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Tara Gum, Tara Powder, Caesalpinia Spinosa, E417, 39300-88-4

Tara Gum, Tara Powder, Caesalpinia Spinosa, E417, 39300-88-4

TARA POWDER (TARA GUM) 

CHEMICAL PROFILE AND IDENTIFICATION

Parameter Information
Product Name Tara Powder, Tara Gum
Botanical Source Caesalpinia spinosa (Tara tree)
Other Names Peruvian Carob, Spiny Holdback, Tara Gum, E417
CAS Number 39300-88-4
E Number E417 (Food additive)
Chemical Formula C₇₅H₅₂O₄₆
Molecular Weight 1688 g/mol
Appearance Light beige to light brown, fine and homogeneous powder
Odor Slightly characteristic, earthy
Tannin Type Pyrogallol group (contains small amounts of catechol derivatives)
Ionic Character Anionic

SECTION 1: PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Molecular Formula C₇₅H₅₂O₄₆
Molecular Weight 1688 g/mol
Appearance Light beige to light brown, fine and homogeneous powder
Odor Slightly characteristic, earthy
Tannin Content 56% ± 4
Active Content 93.5%
Moisture Content 6-8%
Insoluble Matter 5-15%
pH (solution) 3.0 - 5.0
Density 0.6-0.8 g/cm³
Tannin Type Pyrogallol group (hydrolyzable)
Ionic Character Anionic
Shelf Life 24 months (under proper storage)
Solubility Soluble in water (moderate in cold, high in hot)
Particle Size Fine powder (>200 mesh)
Color Property Contains no coloring agents

SECTION 2: BOTANICAL ORIGIN AND HARVESTING

2.1 Plant Profile

Parameter Information
Scientific Name Caesalpinia spinosa (Syn. Caesalpinia tinctoria)
Common Name Tara tree, Peruvian Carob, Spiny Holdback
Family Fabaceae (Legume family)
Origin Peruvian Andes (especially Cajamarca, La Libertad, Ancash)
Growing Conditions Dry and semi-arid regions, 1500-3000 m altitude
Tree Type Dwarf tree or shrub (5-8 meters)
Pod Tannin Content 43-51%
Flowering Seasonal (dependent on rainfall period)
Yield ~5-10 kg dry pods per mature tree

2.2 Harvesting and Processing

Stage Description
Harvest Period April (according to local calendar)
Harvest Method Hand-picked without damaging the trees
Drying Natural sun drying (3-5 days)
Pod Shelling Mechanical pod shelling process
Grinding Mechanical grinding to fine powder
Sieving Sieving for homogeneous particle size (>200 mesh)
Quality Control Tannin content, moisture, insoluble matter analysis
Packaging 25 kg laminated polypropylene bags
Sustainability Planted as erosion control, biodegradable, contributes to local economy

SECTION 3: CHEMICAL COMPOSITION AND TANNIN TYPES

3.1 Chemical Composition

Component Percentage / Value
Total Tannins 56% ± 4
Hydrolyzable Tannins Main component
Gallotannins 93.5% (active substance)
Pyrogallol Group Main tannin type
Catechol Derivatives Small amounts
Moisture 6-8%
Insoluble Matter 5-15%
Coloring Agents None
Mineral Matter (Ash) Low amount (1-2%)
Proteins Trace amounts
Sugars Trace amounts

3.2 Tannin Types

Tannin Type Property Example
Hydrolyzable Tannins Hydrolyzed by acids or enzymes Gallotannins, ellagitannins
Condensed Tannins Polymerized by acids Catechins, procyanidins
Tara Tannin Predominantly hydrolyzable Pyrogallol group

3.3 Tannin Activity

Parameter Value
Tannin Content (Hydrolysis) High
Light Fastness Excellent
Color Change Minimal
Metal Complexation High (especially with iron)
Protein Binding High

SECTION 4: APPLICATIONS

4.1 Leather Industry (Most Common Use - 60-70%)

Tanning and Retanning Applications

Application Description
Vegetable Tanning Used as primary tanning agent
Retanning Used in retanning of chrome leathers
Combined Tanning Chrome and vegetable tanning combination
Imparted Properties Brightness, fullness, softness, elongation resistance
Light Fastness High, minimal color change
Fullness Imparts superior fullness to leather
Porosity Maintains leather breathability

Usage Rates

Leather Type Rate Basis Description
Bovine Leather - Upper 3-8% Shaved weight Standard retanning
Bovine Leather - Upholstery 5-10% Shaved weight High fullness
Goat Leather 2-3% Shaved weight For softness
Calf Leather 2-3% Shaved weight For softness
Deep Black Shades 20% WOF + 1% Leather weight With iron sulfate mordant
Light Colored Leathers 2-5% Shaved weight Lightening property

Tanning Parameters

Parameter Value
pH Range 3.0-5.0
Temperature 25-35°C
Duration 2-6 hours (process dependent)
Penetration Time 15-30 minutes
Fixation Time 60-120 minutes

Special Notes

Note Description
Iron Salt Sensitivity Forms dark complexes with iron
Stain Prevention Sequestering agent recommended to prevent staining
Light Colored Leathers Ideal due to colorless nature
Light Fastness High light fastness, excellent color stability
Fullness Effect Medium to high fullness

4.2 Textile Industry

Application Description
Natural Dyeing Production of black and grey shades
Mordant Use Fixes dyes to fibers
Fastness Improvement Improves light and washing fastness
Fiber Compatibility Better performance on cellulose fibers than protein fibers
Dye Fixation Effective in fixing natural dyes

Usage Rates

Application Rate Notes
General Fastness Improvement 5-10% WOF Standard application
Deep Black Shades 15-20% WOF + 1% With iron mordant
Grey Shades 5-15% WOF With iron mordant
Hot Dyeing Recommended Not suitable for cold dyeing
Dyeing Temperature 60-100°C Requires hot dyeing

Dyeing Results

Parameter Value
Light Fastness (Black) 4-5 (on 1-8 scale)
Washing Fastness 4-5 (on 1-5 scale)
Color Depth High
Color Evenness Good

4.3 Food and Beverage Industry

Application Description
Tannic Acid Production Used as primary raw material
Wine Production Clarification, stabilization and color fixing
Beer Production Clarification additive
Fruit Juice Cloudiness removal
E Number E417 (as food additive)
Usage Form Not directly as powder, as extract
Clarification Mechanism Binds and precipitates proteins and polyphenols

4.4 Pharmaceutical and Cosmetic Industry

Application Description
Gallic Acid Production Used as pharmaceutical raw material
Antioxidant Property In cosmetic formulations
Anti-inflammatory Under research (topical applications)
Antimicrobial Potential as natural preservative
Usage Form Not as direct powder, as extract form
Wound Healing Wound healing properties under research
Skin Care Astringent and tonic properties

4.5 Paper Industry

Application Description
Paper Processing As natural tannin source
Sizing Controls paper water permeability
Durability Enhancement Imparts natural processability to paper
Usage Rate Process dependent, generally in mixture with other extracts

4.6 Agriculture and Soil Management

Application Description
Organic Fertilizer Enriches soil, increases microbial activity
Water Holding Capacity Increases soil water holding capacity
Sustainable Agriculture Alternative to synthetic chemicals
Soil Rehabilitation Erosion control and soil improvement
Organic Matter Adds organic matter to soil

4.7 Water Treatment

Application Description
Coagulant As natural coagulant
Heavy Metal Binding Capacity to bind heavy metals
Wastewater Treatment Treatment of industrial wastewater
Natural Treatment Alternative to chemical coagulants

4.8 Adhesive Industry

Application Description
Natural Adhesives Tannin-based adhesive formulations
Wood Adhesive In wood panel production
Coating Surface coating applications

4.9 Ceramics and Glass

Application Description
Ceramic Decoration As colorant
Glass Production In glass formulations

SECTION 5: SECTORAL COMPLIANCE TABLE

Sector Suitability Level Usage Rates Special Notes
Leather Very High 2-10% (bovine), 2-3% (goat/calf) Most common application
Textile High 5-10% WOF, 15-20% WOF + mordant More effective on cellulose fibers
Food Medium Via extraction As E417
Pharmaceutical Medium Extract form Gallic acid production
Cosmetics Medium Extract form Antioxidant property
Paper Low-Medium Process dependent In mixture with other extracts
Agriculture High Variable Organic fertilizer
Water Treatment Medium Variable Natural coagulant
Adhesive Low-Medium Variable Research stage

SECTION 6: ADVANTAGES AND DISADVANTAGES

Advantages

Advantage Description
Natural and Biodegradable Environmentally friendly, sustainable resource
High Tannin Content 56% ±4 active substance, 93.5% active content
Colorless No coloring agents, ideal for light colored leathers
Light Fastness High, minimal color change
Leather Brightness Superior surface brightness and fullness
Softness Imparts natural softness to leather
Versatile Potential use in 9 different sectors
Local Economy Income source for local communities
Sustainable Planted as erosion control
Low pH Suitable for processes requiring acidic environment
Fast Penetration Rapid penetration into leather
Good Fixation Good binding to leather

Disadvantages

Disadvantage Description
Iron Salt Sensitivity Stain risk, requires sequestering agent
Not Suitable for Cold Dyeing Requires hot dyeing
Lower Effect on Protein Fibers Less effective than on cellulose fibers
Low pH May require balancing in some processes
Moisture Control Moisture content must be controlled during storage
Natural Variation Minor variations between batches possible
Iron Complexation Caution with iron-containing equipment
Caking Caking may occur in high humidity

SECTION 7: STORAGE AND SHELF LIFE

Parameter Information
Storage Temperature 15-25°C (cool)
Storage Conditions Dry, well-ventilated area
Container Requirements Tightly closed, original packaging
Materials to Protect From Moisture, direct sunlight, excessive heat
Shelf Life 24 months (in unopened original packaging under proper storage)
Packaging 25 kg laminated polypropylene bags
Moisture Control Maintain at 6-8%
Caking Prevention Store in moisture-free environment

SECTION 8: CRITICAL WARNINGS

Warning Description
Iron Salt Sensitivity Forms dark complexes with iron; sequestering agent recommended
Hot Dyeing Not suitable for cold dyeing; requires hot dyeing
Low pH pH 3.0-5.0; may require balancing in some processes
Natural Product Minor variations between batches; quality control important
Moisture Sensitivity Caking may occur in high humidity; store in dry conditions
Iron Equipment Risk of staining with iron-containing equipment; prefer stainless steel or plastic equipment
Light Fastness Provides high light fastness; slight fading may occur with prolonged UV exposure
Sequestering Agent Important to prevent iron stains
Dosage Control Overuse may cause hardening of leather; follow dosage recommendations

SECTION 9: SUMMARY AND CRITICAL INFORMATION

SUMMARY

Tara Powder (Caesalpinia spinosa) is a natural, biodegradable, high-tannin product obtained from the pods of a tree native to the Peruvian Andes. Its most common application is in the leather industry, where it imparts brightness, fullness, softness, and high light fastness to leather.

Key Properties

Property Value
Appearance Light beige to light brown powder
Tannin Content 56% ± 4
Active Content 93.5%
pH 3.0 - 5.0
Moisture 6-8%
Shelf Life 24 months
Ionic Character Anionic

Main Application Areas

Sector Application
Leather Industry Tanning, retanning, vegetable tanning
Textile Industry Natural dyeing, mordant, fastness improvement
Food Industry Tannic acid production, wine and beer clarification
Pharmaceutical and Cosmetics Gallic acid production, antioxidant properties
Agriculture Organic fertilizer, soil conditioner

Critical Warnings

Warning Description
Iron Sensitivity Risk of staining with iron salts; use sequestering agent
Hot Dyeing Not suitable for cold dyeing
Low pH May require balancing
Natural Variation Quality control important
Moisture Control Store in dry conditions

LEGAL DISCLAIMER

The information provided in this document is based on our current knowledge and experience and is presented in good faith; however, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications. For complete safety, storage, use, handling, disposal, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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