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Alpha Olefin Sulfonate, Sodium Tetradecene Sulfonate, AOS, 68439-57-6

Alpha Olefin Sulfonate, Sodium Tetradecene Sulfonate, AOS, 68439-57-6

General Information

  • Chemical Name: Alpha Olefin Sulfonate (AOS)

  • Formula: CnH2n-1SO3Na (n = 14–16)

  • Molecular Weight: ~324 g/mol

  • CAS Number: 68439-57-6

  • Appearance: Light yellowish powder or liquid form

  • Nature: Anionic surfactant, biodegradable, mild on skin

Production Process

  • Derived from alpha-olefins (C14–C16 carbon chains).

  • Produced via sulfonation of alpha-olefins.

  • Steps include:

    • Sulfonation reaction

    • Hydrolysis and neutralization (with sodium hydroxide)

    • Purification

  • Raw materials often come from petrochemical processes (ethylene oligomerization, Fischer-Tropsch synthesis).

Applications

  • Household Cleaning: Laundry detergents, dishwashing liquids, liquid soaps.

  • Personal Care: Shampoos, shower gels, facial cleansers, toothpaste, hand soaps.

  • Industrial Uses:

    • Textile, printing, dyeing

    • Firefighting foams

    • Concrete additives (air entrainment)

    • Pesticide emulsifiers

    • Emulsion polymerization

Advantages

  • Excellent foaming and foam stability

  • Works well in both hard and soft water

  • Gentle on skin, low irritation

  • Biodegradable and eco-friendly

  • Compatible with other surfactants (nonionic, amphoteric)

  • Ideal for sulfate-free formulations (alternative to SLS)

Difference from Sodium Lauryl Sulfate (SLS)

  • AOS: Milder, less irritating, preferred for sulfate-free shampoos and body washes.

  • SLS: Stronger, cheaper, but can be harsh and irritating to skin.

Storage

  • Store in a cool, dry place, away from moisture and heat.

Other Names for AOS

  • Alpha Olefin Sulfonate

  • AOS Powder

  • Sodium Alpha Olefin Sulfonate

  • Sodium C14–16 Olefin Sulfonate

  • Sodium Tetradecene Sulfonate

  • Linear Alpha Olefin Sulfonate

  • AOS

Sectoral Usage, Suitability, and Dosage

Sector Suitability Typical Usage Levels
Household Cleaning Laundry detergents, dishwashing liquids, liquid soaps. Strong foaming, good in hard water. 5–20% of formulation
Personal Care Shampoos, shower gels, facial cleansers, toothpaste, hand soaps. Gentle, sulfate-free alternative. 4–15% of formulation
Cosmetics Creams, lotions, pet shampoos, face washes. Mild surfactant, good emulsifier. 2–10% depending on product
Industrial Cleaning Car wash liquids, heavy-duty detergents. High foaming, strong degreasing. 10–30% of formulation
Textile & Dyeing Wetting agent, detergent in textile processing. Compatible with polymers. 5–15%
Construction Concrete additives (air entrainment, density improvement). Small amounts (<5%)
Agriculture Pesticide emulsifier, wetting agent. 2–8% depending on formulation
Firefighting Foams Foam stabilizer in fire suppression systems. Variable, usually 5–10%

Key Notes

  • Mildness: Less irritating than Sodium Lauryl Sulfate (SLS), making it ideal for sulfate-free shampoos and body washes.

  • Flexibility: Can be used alone or combined with nonionic/amphoteric surfactants.

  • Eco-Friendly: Biodegradable, low toxicity, safe for personal care and environmental applications.

  • Concentration Range: Generally used between 4–30% depending on product type and desired foaming/cleaning effect.

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