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Calcium Oxide, Quicklime, Burnt Lime, Caustic Lime, Flux Lime, E529, 1305-78-8

Calcium Oxide, Quicklime, Burnt Lime, Caustic Lime, Flux Lime, E529, 1305-78-8

CALCIUM OXIDE (CaO - QUICKLIME - E529)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Calcium Oxide
Chemical Name Calcium Oxide
Synonyms (Turkish) Kalsiyum Oksit, Sönmemiş Kireç, Yanmış Kireç, Kalsiyum Monooksit, Kireç
Synonyms (English) Calcium Oxide, Quicklime, Burnt Lime, Calx, Calcia, Caustic Lime, Flux Lime
E Number E529
CAS Number 1305-78-8
EC Number 215-138-9
Molecular Formula CaO
Molecular Weight 56.08 g/mol
Appearance White to yellowish or brownish powder or crystalline solid
Odor Odorless

CHEMICAL STRUCTURE

Calcium Oxide Structure:

    Ca²⁺  O²⁻

Structure Description:

  • Ionic compound composed of calcium cation (Ca²⁺) and oxide anion (O²⁻).

  • White to yellowish or brownish crystalline solid.

  • Strongly basic oxide (alkaline earth metal oxide).

  • Reacts exothermically with water to form calcium hydroxide [Ca(OH)₂].

  • High melting and boiling points.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Calcium Oxide
Chemical Name Calcium Oxide
Synonyms (Turkish) Kalsiyum Oksit, Sönmemiş Kireç, Yanmış Kireç, Kalsiyum Monooksit, Kireç
Synonyms (English) Calcium Oxide, Quicklime, Burnt Lime, Calx, Calcia, Caustic Lime, Flux Lime, Airlock Lime
E Number E529
CAS Number 1305-78-8
EC Number 215-138-9
Molecular Formula CaO
Molecular Weight 56.08 g/mol
Chemical Class Inorganic oxide; Basic oxide; Alkaline earth metal oxide
Source Natural (calcination of limestone/calcium carbonate)
Physical State (20°C) Solid (powder or crystalline)
Odor Odorless
Color White to yellowish or brownish

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White to yellowish or brownish powder or crystalline solid Visual
Odor Odorless Olfactometric
Molecular Weight 56.08 g/mol Calculated
Density 3.34 g/cm³ ASTM D4052
Melting Point 2613°C DSC
Boiling Point 2850 – 3850°C (varies by literature)
Solubility in Water Reacts (exothermic) to form Ca(OH)₂
Solubility in Acids Soluble General Method
Solubility in Alcohol Insoluble General Method
pH (Slurry) ~12.4 (strongly alkaline)
Stability Stable; Reacts with water and acids
Reactivity Strongly reactive with water (exothermic)
Hygroscopicity High (absorbs moisture from air)
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP
Magnesium Oxide (MgO) ≤ 1.0%
Silica (SiO₂) ≤ 1.0%
Iron (Fe₂O₃) ≤ 0.5%
Alumina (Al₂O₃) ≤ 0.5%
Loss on Ignition ≤ 2.0% Gravimetric
Assay (CaO) ≥ 90.0 – 98.0% (grade dependent) Titrimetric

SECTION 3: CALCIUM OXIDE vs OTHER CALCIUM COMPOUNDS

Property Calcium Oxide (CaO) Calcium Hydroxide Ca(OH)₂ Calcium Carbonate CaCO₃ Calcium Chloride CaCl₂
CAS Number 1305-78-8 1305-62-0 471-34-1 10043-52-4
Molecular Weight 56.08 g/mol 74.09 g/mol 100.09 g/mol 110.98 g/mol
Solubility in Water Reacts (exothermic) Slightly soluble Insoluble Highly soluble
pH (1% Solution) ~12.4 ~12.4 ~9.5 ~8.0
Reactivity Very high Moderate Low Moderate
Heat of Hydration High (exothermic) None None Moderate
Primary Use Cement, steel, water treatment pH adjustment, mortars Construction, antacid De-icing, drying
CO₂ Content None None ~44% None
Applications High-temperature processes Building materials, water treatment Construction, agriculture De-icing, oil drilling

SECTION 4: MECHANISM OF ACTION

Property Description
Slaking (Hydration) Reacts exothermically with water: CaO + H₂O → Ca(OH)₂ + Heat (64 kJ/mol); Produces calcium hydroxide (slaked lime); Releases significant heat; Used in lime slaking processes.
Basicity / Neutralization Strongly basic oxide; Neutralizes acids to form calcium salts; Used in wastewater treatment (acid neutralization); pH adjustment in various processes.
Fluxing Action (Metallurgy) Reacts with acidic impurities (SiO₂, P₂O₅, S); Forms slag with lower melting point; Removes impurities from molten steel; Improves steel quality.
Coagulation (Water Treatment) Raises pH of water; Precipitates heavy metals as hydroxides; Coagulates suspended solids; Clarifies water.
Carbonation Absorbs CO₂ from air: CaO + CO₂ → CaCO₃; Forms calcium carbonate (limestone) upon exposure to air; Used in CO₂ capture applications.
Drying Acts as a desiccant (drying agent); Absorbs moisture from gases and liquids; Used in dehydration processes.

SECTION 5: PRODUCTION PROCESS

Industrial Production Method (Calcination):

Reaction: CaCO₃ (s) → CaO (s) + CO₂ (g)

Process Flow:
Limestone (Calcium Carbonate) → Quarrying → Crushing → Sizing → Calcination (Kiln, 900-1200°C) → Calcium Oxide (Quicklime) → Cooling → Screening → Packing/Silo Storage

Step-by-Step Description:

  1. Raw Material: High-quality limestone (calcium carbonate, CaCO₃) is quarried.

  2. Crushing and Sizing: Limestone is crushed and screened to appropriate size.

  3. Calcination: Crushed limestone is heated in a kiln (rotary kiln, vertical shaft kiln) at 900-1200°C.

  4. Decomposition: Calcium carbonate decomposes into calcium oxide (quicklime) and carbon dioxide gas.

  5. Cooling: The hot quicklime is cooled in a cooler.

  6. Screening: Cooled quicklime is screened to remove fines.

  7. Storage: Product is stored in sealed silos or packaged immediately to prevent hydration.

Note: The process is highly energy-intensive. The quality of the limestone (purity) determines the quality of the quicklime.

SECTION 6: FUNCTIONAL PROPERTIES

Property Description
Fluxing Agent (Metallurgy) Removes impurities (sulfur, phosphorus, silica) from molten metals; Forms slag; Improves steel quality and purity.
Neutralizing Agent (Water Treatment) Neutralizes acidic wastewater; Raises pH of acidic streams; Precipitates heavy metals (e.g., Fe, Cu, Zn, Pb).
Binder (Construction) Reacts with water and CO₂ to harden; Used in cement and mortar production; Base material for lime-based plasters and mortars.
Soil Amendment (Agriculture) Raises soil pH (corrects acidity); Provides calcium to plants; Improves soil structure and fertility.
Dehydrating Agent Absorbs moisture from gases and liquids; Used as a desiccant; Prevents moisture in various applications.
Precipitating Agent Precipitates impurities from solutions; Used in sugar refining and paper manufacturing; Clarifies liquids.
Catalyst Support Used as a support material for catalysts; Provides high surface area; Used in chemical processes.

SECTION 7: MAIN APPLICATION AREAS

Industry / Sector Function Typical Use
Construction / Cement Binder, cement component Portland cement production (clinker formation); Lime-based mortars and plasters; Concrete additive; Onsuz üretim mümkün değil.
Metallurgy Fluxing agent, slag former Steelmaking (basic oxygen furnace); Removes sulfur, phosphorus, silica; Improves steel quality; Nickel and copper smelting.
Water & Wastewater Treatment Neutralizer, coagulant, pH adjuster Acid neutralization; Heavy metal precipitation; pH adjustment; Drinking water treatment (softening).
Agriculture Soil amendment, fertilizer additive Soil pH adjustment (lime application); Corrects soil acidity; Provides calcium; Improves soil structure.
Paper Industry Precipitant, pulping agent Pulping and bleaching processes; Calcium carbonate precipitation; Paper coating and filling.
Food & Pharmaceutical Processing aid (E529) Sugar refining (clarification); Gelatin production; Food additive (E529); Calcium fortification; pH adjustment.
Energy & Technology CO₂ capture, fuel cells Solid oxide fuel cells; CO₂ capture and sequestration; Oxygen production systems.
Glass Industry Stabilizer, flux Glass manufacturing (lime component); Improves durability; Reduces melting temperature.
Chemical Industry Desiccant, catalyst support Drying agent for gases and liquids; Catalyst support; Production of calcium compounds.
Animal Feed Mineral supplement Calcium source in animal feed formulations; Poultry and livestock nutrition.

SECTION 8: SAMPLE FORMULATIONS

Lime Slurry (For Water Treatment):

Component Amount
Calcium Oxide (Quicklime) 10 – 20%
Water 80 – 90%

Instructions: Slowly add quicklime to water with continuous stirring (caution: exothermic reaction); Use appropriate equipment; Allow to cool; Dilute as needed for application.

Lime Mortar (For Construction):

Component Amount
Calcium Oxide (Slaked to putty) 1 part
Sand 3 parts
Water As required

Instructions: Slake quicklime with water to form lime putty; Mix with sand and water; Use within 1-2 days; Allow to harden by carbonation.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Construction Grade Metallurgical Grade Food/Pharma Grade (E529) Test Method
Appearance White to grey powder White to grey powder White powder Visual
Assay (CaO) ≥ 90.0% ≥ 92.0% ≥ 98.0% Titrimetric
Magnesium Oxide (MgO) ≤ 2.0% ≤ 1.0% ≤ 0.5%
Silica (SiO₂) ≤ 1.0% ≤ 1.0% ≤ 0.5%
Loss on Ignition ≤ 2.0% ≤ 2.0% ≤ 1.0% Gravimetric
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP
Particle Size Customer requirement Customer requirement Customer requirement Sieve

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 3,050 mg/kg (moderate toxicity)
Acute Dermal Toxicity Corrosive; Severe skin burns
Skin Irritation Corrosive (Category 1A/1B/1C)
Eye Irritation Serious eye damage (Category 1)
Inhalation Toxicity May cause respiratory irritation; Corrosive to respiratory tract
Chronic Toxicity Long-term exposure may cause lung damage
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity at normal levels
Environmental Toxicity Harmful to aquatic life; pH increase in water bodies
Special Toxicity Note Corrosive; Causes severe skin burns and eye damage (H314); Harmful if swallowed (H302); May cause respiratory irritation (H335); Reacts exothermically with water (can cause burns); Use appropriate personal protective equipment; Keep away from moisture.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Acute Toxicity (Oral) Category 4 H302
Skin Corrosion/Irritation Category 1 H314
Serious Eye Damage Category 1 H318
Specific Target Organ Toxicity (Single) Category 3 H335

Signal Word: DANGER

Hazard Pictograms: GHS05 (Corrosive), GHS07 (Exclamation Mark)

Hazard Statements (H-Codes):

Code Statement
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
3 0 2 W
(Severe health hazard - corrosive) (Non-flammable) (Moderate reactivity - reacts with water) (Reacts with water)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P310 Immediately call a POISON CENTER/doctor
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages
P363 Wash contaminated clothing before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If breathing is difficult, give oxygen. If respiratory irritation develops, seek medical attention.
Skin Contact IMMEDIATELY REMOVE CONTAMINATED CLOTHING. Brush off dry particles. Rinse with plenty of water for at least 15 minutes. Get immediate medical attention.
Eye Contact IMMEDIATELY rinse with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Get immediate medical attention.
Ingestion DO NOT INDUCE VOMITING. Rinse mouth. Drink plenty of water (only if conscious). Get immediate medical attention.
Note Calcium oxide is corrosive; burns from water contact (slaking reaction) generate heat; do not use wet bandages for dry powder on skin without first brushing off.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-flammable. However, reacts with water to release heat (exothermic).
Hazards Arising from Fire Not combustible; But may cause fire/explosion when in contact with water (heat generation).
Suitable Extinguishing Media Dry chemical powder, sand, CO₂ (for surrounding fires).
Unsuitable Extinguishing Media Water, foam (reacts violently with water)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing, chemical-resistant gloves.
Special Precautions DO NOT USE WATER on burning calcium oxide; Avoid contact with water; Evacuate area; Use dry extinguishing agents.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM MOISTURE; Keep away from water and acids; Store separate from flammable materials.
Container Requirements Tightly closed, moisture-proof containers (sealed silos, PE-lined bags, HDPE drums).
Materials to Protect From Moisture, water, acids, organic materials
Shelf Life 12 – 24 months (in unopened original packaging, under proper storage conditions).
Stability Note Stable under recommended storage conditions; Highly hygroscopic (absorbs moisture); Reacts with CO₂ in air to form CaCO₃; May deteriorate (slake) if exposed to moisture.
Special Storage Requirements Store in a dry, cool place; Avoid exposure to air and moisture; Opened containers must be resealed immediately; Keep away from water and acids.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
PE-Lined Paper Bag 25 kg, 40 kg, 50 kg PE-lined kraft paper bag (moisture-proof)
Plastic Bag 10 kg, 25 kg, 50 kg PE bag (inner-lined, sealed, moisture-proof)
Plastic Drum 25 kg, 50 kg, 100 kg HDPE / Polypropylene (moisture-proof)
Fiber Drum 25 kg, 50 kg PE-lined fiberboard drum
FIBC / Big Bag 500 kg, 1000 kg, 1500 kg PE-lined, moisture-resistant PP woven bag
Silo (Bulk) Custom quantities Sealed steel silo (with inert gas blanketing)

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number UN 1910 (Calcium Oxide)
Hazard Class Class 8 - Corrosive Substances
Packing Group III
ADR/RID Class 8; UN 1910; Packing Group III
IMDG Code Class 8; UN 1910; Marine pollutant: No
IATA (Air) Class 8; UN 1910; Packing Group III
Transport Label Corrosive (Class 8)
Marine Pollutant No
Special Transport Requirements PROTECT FROM MOISTURE; Segregation from water, acids, and combustible materials; Handle with care; Keep dry.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Regulated as corrosive substance; E529 approved as food additive.
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) GRAS (Generally Recognized as Safe); 21 CFR 184.1210; Approved as food additive (E529).
Turkey Regulated as hazardous chemical; Subject to KKDIK regulation; Ministry of Environment and Ministry of Agriculture controls; Food grade E529 requires Ministry of Health approval.
IARC Not classified (non-carcinogenic)
NTP Not listed
OSHA Regulated as corrosive; PEL: 5 mg/m³ (respirable dust).
California (Prop 65) Not listed
Halal Yes (mineral source, not from animals)
Kosher Yes (with certification)
Vegan Yes (mineral, no animal ingredients)

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Kalsiyum Oksit, Sönmemiş Kireç, Yanmış Kireç, Kalsiyum Monooksit, Kireç
English Names Calcium Oxide, Quicklime, Burnt Lime, Calx, Calcia, Caustic Lime, Flux Lime
Sectoral Names Construction: Quicklime; Metallurgy: Flux Lime, Burnt Lime; Water Treatment: Calcium Oxide; Agriculture: Lime, Calcia
E Number E529
CAS Number 1305-78-8
EC Number 215-138-9
HS Code 2825.90

SECTION 20: SUMMARY TABLE

Parameter Value
Product Calcium Oxide (Quicklime - E529)
CAS Number 1305-78-8
E Number E529
Molecular Formula CaO
Molecular Weight 56.08 g/mol
Appearance White to yellowish/brownish powder or crystalline solid
Melting Point 2613°C
Density 3.34 g/cm³
Reaction with Water Exothermic (CaO + H₂O → Ca(OH)₂)
Primary Functions Fluxing agent, neutralizer, binder, soil amendment, desiccant
Main Application Areas Construction (cement), metallurgy (steel), water treatment, agriculture, paper, food (E529), energy, glass
Shelf Life 12 – 24 months
GHS Signal Word DANGER
UN Number 1910
Hazard Class Class 8 (Corrosive)
Packing Group III
Special Properties Strong base; Corrosive; Reacts violently with water (exothermic); Hygroscopic; High temperature stability; Essential in cement and steel production; FDA GRAS; Vegan; Halal.

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • CORROSIVE (H314, H318): Causes severe skin burns and eye damage. PERSONAL PROTECTIVE EQUIPMENT IS MANDATORY.

  • REACTS VIOLENTLY WITH WATER (exothermic): Generates heat and steam; Can cause burns and splashing. DO NOT USE WATER on spills/fires.

  • HARMFUL IF SWALLOWED (H302): Avoid ingestion.

  • MAY CAUSE RESPIRATORY IRRITATION (H335): Avoid inhalation of dust.

  • HYGROSCOPIC: Absorbs moisture from air; Store in tightly closed, moisture-proof containers.

  • REACTS WITH CO₂: Absorbs CO₂ from air to form calcium carbonate (CaCO₃); Affects product quality over time.

  • HIGH TEMPERATURE: Extreme melting point; Suitable for high-temperature processes.

  • ESSENTIAL INDUSTRY: Onsuz çimento ve çelik üretimi mümkün değildir.

  • FOOD GRADE: E529 approved; High purity required for food applications.

BEST PRACTICE RECOMMENDATIONS:

  • Construction / Cement: Use as cement component and binder; Essential for clinker formation; Onsuz çimento üretimi mümkün değil; Use in lime-based mortars and plasters.

  • Metallurgy: Use as fluxing agent and slag former; Steelmaking (basic oxygen furnace); Removes sulfur, phosphorus, silica; Essential in steel production.

  • Water Treatment: Use as neutralizer and coagulant; Acid neutralization; Heavy metal precipitation; pH adjustment; Drinking water softening.

  • Agriculture: Use as soil amendment (lime application); Corrects soil acidity; Apply 1-5 tons per hectare; Provides calcium; Improves soil structure.

  • Paper Industry: Use in pulping and bleaching processes; Calcium carbonate precipitation; Paper coating and filling.

  • Food & Pharmaceutical: Use as processing aid (E529); Sugar refining; Gelatin production; Calcium fortification; Only food-grade material.

  • Handling: Use in well-ventilated areas; Avoid dust formation; Use dust masks (N95/FFP2) when handling powder; Use gloves and safety goggles; Avoid contact with water; Add quicklime to water slowly (not water to quicklime) for slaking.

  • Personal Protective Equipment: MANDATORY: Chemical-resistant gloves (nitrile, neoprene), safety goggles or face shield, protective clothing, dust mask (N95/FFP2 or higher), chemical-resistant boots.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using; Remove contaminated clothing and wash before reuse.

  • Storage: Store in tightly closed, moisture-proof containers; Store in cool, dry, well-ventilated area; Protect from moisture and CO₂; Keep away from water and acids; Opened containers must be resealed immediately; Shelf life: 12-24 months under proper conditions.

  • Spill Management: DO NOT USE WATER. Sweep or vacuum (HEPA) and place in suitable sealed container; Avoid dust formation; Do not allow entry into drains or waterways; Neutralize with dilute acid (carefully) if needed.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Hazardous waste (corrosive); Neutralize with water/acids before disposal (carefully); Use authorized disposal facilities.

DETECTION METHODS:

Method Description Advantages Disadvantages
Titrimetric (Acid-Base) Neutralization with standard acid Simple, accurate, standard method Requires indicator
AAS / ICP Calcium and trace element analysis High sensitivity, accurate High cost, requires expertise
XRF (X-Ray Fluorescence) Elemental analysis Rapid, non-destructive Requires calibration
XRD (X-Ray Diffraction) Phase identification Determines crystalline phases High cost, requires expertise
Loss on Ignition CO₂ and volatile content Simple, standard method Time-consuming

CALCIUM OXIDE vs ALTERNATIVES COMPARISON:

Product Chemical Name / E Code Application Strength Weakness Status
Calcium Oxide (CaO) Quicklime (E529) Cement, steel, water treatment High reactivity, cheap, abundant, high temp stability Corrosive, reacts with water Essential (cement/steel)
Calcium Hydroxide Slaked Lime (E526) Mortar, water treatment Safer, easier to handle Lower reactivity Widely used
Calcium Carbonate Limestone (E170) Construction, antacid Inert, safe, cheap Low reactivity Widely used
Sodium Hydroxide Caustic Soda (E524) Water treatment, pH adjustment High solubility, fast action Higher cost, corrosive Widely used
Magnesium Oxide Magnesia (E530) Refractory, steelmaking High temp stability Higher cost, lower basicity Limited

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Calcium oxide is a corrosive substance that reacts violently with water; strict safety protocols must be followed at all times.

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