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Send EmailChestnut Tannin, Chestnut Extract, Chestnut Bitter Tannin, Chestnut Sweet Tannin, 84695-99-8
Chestnut Tannin / Chestnut Extract / Vegetable Tannin / Tannic Acid Derivative
CAS Number: 84695-99-8
| Parameter | Detail |
|---|---|
| Product Name | Chestnut Bitter (Kpn) / Chestnut Sweet (Kps) |
| Chemical Definition | Vegetable Tannin (Hydrolyzable Tannin) |
| CAS Number | 84695-99-8 |
| Origin | Slovenia |
| Chemical Class | Polyphenolic compound (hydrolyzable tannin) |
| Source | Extract from chestnut wood (Castanea sativa) |
| Appearance | Brown powder |
| Odor | Slight characteristic, vegetable odor |
Chestnut tannin is a natural polyphenolic compound obtained by extraction from the wood and bark of the chestnut tree (Castanea sativa). It belongs to the class of hydrolyzable tannins and has a high molecular weight polymeric structure. It is a versatile natural product widely used in the leather tanning, textile, adhesive, and food industries. It is available in two different forms: Chestnut Bitter, which has a higher tannin content, and Chestnut Sweet, which has a lower tannin content and milder properties.
| Language | Names |
|---|---|
| Turkish | Kestane Taneni, Kestane Özütü, Bitkisel Tanen, Kestane Acı, Kestane Tatlı |
| English | Chestnut Tannin, Chestnut Extract, Vegetable Tannin, Chestnut Wood Extract |
| Chemical Name | Hydrolyzable tannin (gallotannin and ellagitannin derivatives) |
| Common Names | Chestnut bark extract, Chestnut wood extract, Natural tannin, Vegetable tanning agent |
Chestnut tannin belongs to the class of hydrolyzable tannins and is primarily composed of polymeric structures of gallic acid and ellagic acid derivatives. The main backbone consists of galloyl groups ester-bonded to a glucose (sugar) core.
Representative Monomer Structure (Gallic Acid):
COOH
|
C
/ \
/ \
/ \
C C
/ \ / \
/ \ / \
/ \ / \
OH C OH
| \
| \
| \
C H
/ \
/ \
OH OH
Representative Dimer Structure (Gallotannin - Simplified):
CH2OH
|
CHOH
|
CHOH
|
CHOH
|
CHOH
|
CH2O - C(=O) - C6H2(OH)3
|
C(=O) - C6H2(OH)3
|
C(=O) - C6H2(OH)3
Representative Formula: Variable (polymeric structure)
Basic Unit: Galloyl groups (C6H2(OH)3-CO-)
Core: Glucose (C6H12O6) or other polyol cores
| Feature | Description |
|---|---|
| Polymer Type | Hydrolyzable tannin (gallotannin / ellagitannin) |
| Basic Building Block | Gallic acid and ellagic acid derivatives |
| Backbone | Ester bonds around a glucose or other polyol core |
| Functional Groups | Phenolic hydroxyl (-OH), carboxyl (-COOH), ester (-COO-) |
| Molecular Weight Range | 500 – 3,000 Daltons (depending on degree of polymerization) |
| Polyphenolic Structure | High content of phenolic hydroxyl groups |
| Complex Formation | Forms stable complexes with proteins, alkaloids, and metal ions |
| Antioxidant Activity | Strong free radical scavenging properties |
| Property | Value |
|---|---|
| Appearance | Brown powder (light brown to dark brown) |
| Odor | Slight characteristic, vegetable odor |
| Taste | Astringent, bitter (bitter form) / milder (sweet form) |
| Density | 0.4 – 0.6 g/cm3 (bulk density) |
| pH Value (1% solution) | 3.5 – 4.5 |
| pH Value (10% solution) | 3.0 – 4.0 |
| Water Solubility (20°C) | Completely soluble (up to 70-80% by weight) |
| Solubility in Alcohol | Soluble in ethanol and methanol |
| Solubility in Organic Solvents | Slightly soluble in acetone; insoluble in apolar solvents such as ether and benzene |
| Stability | Stable under normal conditions |
| Thermal Stability | Begins to decompose above 150°C |
| Hygroscopicity | Moderately hygroscopic |
| Ash Content | 5 – 8% (depending on source and processing) |
| Tannin Content (Bitter Form) | 65 – 75% (on dry matter) |
| Tannin Content (Sweet Form) | 40 – 55% (on dry matter) |
| Solvent | Solubility | Conditions |
|---|---|---|
| Water | Completely soluble (70-80%) | 20°C |
| Water | Highly soluble | 50°C |
| Ethanol | Soluble | 25°C |
| Methanol | Soluble | 25°C |
| Acetone | Slightly soluble | 25°C |
| Ether | Insoluble | 25°C |
| Benzene | Insoluble | 25°C |
| Toluene | Insoluble | 25°C |
| Mineral Oil | Insoluble | 25°C |
| Functional Group | Presence | Significance |
|---|---|---|
| Phenolic Hydroxyl (-OH) | High | Antioxidant activity, metal chelation, protein binding |
| Carboxyl (-COOH) | Medium | Acidic character, water solubility, metal complex formation |
| Ester (-COO-) | High | Linkage between glucose core and gallic acid; hydrolyzability |
| Aromatic Ring | High | Hydrophobic character, UV absorption |
| Carbonyl (C=O) | High | Polar character, hydrogen bond formation |
Chestnut tannin is produced by extraction from the wood and bark of the chestnut tree.
| Raw Material | Description |
|---|---|
| Chestnut Wood | Castanea sativa species, preferably from mature trees |
| Chestnut Bark | Rich tannin source |
| Water | Extraction solvent |
| Sodium Metabisulfite | Preservative to prevent oxidation (optional) |
| Stage | Description |
|---|---|
| Grinding | Chestnut wood and bark are ground to appropriate sized chips or flour. |
| Extraction | The ground raw material is subjected to extraction with hot water (60-80°C). This process is typically carried out in counter-current extraction systems. |
| Filtration | The extraction liquid is separated from solid particles (lignin, cellulose residues). |
| Concentration | The clarified extract is concentrated under vacuum evaporation until a solids content of 40-50% is reached. |
| Drying | The concentrated extract is converted to powder form by spray drying or vacuum drum drying. |
| Grinding and Screening | The dried product is ground and screened to achieve the desired particle size distribution. |
| Standardization | The product is standardized according to tannin content (classified as bitter or sweet form). |
| Property | Chestnut Bitter (Kpn) | Chestnut Sweet (Kps) |
|---|---|---|
| Tannin Content | 65 – 75% | 40 – 55% |
| Taste Profile | Astringent, bitter | Milder, less astringent |
| Color | Darker brown | Lighter brown |
| Application | Leather tanning, high strength applications | Textiles, adhesives, food additives |
| pH | 3.5 – 4.0 | 3.8 – 4.5 |
| Parameter | Description |
|---|---|
| Collagen Binding | Tannin molecules form hydrogen bonds and hydrophobic interactions with peptide bonds of collagen fibers in leather. |
| Cross-Linking | The polyphenolic structure forms cross-links between collagen fibers, creating a three-dimensional network. |
| Stabilization | This binding stabilizes the leather against microbial degradation, heat, and chemical attack. |
| Water Repellency | The hydrophobic aromatic rings of tannins impart a certain degree of water repellency to the leather. |
| Firmness Control | The amount of tannin can be adjusted to control the firmness and fullness of the leather. |
Chestnut tannin is used as a natural, renewable, and versatile product in many industries.
| Application | Description |
|---|---|
| Vegetable Tanning | Used as the primary tanning agent in traditional vegetable tanning processes. |
| Retanning | Used as a retanning agent to impart fullness, softness, and character to chrome-tanned leather. |
| Combination Tanning | Used in combination tanning systems with chrome or synthetic tannins. |
| Filling Agent | Provides a full and tight feel to the leather. |
| Surface Finish | Creates natural and warm color tones on the leather surface. |
| Application | Description |
|---|---|
| Natural Dyeing | Used as a natural dyestuff and mordant (fixative) in textile fibers. |
| Printing Auxiliary | Functions as a color fixative in textile printing processes. |
| Flocculant | Used in the precipitation of dyes in textile wastewater. |
| Fiber Modification | Imparts antibacterial and antioxidant properties to cellulosic fibers. |
| Application | Description |
|---|---|
| Wood Adhesives | Used as a natural binder in wood adhesive formulations. |
| Phenol-Formaldehyde Resins | Used as a partial or complete replacement for phenol to produce bio-based resins. |
| Tannin-Resin Copolymers | Produced for special resins for adhesive and coating applications. |
| Plywood Production | Used as a binder in plywood and other wood composites. |
| Application | Description |
|---|---|
| Clarifying Agent | Used for clarification of wine and fruit juices by precipitating proteins. |
| Antioxidant | Prevents oxidation as a natural antioxidant. |
| Color Stabilization | Aids in color stabilization in wine. |
| Fermentation Regulator | Used as a regulator in some fermentation processes. |
| Natural Additive | Used as a natural additive in the food industry (with E numbers). |
| Application | Description |
|---|---|
| Ink Production | Used as a source of tannic acid in iron gall ink production. |
| Cosmetics | Used in cosmetic formulations for its antioxidant and skin-tightening properties. |
| Water Treatment | Used as a coagulant and flocculant for removal of heavy metals and organic pollutants. |
| Mining | Used as a flotation aid in ore beneficiation. |
| Dyeing | Used as a colorant and mordant in natural fiber dyeing. |
| Corrosion Inhibitor | Used as a natural corrosion inhibitor on metal surfaces. |
| Raw Material | Description |
|---|---|
| Chestnut Wood | Primary raw material (Castanea sativa) |
| Chestnut Bark | High tannin content by-product or waste material |
| Water | Extraction solvent |
| Sodium Metabisulfite | Oxidation inhibitor |
| Derivative | Application |
|---|---|
| Gallic Acid | Pharmaceutical and food additive |
| Ellagic Acid | Antioxidant and preservative |
| Tannin-Resin Copolymers | Adhesives and coatings |
| Tannin-Formaldehyde Resins | Wood adhesives |
| Iron Tannate | Ink and dye production |
| Chestnut Tannin Extract (Liquid) | Leather tanning and textile applications |
| Parameter | Detail |
|---|---|
| Toxicity | Non-toxic to aquatic and terrestrial organisms. |
| Biodegradability | Completely biodegradable (natural origin). |
| Bioaccumulation | Unlikely. |
| Renewable Resource | Obtained from sustainably managed forests. |
| Environmental Impact | Low environmental impact; natural alternative to synthetic chemicals. |
| WGK Germany | 1 (Low hazard to water). |
| Fate in Environment | Degrades naturally in soil and water. |
| Ozone Depletion Potential | None. |
| Global Warming Potential | Low (bio-based product). |
| Parameter | Detail |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 5000 mg/kg (practically non-toxic) |
| Acute Dermal Toxicity (LD50, Rabbit) | > 2000 mg/kg |
| Acute Inhalation Toxicity | May cause respiratory tract irritation if dust is inhaled. |
| Skin Irritation | May cause mild irritation upon prolonged contact. |
| Eye Irritation | May cause eye irritation in powder form. |
| Skin Sensitization | Not classified as a sensitizer. |
| Mutagenicity | Not mutagenic. |
| Carcinogenicity | Not classified as a carcinogen. |
| Reproductive Toxicity | Not classified as a reproductive toxin. |
| Target Organs | No specific target organs identified. |
| GHS Classification | Not classified as hazardous (natural product). |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move person to fresh air. If breathing difficulty occurs, administer oxygen and seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, consult a physician. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Consult a physician. |
| Ingestion | Rinse mouth. Drink plenty of water. Do not induce vomiting. If unconscious, do not administer anything orally. Seek immediate medical attention. |
| General Note | If symptoms persist, always consult a healthcare facility. |
| Parameter | Information |
|---|---|
| Fire Hazard | Not flammable under normal conditions. May burn as organic matter at high temperatures. |
| Extinguishing Media | Water spray, CO2, dry chemical powder, alcohol-resistant foam. |
| Special Hazards | Thermal decomposition produces carbon monoxide, carbon dioxide, and organic fumes. |
| Protective Equipment | Self-contained breathing apparatus (SCBA), full protective clothing. |
| Explosion Risk | Not explosive; does not form explosive mixtures with air. |
| Parameter | Information |
|---|---|
| Personal Protection | Dust mask, protective goggles, gloves, coverall. |
| Ventilation | Increase ventilation; use local exhaust in confined spaces. |
| Containment | Cover spilled area to prevent dust dispersion. |
| Cleaning Methods | Collect dry using vacuum or careful sweeping. Avoid washing with water (soluble). |
| Environmental Precautions | Prevent entry into drains, sewers, and water bodies. |
| Waste Disposal | Dispose of as organic waste in accordance with local regulations. |
| Parameter | Information |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area at room temperature (15-25°C). |
| Container Requirements | Keep tightly closed in original packaging (25 kg bags). |
| Materials to Avoid | Strong oxidizers, strong alkalis, high humidity. |
| Shelf Life | 24 months (under proper storage conditions). |
| Hygroscopicity | Moderately hygroscopic; protect from moisture to prevent caking and lump formation. |
| Packaging Options | 25 kg bags, 500 kg big-bags, 1000 kg palletized shipment. |
| Handling Notes | Avoid dust formation; use local exhaust ventilation; use protective mask and goggles. Wash hands thoroughly after handling. |
Handling Notes:
Use closed systems to prevent dust formation.
Avoid contact with skin, eyes, and respiratory tract.
Protect from moisture by resealing packaging tightly after use.
In leather tanning applications, dosage should be adjusted according to leather type and desired properties.
| Parameter | Information |
|---|---|
| UN Number | Not applicable (not classified as dangerous goods). |
| Hazard Class | Not classified as hazardous for transport. |
| Packing Group | Not applicable. |
| Proper Shipping Name | Chestnut tannin (Vegetable tannin). |
| Marine Pollutant | No. |
| ADR/RID Label | Not applicable. |
| Transport Category | Category 0 (no restrictions). |
| Air Transport (IATA) | No restrictions. |
| Sea Transport (IMDG) | No restrictions. |
Chestnut tannin is not classified as a dangerous good for international transport and can be safely shipped by road, sea, and air.
| Region | Status |
|---|---|
| EU (REACH) | Registered as a natural product. |
| Turkey (KKDIK) | Mandatory compliance; evaluated as a natural substance. |
| USA (TSCA) | Listed. |
| FDA Compliance | GRAS (Generally Recognized as Safe) as a food additive. |
| EFSA (European Food Safety Authority) | Approved as a food additive. |
| Turkish Food Codex | Permitted for use as a food additive. |
| Canada (DSL) | Listed. |
| Japan (ENCS) | Listed. |
| Australia (AICS) | Listed. |
| China (IECSC) | Listed. |
| Advantage | Description |
|---|---|
| Natural and Renewable | A natural product obtained from sustainably managed forests. |
| Environmentally Friendly | Non-toxic, biodegradable, and offers a natural alternative to synthetic chemicals. |
| Multifunctionality | Can be used in tanning, retanning, textiles, adhesives, food, and many other applications. |
| High Tannin Content | Bitter form provides up to 75% tannin content for high efficiency. |
| Non-Corrosive | Does not cause corrosion in leather tanning applications. |
| Antioxidant Properties | Valuable as a natural antioxidant in food and cosmetic applications. |
| Antibacterial Effect | Exhibits natural antibacterial properties. |
| Property | Chestnut Bitter (Kpn) | Chestnut Sweet (Kps) |
|---|---|---|
| Tannin Content | 65 – 75% | 40 – 55% |
| pH (1% solution) | 3.5 – 4.0 | 3.8 – 4.5 |
| Color | Darker brown | Lighter brown |
| Taste | Astringent, bitter | Milder, less astringent |
| Dissolution Rate | Rapidly soluble | Moderately soluble |
| Primary Application | Leather tanning, high strength | Textiles, adhesives, food additive |
| Color Imparting | Dark, warm tones | Light, natural tones |
| Leather Fullness | High fullness | Medium fullness |
Chestnut Tannin (CAS: 84695-99-8) is a natural polyphenolic compound obtained from the chestnut tree (Castanea sativa). It belongs to the class of hydrolyzable tannins and is a brown powder that is soluble in water. Its basic chemical structure consists of a polymeric structure of gallic acid and ellagic acid derivatives ester-bonded to a glucose core. Its high phenolic hydroxyl content provides antioxidant, protein-binding, and metal-chelating properties.
It is available in two different forms: Chestnut Bitter (Kpn) with high tannin content (65-75%) is preferred for leather tanning and high-strength applications. Chestnut Sweet (Kps) with lower tannin content (40-55%) is used in textiles, adhesives, resin production, and food additives.
Main application areas include leather tanning and retanning, textile auxiliary chemicals, adhesive and resin production, and use as a natural additive in the wine and food industry. It also finds applications in ink production, cosmetics, water treatment, and corrosion inhibition.
As a natural, renewable, non-toxic, and biodegradable product, it offers a sustainable and environmentally friendly alternative to synthetic chemicals.
| Property | Value |
|---|---|
| Appearance | Brown powder |
| CAS Number | 84695-99-8 |
| Origin | Slovenia |
| Source | Chestnut tree (Castanea sativa) |
| Chemical Class | Hydrolyzable tannin |
| pH (1% solution) | 3.5 – 4.5 |
| Solubility | Completely soluble in water |
| Tannin Content (Bitter) | 65 – 75% |
| Tannin Content (Sweet) | 40 – 55% |
| Shelf Life | 24 months |
| Packaging | 25 kg bags |
| Available Quantity | 1750 kg |
| Toxicity | Non-toxic |
| Biodegradability | Completely biodegradable |
| Sector | Applications |
|---|---|
| Leather | Vegetable tanning, retanning, combination tanning, filling agent, surface finish |
| Textiles | Natural dyeing, printing auxiliary, flocculant, fiber modification |
| Adhesives and Resins | Wood adhesives, phenol-formaldehyde resins, plywood production |
| Wine and Food | Clarifying agent, antioxidant, color stabilization, fermentation regulator |
| Other | Ink production, cosmetics, water treatment, mining, corrosion inhibitor |
Natural and Renewable: Chestnut tannin is a natural product obtained from chestnut trees under sustainable forest management. It offers an environmentally friendly alternative to synthetic chemicals.
Two Different Forms: Available as Chestnut Bitter (Kpn) and Chestnut Sweet (Kps). The bitter form with high tannin content is preferred for leather tanning, while the sweet form with lower tannin content is used in textile and food applications.
Leather Tanning Use: Used as the primary tanning agent in vegetable tanning processes. It stabilizes leather by forming hydrogen bonds and hydrophobic interactions with collagen fibers.
Food Applications: Used as a clarifying agent, antioxidant, and color stabilizer in wine and fruit juices. Approved as a food additive by FDA and EFSA.
Hygroscopic Nature: Moderately hygroscopic. Must be stored in dry conditions to prevent moisture absorption, caking, and lump formation.
Color Imparting: Chestnut tannin imparts natural, warm brown tones to leather and textile products. Dosage must be carefully adjusted in applications where light colors are desired.
Dosage Sensitivity: Overdosing in leather tanning and food applications may cause undesirable effects. Optimized trials are recommended prior to use.
Regulatory Compliance: Users are responsible for ensuring compliance with all applicable local, national, and international regulations, including food, feed, and industrial applications.
Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Users are obligated to test the product in their own processes and applications. All local, national, and international occupational health and safety regulations must be followed when working with chestnut tannin.