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Silicic Acid, Orthosilicic Acid, Ortho Silicic Acid, 10193-36-9

Silicic Acid, Orthosilicic Acid, Ortho Silicic Acid, 10193-36-9

SILICIC ACID (INCLUDING ORTHOSILICIC ACID)

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Product Name Silicic Acid
General Formula [SiOx(OH)4-2x]n
CAS Number (Orthosilicic Acid) 10193-36-9
Chemical Class Inorganic acid / Silicate family
Natural Occurrence Dissolved in ocean and river waters (~150 µM)

CHEMICAL DESCRIPTION:

Silicic acid is a hydrated form of silicon oxide. It is the general name for a family of chemical compounds formed by silicon with varying amounts of hydrogen and oxygen molecules. After oxygen, silicon is the most abundant element in nature. In aqueous environments, it does not ionize, allowing silicon salts in oceans to form silicic acid. The most common and biologically available form is orthosilicic acid (H₄SiO₄).

2. TYPES AND PROPERTIES OF SILICIC ACID

Type Chemical Formula Physical Properties Solubility Bioavailability Key Applications
Orthosilicic Acid H₄SiO₄ Colorless, odorless, liquid form Soluble in water High Health supplements, bone and hair health
Metasilicic Acid H₂SiO₃ White, amorphous solid Insoluble in water Low Industrial additives, ceramics, glass
Disilicic Acid H₂Si₂O₅ Crystalline structure Poor solubility Medium Mineral structures, geological formations
Silica Gel (Amorphous) SiO₂·nH₂O White, gelatinous Insoluble None Desiccant, moisture absorbers
Crystalline Silicic Acid SiO₂ Hard, crystalline Insoluble None Glass, electronics, construction materials

3. PHYSICAL PROPERTIES

Property Amorphous Form Crystalline Form
Appearance White, tasteless Rock crystal
Solubility Insoluble in water Insoluble
Density ~2.2 g/cm³ ~2.6 g/cm³
pH Weakly acidic (proton loss begins at pH ~10) -
Molecular Weight (H₄SiO₄) 96.11 g/mol -

4. CHEMICAL REACTIONS

Reaction Description
Polymerization When solubility is exceeded, reacts with itself to form amorphous silica hydrate
Reaction with Aluminum Combines with aluminum hydroxide to form aluminum silicate hydroxide
Reaction with Molybdate Forms heteropolyacids such as silicomolybdic acid with excess molybdate
Reaction with Acids Very dilute silica solution does not precipitate with acids; remains as hydrate
Proton Loss Weakly acidic; first proton loss begins at pH ~10

5. NATURAL OCCURRENCE

Source Description
Oceans Average concentration of ~150 µM; annual net input of 6.1 ± 2.0 teramoles of silicon
Rivers ~80% of global silicic acid input comes from rivers
Plants Borago officinalis (Borage) contains up to 2.2% silicic acid
Marine Sediments Net biogenic silicon yield of 7.1 ± 1.8 teramoles per year
Beverages Naturally found in beverages such as beer

6. APPLICATIONS AND USES

Sector / Application Description
Toothpaste Used as an abrasive gel in combination with calcium carbonate for plaque removal
Desiccant (Silica Gel) Moisture-absorbing properties used in vitamin bottles, electronics, shoes, and leather products
Decorative Used in chemical gardens, magic rocks, and crystal gardens
Industrial Additive in glass, ceramics, fertilizer production, and construction materials
Medical & Supplements Used as orthosilicic acid for bone health, hair, and skin health
Electronics Crystalline silicic acid (quartz) used in electronic circuits
Geology Mineral structures and geological formations

7. HEALTH AND SAFETY

Parameter Information
FDA Status Recognized as safe (GRAS)
Toxicity No known toxicity or carcinogenicity
Skin Irritation May be irritating at high concentrations
Eye Irritation May be irritating at high concentrations
Inhalation Dust inhalation poses risk to lungs and nervous system
Special Warning Use with caution in kidney patients
Personal Protection Use mask and safety goggles when handling powder

8. STORAGE AND HANDLING

Parameter Information
Storage Conditions Dry, cool environment
Keep Away From Moisture
Shelf Life Unlimited under proper storage
Packaging Sealed containers (silica gel packets)
Special Warning Protect from moisture; otherwise may transform into gel form

9. MEDICAL BENEFITS (ORTHOSILICIC ACID)

Application Description
Bone Health A 2008 study of 136 osteopenic patients showed improved bone formation with orthosilicic acid combined with calcium and vitamin D. Stimulates collagen production and bone-forming cell development.
Hair Health A 2007 study of 48 women showed increased hair strength and thickness; improved hair quality with orthosilicic acid supplementation.
Other Potential Uses Being researched for Alzheimer's, arthritis, atherosclerosis, hypertension, heart disease, osteoporosis, and stroke treatment.
Bioavailability Orthosilicic acid is the most bioavailable form of silicon for humans.

10. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Silicic acid is the general name for hydrated silicon oxide forms. Its general formula is [SiOx(OH)4-2x]n. The most common and biologically available form is orthosilicic acid (H₄SiO₄). It exists in two main forms: amorphous and crystalline. It is found dissolved in ocean and river waters and occurs naturally in plants.

Key Types:

Type Formula Application
Orthosilicic Acid H₄SiO₄ Health supplements
Metasilicic Acid H₂SiO₃ Industrial production
Silica Gel SiO₂·nH₂O Desiccant
Quartz SiO₂ Glass, electronics

CRITICAL WARNINGS:

  1. Bioavailability: Orthosilicic acid is the most biologically available form of silicon for humans.

  2. Proton Loss: Silicic acid is a very weak acid; the first proton loss begins at pH ~10.

  3. Polymerization: When solubility is exceeded, amorphous silica hydrate forms.

  4. Health Warnings: Although recognized as safe by the FDA, high concentrations may cause skin and eye irritation. Inhalation poses risks to lungs and nervous system. Use with caution in kidney patients.

  5. Storage: Protect from moisture; otherwise may transform into gel form.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. All local, national, and international regulations must be followed when working with Silicic Acid. Medical applications should be conducted under professional medical supervision.

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