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Tin Phosphate, Stannous Phosphate, Tin Ortho Phosphate, 13774-29-1

Tin Phosphate, Stannous Phosphate, Tin Ortho Phosphate, 13774-29-1

TIN PHOSPHATE

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name Tin(II) phosphate
Other Names Stannous phosphate, Tin orthophosphate
CAS Number 13774-29-1
EC Number (EINECS) 237-398-6
Chemical Formula Sn₃(PO₄)₂
Molecular Weight 626.1 g/mol
Chemical Class Inorganic phosphate / Tin salt
Appearance White to gray powder
Odor Odorless
Density ~4.0 g/cm³
Melting Point Decomposes at high temperatures
Solubility in Water Insoluble
Solubility in Acids Partially soluble
Solubility in Organic Solvents Insoluble
pH (Aqueous Suspension) ~6-7

CHEMICAL STRUCTURE AND DESCRIPTION:

Tin Phosphate (Sn₃(PO₄)₂) is the phosphate salt of tin in the +2 oxidation state. It consists of three tin ions (Sn²⁺) and two phosphate ions (PO₄³⁻). It is insoluble in water but partially soluble in acids. It is used as an additive in the ceramics and glass industry, in pigment production, and in special catalytic applications. Tin compounds are valuable for producing heat-resistant and corrosion-resistant materials.

Structural Features:

  • Tin ion in +2 oxidation state

  • Phosphate ions (PO₄³⁻)

  • Insoluble in water

  • Stable at high temperatures

  • White/gray powder form

2. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Chemical Formula Sn₃(PO₄)₂
Molecular Weight 626.1 g/mol
Appearance White to gray powder
Odor Odorless
Density ~4.0 g/cm³
Melting Point Decomposes at high temperatures
Solubility in Water Insoluble
Solubility in Acids Partially soluble
Solubility in Organic Solvents Insoluble
pH (Aqueous Suspension) ~6-7

3. SOLUBILITY PROFILE

Solvent Solubility
Water Insoluble
Dilute Acids Partially soluble
Concentrated Acids Partially soluble
Organic Solvents Insoluble
Alkalis Insoluble

4. APPLICATIONS AND INDUSTRIAL USES

Sector Application
Ceramics Industry Additive in ceramic production
Glass Industry Additive in glass production
Pigments Pigment production
Catalysts Special catalytic applications
Coatings Protective coating formulations

5. SPECIFICATIONS (TYPICAL)

Parameter Specification
Purity (Sn₃(PO₄)₂) ≥ 98.0%
Appearance White to gray powder
Tin Content (Sn) ~55-58%
Phosphate Content (PO₄) ~40-42%
Insoluble Matter ≤ 0.1%
Lead (Pb) ≤ 0.001%
Iron (Fe) ≤ 0.001%
Chloride (Cl) ≤ 0.01%
Sulfate (SO₄) ≤ 0.01%
Moisture ≤ 0.5%

6. HANDLING AND STORAGE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area
Storage Temperature Room temperature (15-25°C)
Keep Away From Strong acids, moisture
Shelf Life 24-36 months (under proper storage)
Packaging Tightly closed plastic or paper bags
UN Number Not classified as dangerous for transport

Handling Notes:

  • Avoid dust formation and inhalation

  • Avoid skin and eye contact

  • Use in well-ventilated areas

  • Protect from moisture

7. SAFETY AND TOXICOLOGY

Parameter Value
GHS Classification GHS07 (Warning)
Signal Word Warning
Hazard Statements H315 (Skin irritation), H319 (Serious eye irritation), H335 (Respiratory tract irritation)
Precautionary Statements P261, P280, P302+P352, P304+P340, P305+P351+P338
Toxicity Inhalation of dust may be harmful
Exposure Routes Inhalation, skin contact, eye contact
Symptoms Respiratory tract irritation, skin irritation, eye irritation
Target Organs Respiratory system, skin, eyes
Carcinogenicity Not classified
Ecotoxicity Low to moderate aquatic toxicity

Personal Protective Equipment:

  • Chemical-resistant gloves

  • Safety goggles

  • Protective clothing

  • Dust mask (P2 or N95)

  • Adequate ventilation must be provided

8. FIRST AID MEASURES

Exposure Route Action
Inhalation Move to fresh air. If breathing difficulty occurs, administer oxygen. Seek medical attention.
Skin Contact Remove contaminated clothing. Wash with plenty of water and soap. Seek medical attention.
Eye Contact Rinse with plenty of water for at least 15 minutes. Remove contact lenses. Seek medical attention.
Ingestion Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Seek medical attention.

9. ENVIRONMENTAL INFORMATION

Parameter Information
Ecotoxicity Low to moderate aquatic toxicity
Bioaccumulation Not expected
Environmental Impact Must be prevented from entering water and soil sources
Waste Management Must be disposed in accordance with local regulations

10. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified as dangerous for transport
Hazard Class Not classified
Packing Group Not applicable
Proper Shipping Name Tin Phosphate
Marine Pollutant No
ADR/RID Label None

11. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; registration required
USA (TSCA) Listed
Customs Tariff Code 2835.29.00.00.00

12. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Tin Phosphate (Sn₃(PO₄)₂, CAS 13774-29-1) is a white to gray powder with a molecular weight of 626.1 g/mol and density of approximately 4.0 g/cm³. It is insoluble in water but partially soluble in acids.

Its most important applications include use as an additive in the ceramics and glass industry, in pigment production, and in special catalytic applications.

Inhalation of dust may be harmful. May cause skin, eye, and respiratory tract irritation. Storage should be in cool, dry, well-ventilated areas, in tightly closed containers, away from moisture and strong acids.

Key Properties:

Property Value
Formula Sn₃(PO₄)₂
CAS No 13774-29-1
Molecular Weight 626.1 g/mol
Appearance White/gray powder
Density ~4.0 g/cm³
Water Solubility Insoluble
Primary Use Ceramics, glass, pigments

CRITICAL WARNINGS:

  1. Dust Inhalation: Inhalation of dust may cause respiratory tract irritation. Avoid dust formation and use appropriate respiratory protection.

  2. Acid Reactivity: Partially soluble in acids. Avoid contact with strong acids.

  3. Storage: Protect from moisture. Store in tightly closed containers.

  4. Customs Classification: The correct customs tariff code is 2835.29.00.00.00.

  5. Regulatory Compliance: REACH, KKDİK, and TSCA registration requirements apply.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. All local, national, and international regulations must be followed when working with Tin Phosphate.

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