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Nickel Acetate Tetrahydrate, Nickel Acetate Anhydrous, Nickelous Acetate, Nickel Diacetate, 373-02-4, 6018-89-9

Nickel Acetate, Nickel Acetate Tetrahydrate, Nickel Acetate Anhydrous, Nickelous Acetate, Nickel Diacetate, 373-02-4, 6018-89-9

NICKEL ACETATE

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name Nickel(II) Acetate Tetrahydrate
Other Names Nickelous acetate, Nickel diacetate
CAS Number 373-02-4 (anhydrous) / 6018-89-9 (tetrahydrate)
EC Number (EINECS) 206-761-7
Chemical Formula Ni(CH₃COO)₂·4H₂O
Molecular Weight 248.84 g/mol (tetrahydrate)
Chemical Class Transition metal acetate / Organic acid salt
Appearance Greenish crystalline solid or powder
Odor Slight acetic acid odor
Density ~1.74 g/cm³
Melting Point ~235 °C (decomposes)
pH (Aqueous Solution) ~6-7

CHEMICAL STRUCTURE AND DESCRIPTION:

Nickel Acetate (Ni(CH₃COO)₂·4H₂O) is the acetate salt of nickel in the +2 oxidation state. It consists of a nickel ion (Ni²⁺) and two acetate ligands (CH₃COO⁻). It is soluble in water and appears as greenish crystals. It is widely used in electroplating solutions, catalyst production, ceramic and pigment industry, and as a laboratory reagent.

Structural Features:

  • Nickel ion in +2 oxidation state

  • Two acetate ligands

  • Tetrahydrate form (4 water molecules)

  • Soluble in water

  • Green color (characteristic of Ni²⁺)

2. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Chemical Formula Ni(CH₃COO)₂·4H₂O
Molecular Weight 248.84 g/mol
Appearance Greenish crystalline solid or powder
Odor Slight acetic acid odor
Density ~1.74 g/cm³
Melting Point ~235 °C (decomposes)
Solubility in Water Soluble
Solubility in Ethanol Slightly soluble
Solubility in Organic Solvents Limited
pH (Aqueous Solution) ~6-7
Hygroscopicity Slightly hygroscopic
Magnetic Properties Paramagnetic

3. SOLUBILITY PROFILE

Solvent Solubility
Water Soluble
Ethanol Slightly soluble
Organic Solvents Limited
Acids Soluble

4. CHEMICAL PROPERTIES AND REACTIONS

Property Description
Chemical Class Transition metal acetate / Organic acid salt
Oxidation State Ni²⁺ (+2)
Thermal Decomposition Decomposes to NiO at ~235°C
Hydrolysis Mild hydrolysis in aqueous solution
Complex Formation Forms [Ni(NH₃)₆]²⁺ complex with ammonia
Magnetic Properties Paramagnetic

Key Reactions:

Thermal Decomposition:
Ni(CH₃COO)₂·4H₂O → NiO + CH₃COOCH₃ + CO₂ + H₂O (~235°C)

Ammonia Complex Formation:
Ni(CH₃COO)₂ + 6NH₃ → Ni(NH₃)₆₂

5. APPLICATIONS AND INDUSTRIAL USES

Sector Application
Electroplating Nickel plating solutions
Catalysts Hydrogenation and organic synthesis catalysts
Ceramics and Pigments Ceramic coloring and pigment production
Laboratory Analytical reagent and precipitation agent
Battery Technology Active material precursor for nickel-metal hydride batteries
Textile Dyeing and printing processes

6. SPECIFICATIONS (TYPICAL)

Parameter Specification
Purity ≥ 99.0%
Appearance Greenish crystalline solid or powder
Nickel Content (Ni) ~23-24%
Water Insoluble Matter ≤ 0.01%
Chloride (Cl) ≤ 0.005%
Sulfate (SO₄) ≤ 0.01%
Iron (Fe) ≤ 0.001%
Cobalt (Co) ≤ 0.01%
Copper (Cu) ≤ 0.001%
Loss on Drying (105°C) ~28-30%

7. HANDLING AND STORAGE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area
Storage Temperature 15-25°C
Keep Away From Strong oxidizers, strong acids, moisture
Shelf Life 24-36 months (under proper storage)
Packaging Tightly closed plastic or glass containers
UN Number Not classified as dangerous for transport

Handling Notes:

  • Avoid dust formation and inhalation

  • Avoid skin and eye contact

  • Use in well-ventilated areas

  • Slightly hygroscopic; protect from moisture

8. SAFETY AND TOXICOLOGY

Parameter Value
GHS Classification GHS07 (Warning), GHS08 (Health Hazard), GHS09 (Environment)
Signal Word Danger
Hazard Statements H302 (Harmful if swallowed), H315 (Skin irritation), H317 (May cause allergic skin reaction), H319 (Serious eye irritation), H332 (Harmful if inhaled), H335 (Respiratory tract irritation), H341 (Suspected of causing genetic defects), H351 (Suspected of causing cancer), H360 (May damage fertility or unborn child), H372 (Causes damage to organs), H410 (Very toxic to aquatic life)
Precautionary Statements P201, P260, P280, P301+P310, P304+P340, P308+P313
Toxicity Harmful if swallowed or inhaled
Exposure Routes Inhalation, ingestion, skin contact
Symptoms Skin sensitization, respiratory tract irritation, nausea
Target Organs Respiratory system, skin, reproductive system
Carcinogenicity Category 1B (suspected carcinogen)
Reproductive Toxicity Category 1
Ecotoxicity Very toxic to aquatic life

Personal Protective Equipment:

  • Chemical-resistant gloves

  • Safety goggles

  • Protective clothing

  • Respiratory protection (dust mask)

  • Adequate ventilation must be provided

  • Regular health check-ups (nickel exposure)

9. FIRST AID MEASURES

Exposure Route Action
Inhalation Move to fresh air. If breathing difficulty occurs, administer oxygen. Seek medical attention.
Skin Contact Remove contaminated clothing. Wash with plenty of water and soap. Seek medical attention.
Eye Contact Rinse with plenty of water for at least 15 minutes. Seek medical attention.
Ingestion Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Seek medical attention.

10. ENVIRONMENTAL INFORMATION

Parameter Information
Ecotoxicity Very toxic to aquatic organisms
Bioaccumulation Nickel compounds accumulate in the environment
Environmental Impact Must be prevented from entering water and soil sources
Waste Management Nickel-containing waste must be processed at specialized disposal facilities

11. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified as dangerous for transport
Hazard Class Not classified
Packing Group Not applicable
Proper Shipping Name Nickel Acetate
Marine Pollutant Yes
ADR/RID Label None

12. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; registration required
USA (TSCA) Listed
EINECS 206-761-7
Customs Tariff Code 2915.29.00

13. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Nickel Acetate (Ni(CH₃COO)₂·4H₂O, CAS 373-02-4) is a greenish crystalline solid or powder with a molecular weight of 248.84 g/mol and density of approximately 1.74 g/cm³. It is soluble in water and has a slight acetic acid odor.

Its most important applications include use in electroplating solutionscatalyst productionceramic and pigment industry, and as a laboratory reagent.

Nickel compounds may cause allergic reactions and long-term cancer risk. Harmful if swallowed or inhaled. Causes skin irritation, allergic skin reactions, and respiratory tract irritation. Very toxic to aquatic life. Storage should be in cool, dry, well-ventilated areas, in tightly closed containers, away from strong oxidizers and acids.

Key Properties:

Property Value
Formula Ni(CH₃COO)₂·4H₂O
CAS No 373-02-4
Molecular Weight 248.84 g/mol
Appearance Greenish crystalline/powder
Water Solubility Soluble
Density ~1.74 g/cm³
Melting Point ~235 °C

CRITICAL WARNINGS:

  1. Carcinogenicity: Nickel compounds are classified as Category 1B carcinogens (H351).

  2. Allergic Reactions: Skin contact may cause allergic reactions (H317). Inhalation may cause allergy or asthma symptoms (H334).

  3. Reproductive Toxicity: May damage fertility or unborn child (H360).

  4. Organ Damage: Prolonged exposure causes organ damage (H372).

  5. Environmental: Very toxic to aquatic life with long-lasting effects (H410). Must be prevented from entering water and soil sources.

  6. Hygroscopic: Slightly hygroscopic; protect from moisture. Store in tightly closed containers.

  7. Waste Management: Nickel-containing waste must be processed at specialized disposal facilities.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. All local, national, and international regulations must be followed when working with Nickel Acetate.

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