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Send EmailCopper–Nickel Master Alloy, 7440‑50‑8, 7440‑02‑0
| Parameter | Information |
|---|---|
| Product Name | Copper-Nickel Master Alloy |
| Grades | CuNi30 (30Ni), CuNi50 (50Ni) |
| Form | Solid ingot / master alloy |
| Purpose | Designed as a master alloy for controlled nickel addition to copper-based alloys |
| Grade | UNS Designation | Element | CAS No. |
|---|---|---|---|
| 30Ni (Cu ~70%, Ni ~30) | C96400 (70/30 Cu-Ni) | Copper | 7440-50-8 |
| Nickel | 7440-02-0 | ||
| 50Ni (Cu ~50%, Ni ~50) | Alloy 400 / Monel family | Copper | 7440-50-8 |
| Nickel | 7440-02-0 |
Copper-Nickel master alloy is a solid solution of copper (Cu) and nickel (Ni). Copper and nickel are completely miscible in both liquid and solid states, forming a continuous series of solid solutions with a face-centered cubic (FCC) crystal structure. The alloy consists of a homogeneous Cu-Ni solid solution matrix with no significant intermetallic phases.
Crystal Structure:
CuNi MASTER ALLOY
|
Cu-Ni Solid Solution
(FCC Crystal Structure)
|
+----------------+----------------+
| | |
Cu-rich Solid Ni-rich Solid Homogeneous
Solution Solution Distribution
| Phase | Chemical Composition | Crystal System | Description |
|---|---|---|---|
| Cu-Ni Solid Solution | Cu (Ni) | Face-Centered Cubic (FCC) | Continuous solid solution; complete miscibility |
| No Intermetallic Phases | - | - | Cu and Ni form a single-phase system |
| Parameter | CuNi30 | CuNi50 |
|---|---|---|
| Crystal System | Cubic (FCC) | Cubic (FCC) |
| Lattice Parameter (a) | ~3.59 Å | ~3.58 Å |
| Space Group | Fm3̄m | Fm3̄m |
| Coordination Number | 12 | 12 |
| Density | ~8.93 g/cm³ | ~8.94 g/cm³ |
Unless otherwise stated, values are in % by weight. Exact composition may vary slightly by production batch.
| Element | CuNi30 (% wt.) | CuNi50 (% wt.) |
|---|---|---|
| Copper (Cu) | Balance (~70) | Balance (~50) |
| Nickel (Ni) | 30.0 ± 1.0 | 50.0 ± 1.0 |
| Iron (Fe) | ≤ 0.50 | ≤ 0.50 |
| Manganese (Mn) | ≤ 0.50 | ≤ 0.50 |
| Silicon (Si) | ≤ 0.15 | ≤ 0.15 |
| Carbon (C) | ≤ 0.05 | ≤ 0.05 |
| Sulfur (S) | ≤ 0.02 | ≤ 0.02 |
| Phosphorus (P) | ≤ 0.02 | ≤ 0.02 |
| Other Total | ≤ 0.20 | ≤ 0.20 |
Note: Impurity levels are minimized through rigorous production and high-purity raw materials.
| Property | CuNi30 | CuNi50 |
|---|---|---|
| Appearance | Silver-gray metallic ingot | Silver-gray metallic ingot |
| Density (20°C) | ~8.93 g/cm³ | ~8.94 g/cm³ |
| Liquidus Temperature | 1533 K (1260 °C) | 1593 K (1320 °C) |
| Solidus Temperature | 1493 K (1220 °C) | 1563 K (1290 °C) |
| Melting Range | 1220–1260 °C | 1290–1320 °C |
| Thermal Conductivity (RT)¹ | ~40 W/m·K | ~25 W/m·K |
| Electrical Conductivity (%IACS)¹ | ~5–7 | ~3–4 |
¹ Typical values for reference; master alloy is not recommended for direct use as a conductor.
Master alloy ingots are produced for remelting and alloying purposes and are not suitable for structural load-bearing applications. However, based on typical cast structure:
| Property | Description |
|---|---|
| Hardness | Brittle in nature; low impact resistance at room temperature |
| Tensile Strength / Elongation | Standard tensile testing is not applicable due to inhomogeneous phase distribution; ductility is negligible |
| Wear Resistance | Not evaluated as structural component |
Note: These characteristics do not prevent the alloy from dissolving easily and distributing homogeneously in liquid metal.
Copper-Nickel master alloy is used for controlled and homogeneous nickel addition in the following groups:
| Application | Description |
|---|---|
| Casting Alloys | Improvement of strength, corrosion resistance, and high-temperature properties (e.g., Cu-Ni-Zn, Cu-Ni-Sn alloys) |
| Electrical/Electronic Alloys | Conductive-resistance balance for heating wires, resistance materials (e.g., CuNi44, Constantan) |
| Marine/Industrial Alloys | Pre-alloying for cupronickel (90/10, 70/30) production for superior seawater corrosion resistance |
| Special Welding Wires | Production of low-melting point copper alloy welding consumables |
| Coin/Medal Alloys | Precise nickel adjustment in nickel-whitened copper alloys |
| Advantage | Description |
|---|---|
| Homogeneous Distribution | Nickel is distributed very homogeneously in the copper matrix; micro-segregation is minimal |
| Stable Melting Range | Narrow solidus-liquidus range ensures rapid melting and stable cooling, facilitating alloying control |
| High Purity | Low inclusion and gas content improve alloy quality and reduce casting defects |
| Easy Processability | Can be rapidly melted in standard induction furnaces and crucibles; oxidation is negligible |
| Economic Use | High nickel percentage means small additions of master alloy achieve target composition, providing inventory and cost advantages |
Store in a dry, enclosed area
Store ingots on pallets, avoiding direct floor contact
Keep in original packaging to prevent surface oxidation from moisture and condensation
| Step | Recommendation |
|---|---|
| Preheating | Preheat cold ingots to 100–150 °C before adding to molten bath to prevent moisture and thermal shock |
| Addition Method | Add directly to liquid copper or copper alloy bath. Apply stirring to increase dissolution rate |
| Temperature Control | Keep bath temperature 100–200 °C above the liquidus point of the relevant grade (e.g., ~1450–1500 °C for CuNi50). Avoid overheating |
| Protective Cover | Use dry charcoal, graphite powder, or protective flux to reduce oxidation |
| Avoid Contamination | Do not mix alloy with iron, aluminum, or other non-ferrous scrap. Ensure equipment cleanliness |
| Parameter | Information |
|---|---|
| Standard | Approximately 5–10 kg easy-stackable ingots. Shipped on pallets secured with shrink wrap or strapping |
| Special Packaging | Custom sizes, granules, or waffle plates available upon request |
| Labeling | Each pallet is labeled with product name, heat number, net weight, and manufacturer information |
This product is considered non-hazardous in solid form and under normal transport/storage conditions. Not classified under Regulation 1272/2008/EC (CLP).
| Aspect | Recommendation |
|---|---|
| Ventilation | Use local exhaust or general mechanical ventilation. Limit exposure to metal fumes (especially nickel compounds) |
| Personal Protective Equipment (PPE) | Heat-resistant gloves, protective clothing/apron. Face shield or side-shield melting goggles. Respiratory protection with appropriate particle/fume filter (if required) |
| Fire Fighting | Product is non-flammable. Use extinguishing media suitable for surrounding materials (water mist, dry chemical powder, CO₂). Never spray water onto molten metal (steam explosion risk) |
| Route of Exposure | Action to Be Taken |
|---|---|
| Skin Contact | For molten metal splashes, immediately cool with plenty of cold water; seek medical attention. Solid ingot contact is neutral |
| Eye Contact | If metal dust or particles enter eyes, rinse with plenty of water; seek medical attention |
| Ingestion | Ingestion of solid form is unlikely; nevertheless, consult a physician |
Always comply with local occupational health and safety regulations.
| Test | Method |
|---|---|
| Chemical Analysis | Optical Emission Spectrometry (OES) or X-Ray Fluorescence (XRF) |
| Weight and Dimensions | Checked against accepted tolerances |
| Visual Inspection | Ensure no cracks, large shrinkage cavities, or surface contamination |
| Certificate of Analysis (COA) | Provided with each shipment containing heat number, batch number, and chemical composition |
| Regulation | Status |
|---|---|
| EU REACH | Contains Copper (Cu) and Nickel (Ni); refer to SDS for registration details |
| RoHS (Directive 2011/65/EU) | Nickel is not restricted; final alloy must be compliant if used in EEE |
| Conflict Minerals | Sourced only from verified conflict-free smelters |
| Transport | Not classified as dangerous goods in solid ingot form |
| Property | CuNi30 | CuNi50 |
|---|---|---|
| Ni Content | 30.0 ± 1.0% | 50.0 ± 1.0% |
| Melting Range | 1220 – 1260 °C | 1290 – 1320 °C |
| Density | ~8.93 g/cm³ | ~8.94 g/cm³ |
| Form | Ingot (~5–10 kg) | Ingot (~5–10 kg) |
| Crystal Structure | FCC (solid solution) | FCC (solid solution) |
| Main Uses | Master alloy for copper-based systems, electrical, marine, casting alloys | Master alloy for copper-based systems, electrical, marine, casting alloys |
| Key Benefits | Homogeneous distribution, stable melting range, high purity, economic use | Homogeneous distribution, stable melting range, high purity, economic use |
Nickel Content: Two grades available: CuNi30 and CuNi50. Choose appropriate grade for the desired nickel content in the final alloy.
Melting Temperature: Melting ranges are grade-specific. Ensure appropriate temperature control during melting.
Solid Solution System: Cu and Ni form a continuous solid solution with complete miscibility. No intermetallic phases are present.
Corrosion Resistance: Nickel addition improves corrosion resistance, especially in marine environments.
Not Hazardous: Not classified as hazardous in solid form. However, melting operations require appropriate safety measures.
Environmental Protection: Dispose of waste in accordance with local regulations.
Storage:
Store in a dry, enclosed area on pallets
Keep in original packaging to prevent oxidation
No special temperature control required
No shelf life limitation under proper conditions
Handling:
Use protective gloves, safety shoes, and safety goggles
Use appropriate lifting equipment for pallets
Melting:
Preheat ingots to 100–150 °C before addition
Maintain bath temperature 100–200 °C above liquidus
Apply stirring for homogeneity
Use protective cover (charcoal, graphite) to reduce oxidation
Expected nickel recovery >95%
Waste Management:
Do not discharge into sewers or water bodies
Dispose in accordance with local regulations
The values presented in this Technical Data Sheet are typical values compiled from current production data and do not constitute a specification guarantee. Performance testing for specific applications is the responsibility of the user. The manufacturer is not liable for damages resulting from improper use of the product or misinterpretation of the data. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice.