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Diisopropanolamine (DIPA, Dipa), Diisopropanolamine, DIPA, Dipa, 110-97-4

Diisopropanolamine (DIPA, Dipa), Diisopropanolamine, DIPA, Dipa, 110-97-4

 

CAS No.: 110-97-4 

Diisopropanolamine

Molecular Formula: C6H15NO2

Names and Identifiers

Name Diisopropanolamine
Synonyms DIPA
Diisopropanolamine
Bis(2-propanol)amine
DIPA commercial grade
1,1'-Iminodipropan-2-ol
DIPA low freeze grade 85
DIPA low freeze grade 90
1,1'-Iminodi(2-propanol)
1,1'-Iminobis[2-propanol]
2-Propanol, 1,1'-iminodi-
2-Propanol, 1,1'-iminobis-
2-propanol, 1,1'-iminobis-
DI(2-Hydroxy-n-propyl)amine
DIPROPYL-2,2'-DIHYDROXYAMINE
Di(2-hydroxy-n-propyl) amine
(2R,2'S)-1,1'-iminodipropan-2-ol
(2R,2'R)-1,1'-iminodipropan-2-ol
(2S)-2-hydroxy-N-[(2R)-2-hydroxypropyl]propan-1-aminium
(2S)-2-hydroxy-N-[(2S)-2-hydroxypropyl]propan-1-aminium
(2R)-2-hydroxy-N-[(2R)-2-hydroxypropyl]propan-1-aminium
CAS 110-97-4
EINECS 203-820-9
InChI InChI=1/C6H15NO2/c1-5(8)3-7-4-6(2)9/h5-9H,3-4H2,1-2H3/p+1/t5-,6-/m1/s1

Physico-chemical Properties

Molecular Formula C6H15NO2
Molar Mass 133.19
Density 1.004g/mLat 25°C(lit.)
Melting Point 42-45°C(lit.)
Boling Point 249-250°C745mm Hg(lit.)
Flash Point 260°F
Water Solubility 870 G/L (20 ºC)
Solubility H2O: miscible
Vapor Presure 0.02 hPa (20 °C)
Appearance Low Melting Solid
Specific Gravity 0.99
Color Colorless to light yellow
Odor Fishy; ammoniacal.
Merck 14,3195
BRN 605363
pKa 14.54±0.20(Predicted)
PH 11.4 (100g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Stability Hygroscopic
Sensitive Air Sensitive & Hygroscopic
Explosive Limit 1.6-8.0%(V)
Refractive Index 1.4615-1.4635
Physical and Chemical Properties Room temperature for crystalline solid, with weak alkaline.
Use For the removal of hydrogen sulfide and carbon dioxide in natural gas and refinery gas, for fiber additives, tanning agents, pesticides, cutting oil, etc

Risk and Safety

Hazard Symbols Xi - Irritant
Irritant
Risk Codes 36 - Irritating to the eyes
Safety Description 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDs 3259
WGK Germany 1
RTECS UB6600000
FLUKA BRAND F CODES 3-34
TSCA Yes
HS Code 2922 19 00
Hazard Class 8
Packing Group III
Toxicity LD50 orally in Rabbit: 4765 mg/kg LD50 dermal Rabbit 8000 mg/kg

Reference Information

LogP -0.79 at 20℃
Use for removal of hydrogen sulfide and carbon dioxide from natural gas and refinery gas, for fiber additives, tanning agents, pesticides, cutting oil and other
diisopropanolamine is used as an absorbent of acid gas, for example, to absorb CO2 and H2S in natural gas and petroleum refining gas, to remove CO2 in synthesis gas in ammonia industry, and to concentrate CO2 in dry ice production. In addition, it is also used for metal annealing, inert gas manufacturing, neutralization agent of electrophoretic coating, etc. In terms of emulsifier, the product is applied to fiber additives, tanning agents, pesticides, cutting oils, coatings and wax products. Diisopropanolamine reacts with fatty acids to produce fatty acid amides and lipids and is used as the active component of a shampoo.
is an important organic intermediate, because it has hydroxyl and amine groups, it is widely used in the synthesis of fine chemicals such as pharmaceuticals, pesticides, detergents, cosmetics, etc, its largest use is as a desulfurization and decarbonization agent, widely used in the fertilizer industry, petrochemical and natural gas industries.
production method propylene oxide reacts with ammonia to generate mono-isopropanolamine, and continues to react with propylene oxide to generate di-and tri-isopropanolamine. Propylene oxide and ammonia were mixed and then pre-heated to the reaction temperature and entered the reactor for reaction. The reaction product was first stripped to remove ammonia and water, and the ammonia was recycled. Then, the crude isopropanolamine is sent to a vacuum distillation system, and Monoisopropanolamine, diisopropanolamine and triisopropanolamine are fractionated into pure products. When the excess of propylene oxide in the raw material ratio is more, the proportion of triisopropanolamine in the obtained product increases.
category corrosive article
toxicity grade poisoning
Acute toxicity oral-rat LD50: 4765 mg/kg; Abdominal injection-mouse LD50: 96 mg/kg
stimulation data Skin-rabbit 500 mg mild; Eye-rabbit 50 mg severe
explosive hazard characteristics the hydrolysis product ammonia is corrosive to skin
flammability hazard characteristics flammability; Combustion emissions toxic nitrogen oxides and ammonia fumes
storage and transportation characteristics The warehouse is ventilated and dried at low temperature; It is stored separately from acids.
fire extinguishing agent foam, carbon dioxide, dry powder
Occupational Standard sel 1 mg/m3
spontaneous combustion temperature 290°C

 

What is Diisopropanolamine (DIPA)?

A basic chemical used in many applications serving as emulsifiers, stabilizers, chemical intermediates and neutralizers. Specialty alkanolamine that acts as a neutralizers for water-based coatings.

Uses

  • Pesticide Production
  • Institutional Warewash
  • Institutional Fabric Care
  • Electronic Parts Cleaning
  • Food, Feed, Dairy and Beverage
  • Metal Cleaning
  • Bathroom Cleaners
  • Glass Cleaners
  • Home Care Floor Polish
  • Institutional Hard Surface Care
  • Janitorial and Sanitation
  • Kitchen and Catering
  • Kitchen Cleaners
  • Multipurpose Cleaners
  • Vehicle and Transportation
  • Wipes
  • Automotive Coatings OEM
  • General Industrial Finishing
  • Marine Coatings
  • Protective Coatings

Benefits

  • Neutralization of acidic components
  • pH contributor
  • Good surfactant properties—emulsifying agent, wetting agent, contributes cleaning,
    lubrication and viscosity

Diisopropanolamine (DIPOA) is an aminoalcohol.

It’s a water soluble, colorless liquid or white to yellow crystalline solid with an odor of ammonia.

Coatings Diisopropanolamine (DIPOA) is a neutralization agent for anionic stabilized resins. It is suitable for waterborne stoving enamels based on polyesters, alkyds and acrylic resins (secondary dispersions).

DIPOA additionally supports the film forming of stoving enamels.

DIPOA is an intermediate in the production of a special ß-hydroxyalkylamide which is used as a crosslinker in polyester powder coatings. Due to its pendent functionality,

DIPOA can be used as a cross-linking agent and as a building block for polyurethanes. Gas Treatment Natural gas can be purified by removing carbon dioxide and hydrogen sulfide by means of diisopropanolamine in the sulfinol process.

Metal Working Diisopropanolamine (DIPOA) is used as a corrosion inhibitor in the metal processing industry.

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