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Magnesium Nitrate, Magnesium Dinitrate, Magnesium Nitrate Hexahydrate, Anhydrous Magnesium Nitrate, 10377-60-3

Magnesium Nitrate, Magnesium Dinitrate, Magnesium Nitrate Hexahydrate, Anhydrous Magnesium Nitrate, 10377-60-3

MAGNESIUM NITRATE

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Magnesium Nitrate
Chemical Name Magnesium Nitrate
Synonyms (Turkish) Magnezyum Nitrat, Nitrik Asit Magnezyum Tuzu, Hegzahidrat, Anhidrat, Susuz Magnezyum Nitrat, Magniyosan, Nitromagnezit
Synonyms (English) Magnesium Nitrate, Magnesium Dinitrate, Nitric Acid Magnesium Salt, Magnesium Nitrate Hexahydrate, Anhydrous Magnesium Nitrate, Nitromagnesite
CAS Number 10377-60-3
Molecular Formula Mg(NO₃)₂
Molecular Weight 148.32 g/mol (anhydrous)

CHEMICAL STRUCTURE

Magnesium Nitrate Structure:

        O⁻
        ||
   Mg²⁺  O=N—O⁻
        ||
        O

Structure Description:

  • Inorganic nitrate salt of magnesium.

  • Ionic compound composed of magnesium cation (Mg²⁺) and two nitrate anions (NO₃⁻).

  • Highly soluble in water.

  • Exists as anhydrous form and various hydrates (hexahydrate Mg(NO₃)₂·6H₂O is most common).

  • Found naturally as the mineral nitromagnesite.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Magnesium Nitrate
Chemical Name Magnesium Nitrate
Synonyms (Turkish) Magnezyum Nitrat, Nitrik Asit Magnezyum Tuzu, Hegzahidrat, Anhidrat, Susuz Magnezyum Nitrat, Magniyosan, Nitromagnezit
Synonyms (English) Magnesium Nitrate, Magnesium Dinitrate, Nitric Acid Magnesium Salt, Magnesium Nitrate Hexahydrate, Anhydrous Magnesium Nitrate, Nitromagnesite
CAS Number 10377-60-3
EC Number 233-826-7
Molecular Formula Mg(NO₃)₂
Molecular Weight 148.32 g/mol (anhydrous); 256.41 g/mol (hexahydrate)
Chemical Class Inorganic salt; Nitrate; Magnesium compound; Oxidizer
Source Synthetic (reaction of magnesium compounds with nitric acid)
Physical State (20°C) Solid (crystalline)
Odor Odorless
Color White to colorless crystalline solid
Taste Bitter, saline taste

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White to colorless crystalline solid Visual
Odor Odorless Olfactometric
Molecular Weight 148.32 g/mol (anhydrous); 256.41 g/mol (hexahydrate) Calculated
Density (Anhydrous) 2.3 g/cm³ ASTM D4052
Density (Hexahydrate) 1.45 g/cm³ ASTM D4052
Melting Point 129°C (hexahydrate); 330°C (decomposes, anhydrous) DSC
Boiling Point 330°C (decomposes)
Decomposition Temperature ~330°C (NOx, O₂)
Solubility in Water (25°C) 71.2 g/100 g water (very high) General Method
Solubility in Ethanol Soluble General Method
Solubility in Methanol Soluble General Method
pH (5% Solution) ~5.0 – 6.5 pH Meter
Stability Stable under normal conditions; Hygroscopic
Oxidizing Properties Strong oxidizer (when heated/decomposed)
Hygroscopicity Moderately hygroscopic
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP
Magnesium Oxide (MgO) Content ~15% Titrimetric
Nitrate Nitrogen Content ~11% Kjeldahl
Loss on Drying ≤ 0.5% Gravimetric
Water Insoluble Matter ≤ 0.1% Gravimetric
Assay (Mg(NO₃)₂) ≥ 98.0% (anhydrous); ≥ 99.0% (hexahydrate) Titrimetric

SECTION 3: MAGNESIUM NITRATE vs OTHER MAGNESIUM SALTS

Property Magnesium Nitrate Mg(NO₃)₂ Magnesium Sulfate MgSO₄ Magnesium Chloride MgCl₂ Magnesium Carbonate MgCO₃
CAS Number 10377-60-3 7487-88-9 7786-30-3 546-93-0
Molecular Weight 148.32 g/mol 120.37 g/mol 95.21 g/mol 84.31 g/mol
Magnesium Content ~16.5% ~20.2% ~25.5% ~28.8%
Solubility in Water Very high (71.2 g/100 mL) High Very high Insoluble
pH (Solution) ~5.0-6.5 ~5.5-7.0 ~6.0-7.5 ~8.0-9.5
Nitrogen Content ~11% 0% 0% 0%
Oxidizing Properties Yes No No No
Hygroscopicity Moderate Low High Low
Primary Use Fertilizer, catalysis Fertilizer, medicine De-icing, fertilizer Fertilizer, antacid
Organic Farming Not allowed (synthetic nitrate) Allowed Allowed Allowed

SECTION 4: MECHANISM OF ACTION

Property Description
Fertilizer (Magnesium Source) Provides plant-available magnesium (Mg²⁺); Magnesium is the central atom of chlorophyll; Essential for photosynthesis; Enzyme activation and carbohydrate metabolism.
Fertilizer (Nitrogen Source) Provides plant-available nitrate nitrogen (NO₃⁻); Immediate nitrogen uptake; Promotes vegetative growth; Nitrate form is readily absorbed by roots.
Oxidizer Nitrate ion (NO₃⁻) acts as oxygen donor; Supports combustion at elevated temperatures; Decomposes to release nitrogen oxides and oxygen.
Matrix Modifier Used in atomic absorption spectroscopy; Prevents matrix interferences; Enhances analyte signal stability; Improves detection limits.
Desensitizer Used in lithographic plates; Reduces sensitivity of plates; Controls plate characteristics.
Viscosity Modifier Adjusts viscosity in industrial formulations; Improves application properties; Used in inks and coatings.

SECTION 5: PRODUCTION PROCESS

Industrial Production Method:

Reaction 1 (Magnesium Oxide + Nitric Acid): MgO + 2HNO₃ → Mg(NO₃)₂ + H₂O

Reaction 2 (Magnesium Carbonate + Nitric Acid): MgCO₃ + 2HNO₃ → Mg(NO₃)₂ + CO₂ + H₂O

Reaction 3 (Magnesium Hydroxide + Nitric Acid): Mg(OH)₂ + 2HNO₃ → Mg(NO₃)₂ + 2H₂O

Process Flow:
Magnesium Compound (Oxide, Carbonate, Hydroxide, or Metal) + Nitric Acid → Neutralization → Filtration → Evaporation/Concentration → Crystallization → Drying → Final Product

Step-by-Step Description:

  1. Neutralization: Magnesium compound (MgO, MgCO₃, Mg(OH)₂, or Mg metal) is reacted with nitric acid in a neutralization reactor.

  2. Filtration: The resulting solution is filtered to remove impurities.

  3. Evaporation/Concentration: The magnesium nitrate solution is concentrated by evaporation.

  4. Crystallization: Concentrated solution is crystallized to form solid magnesium nitrate (hexahydrate or anhydrous).

  5. Drying: Crystals are dried to achieve specified moisture content.

  6. Final Product: Hexahydrate, anhydrous, or liquid formulations are produced.

Natural Occurrence: Found as the mineral nitromagnesite in mines and caves. However, nearly all commercial production is synthetic.

SECTION 6: FUNCTIONAL PROPERTIES

Property Description
Fertilizer Water-soluble magnesium and nitrogen source; Provides ~11% nitrate nitrogen and ~15% magnesium oxide (MgO); Suitable for foliar, drip, and fertigation applications; Promotes chlorophyll synthesis and photosynthesis; Corrects magnesium deficiencies.
Catalyst Precursor Used as precursor for catalyst production; High-purity magnesium nitrate for nano-material synthesis; Production of magnesium oxide catalysts.
Matrix Modifier (Analytical) Used in atomic absorption spectroscopy (AAS) as matrix modifier; Reduces interferences from other elements; Stabilizes analyte signals; Improves accuracy of trace metal analysis.
Viscosity Modifier Used in industrial applications to adjust viscosity; Improves flow properties of inks and coatings; Enhances application characteristics.
Desensitizer Used in lithographic plate production; Desensitizes plates to improve quality; Controls plate characteristics.
Dehydrating Agent Used in some industrial processes; Removes water from certain systems; Used in denitrification processes.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Agriculture (Fertilizer) Magnesium and nitrogen source Foliar application, drip irrigation, fertigation; Greenhouse and hydroponic commercial applications; Corrects magnesium deficiencies; ~11% N + ~15% MgO.
Agriculture (Fertilizer Blends) Component of compound fertilizers Blended with ammonium nitrate, calcium nitrate, potassium nitrate; Used in NPK formulations; Enhances magnesium content.
Analytical Chemistry Matrix modifier, reagent Atomic Absorption Spectroscopy (AAS); Graphite Furnace AAS; Trace metal analysis; Improves analytical accuracy.
Catalyst Production Precursor material High-purity catalysts; Magnesium oxide production; Nano-material synthesis; Catalyst support materials.
Printing & Inks Viscosity modifier, desensitizer Toner and colorant manufacturing; Inkjet toner formulations; Lithographic plate desensitization.
Pyrotechnics Oxidizer Pyrotechnic compositions; Fireworks and signal flares; Colored flame production.
Chemical Industry Raw material, intermediate Production of other magnesium compounds; Ammonium nitrate production (seed growth and coating aid); Inorganic salt removal at high temperatures.
Industrial Formulations Viscosity adjuster Various industrial applications; Process optimization; Product stability improvement.

SECTION 8: SAMPLE FORMULATIONS

Foliar Spray Fertilizer (Magnesium Nitrate Solution):

Component Amount
Magnesium Nitrate (Hexahydrate) 1 – 2 kg
Water 100 L

Instructions: Dissolve magnesium nitrate in water;

Apply as foliar spray during active growth; Compatible with most pesticides (check compatibility);

Do not apply before rain; Best applied during early morning or late evening.

 

Fertigation Application (Drip Irrigation):

Component Amount
Magnesium Nitrate (Hexahydrate) 0.5 – 2 kg
Water 1000 L

Instructions: Dissolve in irrigation water;

Apply through drip or sprinkler system; Corrects magnesium deficiencies;

Used in greenhouse and hydroponic systems.

 

SECTION 9: QUALITY SPECIFICATIONS

Parameter Fertilizer Grade Technical Grade Analytical Grade Test Method
Appearance White to colorless crystals White to colorless crystals White to colorless crystals Visual
Assay (Mg(NO₃)₂·6H₂O) ≥ 98.0% ≥ 99.0% ≥ 99.5% Titrimetric
Magnesium Oxide (MgO) ~15% ~15% ~15% Titrimetric
Nitrate Nitrogen ~11% ~11% ~11% Kjeldahl
pH (5% Solution) 5.0 – 6.5 5.0 – 6.5 5.0 – 6.5 pH Meter
Loss on Drying ≤ 0.5% ≤ 0.3% ≤ 0.2% Gravimetric
Water Insoluble ≤ 0.1% ≤ 0.05% ≤ 0.02% Gravimetric
Heavy Metals (as Pb) ≤ 10 ppm ≤ 5 ppm ≤ 2 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm ≤ 1 ppm ≤ 0.5 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm ≤ 1 ppm ≤ 0.5 ppm AAS / ICP
Iron (Fe) ≤ 0.001% ≤ 0.0005% ≤ 0.0002% AAS / ICP
Chloride (Cl) ≤ 0.05% ≤ 0.02% ≤ 0.01% Titrimetric

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 5,000 mg/kg (low toxicity)
Acute Dermal Toxicity Low toxicity; May cause mild irritation
Skin Irritation Mild irritant
Eye Irritation May cause irritation
Inhalation Toxicity May cause respiratory irritation (dust)
Chronic Toxicity Low toxicity at normal exposure levels
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity at normal levels
Environmental Toxicity Nitrate can contribute to water contamination; Excessive use may cause eutrophication; Handle with care near water bodies.
Special Toxicity Note LD50 low; Generally considered non-toxic; FDA-approved food additive for specific applications (21 CFR 184.1438); May release toxic nitrogen oxides (NOx) at high temperatures (>330°C); Protective equipment recommended for industrial handling.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Oxidizing Solids Category 3 H272
Eye Irritation Category 2 H319
Specific Target Organ Toxicity (Single) Category 3 H335

Signal Word: WARNING

Hazard Pictograms: GHS03 (Flame Over Circle), GHS07 (Exclamation Mark)

Hazard Statements (H-Codes):

Code Statement
H272 May intensify fire; oxidizer
H319 Causes serious eye irritation
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
1 0 1 OX
(Slight health hazard) (Non-flammable) (Mild reactivity) (Oxidizer)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P220 Keep away from clothing and other combustible materials
P221 Take any precaution to avoid mixing with combustibles
P264 Wash hands thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P337+P313 If eye irritation persists: Get medical advice/attention
P370+P378 In case of fire: Use water spray, foam, or dry chemical powder
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If respiratory irritation develops, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, get medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. Seek medical attention if large quantities are ingested or if feeling unwell.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable but is an oxidizer. May support combustion of other materials.
Hazards Arising from Fire Thermal decomposition produces nitrogen oxides (NOx) and oxygen; May intensify fire in contact with combustibles.
Suitable Extinguishing Media Water spray (large quantities), water fog, foam, dry chemical powder.
Unsuitable Extinguishing Media CO₂ (ineffective for oxidizing agents)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing, firefighting goggles.
Special Precautions Prevent fire-fighting water from entering waterways; Evacuate area; Cool fire-exposed containers with water spray.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM MOISTURE and CONTAMINATION; Separate from combustible materials and reducing agents.
Container Requirements Tightly closed, moisture-proof containers (PE-lined bags, HDPE drums).
Materials to Protect From Moisture, heat, combustible materials, organic substances, reducing agents
Shelf Life 24 – 36 months (in unopened original packaging, under proper storage conditions).
Stability Note Stable under recommended storage conditions; Hygroscopic; Absorbs moisture from air; May deliquesce if exposed to high humidity.
Special Storage Requirements Store in a dry, cool place; Avoid exposure to air and moisture; Opened containers must be resealed immediately; Keep away from combustible materials.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
PE-Lined Paper Bag 25 kg, 50 kg PE-lined kraft paper bag (moisture-proof)
Plastic Bag 10 kg, 25 kg, 50 kg PE bag (inner-lined, sealed, moisture-proof)
Plastic Drum 25 kg, 50 kg HDPE / Polypropylene (moisture-proof, chemical-resistant)
FIBC / Big Bag 500 kg, 1000 kg PE-lined, moisture-resistant PP woven bag

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number UN 1474 (Magnesium Nitrate)
Hazard Class Class 5.1 - Oxidizing Substances
Packing Group III
ADR/RID Class 5.1; UN 1474; Packing Group III
IMDG Code Class 5.1; UN 1474; Marine pollutant: No
IATA (Air) Class 5.1; UN 1474; Packing Group III
Transport Label Oxidizer (Class 5.1)
Marine Pollutant No
Special Transport Requirements Segregation from combustibles and reducing agents; Secure from unauthorized access.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Regulated as oxidizing substance; Approved for use as fertilizer.
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) GRAS (Generally Recognized as Safe); 21 CFR 184.1438 (Food additive: nutrient supplement, dough strengthener, stabilizer, thickener).
USA (EPA) Regulated under fertilizer and industrial chemical programs.
Turkey Regulated as fertilizer and industrial chemical; Subject to KKDIK regulation; Ministry of Agriculture approval for fertilizer use; Organic farming: Not allowed (synthetic nitrate).
Organic Farming NOT PERMITTED in organic agriculture; Magnesium sulfate or magnesium chloride are used as alternatives.
IARC Not classified (non-carcinogenic)
NTP Not listed
California (Prop 65) Not listed
Fertilizer Regulations Subject to national fertilizer standards; Heavy metal limits apply; Labeling requirements apply.

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Magnezyum Nitrat, Nitrik Asit Magnezyum Tuzu, Hegzahidrat, Anhidrat, Susuz Magnezyum Nitrat, Magniyosan, Nitromagnezit
English Names Magnesium Nitrate, Magnesium Dinitrate, Nitric Acid Magnesium Salt, Magnesium Nitrate Hexahydrate, Anhydrous Magnesium Nitrate, Nitromagnesite
CAS Number 10377-60-3
EC Number 233-826-7
HS Code 2834.29
Synonyms Magniyosan, Nitromagnesite, Magnesium (II) nitrate, Magnesium salt of nitric acid

SECTION 20: SUMMARY TABLE

Parameter Value
Product Magnesium Nitrate
CAS Number 10377-60-3
Molecular Formula Mg(NO₃)₂
Molecular Weight 148.32 g/mol (anhydrous)
Appearance White to colorless crystalline solid
Melting Point 129°C (hexahydrate); 330°C (decomposes, anhydrous)
Solubility in Water Very high (71.2 g/100 g at 25°C)
Primary Functions Fertilizer, matrix modifier, catalyst precursor, oxidizer
Main Application Areas Agriculture (fertilizer), analytical chemistry, catalyst production, printing, pyrotechnics
Shelf Life 24 – 36 months
GHS Signal Word WARNING
UN Number 1474
Hazard Class Class 5.1 (Oxidizer)
Packing Group III
Special Properties Oxidizer; Hygroscopic; Water-soluble magnesium and nitrogen source; ~11% N + ~15% MgO; FDA GRAS; Organic farming not permitted; Forms hexahydrate (most common commercial form).

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • OXIDIZER (H272): May intensify fire and support combustion. KEEP AWAY FROM COMBUSTIBLE MATERIALS.

  • CAUSES SERIOUS EYE IRRITATION (H319): Eye contact should be avoided. EYE PROTECTION IS RECOMMENDED.

  • MAY CAUSE RESPIRATORY IRRITATION (H335): Avoid inhalation of dust.

  • HYGROSCOPIC: Absorbs moisture from air; may deliquesce. Store in tightly closed containers.

  • DECOMPOSITION: Decomposes at high temperatures (>330°C) releasing toxic nitrogen oxides (NOx).

  • ORGANIC FARMING NOT PERMITTED: Synthetic nitrate source; not allowed in organic agriculture.

  • FDA GRAS: Approved as food additive for specific applications (nutrient supplement, dough strengthener, stabilizer, thickener).

  • WATER CONTAMINATION: Nitrate can contaminate groundwater; use according to recommended rates.

BEST PRACTICE RECOMMENDATIONS:

  • Agriculture (Fertilizer): Use as foliar spray or fertigation; Recommended dosage: 0.5-2 kg per 1000 L water; Apply during active growth; Compatible with most fertilizers; Best applied in early morning or late evening; Do not apply before rain.

  • Analytical Chemistry: Use as matrix modifier in AAS; Recommended concentration: 0.1-1%; Use high-purity grade; Calibrate instrument accordingly.

  • Handling: Use in well-ventilated areas; Avoid dust formation; Use dust masks (N95/FFP2) when handling powder; Use gloves and safety goggles; Avoid contact with combustible materials.

  • Personal Protective Equipment: Dust mask (N95/FFP2 or higher), safety goggles, chemical-resistant gloves, protective clothing.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using; Remove contaminated clothing and wash before reuse.

  • Storage: Store in tightly closed, moisture-proof containers; Store in cool, dry, well-ventilated area; Protect from moisture and heat; Keep away from combustible materials; Opened containers must be resealed immediately; Shelf life: 24-36 months under proper conditions.

  • Spill Management: Sweep or vacuum (HEPA) and place in suitable sealed container; Avoid dust formation; Do not allow entry into drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Non-hazardous waste; Can be incinerated in compliance with regulations.

DETECTION METHODS:

Method Description Advantages Disadvantages
Titrimetric (EDTA) Magnesium determination by complexometric titration Standard method, accurate Time-consuming
AAS / ICP Magnesium and trace element analysis High sensitivity, accurate High cost, requires expertise
Ion Chromatography Nitrate ion determination Specific nitrate analysis High cost, requires expertise
Gravimetric Analysis Magnesium oxide determination after ignition Standard method Time-consuming
pH Meter pH of solution Simple, rapid Indicative only

MAGNESIUM NITRATE vs ALTERNATIVES COMPARISON:

Product Chemical Name / E Code Application Strength Weakness Status
Magnesium Nitrate Mg(NO₃)₂ Fertilizer, analytical N + Mg source, water-soluble, oxidizer Not organic, oxidizing hazard Approved (not organic)
Magnesium Sulfate (Epsom Salt) MgSO₄ Fertilizer, medicine Safe, organic-approved, cheap No nitrogen, lower solubility Widely used (organic)
Magnesium Chloride MgCl₂ Fertilizer, de-icing High Mg content, water-soluble Can be corrosive, hygroscopic Approved (organic)
Magnesium Carbonate MgCO₃ Fertilizer, antacid Slow release Mg, safe Insoluble, no nitrogen Approved (organic)
Magnesium Oxide MgO Fertilizer, refractory High Mg content, cheap Insoluble, no nitrogen Approved

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Magnesium nitrate is an oxidizer; keep away from combustible materials and follow proper safety protocols.

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