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Aramid Knitted Fabric, Modacrylic Knitted Fabric, Modacrylic Aramid Nylon Knitted Fabric, Technical Textile Knitted Fabric Sales

Aramid Knitted Fabric, Modacrylic Knitted Fabric, Modacrylic Aramid Nylon Knitted Fabric, Technical Textile Knitted Fabric Sales

Technical Breakdown of Flame-Resistant Knitted Fabrics

1. Knit Fire-Blocker Family

Composition: 93% Meta-aramid, 5% Para-aramid, 2% Antistatic fiber

  • Meta-aramid (93%): Limiting Oxygen Index (LOI) ≈ 28-30. Continuous service temperature: 200-220°C. Does not melt; carbonizes above 400°C. Provides inherent flame resistance, low thermal conductivity, and high flexibility.

  • Para-aramid (5%): LOI ≈ 29. Tensile strength 3.0-3.6 GPa, elongation at break 2.4-3.6%. Retains strength above 500°C. Thermal shrinkage <1% (300°C, 15 min). In the blend, it acts as a structural skeleton, enhancing tear and puncture resistance.

  • Antistatic fiber (2%): Conductive carbon or stainless-steel filament yielding surface resistance 10⁵–10⁹ Ω. Required for compliance with EN 1149-1/3 (electrostatic discharge protection).

Knitting & Weight Variants:

Code Knit Type Weight (g/m²) Technical Properties
408 Single Jersey 190 Single needle bed, highest air permeability, thickness ~0.6-0.7 mm. Low thermal resistance (Rct). Suited for base-layer garments (T-shirts, balaclavas). High stitch density ensures opacity at low weight.
381 Interlock 190 Double needle bed, cross-connected 1×1 rib courses. Edge curling eliminated. Thickness ~0.9-1.0 mm (30-40% higher than single jersey). Higher Rct. Used for unlined polo shirts and lightweight outer shells.
322 Interlock 240 Stitch length shortened to increase density. Thickness ~1.2 mm. Excellent dimensional stability in both wale/course directions. Meets EN ISO 11612 for thermal barrier linings.
395 3-Thread Fleece 270 Ground yarn + binding yarn + brushed weft yarn. Inner pile height 1.5-2.5 mm, creating high air entrapment. Significantly higher Rct than flat knits. Cold-weather mid-layer compatible with EN 342 (cold protection).

Standards: Designed for the top tiers of EN ISO 11612 (flame spread, convective/radiant heat) and EN 61482-2 (arc flash protection). The 5% para-aramid prevents severe strength loss after brushing (fleece finishing). Homogeneous antistatic fiber distribution maintains EN 1149-3 compliance after 25+ industrial washes.

2. Knit Body-Guard Family

Composition: 55% Viscose FR, 44% Meta-aramid, 1% Antistatic fiber

  • Viscose FR (55%): LOI 27-28. Phosphorus-based additives provide permanent flame retardancy. Thermal decomposition releases water and forms a char barrier. Moisture regain 11-13%, regulating skin microclimate. Tenacity lower than meta-aramid (~2.0-2.5 cN/dtex); wet strength loss ~30%.

  • Meta-aramid (44%): Ensures non-melting behavior and reinforces the char skeleton.

  • Antistatic (1%): Sufficient for basic static dissipation; 2% is preferred for high-risk ATEX zones.

Knitting & Weight Variants:

Code Knit Type Weight (g/m²) Technical Behavior
351 Single Jersey 220 High moisture vapor transfer from the FR viscose. Low bending rigidity ensures comfort. In ASTM F1930 (flash fire manikin tests), TPP values are targeted to yield <50% predicted body burn.
361 Pique 220 Textured honeycomb structure creates micro air pockets, increasing insulation slightly and accelerating moisture evaporation via enlarged surface area. Less prone to deformation than single jersey; suitable for front panels.
356 3-Thread Fleece 270 Pile density may be lower than pure FR viscose fleece due to meta-aramid content. The 44% meta-aramid increases crush resistance of the brushed surface. Clo value reaches 0.5-0.7 on thermal manikins.

Applicable Standards: EN ISO 11612 (limited flame spread, convective/radiant heat), EN 1149 (antistatic). Not classified for molten metal splash in EN 11611 (welding protection), hence not recommended for heavy welding.

3. Knit Para-Vis Family

Composition Strategy: 78% Viscose FR, 20% Para-aramid, 2% Antistatic fiber

  • Viscose FR (78%): High comfort, lower cost, but higher thermal shrinkage tendency (>5% at 200°C).

  • Para-aramid (20%): Tenacity 10x higher than viscose (20-25 cN/dtex). Near-zero thermal shrinkage (0.1% at 250°C). The blend leverages para-aramid as a rigid skeleton that physically constrains viscose FR shrinkage at elevated temperatures.

  • Antistatic (2%): Full protection level.

Weight Variants:

Code Knit Type Weight (g/m²) Performance Rationale
326 Single Jersey 180 Minimal summer weight T-shirt. Even at 180 g/m², the 20% para-aramid delays tear initiation (Elmendorf tear strength expected >15 N).
327 Single Jersey 230 Increased thickness improves resistance in molten metal splash testing (EN 348). Para-aramid filaments prevent molten metal adhesion and char penetration.

Critical Testing: EN ISO 9185 (molten metal splash resistance) and EN 11611 Class 2 welding compatibility. Fabrics without para-aramid (e.g., 100% FR viscose or modacrylic blends) commonly fail these tests due to hole formation and metal adhesion. Para-Vis resolves this deficiency.

4. Knit Opti-Syn 220

Multi-Blend Analysis:

  • Aramid (33%, meta-aramid): Thermal skeleton, non-melting.

  • Modacrylic (32%): LOI 32-34, high self-extinguishing capacity. Thermal shrinkage >3% above 150°C.

  • Tencel® (Lyocell, 23%): Fibrillation-controlled, high moisture desorption; enhances heat loss through absorption. Improves skin sensorial comfort.

  • Polyamide 6.6 (10%): Melting point ~255°C. In flame tests (ISO 15025), localized melting occurs but is trapped within the aramid framework, preventing dripping. Provides abrasion resistance (Martindale >50,000 cycles).

  • Antistatic (2%): Standard.

Plated Knit Architecture (Face: Pique, Back: Single Jersey):

  • Technical Advantage: Plating allows differential fiber distribution – aramid/modacrylic on the outer face for flame/thermal barrier, Tencel/polyamide on the inner face for moisture management and abrasion durability.

  • Arc Flash Protection (EN 61482-2): ATPV or EBT value typically >8 cal/cm². The multi-fiber blend creates layered thermal insulation against arc plasma through different decomposition temperatures.

  • Thermo-Physiological Comfort: Tencel provides high water vapor permeability (Ret target <10 m²·Pa/W), reducing heat stress.

5. Knit MACO-S Family

Fiber Technology:

  • Modacrylic (60%): LOI 32-34, contains flame-retardant comonomer (e.g., vinylidene chloride or antimony oxide). Low density (1.37 g/cm³), high bulk.

  • Cotton (38%): Natural hydrophilicity (8.5% moisture regain). Forms insulating char upon combustion. Synergy: cotton chars while modacrylic maintains the carbonized skeleton.

  • Thermal Limitation: Modacrylic shrinkage begins above 150°C. Cotton mitigates the visual effect, but total shrinkage can exceed 5% at 200°C. This family may not meet the stricter heat shrinkage criteria of EN ISO 11612; it is primarily used in conjunction with EN 1149 and EN 13034 (limited chemical protection).

Knitting Variants & Suitability:

Code Knit Type Weight (g/m²) Technical Note
352 Single Jersey 220 Highest air permeability, lowest thermal resistance. Indoor or hot outdoor environments.
441 Rib (1×1) 220 High elastic recovery (>95%). Ideal for close-fitting roll-neck base layers, cuffs, and waistbands. Higher course density than single jersey.
442 Interlock 250 Bilateral stability, improved cover factor. Used for winter mid-layer sweatshirts or jacket linings.

Additional Technical Variants Not Present in the Table

  1. 100% Para-aramid Knit (Cut/Puncture Protection)

    • Weight: 200–340 g/m², tight interlock or double jersey.

    • Performance: EN 388 cut resistance Level 3–5; EN 407 contact heat resistance 500°C >10 s. Zero shrinkage under heat, full structural integrity. Used for foundry gloves, glass handling.

  2. Oxidized PAN (O-PAN) Blend Knits

    • Composition: 60% oxidized polyacrylonitrile, 40% FR viscose or aramid.

    • LOI: 45-55. Minimal smoke and toxic gas emission even at 1000°C in oxidizing atmosphere. Designed for aluminum smelter apron linings and blast furnace proximity.

    • Limitation: Low flex fatigue resistance; fiber becomes brittle under continuous dynamic load.

  3. Aluminized Laminated Aramid Knits (Radiant Heat Reflector)

    • Structure: 100% meta-aramid single jersey (120-150 g/m²) + aluminum vapor-coated PET film lamination.

    • Reflectance: 90-95% in the IR spectrum (0.8-10 µm).

    • Application: Thermal liner behind moisture barrier in firefighter turnout gear, inner layer of furnace gloves. Can raise EN ISO 11612 radiant heat (Class C) performance to C4.

  4. FR Wool/Para-aramid Blends (Molten Metal Optimized)

    • Composition: 70% Zirpro-treated wool (permanent FR), 25% para-aramid, 5% polyamide.

    • Mechanism: Wool’s high LOI (25-26) and curling/singe behavior dissipate the kinetic energy of molten metal droplets, preventing adhesion. Para-aramid provides tear resistance. Primary choice for EN 11611 Class 2 molten iron splash.

  5. Phase Change Material (PCM) Integrated FR Knits

    • Technology: Microencapsulated paraffin embedded in FR viscose or acrylic fibers.

    • Thermoregulation: Absorbs/releases latent heat around 28-32°C.

    • Application: Military, special operations firefighting gear to manage heat stress under high metabolic workloads.

Sector-Specific Performance Requirements Matrix

Sector / Risk Dominant Standard Critical Parameter Recommended Fabric Type Reason
Oil & Gas (Flash Fire) EN ISO 11612, NFPA 2112 TPP ≥ 6 cal/cm², predicted burn <50% Body-Guard 220, Para-Vis 180 FR viscose comfort, adequate thermal barrier
Structural Firefighting EN 469 HTI₂₄ ≥ 13 s, shrinkage <5% Fire-Blocker 270 (Code 395) High weight + para-aramid structural integrity
Heavy Welding EN 11611 Class 2 Molten iron droplets ≥ 35 drops (EN 348) Para-Vis 230, FR wool/para-aramid knit Para-aramid puncture resistance; viscose/wool anti-stick
Electric Arc (CAT 2) EN 61482-1-2, ATPV ≥ 8 cal/cm² Arc rating, low shrinkage Opti-Syn 220 Multi-fiber layered arc barrier, Tencel moisture management
ATEX Explosive Atmospheres EN 1149-5 Surface resistance < 2.5×10⁹ Ω All listed products (1-2% antistatic) Inherently dissipative fiber blend
Foundry (Blast Furnace Proximity) EN ISO 9185 Aluminum/iron splash resistance O-PAN blends, aluminized knits High LOI, reflectivity
Military / Ballistic Vest Underlayer MIL-Spec, NFPA 1971 Heat stress (Ret), friction coefficient Fire-Blocker 190 (single jersey), PCM Tencel blends Lightweight, moisture transfer, skin 

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