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Copper–Nickel Master Alloy, 7440‑50‑8, 7440‑02‑0

Copper–Nickel Master Alloy, 7440‑50‑8, 7440‑02‑0

COPPER-NICKEL MASTER ALLOY 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Copper-Nickel Master Alloy
Grades CuNi30 (30Ni), CuNi50 (50Ni)
Form Solid ingot / master alloy
Purpose Designed as a master alloy for controlled nickel addition to copper-based alloys

CAS Number Information

Grade UNS Designation Element CAS No.
30Ni (Cu ~70%, Ni ~30) C96400 (70/30 Cu-Ni) Copper 7440-50-8
    Nickel 7440-02-0
50Ni (Cu ~50%, Ni ~50) Alloy 400 / Monel family Copper 7440-50-8
    Nickel 7440-02-0

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Copper-Nickel master alloy is a solid solution of copper (Cu) and nickel (Ni). Copper and nickel are completely miscible in both liquid and solid states, forming a continuous series of solid solutions with a face-centered cubic (FCC) crystal structure. The alloy consists of a homogeneous Cu-Ni solid solution matrix with no significant intermetallic phases.

Crystal Structure:

                    CuNi MASTER ALLOY
                               |
                 Cu-Ni Solid Solution
                 (FCC Crystal Structure)
                               |
             +----------------+----------------+
             |                |                |
         Cu-rich Solid     Ni-rich Solid     Homogeneous
         Solution          Solution          Distribution

2.2. Phase Structure and Crystallographic Properties

Phase Chemical Composition Crystal System Description
Cu-Ni Solid Solution Cu (Ni) Face-Centered Cubic (FCC) Continuous solid solution; complete miscibility
No Intermetallic Phases - - Cu and Ni form a single-phase system

2.3. Crystal Structure Details

Parameter CuNi30 CuNi50
Crystal System Cubic (FCC) Cubic (FCC)
Lattice Parameter (a) ~3.59 Å ~3.58 Å
Space Group Fm3̄m Fm3̄m
Coordination Number 12 12
Density ~8.93 g/cm³ ~8.94 g/cm³

3. CHEMICAL COMPOSITION

Unless otherwise stated, values are in % by weight. Exact composition may vary slightly by production batch.

Element CuNi30 (% wt.) CuNi50 (% wt.)
Copper (Cu) Balance (~70) Balance (~50)
Nickel (Ni) 30.0 ± 1.0 50.0 ± 1.0
Iron (Fe) ≤ 0.50 ≤ 0.50
Manganese (Mn) ≤ 0.50 ≤ 0.50
Silicon (Si) ≤ 0.15 ≤ 0.15
Carbon (C) ≤ 0.05 ≤ 0.05
Sulfur (S) ≤ 0.02 ≤ 0.02
Phosphorus (P) ≤ 0.02 ≤ 0.02
Other Total ≤ 0.20 ≤ 0.20

Note: Impurity levels are minimized through rigorous production and high-purity raw materials.

4. PHYSICAL PROPERTIES

Property CuNi30 CuNi50
Appearance Silver-gray metallic ingot Silver-gray metallic ingot
Density (20°C) ~8.93 g/cm³ ~8.94 g/cm³
Liquidus Temperature 1533 K (1260 °C) 1593 K (1320 °C)
Solidus Temperature 1493 K (1220 °C) 1563 K (1290 °C)
Melting Range 1220–1260 °C 1290–1320 °C
Thermal Conductivity (RT)¹ ~40 W/m·K ~25 W/m·K
Electrical Conductivity (%IACS)¹ ~5–7 ~3–4

¹ Typical values for reference; master alloy is not recommended for direct use as a conductor.

5. MECHANICAL PROPERTIES

Master alloy ingots are produced for remelting and alloying purposes and are not suitable for structural load-bearing applications. However, based on typical cast structure:

Property Description
Hardness Brittle in nature; low impact resistance at room temperature
Tensile Strength / Elongation Standard tensile testing is not applicable due to inhomogeneous phase distribution; ductility is negligible
Wear Resistance Not evaluated as structural component

Note: These characteristics do not prevent the alloy from dissolving easily and distributing homogeneously in liquid metal.

6. APPLICATION AREAS

Copper-Nickel master alloy is used for controlled and homogeneous nickel addition in the following groups:

Application Description
Casting Alloys Improvement of strength, corrosion resistance, and high-temperature properties (e.g., Cu-Ni-Zn, Cu-Ni-Sn alloys)
Electrical/Electronic Alloys Conductive-resistance balance for heating wires, resistance materials (e.g., CuNi44, Constantan)
Marine/Industrial Alloys Pre-alloying for cupronickel (90/10, 70/30) production for superior seawater corrosion resistance
Special Welding Wires Production of low-melting point copper alloy welding consumables
Coin/Medal Alloys Precise nickel adjustment in nickel-whitened copper alloys

7. ADVANTAGES

Advantage Description
Homogeneous Distribution Nickel is distributed very homogeneously in the copper matrix; micro-segregation is minimal
Stable Melting Range Narrow solidus-liquidus range ensures rapid melting and stable cooling, facilitating alloying control
High Purity Low inclusion and gas content improve alloy quality and reduce casting defects
Easy Processability Can be rapidly melted in standard induction furnaces and crucibles; oxidation is negligible
Economic Use High nickel percentage means small additions of master alloy achieve target composition, providing inventory and cost advantages

8. MELTING AND HANDLING RECOMMENDATIONS

Storage:

  • Store in a dry, enclosed area

  • Store ingots on pallets, avoiding direct floor contact

  • Keep in original packaging to prevent surface oxidation from moisture and condensation

Melting Recommendations:

Step Recommendation
Preheating Preheat cold ingots to 100–150 °C before adding to molten bath to prevent moisture and thermal shock
Addition Method Add directly to liquid copper or copper alloy bath. Apply stirring to increase dissolution rate
Temperature Control Keep bath temperature 100–200 °C above the liquidus point of the relevant grade (e.g., ~1450–1500 °C for CuNi50). Avoid overheating
Protective Cover Use dry charcoal, graphite powder, or protective flux to reduce oxidation
Avoid Contamination Do not mix alloy with iron, aluminum, or other non-ferrous scrap. Ensure equipment cleanliness

9. PACKAGING

Parameter Information
Standard Approximately 5–10 kg easy-stackable ingots. Shipped on pallets secured with shrink wrap or strapping
Special Packaging Custom sizes, granules, or waffle plates available upon request
Labeling Each pallet is labeled with product name, heat number, net weight, and manufacturer information

10. SAFETY INFORMATION

This product is considered non-hazardous in solid form and under normal transport/storage conditions. Not classified under Regulation 1272/2008/EC (CLP).

Precautions During Melting:

Aspect Recommendation
Ventilation Use local exhaust or general mechanical ventilation. Limit exposure to metal fumes (especially nickel compounds)
Personal Protective Equipment (PPE) Heat-resistant gloves, protective clothing/apron. Face shield or side-shield melting goggles. Respiratory protection with appropriate particle/fume filter (if required)
Fire Fighting Product is non-flammable. Use extinguishing media suitable for surrounding materials (water mist, dry chemical powder, CO₂). Never spray water onto molten metal (steam explosion risk)

First Aid:

Route of Exposure Action to Be Taken
Skin Contact For molten metal splashes, immediately cool with plenty of cold water; seek medical attention. Solid ingot contact is neutral
Eye Contact If metal dust or particles enter eyes, rinse with plenty of water; seek medical attention
Ingestion Ingestion of solid form is unlikely; nevertheless, consult a physician

Always comply with local occupational health and safety regulations.

11. QUALITY CONTROL

Test Method
Chemical Analysis Optical Emission Spectrometry (OES) or X-Ray Fluorescence (XRF)
Weight and Dimensions Checked against accepted tolerances
Visual Inspection Ensure no cracks, large shrinkage cavities, or surface contamination
Certificate of Analysis (COA) Provided with each shipment containing heat number, batch number, and chemical composition

12. REGULATORY COMPLIANCE

Regulation Status
EU REACH Contains Copper (Cu) and Nickel (Ni); refer to SDS for registration details
RoHS (Directive 2011/65/EU) Nickel is not restricted; final alloy must be compliant if used in EEE
Conflict Minerals Sourced only from verified conflict-free smelters
Transport Not classified as dangerous goods in solid ingot form

13. QUICK REFERENCE TABLE

Property CuNi30 CuNi50
Ni Content 30.0 ± 1.0% 50.0 ± 1.0%
Melting Range 1220 – 1260 °C 1290 – 1320 °C
Density ~8.93 g/cm³ ~8.94 g/cm³
Form Ingot (~5–10 kg) Ingot (~5–10 kg)
Crystal Structure FCC (solid solution) FCC (solid solution)
Main Uses Master alloy for copper-based systems, electrical, marine, casting alloys Master alloy for copper-based systems, electrical, marine, casting alloys
Key Benefits Homogeneous distribution, stable melting range, high purity, economic use Homogeneous distribution, stable melting range, high purity, economic use

14. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Nickel Content: Two grades available: CuNi30 and CuNi50. Choose appropriate grade for the desired nickel content in the final alloy.

  2. Melting Temperature: Melting ranges are grade-specific. Ensure appropriate temperature control during melting.

  3. Solid Solution System: Cu and Ni form a continuous solid solution with complete miscibility. No intermetallic phases are present.

  4. Corrosion Resistance: Nickel addition improves corrosion resistance, especially in marine environments.

  5. Not Hazardous: Not classified as hazardous in solid form. However, melting operations require appropriate safety measures.

  6. Environmental Protection: Dispose of waste in accordance with local regulations.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a dry, enclosed area on pallets

  • Keep in original packaging to prevent oxidation

  • No special temperature control required

  • No shelf life limitation under proper conditions

Handling:

  • Use protective gloves, safety shoes, and safety goggles

  • Use appropriate lifting equipment for pallets

Melting:

  • Preheat ingots to 100–150 °C before addition

  • Maintain bath temperature 100–200 °C above liquidus

  • Apply stirring for homogeneity

  • Use protective cover (charcoal, graphite) to reduce oxidation

  • Expected nickel recovery >95%

Waste Management:

  • Do not discharge into sewers or water bodies

  • Dispose in accordance with local regulations

LEGAL DISCLAIMER

The values presented in this Technical Data Sheet are typical values compiled from current production data and do not constitute a specification guarantee. Performance testing for specific applications is the responsibility of the user. The manufacturer is not liable for damages resulting from improper use of the product or misinterpretation of the data. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice.

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