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Chestnut Tannin, Chestnut Extract, Chestnut Bitter Tannin, Chestnut Sweet Tannin, 84695-99-8

Chestnut Tannin, Chestnut Extract, Chestnut Bitter Tannin, Chestnut Sweet Tannin, 84695-99-8

CHESTNUT TANNIN (CHESTNUT SWEET AND CHESTNUT BITTER)

Chestnut Tannin / Chestnut Extract / Vegetable Tannin / Tannic Acid Derivative
CAS Number: 84695-99-8

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Detail
Product Name Chestnut Bitter (Kpn) / Chestnut Sweet (Kps)
Chemical Definition Vegetable Tannin (Hydrolyzable Tannin)
CAS Number 84695-99-8
Origin Slovenia
Chemical Class Polyphenolic compound (hydrolyzable tannin)
Source Extract from chestnut wood (Castanea sativa)
Appearance Brown powder
Odor Slight characteristic, vegetable odor

Chestnut tannin is a natural polyphenolic compound obtained by extraction from the wood and bark of the chestnut tree (Castanea sativa). It belongs to the class of hydrolyzable tannins and has a high molecular weight polymeric structure. It is a versatile natural product widely used in the leather tanning, textile, adhesive, and food industries. It is available in two different forms: Chestnut Bitter, which has a higher tannin content, and Chestnut Sweet, which has a lower tannin content and milder properties.

2. SYNONYMS AND IDENTIFIERS

Language Names
Turkish Kestane Taneni, Kestane Özütü, Bitkisel Tanen, Kestane Acı, Kestane Tatlı
English Chestnut Tannin, Chestnut Extract, Vegetable Tannin, Chestnut Wood Extract
Chemical Name Hydrolyzable tannin (gallotannin and ellagitannin derivatives)
Common Names Chestnut bark extract, Chestnut wood extract, Natural tannin, Vegetable tanning agent

3. CHEMICAL STRUCTURE

3.1. General Structural Representation

Chestnut tannin belongs to the class of hydrolyzable tannins and is primarily composed of polymeric structures of gallic acid and ellagic acid derivatives. The main backbone consists of galloyl groups ester-bonded to a glucose (sugar) core.

Representative Monomer Structure (Gallic Acid):

        COOH
         |
         C
        / \
       /   \
      /     \
     C       C
    / \     / \
   /   \   /   \
  /     \ /     \
 OH      C       OH
         | \
         |  \
         |   \
         C    H
        / \
       /   \
      OH    OH

Representative Dimer Structure (Gallotannin - Simplified):

        CH2OH
          |
         CHOH
          |
         CHOH
          |
         CHOH
          |
         CHOH
          |
         CH2O - C(=O) - C6H2(OH)3
                   |
                   C(=O) - C6H2(OH)3
                   |
                   C(=O) - C6H2(OH)3

3.2. Simplified Structural Formula

Representative Formula: Variable (polymeric structure)
Basic Unit: Galloyl groups (C6H2(OH)3-CO-)
Core: Glucose (C6H12O6) or other polyol cores

3.3. Key Structural Features

Feature Description
Polymer Type Hydrolyzable tannin (gallotannin / ellagitannin)
Basic Building Block Gallic acid and ellagic acid derivatives
Backbone Ester bonds around a glucose or other polyol core
Functional Groups Phenolic hydroxyl (-OH), carboxyl (-COOH), ester (-COO-)
Molecular Weight Range 500 – 3,000 Daltons (depending on degree of polymerization)
Polyphenolic Structure High content of phenolic hydroxyl groups
Complex Formation Forms stable complexes with proteins, alkaloids, and metal ions
Antioxidant Activity Strong free radical scavenging properties

4. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Appearance Brown powder (light brown to dark brown)
Odor Slight characteristic, vegetable odor
Taste Astringent, bitter (bitter form) / milder (sweet form)
Density 0.4 – 0.6 g/cm3 (bulk density)
pH Value (1% solution) 3.5 – 4.5
pH Value (10% solution) 3.0 – 4.0
Water Solubility (20°C) Completely soluble (up to 70-80% by weight)
Solubility in Alcohol Soluble in ethanol and methanol
Solubility in Organic Solvents Slightly soluble in acetone; insoluble in apolar solvents such as ether and benzene
Stability Stable under normal conditions
Thermal Stability Begins to decompose above 150°C
Hygroscopicity Moderately hygroscopic
Ash Content 5 – 8% (depending on source and processing)
Tannin Content (Bitter Form) 65 – 75% (on dry matter)
Tannin Content (Sweet Form) 40 – 55% (on dry matter)

5. SOLUBILITY PROFILE

Solvent Solubility Conditions
Water Completely soluble (70-80%) 20°C
Water Highly soluble 50°C
Ethanol Soluble 25°C
Methanol Soluble 25°C
Acetone Slightly soluble 25°C
Ether Insoluble 25°C
Benzene Insoluble 25°C
Toluene Insoluble 25°C
Mineral Oil Insoluble 25°C

6. FUNCTIONAL GROUP ANALYSIS

Functional Group Presence Significance
Phenolic Hydroxyl (-OH) High Antioxidant activity, metal chelation, protein binding
Carboxyl (-COOH) Medium Acidic character, water solubility, metal complex formation
Ester (-COO-) High Linkage between glucose core and gallic acid; hydrolyzability
Aromatic Ring High Hydrophobic character, UV absorption
Carbonyl (C=O) High Polar character, hydrogen bond formation

7. PRODUCTION AND MANUFACTURING PROCESS

Chestnut tannin is produced by extraction from the wood and bark of the chestnut tree.

7.1. Raw Materials

Raw Material Description
Chestnut Wood Castanea sativa species, preferably from mature trees
Chestnut Bark Rich tannin source
Water Extraction solvent
Sodium Metabisulfite Preservative to prevent oxidation (optional)

7.2. Production Stages

Stage Description
Grinding Chestnut wood and bark are ground to appropriate sized chips or flour.
Extraction The ground raw material is subjected to extraction with hot water (60-80°C). This process is typically carried out in counter-current extraction systems.
Filtration The extraction liquid is separated from solid particles (lignin, cellulose residues).
Concentration The clarified extract is concentrated under vacuum evaporation until a solids content of 40-50% is reached.
Drying The concentrated extract is converted to powder form by spray drying or vacuum drum drying.
Grinding and Screening The dried product is ground and screened to achieve the desired particle size distribution.
Standardization The product is standardized according to tannin content (classified as bitter or sweet form).

7.3. Differences Between Bitter and Sweet Forms

Property Chestnut Bitter (Kpn) Chestnut Sweet (Kps)
Tannin Content 65 – 75% 40 – 55%
Taste Profile Astringent, bitter Milder, less astringent
Color Darker brown Lighter brown
Application Leather tanning, high strength applications Textiles, adhesives, food additives
pH 3.5 – 4.0 3.8 – 4.5

8. MECHANISM OF ACTION (LEATHER TANNING)

Parameter Description
Collagen Binding Tannin molecules form hydrogen bonds and hydrophobic interactions with peptide bonds of collagen fibers in leather.
Cross-Linking The polyphenolic structure forms cross-links between collagen fibers, creating a three-dimensional network.
Stabilization This binding stabilizes the leather against microbial degradation, heat, and chemical attack.
Water Repellency The hydrophobic aromatic rings of tannins impart a certain degree of water repellency to the leather.
Firmness Control The amount of tannin can be adjusted to control the firmness and fullness of the leather.

9. APPLICATIONS AND INDUSTRIAL USES

Chestnut tannin is used as a natural, renewable, and versatile product in many industries.

9.1. Leather Tanning Industry (Most Important Application)

Application Description
Vegetable Tanning Used as the primary tanning agent in traditional vegetable tanning processes.
Retanning Used as a retanning agent to impart fullness, softness, and character to chrome-tanned leather.
Combination Tanning Used in combination tanning systems with chrome or synthetic tannins.
Filling Agent Provides a full and tight feel to the leather.
Surface Finish Creates natural and warm color tones on the leather surface.

9.2. Textile Industry

Application Description
Natural Dyeing Used as a natural dyestuff and mordant (fixative) in textile fibers.
Printing Auxiliary Functions as a color fixative in textile printing processes.
Flocculant Used in the precipitation of dyes in textile wastewater.
Fiber Modification Imparts antibacterial and antioxidant properties to cellulosic fibers.

9.3. Adhesive and Resin Production

Application Description
Wood Adhesives Used as a natural binder in wood adhesive formulations.
Phenol-Formaldehyde Resins Used as a partial or complete replacement for phenol to produce bio-based resins.
Tannin-Resin Copolymers Produced for special resins for adhesive and coating applications.
Plywood Production Used as a binder in plywood and other wood composites.

9.4. Wine and Food Industry

Application Description
Clarifying Agent Used for clarification of wine and fruit juices by precipitating proteins.
Antioxidant Prevents oxidation as a natural antioxidant.
Color Stabilization Aids in color stabilization in wine.
Fermentation Regulator Used as a regulator in some fermentation processes.
Natural Additive Used as a natural additive in the food industry (with E numbers).

9.5. Other Applications

Application Description
Ink Production Used as a source of tannic acid in iron gall ink production.
Cosmetics Used in cosmetic formulations for its antioxidant and skin-tightening properties.
Water Treatment Used as a coagulant and flocculant for removal of heavy metals and organic pollutants.
Mining Used as a flotation aid in ore beneficiation.
Dyeing Used as a colorant and mordant in natural fiber dyeing.
Corrosion Inhibitor Used as a natural corrosion inhibitor on metal surfaces.

10. PRECURSORS AND RAW MATERIALS (UPSTREAM)

Raw Material Description
Chestnut Wood Primary raw material (Castanea sativa)
Chestnut Bark High tannin content by-product or waste material
Water Extraction solvent
Sodium Metabisulfite Oxidation inhibitor

11. DERIVATIVES AND DOWNSTREAM PRODUCTS

Derivative Application
Gallic Acid Pharmaceutical and food additive
Ellagic Acid Antioxidant and preservative
Tannin-Resin Copolymers Adhesives and coatings
Tannin-Formaldehyde Resins Wood adhesives
Iron Tannate Ink and dye production
Chestnut Tannin Extract (Liquid) Leather tanning and textile applications

12. ENVIRONMENTAL AND ECOLOGICAL INFORMATION

Parameter Detail
Toxicity Non-toxic to aquatic and terrestrial organisms.
Biodegradability Completely biodegradable (natural origin).
Bioaccumulation Unlikely.
Renewable Resource Obtained from sustainably managed forests.
Environmental Impact Low environmental impact; natural alternative to synthetic chemicals.
WGK Germany 1 (Low hazard to water).
Fate in Environment Degrades naturally in soil and water.
Ozone Depletion Potential None.
Global Warming Potential Low (bio-based product).

13. SAFETY AND TOXICOLOGICAL INFORMATION

Parameter Detail
Acute Oral Toxicity (LD50, Rat) > 5000 mg/kg (practically non-toxic)
Acute Dermal Toxicity (LD50, Rabbit) > 2000 mg/kg
Acute Inhalation Toxicity May cause respiratory tract irritation if dust is inhaled.
Skin Irritation May cause mild irritation upon prolonged contact.
Eye Irritation May cause eye irritation in powder form.
Skin Sensitization Not classified as a sensitizer.
Mutagenicity Not mutagenic.
Carcinogenicity Not classified as a carcinogen.
Reproductive Toxicity Not classified as a reproductive toxin.
Target Organs No specific target organs identified.
GHS Classification Not classified as hazardous (natural product).

14. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move person to fresh air. If breathing difficulty occurs, administer oxygen and seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, consult a physician.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Consult a physician.
Ingestion Rinse mouth. Drink plenty of water. Do not induce vomiting. If unconscious, do not administer anything orally. Seek immediate medical attention.
General Note If symptoms persist, always consult a healthcare facility.

15. FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable under normal conditions. May burn as organic matter at high temperatures.
Extinguishing Media Water spray, CO2, dry chemical powder, alcohol-resistant foam.
Special Hazards Thermal decomposition produces carbon monoxide, carbon dioxide, and organic fumes.
Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing.
Explosion Risk Not explosive; does not form explosive mixtures with air.

16. ACCIDENTAL RELEASE MEASURES

Parameter Information
Personal Protection Dust mask, protective goggles, gloves, coverall.
Ventilation Increase ventilation; use local exhaust in confined spaces.
Containment Cover spilled area to prevent dust dispersion.
Cleaning Methods Collect dry using vacuum or careful sweeping. Avoid washing with water (soluble).
Environmental Precautions Prevent entry into drains, sewers, and water bodies.
Waste Disposal Dispose of as organic waste in accordance with local regulations.

17. STORAGE AND HANDLING

Parameter Information
Storage Conditions Store in a cool, dry, and well-ventilated area at room temperature (15-25°C).
Container Requirements Keep tightly closed in original packaging (25 kg bags).
Materials to Avoid Strong oxidizers, strong alkalis, high humidity.
Shelf Life 24 months (under proper storage conditions).
Hygroscopicity Moderately hygroscopic; protect from moisture to prevent caking and lump formation.
Packaging Options 25 kg bags, 500 kg big-bags, 1000 kg palletized shipment.
Handling Notes Avoid dust formation; use local exhaust ventilation; use protective mask and goggles. Wash hands thoroughly after handling.

Handling Notes:

  • Use closed systems to prevent dust formation.

  • Avoid contact with skin, eyes, and respiratory tract.

  • Protect from moisture by resealing packaging tightly after use.

  • In leather tanning applications, dosage should be adjusted according to leather type and desired properties.

18. TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not classified as dangerous goods).
Hazard Class Not classified as hazardous for transport.
Packing Group Not applicable.
Proper Shipping Name Chestnut tannin (Vegetable tannin).
Marine Pollutant No.
ADR/RID Label Not applicable.
Transport Category Category 0 (no restrictions).
Air Transport (IATA) No restrictions.
Sea Transport (IMDG) No restrictions.

Chestnut tannin is not classified as a dangerous good for international transport and can be safely shipped by road, sea, and air.

19. REGULATORY INFORMATION

Region Status
EU (REACH) Registered as a natural product.
Turkey (KKDIK) Mandatory compliance; evaluated as a natural substance.
USA (TSCA) Listed.
FDA Compliance GRAS (Generally Recognized as Safe) as a food additive.
EFSA (European Food Safety Authority) Approved as a food additive.
Turkish Food Codex Permitted for use as a food additive.
Canada (DSL) Listed.
Japan (ENCS) Listed.
Australia (AICS) Listed.
China (IECSC) Listed.

20. KEY ADVANTAGES AND BENEFITS

Advantage Description
Natural and Renewable A natural product obtained from sustainably managed forests.
Environmentally Friendly Non-toxic, biodegradable, and offers a natural alternative to synthetic chemicals.
Multifunctionality Can be used in tanning, retanning, textiles, adhesives, food, and many other applications.
High Tannin Content Bitter form provides up to 75% tannin content for high efficiency.
Non-Corrosive Does not cause corrosion in leather tanning applications.
Antioxidant Properties Valuable as a natural antioxidant in food and cosmetic applications.
Antibacterial Effect Exhibits natural antibacterial properties.

21. CHESTNUT BITTER VS. CHESTNUT SWEET COMPARISON

Property Chestnut Bitter (Kpn) Chestnut Sweet (Kps)
Tannin Content 65 – 75% 40 – 55%
pH (1% solution) 3.5 – 4.0 3.8 – 4.5
Color Darker brown Lighter brown
Taste Astringent, bitter Milder, less astringent
Dissolution Rate Rapidly soluble Moderately soluble
Primary Application Leather tanning, high strength Textiles, adhesives, food additive
Color Imparting Dark, warm tones Light, natural tones
Leather Fullness High fullness Medium fullness

22. SUMMARY

Chestnut Tannin (CAS: 84695-99-8) is a natural polyphenolic compound obtained from the chestnut tree (Castanea sativa). It belongs to the class of hydrolyzable tannins and is a brown powder that is soluble in water. Its basic chemical structure consists of a polymeric structure of gallic acid and ellagic acid derivatives ester-bonded to a glucose core. Its high phenolic hydroxyl content provides antioxidant, protein-binding, and metal-chelating properties.

It is available in two different forms: Chestnut Bitter (Kpn) with high tannin content (65-75%) is preferred for leather tanning and high-strength applications. Chestnut Sweet (Kps) with lower tannin content (40-55%) is used in textiles, adhesives, resin production, and food additives.

Main application areas include leather tanning and retanning, textile auxiliary chemicals, adhesive and resin production, and use as a natural additive in the wine and food industry. It also finds applications in ink production, cosmetics, water treatment, and corrosion inhibition.

As a natural, renewable, non-toxic, and biodegradable product, it offers a sustainable and environmentally friendly alternative to synthetic chemicals.

23. KEY PROPERTIES (SUMMARY TABLE)

Property Value
Appearance Brown powder
CAS Number 84695-99-8
Origin Slovenia
Source Chestnut tree (Castanea sativa)
Chemical Class Hydrolyzable tannin
pH (1% solution) 3.5 – 4.5
Solubility Completely soluble in water
Tannin Content (Bitter) 65 – 75%
Tannin Content (Sweet) 40 – 55%
Shelf Life 24 months
Packaging 25 kg bags
Available Quantity 1750 kg
Toxicity Non-toxic
Biodegradability Completely biodegradable

24. MAIN APPLICATION AREAS

Sector Applications
Leather Vegetable tanning, retanning, combination tanning, filling agent, surface finish
Textiles Natural dyeing, printing auxiliary, flocculant, fiber modification
Adhesives and Resins Wood adhesives, phenol-formaldehyde resins, plywood production
Wine and Food Clarifying agent, antioxidant, color stabilization, fermentation regulator
Other Ink production, cosmetics, water treatment, mining, corrosion inhibitor

25. CRITICAL NOTICES

  1. Natural and Renewable: Chestnut tannin is a natural product obtained from chestnut trees under sustainable forest management. It offers an environmentally friendly alternative to synthetic chemicals.

  2. Two Different Forms: Available as Chestnut Bitter (Kpn) and Chestnut Sweet (Kps). The bitter form with high tannin content is preferred for leather tanning, while the sweet form with lower tannin content is used in textile and food applications.

  3. Leather Tanning Use: Used as the primary tanning agent in vegetable tanning processes. It stabilizes leather by forming hydrogen bonds and hydrophobic interactions with collagen fibers.

  4. Food Applications: Used as a clarifying agent, antioxidant, and color stabilizer in wine and fruit juices. Approved as a food additive by FDA and EFSA.

  5. Hygroscopic Nature: Moderately hygroscopic. Must be stored in dry conditions to prevent moisture absorption, caking, and lump formation.

  6. Color Imparting: Chestnut tannin imparts natural, warm brown tones to leather and textile products. Dosage must be carefully adjusted in applications where light colors are desired.

  7. Dosage Sensitivity: Overdosing in leather tanning and food applications may cause undesirable effects. Optimized trials are recommended prior to use.

  8. Regulatory Compliance: Users are responsible for ensuring compliance with all applicable local, national, and international regulations, including food, feed, and industrial applications.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Users are obligated to test the product in their own processes and applications. All local, national, and international occupational health and safety regulations must be followed when working with chestnut tannin.

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