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Tributyl phosphate, Tri-n-butyl phosphate, TBP, 126-73-8 , 20046-30-4 

Tributyl phosphate, Tri-n-butyl phosphate, TBP, 126-73-8 , 20046-30-4 

CAS: 126-73-8;20046-30-4

Molecular Formula: C12H27O4P

Names and Identifiers

Name Tributyl phosphate
Synonyms TBP
Tributyl phosphate
Tributyl Phosphsate
Tri-n-butyl phosphate
Tributyl Phosphate (TBP)
1-dibutoxyphosphoryloxybutane
Phosphoric acid tri-n-butyl ester
Nitrogen-Oxygen free radical piperidycol
Three butyl acrylate acid flame retardant agent
CAS 126-73-8
20046-30-4
EINECS 204-800-2
InChI InChI=1/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3

Physico-chemical Properties

Molecular Formula C12H27O4P
Density 0.986g/cm3
Melting Point -79℃
Boling Point 288.3°C at 760 mmHg
Flash Point 193.3°C
Water Solubility 0.6 g/100 mL
Vapor Presure 0.00409mmHg at 25°C
Appearance Transparent liquid
Storage Condition 2-8℃
Sensitive Easily absorbing moisture
Refractive Index 1.43
MDL MFCD00009436
Physical and Chemical Properties Colorless and odorless liquid.

melting point <-80 ℃

boiling point 289 ℃

relative density 0.976

refractive index 1.425

flash point 146 ℃

solubility miscibility with common organic solvents, also soluble in water.
Use Used as extractants for metal complexes, nitrocellulose, cellulose acetate, plasticizers for chlorinated rubber and polyvinyl chloride, solvents for Coatings, Inks and Adhesives

Risk and Safety

Hazard Symbols Xn - Harmful
Harmful
Risk Codes R22 - Harmful if swallowed
R38 - Irritating to the skin
R40 - Limited evidence of a carcinogenic effect
Safety Description S36/37 - Wear suitable protective clothing and gloves.
S46 - If swallowed, seek medical advice immediately and show this container or label.

Upstream Downstream Industry

Raw Materials Phosphorus trichloride
Phosphorus oxychloride
Phosphorus oxychloride
1-Butanol
Downstream Products Tributyl phosphate

Nature

colorless and tasteless liquid. Miscible with a variety of organic solvents, ImL the product is soluble in about 165ml water.

Preparation Method

derived from the reaction of n-butanol with phosphorus oxychloride.

Introduction

No smell, can be mixed with most organic solvents, slightly soluble in water (1ml soluble in about 165ml of water). Low toxicity.

Use

gas chromatography stationary liquid. For the extraction of cobalt, Iridium, manganese, molybdenum, palladium, platinum, rhodium, technetium, uranium, tungsten. Colorimetric Determination of molybdenum. It is used as a solvent and also as a plasticizer for nitrocellulose, cellulose acetate, chlorinated rubber and polyvinyl chloride.

Last Update:2022-01-01 09:26:57

126-73-8 - Safety

rat oral LD50: 3.0g/kg. It has a strong stimulating effect on the skin and respiratory tract, and has a systemic toxic effect. It has mild inhibitory effect on cholinesterase in human blood and plasma. In case of high heat, open flame or contact with oxidant, there is a risk of combustion. Decomposition by heat produces highly toxic phosphorus oxide flue gas. Store in a cool, ventilated warehouse. Keep away from fire and heat source. Keep the container sealed. Should be stored separately from the oxidant, acid, alkali.

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