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DIETHYLENE GLYCOL, DEG, 111-46-6

DIETHYLENE GLYCOL, DEG, 111-46-6

DIETHYLENE GLYCOL

CAS: 111-46-6

Molecular Formula: C4H10O3

Names and Identifiers

Name DIETHYLENE GLYCOL
Synonyms DEG
NSC 36391
Brecolane NDG
Diethyleneglyc
2,2'-oxyethanol
2,2'-Oxyethanol
Diethylene glyco
2,2'-oxydiethanol
2,2'-oxydi-ethano
DIETHYLENE GLYCOL
Diethylene glycol
2,2'-oxybis-ethano
3-Oxa-1,5-pentanediol
3-Oxapentane-1,5-diol
2,2'-dihydroxyethylether
2,2'-Dihydroxyethyl ether
2-(2-Hydroxyethoxy)ethanol
2,2-Di(hydroxyethyl) ether
2-(2-hydroxyethoxy)-ethanol
bis(beta-hydroxyethyl)ether
2-(2-hydroxy-ethoxy)-ethanol
Bis(beta-hydroxyethyl) ether
3-OxapentaMethylene-1,5-diol
Di-ethylene glycol,Ethylene diglycol
2,2'-Oxydiethanol Bis(2-hydroxyethyl) Ether
Diethylene glycol, Bis(2-hydroxyethyl) ether
CAS 111-46-6
EINECS 203-872-2
InChI InChI:1S/C4H10O3/c5-1-3-7-4-2-6/h5-6H,1-4H2
InChIKey MTHSVFCYNBDYFN-UHFFFAOYSA-N

Physico-chemical Properties

Molecular Formula C4H10O3
Molar Mass 106.12
Density 1.118g/mLat 25°C(lit.)
Melting Point −10°C(lit.)
Boling Point 245°C(lit.)
Flash Point 143 °C
Water Solubility SOLUBLE
Solubility Miscible with water, insoluble in benzene, toluene, carbon tetrachloride.
Vapor Presure 0.01 mm Hg ( 20 °C)
Vapor Density 2.14 (vs air)
Appearance Colorless transparent oily liquid
Color colorless
Odor Practically odorless.
Maximum wavelength(λmax) λ: 260 nm Amax: ≤0.02λ: 280 nm Amax: ≤0.01
Merck 14,3119
BRN 969209
pKa 14.03±0.10(Predicted)
PH 5.5-7.0 (25℃, 50mg/mL in H2O)
Storage Condition Keep in dark place,Sealed in dry,Room Temperature
Stability Hygroscopic
Sensitive Hygroscopic
Explosive Limit 2-12.3%
Refractive Index n20/D 1.447(lit.)
MDL MFCD00002882
Physical and Chemical Properties Appearance colorless or light yellow transparent liquid
relative density (d 204) 1.1147~1.1180
boiling point ℃ ≥ 241
boiling range (distilling out 90% by volume)] ℃ ≤ 250
flash point ℃ 141
Use It is used as a gas dehydrating agent and an aromatic extraction solvent, and also used as a lubricant, softener and finishing agent for textiles, as well as a plasticizer, wetting agent, sizing agent, nitrocellulose, resin, grease and other solvents.

Risk and Safety

Risk Codes 22 - Harmful if swallowed
Safety Description 46 - If swallowed, seek medical advice immediately and show this container or label.
WGK Germany 1
RTECS ID5950000
FLUKA BRAND F CODES 10
TSCA Yes
HS Code 29094100
Hazard Note Toxic/Irritant
Toxicity LD50 in rats, guinea pigs (g/kg): 20.76, 13.21 orally (Smyth)

Introduction

Easy to absorb moisture, no smell, spicy sweet taste, soluble in water can be combined with most organic solvents, insoluble in benzene and carbon tetrachloride. Easy to esterify and etherify.

Reference Information

introduction diethylene glycol, also known as diethylene glycol, forms ester when it reacts with anhydride. It reacts with alkyl sulfate or halogenated hydrocarbon to form ether. It is mainly used as a gas dehydrating agent and extractant, and also as a lubricant and finishing agent for textiles. It is obtained by the interaction of ethylene oxide and ethylene glycol. Diethylene glycol has been widely used in various cosmetics as a solvent, heat preservation agent, and viscosity control agent. It has been used in my country for nearly 20 years, and no problems have been found during this period.
application diethylene glycol can directly use solvents, natural gas dehydration desiccant, aromatics separation and extraction agents, textile lubricants, softeners, finishing agents, nitrocellulose, resin, grease, printing ink and other solvents, and are also used as antifreeze components in brake fluid and compressor lubricating oil, it can also be used to prepare cleaning agents and as dispersible solvents in other daily chemicals such as inks.
preparation a diethylene glycol purification process, the steps are: ① dissolution: adding 3-4wt% strong alkali and 3-4wt% chloroethane to the crude diethylene glycol, and stirring at 100 ℃ for 1.5-2 hours to obtain liquid; (2) Decompression distillation: the liquid obtained in step (1) is subjected to decompression distillation, and the fraction at 150 to 155 degrees C is collected to obtain purified diethylene glycol.
chemical properties colorless, odorless, transparent, hygroscopic viscous liquid. It has a spicy sweet taste. Miscible with water, ethanol, acetone, ether, ethylene glycol, not with benzene, toluene, carbon tetrachloride.
use used to prepare plasticizer, also used as extractant, desiccant, heat preservation agent, softener and solvent, etc.
diethylene glycol is mainly used for dehydration of natural gas and aromatics extraction, and is used as a solvent for ink bonding and textile dyes, it is also used in the production of rubber and resin plasticizers, polyester resins, fiber glass, urethane foams, lubricating oil viscosity improvers and other products.
It is used as a gas dehydrating agent and aromatics extraction solvent, as well as as a lubricant, softener and finishing agent for textiles, as well as plasticizer, humidification agent, sizing agent, nitrocellulose, resin and grease And other solvents.
solvent, gas dehydrating agent, extractant, water softener, gas chromatography liquid, suitable for analysis of aqueous solution, selective polyethylene glycol is similar, used for analysis of content oxygen compounds (especially alcohol), aniline, fatty amine, pyridine and quinoline.
production method diethylene glycol is a by-product of ethylene oxide to ethanol.
spontaneous combustion temperature 442 °F

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