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Zinc Nitrate, Zinc Dinitrate, 7779-88-6

Zinc Nitrate, Zinc Dinitrate, 7779-88-6

ZINC NITRATE

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Zinc Nitrate
Chemical Name Zinc Nitrate
Synonyms (Turkish) Çinko Nitrat, Çinko Dinitrat, Nitrik Asit Çinko Tuzu
Synonyms (English) Zinc Nitrate, Zinc Dinitrate, Nitric Acid Zinc Salt
CAS Number 7779-88-6
Molecular Formula Zn(NO₃)₂
Molecular Weight 189.4 g/mol (Anhydrous) / 297.49 g/mol (Hexahydrate)
Appearance Colorless, odorless crystalline solid
Odor Odorless

CHEMICAL STRUCTURE

Zinc Nitrate Structure:

        O
        ||
Zn²⁺  [O—N—O⁻]  (x2)
        ||
        O

Structure Description:

  • Inorganic salt formed by zinc metal (or zinc compounds) and nitric acid.

  • Contains zinc in the +2 oxidation state (Zn²⁺).

  • Contains two nitrate anions (NO₃⁻).

  • Commonly found as the hexahydrate form (Zn(NO₃)₂·6H₂O).

  • Colorless, odorless crystalline solid.

  • Strong oxidizing agent (when heated).

  • Hygroscopic (absorbs moisture from air).

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Zinc Nitrate
Chemical Name Zinc Nitrate
Synonyms (Turkish) Çinko Nitrat, Çinko Dinitrat, Nitrik Asit Çinko Tuzu
Synonyms (English) Zinc Nitrate, Zinc Dinitrate, Nitric Acid Zinc Salt
CAS Number 7779-88-6
EC Number 231-943-8
Molecular Formula Zn(NO₃)₂
Molecular Weight 189.4 g/mol (Anhydrous) / 297.49 g/mol (Hexahydrate)
Chemical Class Inorganic salt; Nitrate; Zinc compound; Oxidizer
Source Synthetic (reaction of zinc or zinc compounds with nitric acid)
Physical State (20°C) Solid (crystalline)
Odor Odorless
Color Colorless

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Colorless, odorless crystalline solid Visual
Odor Odorless Olfactometric
Molecular Weight 189.4 g/mol (Anhydrous) / 297.49 g/mol (Hexahydrate) Calculated
Density (20°C) ~2.065 g/cm³ (Hexahydrate) ASTM D4052
Melting Point 36°C (Hexahydrate, in its own water of crystallization) DSC
Boiling Point Decomposes (at ~105-131°C for hexahydrate)
Decomposition Temperature ~105-131°C (releases NOx, ZnO)
Solubility in Water (20°C) ~93 g/100 mL (Hexahydrate) General Method
Solubility in Ethanol Soluble General Method
pH (5% Solution) ~4.0 – 6.0 (acidic) pH Meter
Stability Stable under normal conditions; Hygroscopic
Oxidizing Properties Strong oxidizer (when heated/decomposed)
Hygroscopicity High
Zinc (Zn) Content ~34.5% (Anhydrous); ~22.0% (Hexahydrate) AAS / ICP
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP
Chloride (Cl) ≤ 0.01% Titrimetric
Sulfate (SO₄) ≤ 0.01% Gravimetric
Loss on Drying ≤ 1.0% Gravimetric
Assay (Zn(NO₃)₂) ≥ 98.0% (various grades) Titrimetric / ICP

SECTION 3: ZINC NITRATE vs OTHER ZINC COMPOUNDS

Property Zinc Nitrate Zn(NO₃)₂ Zinc Sulfate ZnSO₄ Zinc Chloride ZnCl₂ Zinc Oxide ZnO
CAS Number 7779-88-6 7733-02-0 7646-85-7 1314-13-2
Molecular Weight 189.4 g/mol 161.47 g/mol 136.3 g/mol 81.38 g/mol
Zinc Content ~34.5% ~40.5% ~48.0% ~80.3%
Solubility in Water Very high High Very high Insoluble
pH (Solution) ~4.0-6.0 ~5.0-6.5 ~4.0-5.0 ~7.0-8.0
Oxidizing Properties Yes (nitrate) No No No
Hygroscopicity High Low High Low
Nitrate Nitrogen Yes (~14.8%) No No No
Primary Use Fertilizer, catalyst, coating Fertilizer, medicine Flux, disinfectant Rubber, ceramics, sunscreen

SECTION 4: MECHANISM OF ACTION

Property Description
Fertilizer (Zinc Source) Provides plant-available zinc (Zn²⁺); Zinc is an essential micronutrient for plants; Involved in enzyme activation and protein synthesis; Corrects zinc deficiencies in crops.
Fertilizer (Nitrogen Source) Provides plant-available nitrate nitrogen (NO₃⁻); Immediate nitrogen uptake; Promotes vegetative growth; Nitrate form is readily absorbed by roots.
Oxidizer Nitrate ion (NO₃⁻) acts as oxygen donor; Supports combustion at elevated temperatures; Decomposes to release nitrogen oxides and oxygen; Used in pyrotechnic compositions.
Mordant (Textile) Binds with dyes to form insoluble complexes; Fixes dyes to textile fibers; Provides color fastness; Used in textile dyeing and printing.
Cross-linking Agent Improves acid resistance of fibers; Used in fiber production (similar to magnesium chloride); Swelling effect on acetate fibers.
Catalyst Acts as a catalyst in organic reactions; Used in paint, resin, and polymer synthesis; Catalyzes esterification and other reactions.
Electrolyte (Electroplating) Provides zinc ions (Zn²⁺) for electrodeposition; Used in zinc plating baths; Surface treatment and coating applications.

SECTION 5: PRODUCTION PROCESS

Industrial Production Methods:

Method 1: Dissolution of Zinc Metal in Nitric Acid

Reaction: Zn + 2HNO₃ → Zn(NO₃)₂ + H₂↑

Description: Pure zinc metal is reacted with nitric acid. The reaction produces zinc nitrate, water, and hydrogen gas. The resulting solution is evaporated and crystallized to obtain the desired hydrate form.

Method 2: Dissolution of Zinc Oxide in Nitric Acid

Reaction: ZnO + 2HNO₃ → Zn(NO₃)₂ + H₂O

Description: Zinc oxide is dissolved in nitric acid. This method is more controlled and produces less gas. The solution is then evaporated and crystallized.

Method 3: Dissolution of Zinc Hydroxide in Nitric Acid

Reaction: Zn(OH)₂ + 2HNO₃ → Zn(NO₃)₂ + 2H₂O

Description: Zinc hydroxide is dissolved in nitric acid. The solution is evaporated and crystallized to obtain the final product.

SECTION 6: FUNCTIONAL PROPERTIES

Property Description
Fertilizer (Micronutrient) Water-soluble zinc and nitrogen source; Provides ~22% zinc (hexahydrate) and ~11% nitrate nitrogen; Corrects zinc deficiencies in crops; Used in liquid fertilizer formulations.
Oxidizer Supports combustion at elevated temperatures; Decomposes to release nitrogen oxides and oxygen; Used in pyrotechnic compositions.
Mordant (Textile) Color-fixing agent in textile dyeing; Forms insoluble complexes with dyes; Improves color fastness; Used in textile printing.
Catalyst Catalyst for organic reactions; Paint, resin, and polymer synthesis; Catalyzes esterification and other reactions.
Cross-linking Agent Improves acid resistance of fibers; Used in fiber production; Swelling effect on acetate fibers; Improves dye penetration.
Electrolyte (Electroplating) Provides zinc ions for electroplating; Used in zinc plating baths; Surface finishing.
Analytical Reagent Used as analytical reagent in laboratories; Zinc plasma solution; Standard calibration solutions; Starting material for synthesis.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Agriculture Fertilizer (zinc and nitrogen source) Liquid fertilizer formulations; Foliar sprays; Fertigation; Corrects zinc deficiency in crops; Provides essential micronutrient.
Textile Industry Mordant, cross-linking agent Textile dyeing and printing (color fixing); Fiber production (improves acid resistance); Acetate fiber swelling agent; Improves dye penetration.
Chemical Industry Catalyst, intermediate Paint, resin, and polymer synthesis; Catalyst for esterification reactions; Production of zinc acetate (with acetic anhydride); Latex coagulation.
Metal Coating (Electroplating) Electrolyte, surface treatment Zinc electroplating baths; Surface finishing; Corrosion protection coatings.
Analytical Chemistry Analytical reagent, standard solution Zinc plasma solution; Calibration standards; Atomic absorption spectroscopy (AAS); Starting material for synthesis.
Pyrotechnics Oxidizer Pyrotechnic compositions; Fireworks and signal flares; Color stabilization.
Corrosion Inhibitors Preservative Anti-corrosion product formulations; Corrosion inhibitor protection; Stabilizer for inhibitor formulations.

SECTION 8: SAMPLE FORMULATIONS

Liquid Fertilizer (Zinc Solution):

Component Amount
Zinc Nitrate Hexahydrate 10 – 20%
Water To 100%
Surfactants (optional) As required

Instructions: Dissolve zinc nitrate hexahydrate in water with stirring; Adjust pH as required; Use as foliar spray or fertigation; Apply according to crop needs.

Electroplating Bath Solution:

Component Amount
Zinc Nitrate (source of Zn²⁺) 10 – 20%
Electrolyte (KCl, NH₄Cl, etc.) As required
Water To 100%
Brighteners, Additives As required

Instructions: Dissolve zinc nitrate and other components in water; Adjust pH and temperature; Use in electroplating bath with appropriate current density.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Fertilizer Grade Technical Grade Reagent/Analytical Grade Test Method
Appearance Colorless to white crystals Colorless to white crystals Colorless to white crystals Visual
Assay (Zn(NO₃)₂·6H₂O) ≥ 98.0% ≥ 99.0% ≥ 99.5% Titrimetric / ICP
Zinc Content (Zn) ≥ 21.5% ≥ 22.0% ≥ 22.0% AAS / ICP
pH (5% Solution) 4.0 – 6.0 4.0 – 6.0 4.0 – 6.0 pH Meter
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% Gravimetric
Water Insoluble ≤ 0.05% ≤ 0.02% ≤ 0.01% Gravimetric
Chloride (Cl) ≤ 0.02% ≤ 0.01% ≤ 0.005% Titrimetric
Sulfate (SO₄) ≤ 0.02% ≤ 0.01% ≤ 0.005% Gravimetric
Heavy Metals (as Pb) ≤ 10 ppm ≤ 5 ppm ≤ 5 ppm AAS / ICP
Iron (Fe) ≤ 0.01% ≤ 0.005% ≤ 0.002% AAS / ICP
Lead (Pb) ≤ 2 ppm ≤ 1 ppm ≤ 1 ppm AAS / ICP

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 1,000 – 2,000 mg/kg (moderate toxicity)
Acute Dermal Toxicity Low toxicity; May cause irritation
Skin Irritation May cause irritation
Eye Irritation May cause severe irritation
Inhalation Toxicity May cause respiratory irritation; Inhalation of dust may be harmful
Chronic Toxicity Zinc compounds may cause gastrointestinal irritation upon chronic exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No specific reproductive toxicity at normal levels
Environmental Toxicity Toxic to aquatic organisms; May cause long-term adverse effects in the aquatic environment.
Special Toxicity Note Zinc nitrate is an oxidizer and irritant; Causes skin, eye, and respiratory tract irritation; Harmful if swallowed; Use appropriate personal protective equipment; Avoid environmental release; Zinc compounds require careful handling.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Oxidizing Solids Category 2 H272
Acute Toxicity (Oral) Category 4 H302
Skin Irritation Category 2 H315
Eye Irritation Category 2 H319
Acute Aquatic Toxicity Category 1 H400
Chronic Aquatic Toxicity Category 1 H410

Signal Word: WARNING

Hazard Pictograms: GHS03 (Flame Over Circle), GHS07 (Exclamation Mark), GHS09 (Environment)

Hazard Statements (H-Codes):

Code Statement
H272 May intensify fire; oxidizer
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
2 0 1 OX
(Moderate health hazard) (Non-flammable) (Mild reactivity) (Oxidizer)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P220 Keep away from clothing and other combustible materials
P221 Take any precaution to avoid mixing with combustibles
P264 Wash hands thoroughly after handling
P270 Do not eat, drink, or smoke when using this product
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P332+P313 If skin irritation occurs: Get medical advice/attention
P337+P313 If eye irritation persists: Get medical advice/attention
P362+P364 Take off contaminated clothing and wash it before reuse
P370+P378 In case of fire: Use water spray, foam, or dry chemical powder
P391 Collect spillage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If respiratory irritation develops, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, get medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. Do not induce vomiting. Seek medical attention if large quantities are ingested or if feeling unwell.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable but is a strong oxidizer. Will support and accelerate combustion of other materials.
Hazards Arising from Fire Thermal decomposition produces nitrogen oxides (NOx), nitrogen dioxide (NO₂), and zinc oxide (ZnO) fumes; May release toxic fumes.
Suitable Extinguishing Media Water spray (large quantities), water fog, foam, dry chemical powder.
Unsuitable Extinguishing Media CO₂ (may be ineffective), water jet (may spread burning material)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing, firefighting goggles.
Special Precautions Evacuate area; Prevent fire-fighting water from entering waterways; Cool fire-exposed containers with water spray; Avoid mixing with combustible materials during fire fighting.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM MOISTURE and CONTAMINATION; Separate from combustible materials and reducing agents.
Container Requirements Tightly closed, moisture-proof containers (PE-lined bags, HDPE drums).
Materials to Protect From Moisture, heat, combustible materials, organic substances, reducing agents
Shelf Life 24 – 36 months (in unopened original packaging, under proper storage conditions).
Stability Note Stable under recommended storage conditions; Hygroscopic; Absorbs moisture from air; May deliquesce if exposed to high humidity; Protect from light and heat.
Special Storage Requirements Store in a dry, cool place; Avoid exposure to air and moisture; Opened containers must be resealed immediately; Keep away from combustible materials.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
PE-Lined Paper Bag 25 kg, 50 kg PE-lined kraft paper bag (moisture-proof)
Plastic Bag 10 kg, 25 kg, 50 kg PE bag (inner-lined, sealed, moisture-proof)
Plastic Drum 25 kg, 50 kg HDPE / Polypropylene (moisture-proof, chemical-resistant)
Fiber Drum 25 kg, 50 kg PE-lined fiberboard drum
FIBC / Big Bag 500 kg, 1000 kg PE-lined, moisture-resistant PP woven bag

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number UN 1514 (Zinc Nitrate)
Hazard Class Class 5.1 - Oxidizing Substances
Packing Group II
ADR/RID Class 5.1; UN 1514; Packing Group II
IMDG Code Class 5.1; UN 1514; Marine pollutant: Yes
IATA (Air) Class 5.1; UN 1514; Packing Group II
Transport Label Oxidizer (Class 5.1)
Marine Pollutant Yes
Special Transport Requirements Segregation from combustibles and reducing agents; Secure from unauthorized access; Protect from moisture.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Regulated as oxidizing substance; Environmental hazard classification.
USA (TSCA) Listed (TSCA Inventory)
USA (EPA) Regulated under toxic substances and environmental programs.
Turkey Regulated as hazardous chemical; Subject to KKDIK regulation; Environmental Ministry controls; Storage and transportation permits required.
IARC Not classified (non-carcinogenic)
NTP Not listed
OSHA Regulated as oxidizer and irritant; Hazard Communication Standard.
California (Prop 65) Not listed
Fertilizer Regulations Subject to national fertilizer standards; Heavy metal limits apply.

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Çinko Nitrat, Çinko Dinitrat, Nitrik Asit Çinko Tuzu
English Names Zinc Nitrate, Zinc Dinitrate, Nitric Acid Zinc Salt
CAS Number 7779-88-6
EC Number 231-943-8
HS Code 2834.29

SECTION 20: SUMMARY TABLE

Parameter Value
Product Zinc Nitrate
CAS Number 7779-88-6
Molecular Formula Zn(NO₃)₂
Molecular Weight 189.4 g/mol (Anhydrous) / 297.49 g/mol (Hexahydrate)
Appearance Colorless, odorless crystalline solid
Melting Point 36°C (Hexahydrate)
Solubility in Water Very high (~93 g/100 mL at 20°C)
Primary Functions Fertilizer, oxidizer, mordant, catalyst, electrolyte
Main Application Areas Agriculture (fertilizer), textile, chemical, metal coating, analytical chemistry, pyrotechnics
Shelf Life 24 – 36 months
GHS Signal Word WARNING
UN Number 1514
Hazard Class Class 5.1 (Oxidizer)
Packing Group II
Special Properties Strong oxidizer; Hygroscopic; Water-soluble zinc and nitrogen source; ~22% Zn + ~11% nitrate nitrogen; Marine pollutant; Environmental hazard.

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • STRONG OXIDIZER (H272): Will intensify fire and support combustion. KEEP AWAY FROM COMBUSTIBLE MATERIALS.

  • HARMFUL IF SWALLOWED (H302): Avoid ingestion; Use appropriate safety measures.

  • CAUSES SKIN AND EYE IRRITATION (H315, H319): Personal protective equipment is mandatory.

  • VERY TOXIC TO AQUATIC LIFE (H400, H410): AVOID RELEASE TO THE ENVIRONMENT.

  • HYGROSCOPIC: Absorbs moisture from air; Store in tightly closed containers.

  • DECOMPOSITION: Decomposes upon heating, releasing toxic nitrogen oxides (NOx), nitrogen dioxide (NO₂), and zinc oxide (ZnO) fumes.

  • HEAT SENSITIVE: May decompose above 105-131°C.

  • ZINC COMPOUND: Zinc is a heavy metal; handle with care; dispose of properly.

  • ENVIRONMENTAL HAZARD: Marine pollutant (UN 1514).

BEST PRACTICE RECOMMENDATIONS:

  • Agriculture (Fertilizer): Use as liquid fertilizer and zinc source; Dosage: 10-20% in liquid formulations; Apply as foliar spray or fertigation; Follow agricultural guidelines; Corrects zinc deficiencies.

  • Textile Industry: Use as mordant and cross-linking agent; Dyeing and printing applications; Fiber production; Improves acid resistance and dye penetration; Dosage: 1-5% (depending on application).

  • Chemical Industry: Use as catalyst and intermediate; Paint, resin, and polymer synthesis; Latex coagulation; Production of zinc acetate (with acetic anhydride).

  • Metal Coating: Use as electrolyte in zinc plating baths; Surface finishing; Corrosion protection; Dosage: 10-20% in electroplating baths.

  • Handling: Use in well-ventilated areas; Avoid dust formation; Use dust masks (N95/FFP2) when handling powder; Use gloves and safety goggles; Avoid contact with eyes and skin.

  • Personal Protective Equipment: MANDATORY: Chemical-resistant gloves, safety goggles or face shield, protective clothing, dust mask (N95/FFP2 or higher), fire-retardant clothing.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using; Remove contaminated clothing and wash before reuse.

  • Storage: Store in tightly closed, moisture-proof containers; Store in cool, dry, well-ventilated area; Protect from moisture and heat; Keep away from combustible materials; Opened containers must be resealed immediately; Shelf life: 24-36 months under proper conditions.

  • Spill Management: Sweep or vacuum (HEPA) and place in suitable sealed container; Avoid dust formation; Do not allow entry into drains or waterways; Dispose as hazardous waste.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Hazardous waste (oxidizer, environmental hazard); Use authorized disposal facilities.

DETECTION METHODS:

Method Description Advantages Disadvantages
AAS / ICP Zinc and trace element analysis High sensitivity, accurate, specific High cost, requires expertise
Titrimetric Zinc determination by complexometric titration Simple, standard method Requires careful technique
UV-Vis Spectrophotometry Colorimetric determination Rapid, moderate cost Requires calibration
Ion Chromatography Nitrate ion determination Specific nitrate analysis High cost, requires expertise
Gravimetric Analysis Zinc determination by precipitation Standard method Time-consuming
pH Meter pH of solution Simple, rapid Indicative only

ZINC NITRATE vs ALTERNATIVES COMPARISON:

Product Chemical Name / E Code Application Strength Weakness Status
Zinc Nitrate Zn(NO₃)₂ Agriculture, textile, catalyst Soluble, oxidizer, N + Zn source Environmental toxicity, hygroscopic Regulated
Zinc Sulfate ZnSO₄ Agriculture, medicine Cheap, stable, soluble No nitrogen, acidic Widely used
Zinc Chloride ZnCl₂ Flux, disinfectant Soluble, zinc source Corrosive, hygroscopic Widely used
Zinc Oxide ZnO Rubber, ceramics, sunscreen High zinc content, stable Insoluble, no nitrogen Widely used
Zinc Acetate Zn(CH₃COO)₂ Catalyst, dietary supplement Organic soluble Lower zinc content Limited

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Zinc nitrate is a strong oxidizer and environmental hazard; handle with appropriate precautions and avoid environmental release.

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