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Send EmailName | Polyvinylpyrrolidone |
Synonyms | PVP K-30 PVP-K PVP-K30 PVP-K17 PVP-K25 PVP-K90 Povidone PVP K 30 Crospovidone Polyinylpyrrolidone Polyvinylpyrrolidine Polyvinylpyrrolidone Polyvinglpyrrolidone Polyvinyl pyrrolidone poly vinyl pyrrolidone |
CAS | 9003-39-8 |
EINECS | 1312995-182-4 |
Molecular Formula | (C6H9NO)n |
Molar Mass | 111.143 |
Density | 1,69 g/cm3 |
Melting Point | 130℃ |
Boling Point | 90-93 °C |
Water Solubility | >=10 g/100 mL at 20 C |
Appearance | White powder |
Storage Condition | Room Temprature |
Physical and Chemical Properties |
Melting Point: 130°C |
Use | Used as stationary liquid for gas chromatography |
Safety Description | S24/25 - Avoid contact with skin and eyes. |
Raw Materials | Ethanolamine 1,3-BUTADIENE 1,4-Butanediol N-Vinyl-2-pyrrolidone |
Preparation Method
Standard
Trait
Use
Differential diagnosis
Safety
sealed and preserved at room temperature, dry and protected from light.
Exam
take L. 00g of this product (calculated as anhydrous), weigh it accurately, put it in a 100ml measuring flask, add appropriate amount of water to dissolve it, after placing in a constant temperature water bath at 25°C ± 0.05°C for 1 hour, add water to dilute to the scale, check according to law (General rule 0633 method), and measure the relative viscosity to calculate the k value according to the following formula, should be 27.0 to 32.0.
take this product 1.0g (calculated by anhydrous), add water 20ml dissolved, check according to law (General rule 0631), pH value should be 3.0-7.0.
take about 20.0g of this product (calculated as anhydrous), put it in a round-bottom flask, add 4.5mol/L sulfuric acid solution, heat and reflux for 45 minutes, and let it cool; separately take hydroxylamine hydrochloride solution (take hydroxylamine hydrochloride 6.95g, add water to dissolve and dilute to 100ml, adjust pH value to 3.1ml with ammonia test solution) 20ml, put the Erlenmeyer flask, then place the Erlenmeyer flask in ice bath, connect the distillation device, the lower end of the condenser tube was inserted under the liquid surface of the human hydroxylamine hydrochloride solution, and heated for distillation. When the total volume of the receiving liquid was about 120ml, the distillation was stopped, and the distillate was titrated with sodium hydroxide solution (O .lmol/L) titration to pH value of 3.1, and the titration results with blank test correction, consumption of sodium hydroxide titration solution (0.lmol/L) shall not exceed 9.lml.
take 10.0g of this product (calculated as anhydrous), add water 80ml to dissolve, add sodium acetate lg, precision Iodine titration solution (0.05mol/L)10ml, place for 10 minutes, with sodium thiosulfate titration solution (O.lmol/L) titration, when the end point is reached, add 2ml of starch indicator solution, continue titration until the blue color disappears, and correct the titration result with blank test, consumption of Iodine titration solution (0.05mol/L) should not exceed 3.6.
take this product, according to the determination of moisture (General 0832), the water content shall not exceed 5.0%.
take l.Og of this product and check it according to law (General rule 0841). The residue left shall not exceed 0.1%.
The residue left under the item of taking the ignition residue shall not contain more than 10 parts per million of heavy metal when examined by law (General Principles 0821, Law II).
take this product about O.lg, precision weighing, put in the Kjeldahl nitrogen determination bottle, add potassium sulfate log and copper sulfate 0.5g successively, slowly add 20ml sulfuric acid along the wall of the bottle, put a small funnel at the mouth of the Kjeldahl nitrogen determination bottle, slowly heat with direct fire, once the solution had a clear green color, heating was continued for 30 minutes and allowed to cool. Transfer to a 100ml measuring flask, dilute to the scale with water, and shake. The distillate is titrated with a sulfuric acid titration solution (0704 mol/L) and the titration result is corrected with a blank test by precisely sucking 10ml and measuring according to the nitrogen determination method (General rule 0.005 second method). The nitrogen content should be between 11.5% and 12.8%, calculated as anhydrous.
Category
Storage
Nature
storage conditions | 2-8°C |
solubility | H2O: soluble100mg/mL |
morphology | powder |
color | White to yellow-white |
PH value | 3.0-5.0 |
water solubility | Soluble in water. |
sensitivity | Hygroscopic |
Merck | 14,7697 |
stability | Stable. Incompatible with strong oxidizing agents. Light sensitive. Hygroscopic. |
(IARC) Carcinogen Classification | 3 (Vol. 19, Sup 7, 71) 1987 |
Security information
WGK Germany | 1 |
RTECS number | TR8370000 |
auto-ignition temperature | 440 °C |
TSCA | Yes |
customs code | 39059990 |
Toxicity | LD50 orally in Rabbit: > 2000 mg/kg |