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Ferro Copper Master Alloy, Copper-Iron Alloy, 11084-94-9, 7440-50-8, 7439-89-6

Ferro Copper Master Alloy, Copper-Iron Alloy, 11084-94-9, 7440-50-8, 7439-89-6

 

FERRO COPPER MASTER ALLOY

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Ferro Copper Master Alloy
Chemical Name Copper-Iron Alloy
Grades FeCu20 (20Fe), FeCu50 (50Fe)
Form Solid ingot
Appearance Metallic, gray-colored
CAS Number (Alloy) 11084-94-9 (Copper-Iron)
CAS Number (Copper) 7440-50-8
CAS Number (Iron) 7439-89-6
HS Code (Recommended) 7403.19 (Unwrought copper alloys)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Ferro Copper master alloy is a copper-iron intermetallic system. Copper and iron have limited solubility in the solid state, forming a copper-rich matrix with finely distributed iron-rich precipitates. The alloy consists primarily of a Cu-rich solid solution (FCC) with dispersed Fe-rich phases (BCC). This structure ensures rapid dissolution when added to copper melts.

Crystal Structure:

                    FERRO COPPER MASTER ALLOY
                               |
                 Cu Matrix + Fe-rich Precipitates
                               |
             +----------------+----------------+
             |                |                |
         Cu-rich Matrix    Fe-rich Phases    Fine
         (FCC)             (BCC)              Distribution

2.2. Phase Structure and Crystallographic Properties

Phase Crystal System Description
Cu-rich Matrix Face-Centered Cubic (FCC) Copper solid solution with dissolved iron
Fe-rich Phase Body-Centered Cubic (BCC) Iron-rich precipitates dispersed in matrix

2.3. Crystal Structure Details

Parameter Cu-rich Matrix Fe-rich Phase
Crystal System Cubic (FCC) Cubic (BCC)
Space Group Fm3̄m Im3̄m
Lattice Parameter (a) 3.61 Å 2.87 Å
Coordination Number 12 8
Density ~8.5-8.9 g/cm³ ~7.8 g/cm³

3. TECHNICAL SPECIFICATIONS

Property FeCu20 (20Fe) FeCu50 (50Fe)
Liquidus Temperature (°C) 1400 1430
Solidus Temperature (°C) 1096 1096
Typical Iron Content (%) 18 – 22 48 – 52
Density (approx.) ~8.5 g/cm³ ~7.8 g/cm³
Form Solid ingot Solid ingot
CAS Number (Component) Cu: 7440-50-8 / Fe: 7439-89-6 Cu: 7440-50-8 / Fe: 7439-89-6
Appearance Metallic, gray Metallic, gray

4. METALLURGICAL PROPERTIES

4.1. Phase Diagram Information

The Copper-Iron system exhibits a miscibility gap in the solid state. At room temperature, the equilibrium phases are Cu-rich FCC (α-Cu) and Fe-rich BCC (α-Fe). The limited solid solubility of iron in copper at room temperature means that iron forms precipitates rather than remaining in solid solution. This precipitation behavior is key to the strengthening mechanisms in iron-containing copper alloys.

4.2. Metallurgical Mechanisms

Mechanism Description
Grain Refinement Iron acts as a grain refiner, reducing cast grain size and improving mechanical properties
Precipitation Strengthening Fine Fe-rich precipitates impede dislocation movement, increasing strength and hardness
Solid Solution Strengthening Dissolved iron atoms distort the copper lattice, providing moderate strengthening
Recrystallization Resistance Iron increases recrystallization temperature, improving high-temperature strength
Wear Resistance Hard Fe-rich precipitates enhance wear resistance

4.3. Iron Addition Effects

Effect Description Mechanism
Strength Increase Increases tensile strength and hardness Precipitation strengthening + grain refinement
High Temperature Strength Improves softening resistance Increased recrystallization temperature
Wear Resistance Enhances wear resistance Hard precipitates
Ductility Moderate reduction in ductility Precipitate formation
Corrosion Resistance May improve or reduce depending on alloy Varies by application

5. DETAILED APPLICATION AREAS

5.1. High-Strength Wear-Resistant Alloys

Application Function
Marine Propellers High strength and wear resistance in seawater environments
Heavy-Duty Gears and Worm Wheels Improved mechanical properties and wear resistance
Pump Casings Enhanced strength and corrosion resistance
Bearing Alloys Improved anti-friction properties
Sliding Components Reduced wear and extended service life

Why Choose Master Alloy? Iron refines grain structure, increasing strength and wear resistance. The master alloy form ensures homogeneous distribution and high recovery without oxidation losses.

5.2. Electrical and Welding Industry

Application Function
Resistance Welding Electrodes High temperature strength and conductivity
Semiconductor Components Controlled thermal expansion and conductivity
High-Conductivity Connectors Improved mechanical properties with minimal conductivity loss
Welding Consumables Controlled composition for welding applications
Current-Carrying Components High temperature softening resistance

Why Choose Master Alloy? Iron significantly improves high-temperature strength (softening resistance) while maintaining good conductivity. Precise composition control is essential for these applications.

5.3. Grain Refinement (Microalloying)

Application Function
Brass Castings Improved mechanical properties and surface quality
Bronze Castings Enhanced strength and wear resistance
All Foundry Processes Refined grain structure and improved castability
Continuous Casting Homogeneous, equiaxed grain structure
Sand Casting Reduced porosity and improved sealing

Why Choose Master Alloy? Trace iron additions create finer and more homogeneous grain structure during solidification. This improves mechanical properties, enhances sealing, and provides better surface quality.

5.4. Copper Alloy Production

Application Function
High-Strength Brasses Improved mechanical properties
Aluminum Bronzes Enhanced strength and wear resistance
Silicon Bronzes Improved high-temperature properties
Copper-Nickel Alloys Controlled iron addition for corrosion resistance
Beryllium Copper Alternatives Non-toxic, cost-effective alternative

6. ADVANTAGES OVER PURE IRON OR SCRAP

Feature FeCu Master Alloy Pure Iron / Scrap
Melting Point 1400-1430°C 1538°C
Dissolution Rate Rapid Very slow
Recovery Rate >98% 60-85%
Composition Control Precise Poor
Oxidation Loss Minimal Significant
Slag Formation Minimal High
Energy Consumption Low High
Melting Time Short Long
Homogeneity Excellent Variable
Casting Defects Reduced Increased

6.1. Critical Advantages

  1. Lower Melting Point, Higher Yield: Pure iron melts at 1538°C and dissolves slowly in copper melts. FeCu20 (1400°C) and FeCu50 (1430°C) dissolve rapidly with >98% yield, reducing scrap and energy costs.

  2. Precise and Homogeneous Composition Control: Unlike powder or scrap iron, master alloy has a precisely known composition, making weighing and target analysis extremely easy. This ensures consistent mechanical properties with every cast.

  3. Clean Melt, Minimum Slag: The master alloy form protects iron within the copper matrix, minimizing oxidation losses. The melt remains cleaner, gas absorption is reduced, and slag cleaning is minimized.

  4. Energy and Time Savings: Dissolution time of master alloy ingots is significantly shorter than equivalent amounts of iron/steel scrap. This reduces furnace cycle time and increases production capacity.

7. GRADE SELECTION GUIDE

FeCu20 (20% Fe) — For High Precision:

  • Best For: Low iron content, precision alloys (total 0.05-2.5% Fe)

  • Advantages: Eliminates risk of exceeding target composition; wider weighing tolerance

  • Applications: Resistance welding electrodes, high-conductivity connector alloys, precision copper alloys

  • Recommended When: Final alloy requires precise, low-level iron addition

FeCu50 (50% Fe) — For High Efficiency and Low Dilution:

  • Best For: High iron content alloys (total 2-5% Fe and above)

  • Advantages: Less master alloy addition required; melt temperature drops less

  • Applications: High-strength brasses, aluminum bronzes, heavy-duty components

  • Recommended When: Large quantities of iron addition are required

8. COMPARISON WITH OTHER ALLOYING METHODS

Method Advantages Disadvantages
Ferro Copper Master Alloy High recovery, precise control, clean melt, fast dissolution Higher cost than scrap
Pure Iron Addition Lower material cost Slow dissolution, poor recovery, high oxidation, composition uncertainty
Iron Scrap/Steel Addition Low cost, available Unpredictable composition, contamination risk, slow dissolution, high slag
Iron Powder Addition Precise weight control Oxidation losses, dust hazards, poor recovery, slow dissolution

9. PACKAGING AND STORAGE

Parameter Information
Packaging Standard cast ingots, palletized and strapped for shipping convenience
Storage Store in a dry, ventilated area
Shelf Life Unlimited under proper storage conditions
Precautions Protect from moisture; keep in original packaging

10. SAFETY AND HANDLING INSTRUCTIONS

Aspect Recommendation
General Non-hazardous under normal handling conditions
Melting Operations Use appropriate personal protective equipment (heat-resistant gloves, protective goggles/face shield, aluminum-coated clothing)
Critical Warning Never add moist or wet ingots to liquid metal. Steam explosion can cause severe burns
Post-Use After use, seal packaging tightly and store in a dry place
Waste Management Slag and metal waste should be sent to recycling facilities in accordance with local environmental regulations

11. QUALITY CONTROL

Test Method Acceptance Criteria
Chemical Analysis ICP-OES Fe: 18-22% (FeCu20) / 48-52% (FeCu50)
Impurity Analysis ICP-OES Total impurities < 0.5%
Weight and Dimensions Checked against tolerances Within specified limits
Visual Inspection Metallographic No cracks, large shrinkage cavities, or surface contamination
Microstructure Optical Microscope / SEM Fine Fe-rich precipitates in copper matrix
Certificate of Analysis (COA) Provided with each shipment Heat number, batch number, and chemical composition

12. REGULATORY COMPLIANCE

Regulation Status
EU REACH Registered for copper and iron substances; alloy is exempt from registration as a mixture
RoHS (Directive 2011/65/EU) Compliant
Conflict Minerals Copper and iron sourced from conflict-free smelters
Transport Not classified as dangerous goods

13. QUICK REFERENCE TABLE

Property FeCu20 FeCu50
Product Name Ferro Copper Master Alloy Ferro Copper Master Alloy
Grade 20Fe 50Fe
Iron Content 18 – 22% 48 – 52%
Copper Content Balance (~78-82%) Balance (~48-52%)
Liquidus Temperature 1400 °C 1430 °C
Solidus Temperature 1096 °C 1096 °C
Density ~8.5 g/cm³ ~7.8 g/cm³
Form Solid ingot Solid ingot
CAS (Alloy) 11084-94-9 11084-94-9
HS Code 7403.19 7403.19
Primary Use Low Fe precision alloys High Fe alloys
Key Advantage Precision, wide tolerance High efficiency, low dilution
Typical Applications Welding electrodes, connectors High-strength brasses, aluminum bronzes

14. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Never Add Wet Ingots: Moist or wet ingots must never be added to molten metal. Steam explosion can cause severe burns and equipment damage.

  2. Moisture Protection: Store in a dry area and keep packaging sealed after use.

  3. Grade Selection: Choose FeCu20 for precise low-iron alloys; choose FeCu50 for high-iron alloys requiring efficient addition.

  4. Melting Temperature: Ensure appropriate bath temperature (1400-1450°C) for rapid dissolution.

  5. Recovery Rate: Expected iron recovery >98% under proper conditions.

  6. Contamination Prevention: Use clean tools and crucibles to prevent contamination.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a dry, ventilated area

  • Keep in original packaging

  • No shelf life limitation under proper conditions

Handling:

  • Use appropriate PPE (heat-resistant gloves, safety goggles, protective clothing)

  • Use clean, dry tools and crucibles

  • Preheat if moisture is suspected

Melting:

  • Maintain bath temperature 1400-1450°C

  • Add master alloy to the melt

  • Apply gentle stirring for homogeneity

  • Expected iron recovery >98%

Waste Management:

  • Recycle as copper scrap

  • Do not dispose with household waste

  • Follow local environmental regulations

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice.

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