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Copper Chloride, Cupric Chloride, Copper Chloride Anhydrous, Copper Chloride Dihydrate, 7447-39-4, 7758-89-6, 75763-85-8

Copper Chloride, Cupric Chloride, Copper Chloride Anhydrous, Copper Chloride Dihydrate, 7447-39-4, 7758-89-6, 75763-85-8

CUPRIC CHLORIDE (COPPER CHLORIDE)

PRODUCT IDENTIFIER INFORMATION

Parameter Information
Product Name Cupric Chloride (Copper Chloride)
Chemical Name (IUPAC) Copper(II) Chloride
CAS Number (Anhydrous) 7447-39-4
CAS Number (Dihydrate) 7758-89-6
CAS Number (Synonym Group) 75763-85-8
EC Number (EINECS) 231-210-2
Molecular Formula CuCl₂
Molecular Weight 134.45 g/mol (anhydrous); 170.48 g/mol (dihydrate)

CHEMICAL STRUCTURE

        Cl⁻
         |
    Cu²⁺ — Cl⁻
    
    Cupric Chloride (CuCl₂)
    Ionic Structure

Cupric Chloride Molecular Structure

Molecular Formula: CuCl₂
SMILES: Cl[Cu]Cl
InChI: 1S/2ClH.Cu/h2*1H;/q;;+2/p-2
Crystal System: Anhydrous: Orthorhombic; Dihydrate: Monoclinic

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Cupric Chloride (Copper Chloride)
Chemical Name (IUPAC) Copper(II) Chloride
Synonyms (English) Cupric Chloride, Copper Chloride, Copper(II) Chloride, Chloro Copper, Copper Dichloride, Copper Chloride Anhydrous, Copper Chloride Dihydrate
CAS Number 7447-39-4 (Anhydrous); 7758-89-6 (Dihydrate); 75763-85-8 (Synonym group)
EC Number (EINECS) 231-210-2
Molecular Formula CuCl₂
Molecular Weight 134.45 g/mol (anhydrous); 170.48 g/mol (dihydrate)
Chemical Class Inorganic compound; transition metal halide; copper salt
Physical State (20°C) Crystalline solid
Odor Odorless
Appearance Anhydrous: Brownish-yellow crystalline solid; Dihydrate: Blue-green crystalline solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Brownish-yellow (anhydrous) or blue-green (dihydrate) crystalline solid Visual
Color Anhydrous: Brownish-yellow; Dihydrate: Blue-green Visual
Odor Odorless Olfactometric
Molecular Weight 134.45 g/mol (anhydrous); 170.48 g/mol (dihydrate) Calculated
Density 3.386 g/cm³ (anhydrous); 2.51 g/cm³ (dihydrate) ASTM D4052
Melting Point 498 °C (anhydrous) DSC
Boiling Point 993 °C (decomposes) -
Solubility in Water Soluble: 70.6 g/100 mL (0°C); 75.7 g/100 mL (20°C); 107.9 g/100 mL (100°C) General Method
Solubility in Ethanol Soluble General Method
Solubility in Acetone Slightly soluble General Method
Solubility in Ether Slightly soluble General Method
pH (5% Solution) ~3.0 - 4.0 (acidic) pH Meter
Hygroscopicity Hygroscopic (absorbs moisture from air) -
Stability Stable under normal conditions; deliquescent in moist air; decomposes upon heating -
Corrosivity Corrosive to many metals -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Inorganic transition metal chloride; acidic salt; forms complexes with various ligands; Lewis acid
Stability Stable under normal conditions; hygroscopic; decomposes upon heating
Reactivity Reacts with bases to form copper hydroxide; forms complexes with ammonia, chloride ions, and other ligands; can be reduced to copper(I) chloride or copper metal; reacts with metals to displace less reactive metals
Incompatible Materials Strong oxidizing agents, strong reducing agents, alkali metals, aluminum, magnesium, zinc, acetylene, hydrazine
Polymerization Does not polymerize
Decomposition Products (Heating) Copper(I) chloride (CuCl), Chlorine (Cl₂), Copper oxide (CuO), Copper (Cu)
Hazardous Reactions May react violently with strong reducing agents; can form explosive compounds with acetylene; corrosive to many metals
Reaction with Water Dissolves readily; acidic solution due to hydrolysis
Reaction with Bases CuCl₂ + 2NaOH → Cu(OH)₂↓ + 2NaCl
Reaction with Ammonia CuCl₂ + 4NH₃ → [Cu(NH₃)₄]Cl₂ (deep blue complex)
Reaction with Metals CuCl₂ + Fe → FeCl₂ + Cu (copper deposition)
Reduction 2CuCl₂ → 2CuCl + Cl₂ (upon heating)

SECTION 4: PRODUCTION METHODS

Method 1: Direct Chlorination

Reaction:

Cu + Cl₂ → CuCl₂

Description:

  • Copper metal is reacted with chlorine gas at elevated temperatures

  • Produces anhydrous copper(II) chloride

  • High purity product

Method 2: Hydrochloric Acid Dissolution

Reaction:

CuO + 2HCl → CuCl₂ + H₂O
Cu(OH)₂ + 2HCl → CuCl₂ + 2H₂O
Cu₂O + 4HCl → 2CuCl₂ + 2H₂O + H₂

Description:

  • Copper oxide or copper hydroxide is dissolved in hydrochloric acid

  • Solution is evaporated and crystallized

  • Product can be obtained as anhydrous or dihydrate depending on drying conditions

Method 3: Copper Scrap Dissolution

Reaction:

Cu + 2HCl + H₂O₂ → CuCl₂ + 2H₂O

Description:

  • Copper scrap is dissolved in hydrochloric acid with an oxidizing agent (H₂O₂)

  • Economic method for industrial production

  • Solution is concentrated and crystallized

SECTION 5: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Catalytic Activity Acts as a catalyst in organic synthesis; used in chlorination, oxidation, and coupling reactions; catalyzes various chemical transformations
Mordant Used in textile dyeing as a mordant; fixes dyes to fabrics; improves color fastness; used as pigment precursor
Wood Preservative Effective wood preservative; protects against fungal decay and insect attack; used in combination with other preservatives
Complex Formation Forms coordination complexes with various ligands; deep blue complex with ammonia; used in analytical chemistry
Copper Source Provides copper ions for various applications; used in copper plating; source of copper in animal feed and fertilizers
Oxidizing Agent Acts as mild oxidizing agent in organic synthesis; can oxidize alcohols and other organic compounds
Chlorinating Agent Provides chlorine in organic chlorination reactions; used in synthesis of chlorinated organic compounds
Analytical Reagent Used in various analytical procedures; serves as a colorimetric reagent; used in gravimetric analysis

SECTION 6: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Textile Industry Mordant / pigment precursor Textile dyeing and printing; fixing dyes to fabrics; pigment precursor in textile processing
Chemical Industry Catalyst / reagent Catalyst in organic synthesis; chlorination reactions; oxidation reactions; petrochemical catalysts
Wood Preservation Preservative agent Wood preservative formulations; protection against fungal decay and insects
Agriculture Micronutrient / pesticide Copper micronutrient in fertilizers; pesticide formulations (limited use)
Laboratory Reagent Analytical reagent; colorimetric reagent; chemical synthesis; gravimetric analysis
Electroplating Copper source Copper plating and electroplating baths; surface finishing
Catalysis Catalyst / co-catalyst Petrochemical catalysts; polymerization catalysts; organic synthesis catalysts
Water Treatment Algaecide / fungicide Swimming pool algaecides; industrial water treatment (limited)
Pigment Industry Pigment precursor Production of copper-based pigments; colorants
Electronics Precursor / etchant Printed circuit board etching; electronic component manufacture

SECTION 7: QUALITY SPECIFICATIONS

Parameter Specification (Industrial) Specification (Analytical) Test Method
Appearance Brownish-yellow or blue-green crystalline solid Brownish-yellow or blue-green crystalline solid Visual
Assay (CuCl₂) ≥ 98.0 % ≥ 99.0 % Titrimetric
Copper Content ≥ 46.5 % ≥ 47.0 % Gravimetric
Loss on Drying ≤ 1.0 % ≤ 0.5 % Gravimetric
Water Insoluble Matter ≤ 0.1 % ≤ 0.02 % Gravimetric
Chlorides (as Cl) ≥ 52.0 % ≥ 53.0 % Titrimetric
Sulfates (as SO₄) ≤ 0.05 % ≤ 0.01 % Turbidimetric
Iron (Fe) ≤ 0.01 % ≤ 0.005 % AAS / ICP
Heavy Metals (as Pb) ≤ 0.01 % ≤ 0.005 % AAS / ICP
Zinc (Zn) ≤ 0.01 % ≤ 0.005 % AAS / ICP
pH (5% Solution) 3.0 - 4.0 3.0 - 4.0 pH Meter
Particle Size As specified by customer requirement - Sieve / Laser Diffraction
Trace Metals - By ICP-MS ICP-MS

SECTION 8: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 140 - 600 mg/kg (moderate to high toxicity)
Acute Dermal Toxicity (LD50, Rabbit) > 2,000 mg/kg (moderate toxicity)
Acute Inhalation Toxicity (LC50, Rat, 4h) ~ 10 mg/L (dust; toxic)
Skin Irritation Corrosive; causes skin burns upon contact
Eye Irritation Corrosive; causes severe eye damage
Respiratory Irritation Dust causes respiratory tract irritation; may cause pulmonary edema
Chronic Toxicity Chronic copper exposure may affect liver, kidneys, and nervous system; Wilson's disease risk; may cause hemolysis
Carcinogenicity Not classified (IARC)
Mutagenicity Not classified
Reproductive Toxicity May affect reproductive health at high doses
Target Organs Liver, kidneys, eyes, skin, respiratory system, nervous system
Occupational Exposure Limit (8h TWA) 1.0 mg/m³ (as Cu, ACGIH/OSHA)
Short-Term Exposure Limit (STEL) 2.0 mg/m³ (as Cu, ACGIH)
Special Toxicity Note Toxic if ingested/inhaled; corrosive to skin and eyes; harmful to aquatic life with long-lasting effects

SECTION 9: GHS CLASSIFICATION AND LABELING

GHS Classification (according to 1272/2008/EC and UN GHS):

Hazard Class Category H-Statement
Acute Toxicity (Oral) Category 4 H302
Acute Toxicity (Inhalation) Category 4 H332
Skin Corrosion/Irritation Category 1B H314
Serious Eye Damage/Irritation Category 1 H318
Specific Target Organ Toxicity - SE Category 3 H335
Chronic Aquatic Toxicity Category 1 H410

Signal Word: DANGER

Hazard Pictograms: GHS06 (Skull and Crossbones), GHS05 (Corrosion), GHS07 (Exclamation Mark), GHS09 (Environment)

Hazard Statements (H-Codes):

Code Statement
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H332 Harmful if inhaled
H335 May cause respiratory irritation
H410 Very toxic to aquatic life with long-lasting effects

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
3 0 1 -
(Severe health hazard) (Non-flammable) (Slightly reactive) (None)

SECTION 10: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P262 Do not get in eyes, on skin, or on clothing
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves / protective clothing / eye protection / face protection
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER / doctor
P330 Rinse mouth
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 11: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. Seek immediate medical attention.
Skin Contact Remove contaminated clothing immediately. Rinse skin with copious amounts of water for at least 15-20 minutes. Wash with soap and water. Seek medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15-20 minutes. Hold eyelids open. Remove contact lenses if present. Seek immediate medical attention.
Ingestion Rinse mouth. Do NOT induce vomiting. Seek immediate medical attention. Note: Copper compounds are toxic and may cause liver and kidney damage.

SECTION 12: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Non-flammable; may decompose at high temperatures to release toxic fumes
Hazards During Fire Thermal decomposition produces toxic copper chloride fumes, chlorine gas, and copper oxide fumes
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray (for cooling), alcohol-resistant foam
Unsuitable Extinguishing Media Water jet (may spread hazardous material; may create corrosive solutions)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing, acid-resistant gloves
Special Precautions Cool containers with water fog from safe distance; prevent runoff water from entering drains and waterways; avoid contact with reducing agents

SECTION 13: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; away from heat, moisture, and incompatible materials; airtight, moisture-free containers
Container Requirements Tightly closed, properly labeled containers; use moisture-resistant packaging; use acid-resistant containers (HDPE, glass)
Materials to Protect From Strong reducing agents, alkali metals, aluminum, magnesium, zinc, acetylene, hydrazine, moisture
Shelf Life 24 months (in unopened original packaging, under proper storage conditions)
Stability Note Stable under normal conditions; hygroscopic and deliquescent; absorbs moisture from air; protect from humidity; may form complexes upon exposure to ammonia

SECTION 14: PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Bottle 100 g, 500 g, 1 kg Glass / HDPE
Plastic Bag 5 kg, 10 kg, 25 kg PE bag
Fiber Drum 25 kg, 50 kg PE-lined fiberboard
Plastic Drum 25 kg, 50 kg, 100 kg HDPE / Polypropylene
Bulk Bag (FIBC) 500 kg, 1000 kg PE-lined woven PP

SECTION 15: TRANSPORT INFORMATION

Parameter Information
UN Number UN 2802 (Copper chloride)
Hazard Class 8 (Corrosive Substance)
Packing Group III
ADR/RID UN 2802, Copper chloride, 8, PG III
IMDG Code UN 2802, Copper chloride, 8, PG III, Marine Pollutant: Yes
IATA (Air) UN 2802, Copper chloride, 8, PG III
Marine Pollutant Yes
Transport Temperature Ambient; protect from moisture

SECTION 16: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; classified as hazardous substance
USA (TSCA) Listed
Turkey Industrial chemical; subject to KKDIK regulation
IARC Not classified as carcinogenic
OSHA Regulated (toxic and corrosive substance)
FDA Not approved for food contact or food additives
EPA Regulated under various environmental laws

SECTION 17: OTHER NAMES AND SYNONYMS

Type Name
English Synonyms Cupric Chloride, Copper Chloride, Copper(II) Chloride, Chloro Copper, Copper Dichloride, Copper Chloride Anhydrous, Copper Chloride Dihydrate
Turkish Synonyms Küprik Klorür, Bakır Klorür, Bakır(II) Klorür, Kloro Bakır
Chemical Names Copper(II) Chloride; Cupric Chloride; Copper Dichloride
CAS Number (Anhydrous) 7447-39-4
CAS Number (Dihydrate) 7758-89-6
CAS Number (Synonym Group) 75763-85-8
EC Number 231-210-2

SECTION 18: ALTERNATIVE PRODUCTS / SUBSTITUTES

Alternative Best Suited For Key Difference
Copper Sulfate (CuSO₄) Agriculture, water treatment, algaecides Widely used in agriculture; different anion; similar copper content; less corrosive
Iron(III) Chloride (FeCl₃) Water treatment, coagulant, etching Different metal; used in water treatment as coagulant; less toxic than copper chloride
Nickel Chloride (NiCl₂) Electroplating, catalysis Different metal; similar chemistry; different applications
Zinc Chloride (ZnCl₂) Wood preservation, flux Different metal; similar corrosive properties; different applications
Copper Nitrate (Cu(NO₃)₂) Catalysis, pigment Different anion; more soluble; different properties

SECTION 19: SECTORAL SUITABILITY TABLE

Sector Suitability Notes
Textile Industry Fully Suitable Used as mordant and pigment precursor in textile dyeing and printing
Chemical Industry Fully Suitable Used as catalyst in organic synthesis, chlorination and oxidation reactions
Construction Not Suitable Not typically used in construction applications
Pharmaceuticals Not Suitable Not used in pharmaceutical formulations; used as reagent only
Agriculture Partially Suitable Limited use in pesticide formulations; copper micronutrient
Wood Preservation Fully Suitable Used in wood preservative formulations
Laboratory Fully Suitable Used as analytical reagent and in chemical synthesis
Electronics Partially Suitable Used in PCB etching; limited applications

SECTION 20: SUMMARY TABLE

Parameter Value
Product Cupric Chloride (Copper Chloride)
CAS Number (Anhydrous) 7447-39-4
Molecular Formula CuCl₂
Molecular Weight 134.45 g/mol (anhydrous)
Appearance Brownish-yellow (anhydrous) or blue-green (dihydrate) crystalline solid
Density 3.386 g/cm³ (anhydrous)
Melting Point 498 °C
Solubility in Water Soluble: 70.6 g/100 mL (0°C)
Primary Function Catalyst, mordant, wood preservative, reagent
Main Applications Textile, chemical industry, wood preservation, laboratory
Shelf Life 24 months
GHS Signal Word DANGER
UN Number UN 2802

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Harmful if swallowed or inhaled (H302/H332). Copper compounds are toxic.

  • Causes severe skin burns and eye damage (H314/H318). Use full PPE.

  • Very toxic to aquatic life with long-lasting effects (H410). Prevent environmental release.

  • Corrosive to many metals; store in acid-resistant containers.

  • Hygroscopic: Absorbs moisture from air; store in airtight containers.

  • Incompatibilities: Keep away from strong reducing agents, alkali metals, aluminum, magnesium, zinc, acetylene, hydrazine, and moisture.

  • Toxic to aquatic organisms; wastewater treatment required before disposal.

  • REACH registration required for EU trade.

BEST PRACTICE RECOMMENDATIONS:

  • Textile Industry: Use as mordant and pigment precursor; ensure proper wastewater treatment before disposal; recover copper from waste streams when possible.

  • Chemical Industry: Use as catalyst for chlorination and oxidation reactions; handle under controlled conditions; ensure proper waste treatment.

  • Wood Preservation: Use in wood preservative formulations; ensure proper application and disposal; follow environmental regulations.

  • Handling: Use in well-ventilated areas or under fume hood; wear chemical-resistant gloves (neoprene, nitrile), safety goggles, face shield, and appropriate respiratory protection; avoid creating dust.

  • Personal Protective Equipment: Use chemical safety glasses, suitable protective clothing, chemical protective gloves; use respirator when airborne concentration exceeds standards.

  • Hygiene: Do not eat, drink or smoke while handling; wash hands thoroughly after handling; shower at end of work shift.

  • Storage: Store in tightly closed, properly labeled containers in cool, dry, well-ventilated conditions; keep away from heat, moisture, and incompatible materials.

  • Spill Response: Avoid creating dust; wear full PPE; vacuum or wet sweep; place in sealed containers for disposal; prevent discharge to water bodies.

  • Waste Management: Neutralize before disposal; copper recovery possible from electronic waste; follow local, regional and national regulations.

  • Disposal: Dispose of in accordance with local, regional and national regulations; do not discharge into drains or water bodies; copper compounds are regulated as hazardous waste.

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability of the product for their specific applications. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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