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Sodium Silicate, Sodium Siliconate, Sodium Polysilicate, Sodium Silicate Glass, 2 Module, 3 Module, 1344-09-8, 106985-35-7, 11105-00-3, 37299-97-1, 12013-79-5

Sodium Silicate, Sodium Siliconate, Sodium Polysilicate, Sodium Silicate Glass, 2 Module, 3 Module, 1344-09-8, 106985-35-7, 11105-00-3, 37299-97-1, 12013-79-5

SODIUM SILICATE (WATER GLASS)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Sodium Silicate
Chemical Name / Formula Sodium Silicate – Na₂(SiO₂)ₙO
Synonyms (Turkish) Sodyum Silikat, Cam Suyu, Water Glass, Soluble Glass, Sodyum Polisilikat, Sodyum Metasilikat
Synonyms (English) Sodium Silicate, Water Glass, Soluble Glass, Sodium Polysilicate, Sodium Sesquisilicate, Sodium Silicate Glass
CAS Numbers 1344-09-8 (General) / 106985-35-7 (Polysilicate) / 11105-00-3 (Sesquisilicate) / 37299-97-1 (Glass) / 12013-79-5 (Tetrasodium Orthosilicate)
EC Number 215-687-4
Appearance Clear, colorless, odorless; Commercial grades may appear green/blue tinted
Odor Odorless

CHEMICAL STRUCTURE

Sodium Silicate Structure (General):

    Na₂O · nSiO₂ · xH₂O

Structure Description:

  • Inorganic polymer composed of sodium oxide (Na₂O) and silicon dioxide (SiO₂).

  • Variable ratio of SiO₂ to Na₂O (modulus).

  • Clear, colorless, odorless liquid or solid (glass-like).

  • Highly alkaline (pH 11-12.5).

  • Soluble in water (solubility increases with temperature).

  • Forms colloidal solutions in water.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Sodium Silicate
Chemical Name / Formula Sodium Silicate – Na₂(SiO₂)ₙO
Synonyms (Turkish) Sodyum Silikat, Cam Suyu, Water Glass, Soluble Glass, Sodyum Polisilikat, Sodyum Metasilikat
Synonyms (English) Sodium Silicate, Water Glass, Soluble Glass, Sodium Polysilicate, Sodium Sesquisilicate, Sodium Silicate Glass, Sodium Siliconate
CAS Numbers 1344-09-8 (General) / 106985-35-7 (Polysilicate) / 11105-00-3 (Sesquisilicate) / 37299-97-1 (Glass) / 12013-79-5 (Tetrasodium Orthosilicate)
EC Number 215-687-4
Chemical Class Inorganic polymer; Silicate; Alkali silicate
Source Synthetic (fusion of silica sand with sodium carbonate)
Physical State (20°C) Liquid (viscous) or Solid (glass-like)
Odor Odorless
Color Clear, colorless; Commercial grades may appear green/blue tinted

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Clear, colorless, odorless liquid or glass-like solid Visual
Odor Odorless Olfactometric
Density 1.4 – 1.6 g/cm³ (liquid grades) ASTM D4052
pH (1% Solution) 11.0 – 12.5 (highly alkaline) pH Meter
Solubility in Water Soluble; Increases with temperature General Method
Viscosity Depends on polymerization degree and modulus Brookfield
Refractive Index 1.36 – 1.42 (depends on concentration)
Melting Point ~1088°C (solid)
Boiling Point ~100°C (as solution)
SiO₂ to Na₂O Ratio (Modulus) 1.5 – 4.0 (typical commercial grades: 2.0 and 3.0) Titrimetric
Stability Stable under normal conditions; Reacts with acids
Hygroscopicity Low to moderate
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP

SECTION 3: MODULUS COMPARISON

Property 2 Modulus (~2.0 SiO₂/Na₂O) 3 Modulus (~3.0 SiO₂/Na₂O)
Alkalinity Higher (more alkaline) Lower (less alkaline)
Viscosity Lower (more fluid) Higher (more viscous)
Solubility Higher Lower
SiO₂ Content Lower Higher
Na₂O Content Higher Lower
pH ~12.0 – 12.5 ~11.0 – 11.5
Polymerization Low High
Primary Applications General industrial, detergents, soap, textiles, ceramics, water softening Technical specialties, flameproof textiles, electrical insulation, wood preservation, refining

SECTION 4: SODIUM SILICATE vs OTHER SILICATES

Property / Application Sodium Silicate (Na₂(SiO₂)ₙO) Potassium Silicate (K₂SiO₃) Lithium Silicate (Li₂SiO₃) Calcium Silicate (Ca₂SiO₄ / CaSiO₃) Magnesium Silicate (Mg₂SiO₄ / MgSiO₃) Aluminum Silicate (Al₂SiO₅)
Form Liquid, glassy solid, powder Liquid, powder Liquid, powder Solid, powder Solid, powder Solid mineral
Appearance Clear, sometimes blue/green Clear or white Clear White powder White/gray powder White crystal
Alkalinity (pH) Strongly alkaline Alkaline, milder than sodium Alkaline, low viscosity Neutral – slightly basic Neutral Neutral
Solubility Soluble in water Soluble in water High solubility Insoluble (filler) Insoluble Insoluble
Primary Use Detergents, textiles, paper, cement, water treatment, adhesives, fire retardants Agriculture (foliar fertilizer), fireproof coatings, detergents Concrete hardener, lithium battery binder, high-performance coatings Insulation boards, fireproof materials, cement additive Substitute for talc, ceramics, refractories Ceramics, refractories, fillers
Construction Concrete hardener, waterproofing Fireproof coatings, cement stabilizer Concrete densifier Thermal insulation, cement additive Refractory bricks, ceramics Ceramic reinforcement
Detergent & Cleaning Builder, stabilizer Builder, stabilizer Limited use Not used Not used Not used
Textile Bleach stabilizer, flame retardant additive Flame retardant additive Flame retardant additive Not used Not used Not used
Water Treatment Coagulant, flocculant Limited use Limited use Not used Not used Not used
Special Uses Adhesives, coatings, metallurgy Silicon fertilizer in agriculture, protective coatings Lithium-ion battery industry, advanced coatings Fireproof insulation boards Talc substitute, ceramics High-temperature ceramics

SECTION 5: MECHANISM OF ACTION

Property Description
Alkalinity Provides high pH (11-12.5) in aqueous solutions; Acts as an alkaline buffer; Neutralizes acids; Used as a pH regulator and stabilizer.
Colloidal Behavior Forms colloidal silica particles in water; Polymerization creates network structures; Provides binding and adhesive properties; Used as a binder.
Precipitation / Coagulation Reacts with metal ions to form insoluble metal silicates; Used in water treatment as a coagulant and flocculant; Removes suspended solids and heavy metals.
Surface Binding Forms strong bonds with inorganic surfaces; Creates a protective film on surfaces; Used as a sealant and hardener in concrete and coatings.
Acid Reaction Reacts with acids to form silicic acid (H₂SiO₃) and sodium salts; Gelation occurs upon acidification; Forms silica gel; Used in various applications.
Viscosity Modification Polymerizes and depolymerizes depending on concentration and temperature; Modifies rheological properties; Used as a thickener and stabilizer.

SECTION 6: PRODUCTION PROCESS

Industrial Production Method:

Process Flow:
Silica Sand (SiO₂) + Sodium Carbonate (Na₂CO₃) → Fusion (1100-1400°C) → Sodium Silicate Glass (Water Glass) → Dissolution in Water → Filtration → Concentration → Cooling → Final Product

Step-by-Step Description:

  1. Raw Materials: High-purity silica sand (SiO₂) and sodium carbonate (Na₂CO₃, soda ash) are used as raw materials.

  2. Fusion: The raw materials are mixed and fused in a furnace at 1100-1400°C. The reaction produces sodium silicate glass (water glass).

  3. Dissolution: The cooled glass is dissolved in hot water under pressure to form an aqueous solution.

  4. Filtration: The solution is filtered to remove undissolved impurities.

  5. Concentration: The filtered solution is concentrated by evaporation to achieve the desired solids content.

  6. Cooling: The concentrated solution is cooled.

  7. Final Product: Liquid sodium silicate is obtained. Solid grades are obtained by further drying.

SECTION 7: FUNCTIONAL PROPERTIES

Property Description
Alkaline Builder Provides alkalinity in detergent formulations; Helps remove dirt and stains; Softens water; Prevents soil redeposition.
Binder / Adhesive Forms strong, rigid bonds; Used in paperboard, fiberboard, and laminated products; Provides high bonding strength.
Concrete Hardener Reacts with calcium hydroxide in cement; Forms calcium silicate hydrate; Improves mechanical strength; Reduces porosity; Enhances water resistance.
Flame Retardant Forms a protective glassy layer on surfaces; Acts as a fire barrier; Used in fireproof coatings and textiles; Reduces flame spread.
Water Treatment Acts as a coagulant and flocculant; Removes suspended solids; Precipitates heavy metals; Stabilizes pH; Improves water clarity.
Textile Auxiliary Stabilizes hydrogen peroxide in bleaching; Improves dye uptake; Enhances fabric flame retardancy; Regulates pH in dye baths.
Surface Sealer Forms a hard, impermeable layer on surfaces; Seals pores in concrete and masonry; Provides water resistance; Protects against acid attack.

SECTION 8: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Detergents & Cleaning Alkaline builder, soil dispersant, stabilizer Powder detergents (5-15% of formulation); Liquid detergents (2-5% viscosity regulator); Prevents scale formation; Disperses soil particles.
Textile Industry pH regulator, peroxide stabilizer, flame retardant, print fixative Bleaching baths (1-3%); Print fixing (2-4% solution); Flame retardant finishing; Stabilizes hydrogen peroxide.
Paper & Board Adhesive, surface hardener, ink fixative Paperboard adhesives (10-20% of formulation); Surface coating (5-10%); Improves board strength; Reduces ink spread.
Cement & Concrete Hardener, waterproofing additive, acid resistance enhancer Concrete additives (3-8%); Surface coating (10-15% solution); Improves mechanical strength; Optimizes curing time; Protects against acids.
Ceramics Clay deflocculant, binder, anti-coagulant Clay preparation (1-2%); Binder (3-5%); Improves workability; Prevents cracking and coagulation.
Water Treatment Coagulant, flocculant, pH buffer Treatment plants (10-50 mg/L dosage); Precipitates pollutants; Provides flocculation; Stabilizes pH.
Wood Preservation Preservative, fungicide, flame retardant Impregnation solutions (5-15%); Surface coating (10-20%); Protects against fungi and insects; Imparts flame retardancy.
Metallurgy & Foundry Mold binder, refractory additive, surface protectant Sand molds binder (3-6%); Refractory coatings (10-15%); Increases mold strength; Provides high-temperature stability.
Fire Protection Fireproof coating, additive Coating solutions (20-30%); Fire retardant mixtures (10-15%); Forms protective glassy film; Delays flame spread.

SECTION 9: QUALITY SPECIFICATIONS

Parameter 2 Modulus Grade 3 Modulus Grade Test Method
Appearance Clear, colorless to green/blue liquid Clear, colorless to green/blue liquid Visual
SiO₂ Content ~25 – 30% ~28 – 33% Titrimetric
Na₂O Content ~12 – 15% ~9 – 12% Titrimetric
Modulus (SiO₂/Na₂O) ~2.0 (±0.2) ~3.0 (±0.3) Titrimetric
Density (20°C) 1.40 – 1.50 g/cm³ 1.45 – 1.55 g/cm³ ASTM D4052
pH (1% Solution) 12.0 – 12.5 11.0 – 11.5 pH Meter
Viscosity (25°C) 5 – 50 cP 50 – 500 cP Brookfield
Iron (Fe) ≤ 50 ppm ≤ 50 ppm AAS / ICP
Heavy Metals (as Pb) ≤ 10 ppm ≤ 10 ppm AAS / ICP
Water Insoluble ≤ 0.1% ≤ 0.1% Gravimetric

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 1,500 – 2,500 mg/kg (moderate toxicity)
Acute Dermal Toxicity Corrosive; Causes severe skin burns
Skin Irritation Corrosive (Category 1A/1B/1C)
Eye Irritation Serious eye damage (Category 1)
Inhalation Toxicity May cause respiratory irritation; Corrosive to respiratory tract
Chronic Toxicity Repeated exposure may cause dermatitis; Inhalation may cause lung damage
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity at normal levels
Environmental Toxicity May be harmful to aquatic life at high pH; Toxic at high concentrations
Special Toxicity Note Corrosive; Causes severe skin burns and eye damage (H314); Harmful if swallowed (H302); May cause respiratory irritation (H335); High alkalinity; Use appropriate PPE; Avoid contact with eyes and skin.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Acute Toxicity (Oral) Category 4 H302
Skin Corrosion/Irritation Category 1A H314
Serious Eye Damage Category 1 H318
Specific Target Organ Toxicity (Single) Category 3 H335

Signal Word: DANGER

Hazard Pictograms: GHS05 (Corrosive), GHS07 (Exclamation Mark)

Hazard Statements (H-Codes):

Code Statement
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
3 0 1 ALK
(Severe health hazard - corrosive) (Non-flammable) (Mild reactivity) (Alkali)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P310 Immediately call a POISON CENTER/doctor
P363 Wash contaminated clothing before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If respiratory irritation develops, seek medical attention.
Skin Contact Immediately remove contaminated clothing. Rinse with plenty of water for at least 15 minutes. Get immediate medical attention.
Eye Contact Immediately rinse with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Get immediate medical attention.
Ingestion DO NOT INDUCE VOMITING. Rinse mouth. Drink plenty of water (only if conscious). Get immediate medical attention.
Note Sodium silicate is corrosive; do not attempt to neutralize with acids; high alkalinity causes burns.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-flammable.
Hazards Arising from Fire May release sodium oxide and silicon dioxide fumes at high temperatures.
Suitable Extinguishing Media Water spray, CO₂, dry chemical powder, foam.
Unsuitable Extinguishing Media None
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing, chemical-resistant gloves.
Special Precautions Prevent material from entering sewers and waterways; Evacuate area; Use protective equipment.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM MOISTURE and CO₂; Keep away from acids.
Container Requirements Tightly closed, corrosion-resistant containers (HDPE, lined steel, coated drums).
Materials to Protect From Moisture, CO₂, acids, organic materials
Shelf Life 12 – 36 months (in unopened original packaging, under proper storage conditions).
Stability Note Stable under recommended storage conditions; May absorb CO₂ and form sodium carbonate; Protect from moisture; May thicken at low temperatures.
Special Storage Requirements Store in a dry, cool place; Avoid exposure to air and moisture; Opened containers must be resealed immediately; Keep away from acids.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
HDPE Canister 5 L, 10 L, 20 L HDPE (chemical-resistant)
HDPE Drum 80 kg, 100 kg, 200 kg HDPE (sealed, chemical-resistant)
IBC Container 1400 kg, 1500 kg HDPE or coated steel IBC
Road Tanker 10,000 – 30,000 kg Stainless steel or lined carbon steel

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number UN 1824 (Sodium Hydroxide Solution) / UN 3253 (Disodium Trioxosilicate)
Hazard Class Class 8 - Corrosive Substances
Packing Group III
ADR/RID Class 8; UN 1824; Packing Group III
IMDG Code Class 8; UN 1824; Marine pollutant: No
IATA (Air) Class 8; UN 1824; Packing Group III
Transport Label Corrosive (Class 8)
Marine Pollutant No
Special Transport Requirements Segregation from acids and combustible materials; Protect from moisture; Handle with care.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Regulated as corrosive substance; Approved for industrial use.
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) Approved for food contact applications (indirect).
Turkey Regulated as hazardous chemical; Subject to KKDIK regulation; Ministry of Environment controls.
IARC Not classified (non-carcinogenic)
NTP Not listed
OSHA Regulated as corrosive.
California (Prop 65) Not listed
Halal Yes (with certification)
Kosher Yes (with certification)
Vegan Yes (mineral, no animal ingredients)

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Sodyum Silikat, Cam Suyu, Water Glass, Soluble Glass, Sodyum Polisilikat, Sodyum Metasilikat
English Names Sodium Silicate, Water Glass, Soluble Glass, Sodium Polysilicate, Sodium Sesquisilicate, Sodium Silicate Glass, Sodium Siliconate
CAS Numbers 1344-09-8 / 106985-35-7 / 11105-00-3 / 37299-97-1 / 12013-79-5
EC Number 215-687-4
HS Code 2839.19

SECTION 20: SUMMARY TABLE

Parameter Value
Product Sodium Silicate (Water Glass)
CAS Number 1344-09-8 (General)
Chemical Formula Na₂(SiO₂)ₙO
Appearance Clear, colorless, odorless liquid or glass-like solid
Density 1.4 – 1.6 g/cm³
pH (1% Solution) 11.0 – 12.5
Modulus (SiO₂/Na₂O) 2.0 – 3.0 (commercial grades)
Primary Functions Alkaline builder, binder, hardener, coagulant, flame retardant
Main Application Areas Detergents, textiles, paper, cement, water treatment, wood preservation, metallurgy, fire protection
Shelf Life 12 – 36 months
GHS Signal Word DANGER
UN Number 1824
Hazard Class Class 8 (Corrosive)
Packing Group III
Special Properties Strong alkali; Corrosive; pH buffer; Binder; Coagulant; Water-soluble; Non-flammable; Versatile industrial uses.

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • CORROSIVE (H314, H318): Causes severe skin burns and eye damage. PERSONAL PROTECTIVE EQUIPMENT IS MANDATORY.

  • HARMFUL IF SWALLOWED (H302): Avoid ingestion; Use appropriate safety measures.

  • MAY CAUSE RESPIRATORY IRRITATION (H335): Avoid inhalation of vapors/mists.

  • HIGH ALKALINITY: pH 11-12.5; Reacts with acids (neutralization).

  • REACTS WITH CO₂: Absorbs CO₂ from air to form sodium carbonate; Affects product quality over time.

  • VERY THICK / VISCOUS: Low temperatures may increase viscosity; Warm before use if needed.

  • INCOMPATIBLE WITH ACIDS: May react violently; May form silica gel upon acidification.

  • METAL CORROSION: Corrosive to aluminum, zinc, tin, and other metals.

  • ENVIRONMENTAL: High pH may harm aquatic life; Dilute before discharge.

BEST PRACTICE RECOMMENDATIONS:

  • Detergents & Cleaning: Use as alkaline builder; Dosage: 5-15% (powder), 2-5% (liquid); Prevents scale formation and soil redeposition.

  • Textile Industry: Use as bleach stabilizer and flame retardant; Dosage: 1-3% (bleaching), 2-4% (print fixing); Stabilizes hydrogen peroxide.

  • Paper & Board: Use as adhesive and surface hardener; Dosage: 10-20% (adhesives), 5-10% (surface coating); Improves board strength.

  • Cement & Concrete: Use as hardener and waterproofing additive; Dosage: 3-8% (additive), 10-15% (surface coating); Improves mechanical strength and acid resistance.

  • Water Treatment: Use as coagulant and flocculant; Dosage: 10-50 mg/L; Removes suspended solids and heavy metals.

  • Wood Preservation: Use as preservative and flame retardant; Dosage: 5-15% (impregnation), 10-20% (surface coating); Protects against fungi and insects.

  • Handling: Use in well-ventilated areas; Avoid inhalation of vapors/mists; Use chemical-resistant equipment; Avoid contact with eyes and skin; Wear appropriate PPE.

  • Personal Protective Equipment: MANDATORY: Chemical-resistant gloves (nitrile, neoprene), safety goggles or face shield, protective clothing (PVC or neoprene), chemical-resistant apron, chemical-resistant boots.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using; Remove contaminated clothing and wash before reuse.

  • Storage: Store in tightly closed, corrosion-resistant containers; Store in cool, dry, well-ventilated area; Protect from CO₂ and moisture; Keep away from acids; Opened containers must be resealed immediately; Shelf life: 12-36 months under proper conditions.

  • Spill Management: Neutralize with acid (carefully); Absorb with inert material (sand, vermiculite); Collect in suitable sealed container; Do not allow entry into drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Hazardous waste (corrosive); Neutralize before disposal; Use authorized disposal facilities.

DETECTION METHODS:

Method Description Advantages Disadvantages
Titrimetric (Acid-Base) Neutralization with standard acid Simple, accurate, standard method Requires indicator
Gravimetric (SiO₂) Silica precipitation and weighing Accurate for modulus determination Time-consuming
AAS / ICP Trace metal analysis (Fe, Na, etc.) High sensitivity, accurate High cost, requires expertise
pH Meter pH of solution Simple, rapid Indicative only
Viscometry Viscosity measurement Rapid, simple Not specific
Density Measurement Specific gravity Rapid, simple Not specific

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Sodium silicate is a corrosive substance; strict safety protocols must be followed at all times.

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