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SHMP, Sodium hexametaphosphate, 10124-56-8

SHMP, Sodium hexametaphosphate, 10124-56-8

CAS: 10124-56-8

Molecular Formula: Na6O18P6SHMP - Names and Identifiers

Name Sodium hexametaphosphate
Synonyms SHMP
Glassy sodium
Sodium Hexametapho
sodium henamephosphate
Sodium hexametaphosphate
Hexasodium metaphosphate
Sodium Hexameta phosphate
Sodium phosphate (Na6(PO3)6)
Metaphosphoric acid, hexasodium salt
Graham's Salt, Sodium Polymetaphosphate
hexasodium cyclohexaphosphoxane-2,4,6,8,10,12-hexolate 2,4,6,8,10,12-hexaoxide
CAS 10124-56-8
EINECS 233-343-1
InChI InChI=1/6Na.H6O18P6/c;;;;;;1-19(2)13-20(3,4)15-22(7,8)17-24(11,12)18-23(9,10)16-21(5,6)14-19/h;;;;;;(H,1,2)(H,3,4)(H,5,6)(H,7,8)(H,9,10)(H,11,12)/q6*+1;/p-6
InChIKey AUMBZPPBWALQRO-UHFFFAOYSA-L

SHMP - Physico-chemical Properties

Molecular Formula Na6O18P6
Molar Mass 611.77
Melting Point 183-188 °C
Solubility Soluble in water, insoluble in organic solvents,
Appearance Powder
Color White to off-white
Storage Condition Room Temprature
Sensitive Easily absorbing moisture
MDL MFCD00136045
Physical and Chemical Properties Properties of colorless transparent glass flake or white granular crystals.
melting point 616 ℃ (decomposition)
relative density 2.484(20 ℃)
solubility soluble in water, insoluble in organic solvents.
Use Used as water softener, detergent, preservative, cement hardening agent, fiber and bleaching and dyeing cleaning agent, also used in medicine, food oil, printing and dyeing, tanning, paper making, etc.

SHMP - Risk and Safety

Risk Codes 36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description S24/25 - Avoid contact with skin and eyes.
UN IDs N/A
HS Code 29302000

SHMP - Upstream Downstream Industry

Raw Materials Sodium carbonate
White phosphorus
Phosphoric acid
sodium dihydrogen phosphate anhydrous
Sulfuric acid
Sodium hydroxide
Sodium hydroxide
Sodium carbonate
Downstream Products Sodium monofluorophosphate

SHMP - Reference

Reference 

Show more

1. Li, Wenhui, et al. "Low and high methoxyl pectin lowers on structural change and digestibility of fried potato starch...

SHMP - Nature

colorless transparent liquid flake or white granular crystals. Relative density 2. 484, melting point 616 ℃ (decomposition). Soluble in water, insoluble in organic solvents. Strong hygroscopicity, and calcium, magnesium and other metal ions can form soluble complexes. Gradual hydrolysis in water produces orthophosphate.

SHMP - Preparation Method

sodium dihydrogen phosphate dihydrate was prepared by neutralization reaction of soda ash solution and phosphoric acid at 80~100 ℃, and the resulting sodium dihydrogen phosphate solution was concentrated by evaporation, cooled and crystallized, two crystal water are removed by heating to 110-230 ° C., the structural water is removed by heating, and dehydration is further performed by heating to 620 ° C. To form a sodium metaphosphate melt and polymerize into sodium hexametaphosphate. Alternatively, the yellow phosphorus is oxidized by combustion in a stream of dry air and cooled to obtain phosphorus pentoxide, which is mixed with soda ash in a certain proportion. After the mixture was pulverized, it was put into a graphite crucible, heated to dehydrate and melt-polymerize the resulting sodium hexametaphosphate melt, quenched and tableted, and pulverized to obtain sodium hexametaphosphate.

SHMP - Introduction

It is easy to deliquesce in the air and soluble in water. It dissolves 973 · 2 grams per liter of water at 20 ℃ and 1744 grams per liter of water at 80 ℃. The PH value of 1% solution is about 5-5-6-5, which is insoluble in organic solvent. In neutral medium, the final product of hydrolysis is orthophosphate. The hygroscopicity is very strong, and it can gradually absorb moisture when exposed to the air and form a viscose. It can synthesize soluble double salt with alkaline earth metallization, so it has the function of dissolving scale and is a good water softener.

SHMP - Use

The most commonly used polyphosphoric acids are sodium hexametaphosphate and sodium tripolyphosphate. From the corrosion inhibition effect, sodium hexametaphosphate is better than sodium tripolyphosphate, therefore, sodium hexametaphosphate is more widely used.

SHMP - Safety

ingestion of sodium hexametaphosphate by mistake can cause severe poisoning and even death. The most common symptoms of poisoning are Shock, arrhythmia, bradycardia and so on. Once poisoning, should as soon as possible to the hospital for treatment. Six Poly sodium phosphate should be stored in a cool, ventilated, dry, clean, non-toxic warehouse. Co-storage and mixed transportation with toxic substances is strictly prohibited

SHMP - Use

Zinc dibenzyl dithiocarbamate is a useful analytical tool for the detection of copper in plants and biological tissues. It is also used to prepare dithiocarbamate ligands for stabilizing gold nanoparticles.

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