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Chlorinated Paraffin, Chlorinated Paraffin 52, Solid Chlorinated Alkane, CP-52, CPW-52, 85535-85-9, 68920-70-7, 63449-39-8, 106232-86-4, 61788-76-9, 108171-26-2

Chlorinated Paraffin, Chlorinated Paraffin 52, Solid Chlorinated Alkane, Chlorinated alkanes,  108171-26-2, 63449-39-8, 68920-70-7, 61788-76-9, 85535-84-8, 85535-85-9,  85535-86-0, 106232-86-4,  85535-87-1, 85535-88-2, 85535-89-3, 85535-90-6, 85535-91-7, 85535-92-8

CAS No:108171-26-2, 63449-39-8, 68920-70-7, 61788-76-9, 85535-84-8, 85535-85-9,  85535-86-0, 106232-86-4,  85535-87-1, 85535-88-2, 85535-89-3, 85535-90-6, 85535-91-7, 85535-92-8

Chlorinated paraffins (CPs) are complex mixtures of polychlorinated n-alkanes classified based on carbon chain length and chlorine content. Here are some common CAS numbers for different types of chlorinated paraffins:

Short-Chain Chlorinated Paraffins (SCCPs, C10–13)

  • Generic SCCPs85535-84-8

  • Specific examples:

    • Chlorinated decanes (C10): 85535-85-9

    • Chlorinated undecanes (C11): 85535-86-0

    • Chlorinated dodecanes (C12): 85535-87-1

    • Chlorinated tridecanes (C13): 85535-88-2

Medium-Chain Chlorinated Paraffins (MCCPs, C14–17)

  • Generic MCCPs85535-85-9 (sometimes overlaps with SCCP listings)

  • Specific examples:

    • Chlorinated tetradecanes (C14): 85535-89-3

    • Chlorinated pentadecanes (C15): 85535-90-6

    • Chlorinated hexadecanes (C16): 85535-91-7

    • Chlorinated heptadecanes (C17): 85535-92-8

Long-Chain Chlorinated Paraffins (LCCPs, C18–30)

  • Generic LCCPs63449-39-8

  • Less standardized, as commercial LCCPs vary widely in composition.

Other Related CAS Numbers

  • Chlorinated paraffin (unspecified)61788-76-9

  • Chlorinated alkanes (general)63449-39-8

Regulatory Notes

  • SCCPs (C10–13) are listed under the Stockholm Convention as persistent organic pollutants (POPs) and are restricted in many countries.

  • MCCPs (C14–17) are under increasing regulatory scrutiny but are not yet globally banned.

  • LCCPs (C18+) are less studied but may face future restrictions.

Chlorinated Paraffins (CPs) are industrial chemicals produced by chlorination of n-alkane (paraffin) fractions. They are classified based on carbon chain length and chlorine content (typically 30–70% by weight).

Types of Chlorinated Paraffins

  1. Short-Chain Chlorinated Paraffins (SCCPs, C10–13)

    • CAS No.85535-84-8 (generic)

    • Regulation: Banned under the Stockholm Convention (POPs list) due to persistence, toxicity, and bioaccumulation.

    • Uses: Flame retardants, plasticizers, metalworking fluids.

  2. Medium-Chain Chlorinated Paraffins (MCCPs, C14–17)

    • CAS No.85535-85-9 (generic, sometimes overlaps with SCCPs)

    • Regulation: Increasing restrictions (e.g., EU REACH, proposed for global regulation).

    • Uses: PVC plasticizers, lubricants, sealants.

  3. Long-Chain Chlorinated Paraffins (LCCPs, C18–30)

    • CAS No.63449-39-8 (generic)

    • Regulation: Less restricted but under review (potential future bans).

    • Uses: High-temperature lubricants, adhesives.

Key Properties

  • Appearance: Colorless to yellowish oily liquids or solids.

  • Solubility: Insoluble in water, soluble in organic solvents.

  • Stability: Resistant to degradation (persistent in the environment).

Common Applications

  • Plasticizers (flexible PVC products)

  • Flame retardants (rubber, paints, textiles)

  • Metalworking fluids (cutting/forming lubricants)

  • Adhesives & sealants

Regulatory Status

  • SCCPs: Banned in EU, Canada, Japan, and others.

  • MCCPs: Restricted in some regions (EU, UK).

  • LCCPs: Still in use but monitored.

Here are the key properties of chlorinated paraffins (CPs), categorized by physical, chemical, and environmental characteristics:


1. Physical Properties

Property Description
Appearance Viscous, pale yellow to colorless liquids (short-medium chains) or waxy solids (long chains).
Odor Mild, characteristic hydrocarbon-like smell.
Density 1.1–1.6 g/cm³ (increases with chlorine content).
Melting Point Varies by chain length:
SCCPs: Liquid at room temp.
LCCPs: Solids (up to 100°C for C18+).
Boiling Point Decomposes before boiling (typically 200–400°C).
Viscosity 50–500 mPa·s (at 25°C; rises with chlorine %).
Solubility Water: Insoluble (<0.1 mg/L).
Organic solvents: Soluble in fats, oils, acetone, ether, chlorinated solvents.

2. Chemical Properties

Property Description
Chemical Formula CₓH₍₂ₓ₊₂₋ᵧ₎Clᵧ (where x = chain length, y = Cl atoms).
Chlorine Content Typically 30–70% by weight (higher Cl = more viscous/dense).
Thermal Stability Decomposes at >200°C, releasing HCl gas (corrosive).
Flame Retardancy Acts as a flame suppressant by releasing chlorine radicals.
Reactivity Stable under normal conditions but reacts with strong oxidizers.

3. Environmental & Toxicological Properties

Property Description
Persistence SCCPs: Highly persistent (half-life >1 year in soil/water).
MCCPs/LCCPs: Moderate to high persistence.
Bioaccumulation SCCPs: High (log Kow = 4–9).
- Longer chains accumulate in fatty tissues.
Toxicity Acute: Low to moderate (LD50 >2,000 mg/kg in rats).
Chronic: Potential liver/kidney damage, carcinogenicity (SCCPs classified as Group 2B by IARC).
Environmental Fate Adsorbs to sediments; resistant to hydrolysis/microbial degradation.

4. Technical Performance Properties

  • Plasticizing Efficiency: Improves flexibility in PVC (compares to phthalates).

  • Lubricity: Reduces friction in metalworking fluids.

  • Acid Resistance: Stable in non-oxidizing acids.

  • Electrical Insulation: Used in cable coatings.


Key Variations by Chain Length

Chain Length Chlorine Content (%) Typical State Key Use
SCCPs (C10–13) 50–70 Liquid Flame retardants, coatings
MCCPs (C14–17) 40–60 Liquid/semi-solid PVC plasticizers, lubricants
LCCPs (C18–30) 30–50 Solid High-temp lubricants

Safety & Handling

  • Storage: Keep in airtight containers (avoid moisture/heat).

  • Decomposition: Avoid temperatures >200°C (risk of HCl release).

  • Regulatory NotesSCCPs are banned in many countries; MCCPs restricted under REACH.

Chlorinated paraffins are known by various alternative namestrade names, and abbreviations depending on their chain length, chlorine content, and regional usage. Here’s a comprehensive list:


IUPAC & Chemical Names

  • Chlorinated alkanes

  • Polychlorinated alkanes (PCAs)

  • Chlorinated n-alkanes

  • Alkanes, chloro derivatives


Common Abbreviations

  • CPs (Chlorinated Paraffins)

  • SCCPs (Short-Chain Chlorinated Paraffins, C10–13)

  • MCCPs (Medium-Chain Chlorinated Paraffins, C14–17)

  • LCCPs (Long-Chain Chlorinated Paraffins, C18–30)


Trade Names & Commercial Brands

Manufacturer Trade Name Notes
Dover Chemical Chlorowax®, Doverguard® Widely used in PVC and lubricants
Leuna Tenside LEUNA Chlorparaffins German producer
Caffaro Industrie Cereclor® (UK/EU) Includes SCCPs/MCCPs
Química del Cinca Paroil® Spanish brand
NCP Chlorchem Chlorez® South African producer
Handy Chemical Hordaflex® Canadian brand

Regional & Industry-Specific Names

  • Japan: "Kureha Chlorinated Paraffin"

  • India: "Aditya Birla Chlorinated Paraffin"

  • Metalworking Fluids: Often called "Extreme Pressure (EP) Additives"

  • PVC Industry: Referred to as "Secondary Plasticizers"


Regulatory/Legal Names

  • EU REACH: Listed as "Alkanes, C10-13, chloro" (SCCPs)

  • US EPA: Classified under "Chlorinated Alkanes"

  • Stockholm Convention: Listed as "Short-Chain Chlorinated Paraffins" (SCCPs, Annex A)


Deprecated or Historical Names

  • "Chlorinated Diphenyls" (outdated, now refers to PCBs)

  • "Paraffin Chloride" (older term, rarely used today)


Key Notes

  • SCCPs are often explicitly named in regulations (e.g., "C10-13 Chloroalkanes").

  • MCCPs/LCCPs may be listed generically as "Chlorinated Paraffins" in safety sheets.

 

 

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