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Send EmailNickel Acetate, Nickel Acetate Tetrahydrate, Nickel Acetate Anhydrous, Nickelous Acetate, Nickel Diacetate, 373-02-4, 6018-89-9
| Parameter | Description |
|---|---|
| Chemical Name | Nickel(II) Acetate Tetrahydrate |
| Other Names | Nickelous acetate, Nickel diacetate |
| CAS Number | 373-02-4 (anhydrous) / 6018-89-9 (tetrahydrate) |
| EC Number (EINECS) | 206-761-7 |
| Chemical Formula | Ni(CH₃COO)₂·4H₂O |
| Molecular Weight | 248.84 g/mol (tetrahydrate) |
| Chemical Class | Transition metal acetate / Organic acid salt |
| Appearance | Greenish crystalline solid or powder |
| Odor | Slight acetic acid odor |
| Density | ~1.74 g/cm³ |
| Melting Point | ~235 °C (decomposes) |
| pH (Aqueous Solution) | ~6-7 |
CHEMICAL STRUCTURE AND DESCRIPTION:
Nickel Acetate (Ni(CH₃COO)₂·4H₂O) is the acetate salt of nickel in the +2 oxidation state. It consists of a nickel ion (Ni²⁺) and two acetate ligands (CH₃COO⁻). It is soluble in water and appears as greenish crystals. It is widely used in electroplating solutions, catalyst production, ceramic and pigment industry, and as a laboratory reagent.
Structural Features:
Nickel ion in +2 oxidation state
Two acetate ligands
Tetrahydrate form (4 water molecules)
Soluble in water
Green color (characteristic of Ni²⁺)
| Property | Value |
|---|---|
| Chemical Formula | Ni(CH₃COO)₂·4H₂O |
| Molecular Weight | 248.84 g/mol |
| Appearance | Greenish crystalline solid or powder |
| Odor | Slight acetic acid odor |
| Density | ~1.74 g/cm³ |
| Melting Point | ~235 °C (decomposes) |
| Solubility in Water | Soluble |
| Solubility in Ethanol | Slightly soluble |
| Solubility in Organic Solvents | Limited |
| pH (Aqueous Solution) | ~6-7 |
| Hygroscopicity | Slightly hygroscopic |
| Magnetic Properties | Paramagnetic |
| Solvent | Solubility |
|---|---|
| Water | Soluble |
| Ethanol | Slightly soluble |
| Organic Solvents | Limited |
| Acids | Soluble |
| Property | Description |
|---|---|
| Chemical Class | Transition metal acetate / Organic acid salt |
| Oxidation State | Ni²⁺ (+2) |
| Thermal Decomposition | Decomposes to NiO at ~235°C |
| Hydrolysis | Mild hydrolysis in aqueous solution |
| Complex Formation | Forms [Ni(NH₃)₆]²⁺ complex with ammonia |
| Magnetic Properties | Paramagnetic |
Key Reactions:
Thermal Decomposition:
Ni(CH₃COO)₂·4H₂O → NiO + CH₃COOCH₃ + CO₂ + H₂O (~235°C)
Ammonia Complex Formation:
Ni(CH₃COO)₂ + 6NH₃ → Ni(NH₃)₆₂
| Sector | Application |
|---|---|
| Electroplating | Nickel plating solutions |
| Catalysts | Hydrogenation and organic synthesis catalysts |
| Ceramics and Pigments | Ceramic coloring and pigment production |
| Laboratory | Analytical reagent and precipitation agent |
| Battery Technology | Active material precursor for nickel-metal hydride batteries |
| Textile | Dyeing and printing processes |
| Parameter | Specification |
|---|---|
| Purity | ≥ 99.0% |
| Appearance | Greenish crystalline solid or powder |
| Nickel Content (Ni) | ~23-24% |
| Water Insoluble Matter | ≤ 0.01% |
| Chloride (Cl) | ≤ 0.005% |
| Sulfate (SO₄) | ≤ 0.01% |
| Iron (Fe) | ≤ 0.001% |
| Cobalt (Co) | ≤ 0.01% |
| Copper (Cu) | ≤ 0.001% |
| Loss on Drying (105°C) | ~28-30% |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area |
| Storage Temperature | 15-25°C |
| Keep Away From | Strong oxidizers, strong acids, moisture |
| Shelf Life | 24-36 months (under proper storage) |
| Packaging | Tightly closed plastic or glass containers |
| UN Number | Not classified as dangerous for transport |
Handling Notes:
Avoid dust formation and inhalation
Avoid skin and eye contact
Use in well-ventilated areas
Slightly hygroscopic; protect from moisture
| Parameter | Value |
|---|---|
| GHS Classification | GHS07 (Warning), GHS08 (Health Hazard), GHS09 (Environment) |
| Signal Word | Danger |
| Hazard Statements | H302 (Harmful if swallowed), H315 (Skin irritation), H317 (May cause allergic skin reaction), H319 (Serious eye irritation), H332 (Harmful if inhaled), H335 (Respiratory tract irritation), H341 (Suspected of causing genetic defects), H351 (Suspected of causing cancer), H360 (May damage fertility or unborn child), H372 (Causes damage to organs), H410 (Very toxic to aquatic life) |
| Precautionary Statements | P201, P260, P280, P301+P310, P304+P340, P308+P313 |
| Toxicity | Harmful if swallowed or inhaled |
| Exposure Routes | Inhalation, ingestion, skin contact |
| Symptoms | Skin sensitization, respiratory tract irritation, nausea |
| Target Organs | Respiratory system, skin, reproductive system |
| Carcinogenicity | Category 1B (suspected carcinogen) |
| Reproductive Toxicity | Category 1 |
| Ecotoxicity | Very toxic to aquatic life |
Personal Protective Equipment:
Chemical-resistant gloves
Safety goggles
Protective clothing
Respiratory protection (dust mask)
Adequate ventilation must be provided
Regular health check-ups (nickel exposure)
| Exposure Route | Action |
|---|---|
| Inhalation | Move to fresh air. If breathing difficulty occurs, administer oxygen. Seek medical attention. |
| Skin Contact | Remove contaminated clothing. Wash with plenty of water and soap. Seek medical attention. |
| Eye Contact | Rinse with plenty of water for at least 15 minutes. Seek medical attention. |
| Ingestion | Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Seek medical attention. |
| Parameter | Information |
|---|---|
| Ecotoxicity | Very toxic to aquatic organisms |
| Bioaccumulation | Nickel compounds accumulate in the environment |
| Environmental Impact | Must be prevented from entering water and soil sources |
| Waste Management | Nickel-containing waste must be processed at specialized disposal facilities |
| Parameter | Information |
|---|---|
| UN Number | Not classified as dangerous for transport |
| Hazard Class | Not classified |
| Packing Group | Not applicable |
| Proper Shipping Name | Nickel Acetate |
| Marine Pollutant | Yes |
| ADR/RID Label | None |
| Region | Status |
|---|---|
| EU | REACH registered |
| Turkey (KKDİK) | Mandatory compliance; registration required |
| USA (TSCA) | Listed |
| EINECS | 206-761-7 |
| Customs Tariff Code | 2915.29.00 |
SUMMARY:
Nickel Acetate (Ni(CH₃COO)₂·4H₂O, CAS 373-02-4) is a greenish crystalline solid or powder with a molecular weight of 248.84 g/mol and density of approximately 1.74 g/cm³. It is soluble in water and has a slight acetic acid odor.
Its most important applications include use in electroplating solutions, catalyst production, ceramic and pigment industry, and as a laboratory reagent.
Nickel compounds may cause allergic reactions and long-term cancer risk. Harmful if swallowed or inhaled. Causes skin irritation, allergic skin reactions, and respiratory tract irritation. Very toxic to aquatic life. Storage should be in cool, dry, well-ventilated areas, in tightly closed containers, away from strong oxidizers and acids.
Key Properties:
| Property | Value |
|---|---|
| Formula | Ni(CH₃COO)₂·4H₂O |
| CAS No | 373-02-4 |
| Molecular Weight | 248.84 g/mol |
| Appearance | Greenish crystalline/powder |
| Water Solubility | Soluble |
| Density | ~1.74 g/cm³ |
| Melting Point | ~235 °C |
CRITICAL WARNINGS:
Carcinogenicity: Nickel compounds are classified as Category 1B carcinogens (H351).
Allergic Reactions: Skin contact may cause allergic reactions (H317). Inhalation may cause allergy or asthma symptoms (H334).
Reproductive Toxicity: May damage fertility or unborn child (H360).
Organ Damage: Prolonged exposure causes organ damage (H372).
Environmental: Very toxic to aquatic life with long-lasting effects (H410). Must be prevented from entering water and soil sources.
Hygroscopic: Slightly hygroscopic; protect from moisture. Store in tightly closed containers.
Waste Management: Nickel-containing waste must be processed at specialized disposal facilities.
Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. All local, national, and international regulations must be followed when working with Nickel Acetate.