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Cobalt sulfate anhydrous, Cobalt sulfate, CoSO4, 10124-43-3 

Cobalt sulfate anhydrous, Cobalt sulfateCoSO4, 10124-43-3 

Cobalt sulfate anhydrous

CAS: 10124-43-3;10393-49-4

Molecular Formula: CoO4S

Names and Identifiers

Name Cobalt sulfate anhydrous
Synonyms CoSO4
Cobalt sulfate
Cobalt(II) sulfate
Cobalt (2+) sulfate
cobaltsulfate(coso4)
cobaltous sulfate Cobalt
Cobalt sulfate anhydrous
CAS 10124-43-3
10393-49-4
EINECS 233-334-2
InChI InChI=1/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)/p-2

Physico-chemical Properties

Molecular Formula CoO4S
Molar Mass 155
Density d425 3.71
Melting Point decomposes at 1140℃ [JAN85]
Boling Point 330°C at 760 mmHg
Water Solubility dissolves slowly in boiling H2O [MER06]; g/100g solution H2O: 19.7 ± 0.1 (0°C), 27.2 ± 0.1 (25°C), 27.8 (100°C); solid phase, CoSO4 · 7H2O (0°C, 25°C), CoSO4 ·H2O (100°C) [KRU93]
Solubility H2O: soluble
Vapor Presure 0Pa at 20℃
Appearance red orthorhombic crystals
Merck 13,2473
Physical and Chemical Properties Brown-yellow red crystals, soluble in water and methanol, ethanol-soluble, easy weathering in the air.
cobalt sulfate is widely used as a desiccant for electroplating, ceramic colorants, inks and paints. Animal experiments have confirmed that cobalt sulfate can cause adrenal tumors and lung tumors. On World Health Organization (WHO), the International Agency for Research on Cancer published a preliminary list of carcinogens reference, Cobalt sulfate and other soluble cobalt (II) salts in the 2B list of carcinogens.
Use For the electroplating industry and glaze coloring

Risk and Safety

Risk Codes R49 - May cause cancer by inhalation
R42/43 - May cause sensitization by inhalation and skin contact.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R22 - Harmful if swallowed
R68 - Possible risk of irreversible effects
R60 - May impair fertility
Safety Description S53 - Avoid exposure - obtain special instructions before use.
S23 - Do not breathe vapour.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
S60 - This material and its container must be disposed of as hazardous waste.
S22 - Do not breathe dust.
UN IDs UN 3082 9/PG 3
WGK Germany 2

Reference Information

toxic sulfur oxides and cobalt-containing compounds

Application cobalt sulfate is used in ceramic glaze and paint drying agent, also used in electroplating, alkaline batteries, production of cobalt-containing pigments and other cobalt products, also used in catalysts, Analytical reagents, feed additives, tire adhesives, Lithopone additives.
for electroplating industry and glaze coloring
solubility in water (g/100ml) grams dissolved per 100ml of water at different temperatures (℃): 25.5g/0 ℃;30.5g/10 ℃;36.1g/20 ℃;42g/30 ℃;48.8g/40 ℃; 55g/60 ℃;53.8g/80 ℃;45.3g/90 ℃;38.9g/100 ℃
production method preparation method the hydrated cobalt sulfate CoSO4 · 7H2O is first heated at a temperature of about 100 ℃ for 1H, the temperature was then raised to 250-350 °c and heating was continued to completely dehydrate the Anhydrous cobalt sulfate.
category toxic substances
toxicity grade high toxicity
Acute toxicity oral-rat LD50 424 mg/kg
flammability hazard characteristics non-combustible;
storage and transportation characteristics The warehouse is low temperature, ventilated and dry, and stored separately from food raw materials
extinguishing agent water, carbon dioxide, dry powder, sand

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