plastics and Rubber Coloring agent
Ceramics and Glass Glaze colorant
Cosmetics Colorant (classified as safe)

3.2 Construction and Building Materials

Application Description
Cement and Concrete Coloration and pigment
Bricks and Tiles Colorant
Asphalt Coating Coloration

3.3 Steel and Metallurgy

Application Description
Iron Ore Raw material for steel production
Blast Furnaces Iron production

3.4 Catalyst

Application Description
Catalytic Reactions Fe(III) oxide as catalyst in oxidation reactions
Ammonia Synthesis Haber-Bosch process
Water-Gas Shift Reaction Shift reaction

3.5 Nanotechnology and Biomedical

Application Description
Magnetic Nanoparticles MRI contrast agent
Drug Delivery Systems Targeted drug delivery
Hyperthermia Therapy Magnetic hyperthermia in cancer treatment
Environmental Applications Heavy metal adsorption

3.6 Other Applications

Application Description
Metal Polishing Rouge (polishing powder)
Water Treatment Heavy metal adsorption (arsenic, lead, cadmium)
Magnetic Storage Magnetic media
Solar Cells Photocatalytic applications

SECTION 4: NANOPARTICLE PROPERTIES

Property Description
Superparamagnetism Size-dependent magnetic properties
High Surface Area Increased adsorption capacity in nanoparticles
Synthesis Methods Thermal decomposition, co-precipitation, sol-gel
Magnetic Saturation (Ms) 74.4-92.6 emu/g (temperature dependent)

SECTION 5: SAFETY INFORMATION

Parameter Value
GHS Classification Generally non-toxic
Skin Irritation May cause irritation (dust)
Eye Irritation May cause irritation (dust)
Inhalation Dust may be harmful
Ingestion May be harmful (seek medical attention)
Carcinogenicity Not classified as carcinogenic

SECTION 6: STORAGE

Parameter Information
Storage Conditions Dry, well-ventilated area
Materials to Protect From Moisture, acids
Shelf Life Unlimited (under proper storage)
Packaging Tightly closed, original packaging

SECTION 7: SYNONYMS AND TRADE NAMES

Synonym Description
Caput mortuum Historical pigment name
Colloidal ferric oxide Fine particle form
Deanox Trade name
Ferrugo Rust pigment
Iron sesquioxide Chemical synonym
Jeweler's rouge Polishing compound
Rouge Polishing powder
Rubigo Rust
Crocus (iron oxide) Polishing compound
α-Ferric oxide Alpha crystalline form
γ-Ferric oxide Gamma crystalline form
Colcothar Red iron oxide pigment
Bayer S 11 Brand name
Felac Brand name
Pigdex 100 Brand name
Red oxide Common name
Venetian red Red pigment
English red Red pigment
Mars red Synthetic red iron oxide
Pferrox 2228 Brand name
Bayferrox 110M Brand name
Mapico Red 347 Brand name
Micronox Nanoparticle form
Nanogard Nanoparticle form
Bengara Japanese red iron oxide
Toda Color Brand name
Sicotrans Red Transparent red iron oxide
Bengala Red iron oxide
Sanylene Brown Brown pigment
Kroma Red Brand name
Cerac I Brand name
SunPuro Red Brand name
Synox HR 1208 Brand name
Nubifer EF Brand name
Colortherm Red Brand name
Ferroxide Brand name
Tarox Brand name

LEGAL DISCLAIMER

The information provided in this document is based on our current knowledge and experience and is presented in good faith; however, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications. For complete safety, storage, use, handling, disposal, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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