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Modified Rosin, Polyterpene Resin, Terpene Phenol Resin, Alpha Methylstyrene Resin, Tall Oil Rosin, Disproportionated Rosin, Rosin Ester, Rosin Soap, Alpha Pinene, Beta Pinene, Dipentene

Modified Rosin, Polyterpene Resin, Terpene Phenol Resin, Alpha Methylstyrene Resin, Tall Oil Rosin, Disproportionated Rosin, Rosin Ester, Rosin Soap, Alpha Pinene, Beta Pinene, Dipentene

1. UNI-TAC™ 70 Modified Rosin Tackifier

Overview

UNI-TAC 70 is a modified rosin that offers excellent oxidation and crystallization resistance. It functions as a tackifier for various polymers. It contains 98% USDA certified biobased content.

Key Features

Feature Description
Tack Provides good initial adhesion
Stability High stability
Crystallization No tendency to crystallize
Oxidation Resistance Resistant to oxidation
Bio-Based Content 98% (USDA certified)
Low Tg 33°C – provides low-temperature flexibility

Potential Applications

Application Description
Flooring Provides flexibility and adhesion
Pressure Sensitive Adhesives (PSA) Balance of tack, peel, and cohesion
Sealants Flexible and durable sealing
Rubber Products Compatible with natural and synthetic rubbers

Sales Specifications

Property Test Method Specification Typical Value
Softening Point (°C) AQCM 003 75 – 85 80
Color, Gardner (50% in toluene) AQCM 002 Max 14 9.9
Acid Number (mg KOH/g) AQCM 001 145 – 160 153

Typical Values

Property Test Method Typical Value
Glass Transition Temperature (Tg °C) AQCM 218 33
Viscosity @ 125°C (cps) AQCM 004 765
Viscosity @ 150°C (cps) AQCM 004 115
Viscosity @ 177°C (cps) AQCM 004 35

Solubility

Soluble In Insoluble In
Aromatic solvents (toluene)
Aliphatic hydrocarbon solvents (hexane)
Chlorinated solvents

Compatibility

UNI-TAC 70 is compatible with:

Polymer Type Examples
Ethylene Copolymers EVA, EBA
Styrenic Block Copolymers SIS, SBS, SB Rubber
Natural and Synthetic Rubbers Natural Rubber, Butyl Rubber, Neoprene
Acrylic Polymers Acrylic-based systems
Plasticizers Phthalate and polyester plasticizers
Resins Alkyds and hydrocarbon resins

Packaging

Type Description
Pastille Form Multi-wall paper bags, 50 lb net
Molten Bulk Tank trucks or ISO containers

Storage Recommendations

Condition Recommendation
Temperature Below 20°C (70°F), dry area
Light Away from direct sunlight
Heat Away from heat sources (prevens remassing)
Pallet Stacking Do not stack pallets due to low Tg
Remassing Mild remassing is not a reason for rejection

Comparison with Similar Products

Product Type Softening Point (°C) Tg (°C) Acid Number Bio-Based
UNI-TAC 70 Modified Rosin 75-85 33 145-160 98%
RE 85 Rosin Ester (Glycerol) 80-85 30-33 ≤10-13 100%
RE 103S Rosin Ester 100-106 52 ≤10 97%
RE 25 Liquid Rosin Ester 24-32 -13 20-24 93%

Key Difference: UNI-TAC 70 has a much higher acid number (145-160) compared to RE 85 (≤10-13). This means it is less esterified and more polar, which may provide better adhesion to certain substrates.

2. SYLVATRAXX™ Tread Performance Additives

Note: This is a marketing brochure, not a technical data sheet. Key information from the brochure is summarized below.

Company Heritage (Know-How)

Area Experience
Tire & Rubber Industry 65+ years
TEA™ Technology Innovations 20+ years
SYLVATRAXX Brand 11+ years
Pine Chemical Refining 80+ years

Product Purpose

SYLVATRAXX TEA™ (Tread Enhancement Additives) are designed to improve rubber compound performance in tire applications.

Target Performance Balance

Performance Criterion Effect
Wet Grip Increased – safety
Rolling Resistance Decreased – fuel efficiency / EV range
Wear Resistance Increased – tire life

Sustainability

Feature Description
Bio-Based Certifications USDA BioPreferred® Program, European Biobased Certification (EN 16785-1:2015)
EcoVadis Rating Platinum – company-wide sustainability efforts
Circular Economy Breaking down waste plastics to original state

R&D and Technical Capabilities

Kraton's R&D team has experience in:

Expertise Area
Tires
Fillers
Rubber polymers
Coupling agents
Tackifiers
Resins
Process aids
Specialty additives

SYLVATRAXX Product Portfolio Summary

The brochure does not detail specific product codes (2097, 4150, 4401, 4404, 5216, etc.), but states the portfolio includes:

Product Type Description
Natural From renewable raw materials
Synthetic Petroleum-based
Hybrid Blend of natural and synthetic

3. Simplified Single Line Format

English:
Modified Rosin, 98% BioBased

Turkish:
Modifiye Reçine, %98 Biyo Bazlı

CAS:
8052-10-6

1. UNI-TAC™ 70 Modified Rosin Tackifier

Industry Suitability Table

Industry / Application Suitability Description
Flooring ⭐⭐⭐⭐⭐ Low Tg (33°C) provides flexibility and good adhesion
Pressure Sensitive Adhesives (PSA) ⭐⭐⭐⭐⭐ Balance of tack, peel, and cohesion
Sealants ⭐⭐⭐⭐ Flexible and durable sealing
Rubber Products ⭐⭐⭐⭐ High compatibility with natural and synthetic rubbers
Packaging ⭐⭐⭐ Moderate suitability, mainly for flexible applications
Woodworking ⭐⭐ Low viscosity, suitable for special formulations

Production Process

UNI-TAC 70 is produced as a modified rosin through the following steps:

Step Description
1. Raw Material Tall Oil Rosin – by-product of paper production
2. Modification Partial esterification or thermal treatment of rosin acids
3. Oxidation Resistance Disproportionation-like process to increase stability
4. Anti-Crystallization Special treatment to minimize crystallization tendency
5. Pastillation Molten rosin is cooled and converted into pastille form
6. Packaging 50 lb paper bags or bulk shipment

Production Flow:

Tall Oil Rosin → Modification → Stability Treatment → Pastillation → Packaging

Usage Ratios (In Formulations)

Base Polymer UNI-TAC 70 Ratio (phr) Description
EVA (Ethylene Vinyl Acetate) 80 – 120 Low viscosity, good flexibility
SIS (Styrene-Isoprene-Styrene) 60 – 100 Tack enhancement for PSA applications
SBS (Styrene-Butadiene-Styrene) 50 – 80 Balance of cohesion and flexibility
Natural Rubber (NR) 40 – 80 Adhesion and flexibility
Butyl Rubber (IIR) 30 – 60 Sealant applications
Acrylic Polymers 20 – 50 Co-tackifier for water-based systems

Note: phr = parts per hundred rubber (per 100 parts of polymer)

Example PSA Formulation (SIS-based):

Component Ratio (phr)
SIS Polymer 100
UNI-TAC 70 80 – 120
Plasticizer (Mineral Oil) 10 – 30
Antioxidant 1 – 2

2. SYLVATRAXX™ Tread Performance Additives (TEA™)

Industry Suitability Table

Industry / Application Suitability Description
Passenger Car Tires (PCR) ⭐⭐⭐⭐⭐ Balance of wet grip and rolling resistance
Electric Vehicle Tires (EV) ⭐⭐⭐⭐⭐ High torque and weight management
Truck & Bus Tires (TBR) ⭐⭐⭐⭐ Wear resistance and heat management
Winter Tires ⭐⭐⭐⭐ Cold weather performance
High Performance Summer Tires ⭐⭐⭐⭐⭐ Maximum wet grip
Off-Road / All-Terrain Tires ⭐⭐⭐ Durability and wear resistance

Production Process

SYLVATRAXX additives are produced through the following methods:

Product Type Production Method Description
Natural (Bio-Based) Terpene polymerization Polymerization of terpene monomers obtained from pine trees
Synthetic Petroleum-based polymerization Polymerization of alpha-methyl styrene or other aromatic monomers
Hybrid Copolymerization Co-polymerization of natural and synthetic monomers

Production Flow (Polyterpene Type):

Pine Turpentine → Distillation → Alpha/Beta Pinene → Cationic Polymerization → SYLVATRAXX Resin

Usage Ratios (In Tire Compounds)

Tire Type SYLVATRAXX Usage Ratio (phr) Description
Summer Tire (Tread) 5 – 15 Increases wet grip
Winter Tire (Tread) 8 – 20 Improves cold weather performance
EV Tire (Tread) 10 – 25 Wear resistance under high torque
Performance Tire 5 – 12 Balance of rolling resistance and wet grip

Example Tire Tread Formulation:

Component Ratio (phr) Function
SBR (Styrene-Butadiene Rubber) 70 – 100 Base polymer
BR (Butadiene Rubber) 0 – 30 Wear resistance
Silica 50 – 80 Wet grip
Silane 5 – 10 Coupling agent
SYLVATRAXX TEA™ 5 – 20 Tread performance additive
Carbon Black 5 – 15 Reinforcement
Zinc Oxide 2 – 3 Activation
Sulfur 1 – 2 Vulcanization

3. Summary Comparison Table

Property UNI-TAC 70 SYLVATRAXX TEA™
Primary Application Adhesives, flooring, sealants Tire tread performance
Product Type Modified Rosin Tread Enhancement Additive
Bio-Based Content 98% 70-100% (varies by product)
Tg Range 33°C -20°C to +90°C (varies by product)
Softening Point 75-85°C 25°C to 165°C (varies by product)
Usage Ratio 20-120 phr (depending on polymer) 5-25 phr (depending on tire type)
Production Tall oil rosin modification Terpene polymerization / synthetic

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