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Lead(II) acetate trihydrate, Lead Acetate Hydrate, Lead Acetate Trihydrate, 6080-56-4

Lead(II) acetate trihydrate, Lead Acetate Hydrate, Lead Acetate Trihydrate, 6080-56-4

Lead(II) acetate trihydrate

CAS: 6080-56-4

Molecular Formula: C4H12O7Pb

Names and Identifiers

Name Lead(II) acetate trihydrate
Synonyms Lead acetate hydrate
PLATINIZING SOLUTION
lead acetate trihydrate
Sugar of lead trihydrate
PLATINIZING SOLUTION, ASTM
Lead(Ⅱ) acetate trihydrate
Lead(II)acetate trihydrate
Lead Acetate Trihydrate BPC
lead (ii) acetate 3-hydrate
Lead(II) acetate trihydrate
LEAD(II) ACETATE TRIHYDRATE, ACS
acetic acid, lead salt, trihydrate
LEAD ACETATE TRIHYDRATE ACS REAGENT
LEAD ACETATE-3-HYDRATE R. G., REAG. ACS, REAG. ISO, REAG
CAS 6080-56-4
EINECS 612-031-2
InChI InChI=1/2C2H4O2.3H2O.Pb/c2*1-2(3)4;;;;/h2*1H3,(H,3,4);3*1H2
InChIKey DYRQFRHCGBQJII-UHFFFAOYSA-M

6080-56-4 - Physico-chemical Properties

Molecular Formula C4H12O7Pb
Molar Mass 379.33
Density 2,55 g/cm3
Melting Point 75°C (dec.)(lit.)
Boling Point 280°C
Flash Point 40°C
Water Solubility 625 g/L
Solubility 443g/l
Vapor Presure 13.9mmHg at 25°C
Appearance Solid
Specific Gravity 2.55
Color White or colorless, efflorescent
Exposure Limit NIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3
Merck 14,5397
BRN 3730298
PH 5.5-6.5 (50g/l, H2O, 20℃)
Storage Condition 2-8°C
Sensitive 0: forms stable aqueous solutions
Physical and Chemical Properties White crystalline or flaky powder, often large brown or gray in industrial form.
melting point 75 ℃ (water loss)
boiling point 280 ℃
relative density 2.50g/cm3
solubility soluble in water, slightly soluble in alcohol, soluble in glycerol.
Use Used as pigment, stabilizer and catalyst

Risk and Safety

Risk Codes R61 - May cause harm to the unborn child
R33 - Danger of cumulative effects
R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62 - Possible risk of impaired fertility
Safety Description S53 - Avoid exposure - obtain special instructions before use.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDs UN 1616 6.1/PG 3
WGK Germany 2
RTECS OF8050000
TSCA Yes
HS Code 29152900
Hazard Class 6.1
Packing Group III
Toxicity LD50 orally in Rabbit: 4665 mg/kg

Upstream Downstream Industry

Raw Materials Acetic acid
Acetic acid
Lead
Lead
Downstream Products Lead isocaprylate
Lead naphthenate
Magentagreencrystals
Lead(II) acetate basic
Lead(II) oxide
Lead (II) stearate

Nature

colorless crystal or white powder. Slightly acetic acid. mp 60~62 C I d 2.55. Soluble in water, slightly soluble in alcohol, soluble in glycerol. lg the product is soluble in 1-6ml water, 0.5ml boiling water, 30ml ethanol, soluble in glycerol. After absorption of carbon dioxide in air, it becomes an insoluble basic carbonate. The acetic acid was lost at 100 °c and completely decomposed at 200 °c. Flammable in case of open flame and high heat. By high heat decomposition of toxic gases.

Use

Analytical reagents for the determination of sulfide, chromium trioxide, molybdenum trioxide, biological dyeing and organic synthesis.

Preparation Method

lead oxide was dissolved in hot acetic acid, and after filtration, acetic acid was added to the filtrate to react and evaporated to a relative density of 1-40. After cooling, the crystals were isolated and dried to obtain pure lead acetate.

Safety

mice were injected intravenously with LD50:174mg/kg. According to RTECS standard, it was suspicious for tumor. The maximum allowable concentration of harmful substances in the air of the workshop is 0. 05mg/m3. Staff should be protected and immediately rinsed with running water when touching eyes and skin. It is strictly prohibited to mix with acids, oxidants, food and food additives.

Reference Information

introduction lead acetate trihydrate is colorless crystal, white particles or powder, which will deliquesce. Easily soluble in water with sweet taste. Lead acetate trihydrate is used to make various lead salts, pigments, dyes, lead plating, polyester catalysts, waterproof paints, desiccants, pesticides and medicines.
safety information lead acetate trihydrate rats were given LD50130mg/kg orally and 120 mg/kg intravenously. the metabolic symptoms after absorption in the body were the same as those of common inorganic lead compounds. The United Nations, the International Maritime Organization, the United States and the United Kingdom classify it as a toxic and dangerous substance, and there are corresponding regulations and restrictions when storing, transporting, packaging and treating as waste.
solubility in water (g/100ml) dissolution grams per 100ml of water at different temperatures (℃): 19.8g/0 ℃;29.5g/10 ℃;44.3g/20 ℃;69.8g/30 ℃;116g/40 ℃
use used as pigment, stabilizer and catalyst
this product can produce various lead salts, anti-fouling coatings, water quality protection agents, pigment fillers, paint desiccants, fiber dyes, and solvents in the cyanidation process of heavy metals. It is widely used in medicine, pesticides, dyes, coatings and other industrial production. It is also a reagent for the determination of chromium trioxide and molybdenum trioxide in chemical analysis.
Used as an analytical reagent, also used in biological dyeing, organic synthesis and pharmaceutical industry
production method lead oxide reacts with acetic acid. Dissolve lead oxide in 80% hot acetic acid until it is soaked, filter, add a small amount of acetic acid to the filtrate, and evaporate to a relative density of 1.40. Cool, filter, and dry to get lead acetate. The general purity of industrial lead acetate can reach above 98%. After purification, recrystallize with 1% acetic acid solution, or dissolve lead acetate trihydrate in water and pass hydrogen sulfide to precipitate lead sulfide and other impurities. After filtration, fluorescent gallium reagent (Co,Al,Cu, etc.) is added to the filtrate, a small amount of activated carbon is added, and EDTA sodium salt is added to obtain extremely pure reagent grade products.
category toxic substances
toxicity classification poisoning
acute toxicity oral administration-rat LD50 4665 mg/kg; Abdominal cavity-mouse LD50: 174 mg/kg
flammability hazard characteristics combustible, the fire site discharges lead-containing spicy and stimulating smoke
storage and transportation characteristics warehouse low temperature, ventilation, drying
fire extinguishing agent water, carbon dioxide, dry powder, foam
occupational standard TWA 0.1 mg (lead)/m3

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