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Send EmailChlorinated Paraffin, Chlorinated Paraffin 52, Solid Chlorinated Alkane, Chlorinated alkanes, 108171-26-2, 63449-39-8,
68920-70-7, 61788-76-9, 85535-84-8,
85535-85-9, 85535-86-0,
106232-86-4, 85535-87-1, 85535-88-2, 85535-89-3, 85535-90-6, 85535-91-7, 85535-92-8
CAS No:108171-26-2, 63449-39-8,
68920-70-7, 61788-76-9, 85535-84-8,
85535-85-9, 85535-86-0,
106232-86-4, 85535-87-1, 85535-88-2, 85535-89-3, 85535-90-6, 85535-91-7,
85535-92-8
Chlorinated paraffins (CPs) are complex mixtures of polychlorinated n-alkanes classified based on carbon chain length and chlorine content. Here are some common CAS numbers for different types of chlorinated paraffins:
Generic SCCPs: 85535-84-8
Specific examples:
Chlorinated decanes (C10): 85535-85-9
Chlorinated undecanes (C11): 85535-86-0
Chlorinated dodecanes (C12): 85535-87-1
Chlorinated tridecanes (C13): 85535-88-2
Generic MCCPs: 85535-85-9
(sometimes overlaps with SCCP listings)
Specific examples:
Chlorinated tetradecanes (C14): 85535-89-3
Chlorinated pentadecanes (C15): 85535-90-6
Chlorinated hexadecanes (C16): 85535-91-7
Chlorinated heptadecanes (C17): 85535-92-8
Generic LCCPs: 63449-39-8
Less standardized, as commercial LCCPs vary widely in composition.
Chlorinated paraffin (unspecified): 61788-76-9
Chlorinated alkanes (general): 63449-39-8
SCCPs (C10–13) are listed under the Stockholm Convention as persistent organic pollutants (POPs) and are restricted in many countries.
MCCPs (C14–17) are under increasing regulatory scrutiny but are not yet globally banned.
LCCPs (C18+) are less studied but may face future restrictions.
Chlorinated Paraffins (CPs) are industrial chemicals produced by chlorination of n-alkane (paraffin) fractions. They are classified based on carbon chain length and chlorine content (typically 30–70% by weight).
Short-Chain Chlorinated Paraffins (SCCPs, C10–13)
CAS No.: 85535-84-8
(generic)
Regulation: Banned under the Stockholm Convention (POPs list) due to persistence, toxicity, and bioaccumulation.
Uses: Flame retardants, plasticizers, metalworking fluids.
Medium-Chain Chlorinated Paraffins (MCCPs, C14–17)
CAS No.: 85535-85-9
(generic, sometimes overlaps with SCCPs)
Regulation: Increasing restrictions (e.g., EU REACH, proposed for global regulation).
Uses: PVC plasticizers, lubricants, sealants.
Long-Chain Chlorinated Paraffins (LCCPs, C18–30)
CAS No.: 63449-39-8
(generic)
Regulation: Less restricted but under review (potential future bans).
Uses: High-temperature lubricants, adhesives.
Appearance: Colorless to yellowish oily liquids or solids.
Solubility: Insoluble in water, soluble in organic solvents.
Stability: Resistant to degradation (persistent in the environment).
Plasticizers (flexible PVC products)
Flame retardants (rubber, paints, textiles)
Metalworking fluids (cutting/forming lubricants)
Adhesives & sealants
SCCPs: Banned in EU, Canada, Japan, and others.
MCCPs: Restricted in some regions (EU, UK).
LCCPs: Still in use but monitored.
Here are the key properties of chlorinated paraffins (CPs), categorized by physical, chemical, and environmental characteristics:
Property | Description |
---|---|
Appearance | Viscous, pale yellow to colorless liquids (short-medium chains) or waxy solids (long chains). |
Odor | Mild, characteristic hydrocarbon-like smell. |
Density | 1.1–1.6 g/cm³ (increases with chlorine content). |
Melting Point | Varies by chain length: - SCCPs: Liquid at room temp. - LCCPs: Solids (up to 100°C for C18+). |
Boiling Point | Decomposes before boiling (typically 200–400°C). |
Viscosity | 50–500 mPa·s (at 25°C; rises with chlorine %). |
Solubility | - Water: Insoluble (<0.1 mg/L). - Organic solvents: Soluble in fats, oils, acetone, ether, chlorinated solvents. |
Property | Description |
---|---|
Chemical Formula | CₓH₍₂ₓ₊₂₋ᵧ₎Clᵧ (where x = chain length, y = Cl atoms). |
Chlorine Content | Typically 30–70% by weight (higher Cl = more viscous/dense). |
Thermal Stability | Decomposes at >200°C, releasing HCl gas (corrosive). |
Flame Retardancy | Acts as a flame suppressant by releasing chlorine radicals. |
Reactivity | Stable under normal conditions but reacts with strong oxidizers. |
Property | Description |
---|---|
Persistence | - SCCPs: Highly persistent (half-life >1 year in soil/water). - MCCPs/LCCPs: Moderate to high persistence. |
Bioaccumulation | - SCCPs: High (log Kow = 4–9). - Longer chains accumulate in fatty tissues. |
Toxicity | - Acute: Low to moderate (LD50 >2,000 mg/kg in rats). - Chronic: Potential liver/kidney damage, carcinogenicity (SCCPs classified as Group 2B by IARC). |
Environmental Fate | Adsorbs to sediments; resistant to hydrolysis/microbial degradation. |
Plasticizing Efficiency: Improves flexibility in PVC (compares to phthalates).
Lubricity: Reduces friction in metalworking fluids.
Acid Resistance: Stable in non-oxidizing acids.
Electrical Insulation: Used in cable coatings.
Chain Length | Chlorine Content (%) | Typical State | Key Use |
---|---|---|---|
SCCPs (C10–13) | 50–70 | Liquid | Flame retardants, coatings |
MCCPs (C14–17) | 40–60 | Liquid/semi-solid | PVC plasticizers, lubricants |
LCCPs (C18–30) | 30–50 | Solid | High-temp lubricants |
Storage: Keep in airtight containers (avoid moisture/heat).
Decomposition: Avoid temperatures >200°C (risk of HCl release).
Regulatory Notes: SCCPs are banned in many countries; MCCPs restricted under REACH.
Chlorinated paraffins are known by various alternative names, trade names, and abbreviations depending on their chain length, chlorine content, and regional usage. Here’s a comprehensive list:
Chlorinated alkanes
Polychlorinated alkanes (PCAs)
Chlorinated n-alkanes
Alkanes, chloro derivatives
CPs (Chlorinated Paraffins)
SCCPs (Short-Chain Chlorinated Paraffins, C10–13)
MCCPs (Medium-Chain Chlorinated Paraffins, C14–17)
LCCPs (Long-Chain Chlorinated Paraffins, C18–30)
Manufacturer | Trade Name | Notes |
---|---|---|
Dover Chemical | Chlorowax®, Doverguard® | Widely used in PVC and lubricants |
Leuna Tenside | LEUNA Chlorparaffins | German producer |
Caffaro Industrie | Cereclor® (UK/EU) | Includes SCCPs/MCCPs |
Química del Cinca | Paroil® | Spanish brand |
NCP Chlorchem | Chlorez® | South African producer |
Handy Chemical | Hordaflex® | Canadian brand |
Japan: "Kureha Chlorinated Paraffin"
India: "Aditya Birla Chlorinated Paraffin"
Metalworking Fluids: Often called "Extreme Pressure (EP) Additives"
PVC Industry: Referred to as "Secondary Plasticizers"
EU REACH: Listed as "Alkanes, C10-13, chloro" (SCCPs)
US EPA: Classified under "Chlorinated Alkanes"
Stockholm Convention: Listed as "Short-Chain Chlorinated Paraffins" (SCCPs, Annex A)
"Chlorinated Diphenyls" (outdated, now refers to PCBs)
"Paraffin Chloride" (older term, rarely used today)
SCCPs are often explicitly named in regulations (e.g., "C10-13 Chloroalkanes").
MCCPs/LCCPs may be listed generically as "Chlorinated Paraffins" in safety sheets.