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Tetraisobutyl Thiuram Disulfide, Thioperoxy Dicarbonic Diamide, Isobutyl Thiuram Disulfide, TiBTD, 3064-73-1

Tetraisobutyl Thiuram Disulfide, Thioperoxy Dicarbonic Diamide, Isobutyl Thiuram Disulfide, TiBTD, 3064-73-1

TETRAISOBUTYLTHIURAM DISULFIDE (TiBTD)

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name Thioperoxydicarbonic diamide, tetrakis(2-methylpropyl)
Other Names Tetraisobutylthiuram disulfide, TiBTD, Isobutyl thiuram disulfide
CAS Number 3064-73-1
Molecular Formula C₁₈H₃₆N₂S₄
Molecular Weight 408.75 g/mol
Chemical Class Thiuram sulfide / Vulcanization accelerator
Appearance Light yellow / beige granules or powder
Odor Slight characteristic odor
Density ~1.2 g/cm³
Melting Point 100 – 110 °C
Solubility in Water Insoluble
Solubility in Organic Solvents Limited solubility

2. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Molecular Formula C₁₈H₃₆N₂S₄
Molecular Weight 408.75 g/mol
Appearance Light yellow / beige granules or powder
Density ~1.2 g/cm³
Melting Point 100 – 110 °C
Solubility in Water Insoluble
Solubility in Organic Solvents Limited
Dust Explosion Class St 1 (moderate explosive)
Shelf Life 12-24 months (under proper storage)

3. APPLICATIONS AND INDUSTRIAL USES

Sector Application
Rubber Industry Accelerator in rubber vulcanization
Tire Manufacturing Vulcanization of natural and synthetic rubber
Rubber Products Industrial rubber goods
Rubber Compounds Primary or secondary accelerator in vulcanization systems

4. HAZARD INFORMATION

Parameter Value
GHS Classification GHS07 (Warning), GHS09 (Environment)
Signal Word Warning
Hazard Statements H302 (Harmful if swallowed), H315 (Skin irritation), H319 (Serious eye irritation), H335 (Respiratory tract irritation), H413 (May cause long-lasting harmful effects to aquatic life)
Precautionary Statements P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P405, P501
Risks Dust explosion hazard (flammable dust)
Exposure Limits Occupational exposure limits vary by country

5. HEALTH RISKS

Exposure Route Effect
Inhalation Dust inhalation may cause respiratory tract irritation
Skin Contact May cause skin irritation
Eye Contact May cause serious eye irritation
Ingestion Harmful if swallowed
Chronic Effects Prolonged exposure may cause skin sensitization

6. FIRST AID MEASURES

Exposure Route Action
Eye Contact Rinse with plenty of water for at least 15 minutes. Remove contact lenses. Seek medical attention.
Skin Contact Wash with water and soap. Remove contaminated clothing. If irritation persists, seek medical attention.
Inhalation Move to fresh air. If symptoms persist, seek medical attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek medical attention.

7. FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Flammable dust explosion hazard
Suitable Extinguishing Media Water spray, foam, dry chemical powder, CO₂
Special Hazards Combustion produces toxic fumes (carbon oxides, nitrogen oxides, sulfur compounds)
Protective Equipment Full face mask and self-contained breathing apparatus (SCBA)
Explosion Hazards Dust-air mixtures may be explosive

8. HANDLING AND STORAGE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area
Storage Temperature < 30°C
Keep Away From Heat, sparks, open flames, strong oxidizers, acids
Shelf Life 12-24 months (under proper storage)
Packaging Tightly closed, moisture-protected containers
Hygroscopicity No
Dust Control Use closed systems to prevent dust formation

9. TRANSPORT INFORMATION

Parameter Information
UN Number 3077 (Environmentally hazardous substance)
Hazard Class 9
Packing Group III
Proper Shipping Name Thioperoxydicarbonic diamide, tetrakis(2-methylpropyl)
Marine Pollutant Yes
ADR/RID Label 9

Transport Notes:

  • Subject to ADR/RID, IMDG, IATA hazardous goods regulations

  • Static electricity precautions required when handling in powder form

10. ENVIRONMENTAL INFORMATION

Parameter Information
Ecotoxicity May cause long-lasting harmful effects to aquatic life (H413)
Bioaccumulation Low
Environmental Impact Must be prevented from entering water sources
Waste Management Must be disposed in accordance with local environmental regulations
Recycling Not feasible; requires special disposal

11. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; registration required
USA (TSCA) Listed
EINECS 221-307-8
Customs Tariff Code 2930.30.00

12. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Tetraisobutylthiuram Disulfide (TiBTD, CAS 3064-73-1) is a light yellow/beige granule or powder used as a thiuram sulfide vulcanization accelerator in the rubber industry. It is used as a primary or secondary accelerator in the vulcanization of natural and synthetic rubber.

Key Properties:

Property Value
Formula C₁₈H₃₆N₂S₄
CAS No 3064-73-1
Molecular Weight 408.75 g/mol
Melting Point 100-110 °C
Appearance Light yellow/beige granule/powder
UN No 3077

CRITICAL WARNINGS:

  1. Dust Explosion Risk: TiBTD in powder form presents a flammable dust explosion hazard. Use closed systems to prevent dust formation and implement static electricity precautions.

  2. Environmental Impact: May cause long-lasting harmful effects to aquatic life (H413). Must be strictly prevented from entering water sources.

  3. Storage: Store in cool, dry, well-ventilated areas away from heat and ignition sources. Protect from moisture.

  4. Personal Protection: Use protective gloves, safety goggles, and dust mask during handling. Ensure adequate ventilation.

  5. Transport: Classified as UN 3077 (Environmentally hazardous substance). Must be transported in accordance with ADR/RID, IMDG, and IATA regulations.

  6. Waste Management: Must be disposed in accordance with local environmental regulations.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. All local, national, and international regulations must be followed when working with Tetraisobutylthiuram Disulfide.

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