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Send EmailEuropium Fluoride, Europium Trifluoride, 13765-25-8
| Parameter | Information |
|---|---|
| Product Name | Europium Fluoride / Europium Fluoride |
| Other Technical Names | Europium Trifluoride, Europium(III) Fluoride |
| CAS Number | 13765-25-8 |
| Chemical Formula | EuF₃ |
| Molecular Weight | 208.96 g/mol |
| Product Family | Rare Earth Fluoride Salt |
| Appearance | White crystalline or powder |
Europium Fluoride (EuF₃)
Europium Ions (Eu³⁺) and Fluoride Ions (F⁻)
in Crystal Structure
F⁻ Eu³⁺ F⁻
\ | /
F⁻Eu³⁺F⁻
/ | \
F⁻ Eu³⁺ F⁻
Europium Ions (Eu³⁺) with Fluoride Ions (F⁻)
Rare Earth Fluoride Salt
White Crystalline Solid
Used as Phosphor Activator
Molecular Formula: EuF₃
Ionic Structure: Eu³⁺ and F⁻ ions
Oxidation State: +3
Color Provider: Phosphor activator
| Parameter | Information |
|---|---|
| Product Name | Europium Fluoride / Europium Fluoride |
| Other Technical Names (English) | Europium Fluoride, Europium(III) Fluoride, Europium Trifluoride |
| Other Technical Names (Turkish) | Europium Florür, Europium(III) Florür, Europium Triflorür |
| Other Technical Names (German) | Europiumfluorid, Europium(III)-fluorid, Europiumtrifluorid |
| Other Technical Names (French) | Fluorure de Europium, Fluorure d'Europium(III), Trifluorure de Europium |
| Other Technical Names (Spanish) | Fluoruro de Europio, Fluoruro de Europio(III), Trifluoruro de Europio |
| CAS Number | 13765-25-8 |
| Chemical Formula | EuF₃ |
| Molecular Weight | 208.96 g/mol |
| Chemical Class | Rare Earth Fluoride Salt |
| Appearance | White crystalline or powder |
| Odor | Odorless |
| Color | White |
| Crystal Structure | Crystalline solid |
| Property | Value | Test Method / Note |
|---|---|---|
| Appearance | White crystalline or powder | Visual |
| Chemical Formula | EuF₃ | - |
| Molecular Weight | 208.96 g/mol | Calculated |
| Density | Not specified | - |
| Melting Point | Not specified (decomposes upon heating) | - |
| Solubility | Insoluble in water; Moderately soluble in strong mineral acids | - |
| Stability | Slightly hygroscopic (absorbs moisture) | - |
| Color | White | - |
| Hygroscopicity | Slightly hygroscopic | - |
| Parameter | Information |
|---|---|
| Chemical Character | Rare earth fluoride salt; Derived from europium element; Used as phosphor activator |
| Stability | Slightly hygroscopic (absorbs moisture); Stable under normal conditions; Decomposes upon heating |
| Reactivity | Insoluble in water; Moderately soluble in strong mineral acids; Decomposes at high temperatures |
| Incompatible Materials | Strong acids, oxidizing agents, moisture (long-term) |
| Thermal Decomposition | EuF₃ → heat → EuOF + F₂ (decomposes upon heating) |
| Solubility in Water | Insoluble in water |
| Acid Solubility | Moderately soluble in strong mineral acids |
| Special Property | Used as phosphor activator; Used in display technologies and fluorescent lighting |
| Property | Europium Fluoride | Terbium Fluoride | Gadolinium Fluoride | Explanation |
|---|---|---|---|---|
| Chemical Formula | EuF₃ | TbF₃ | GdF₃ | - |
| CAS Number | 13765-25-8 | 13708-63-9 | 13765-26-9 | - |
| Appearance | White crystalline | White crystalline | White crystalline | - |
| Solubility | Insoluble in water | Insoluble in water | Insoluble in water | All are insoluble in water |
| Hygroscopic | Slightly | Slightly | Slightly | All are hygroscopic |
| Use | Phosphor activator | Phosphor activator | MRI contrast agent | - |
| Special Feature | Red/blue phosphor | Green phosphor | Magnetic | - |
| Product Code | Purity (%) | Form | Application Areas |
|---|---|---|---|
| 6341 | ≥ 99.999% | Crystalline powder | High-purity research, quantum technology |
| 6343 | ≥ 99.99% | Crystalline powder | Display technologies, fluorescent lighting |
| 6345 | ≥ 99.9% | Crystalline powder | Industrial applications, research |
| Property | Explanation |
|---|---|
| Rare Earth Compound | Derived from europium element belonging to the lanthanide group. Consists of europium ions (Eu³⁺) and fluoride ions (F⁻). |
| Optical Properties | Used as phosphor activator. Europium ions provide characteristic red (613 nm) and blue emission upon excitation. |
| Phosphor Activator | Used as phosphor activator in CRT, LCD screens and plasma displays. Used in red and blue color production in energy-saving lamps. |
| Hygroscopic Property | Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers. |
| Solubility | Insoluble in water, moderately soluble in strong mineral acids. |
| Security Applications | Used in anti-counterfeiting phosphors in Euro banknotes. |
| Industry / Application | Function | Typical Use |
|---|---|---|
| Display Technology | Phosphor activator | Used as phosphor activator in color cathode ray tubes (CRT) and LCD screens. |
| Fluorescent Lighting | Color production | Used in blue phosphor production for color TV, computer screens and fluorescent lamps. |
| Biotechnology | Fluorescence tracking | Europium fluorescence is used to study biomolecular interactions in drug discovery studies. |
| Security | Anti-counterfeiting | Used in anti-counterfeiting phosphors in Euro banknotes. |
| Quantum Technology | Data storage | Researched since 2015 for quantum memory chips, in systems that can store data for days. |
| LED Technology | Phosphor activator | Used as phosphor activator in white LED production. |
| Parameter | Explanation |
|---|---|
| Red Phosphor | Europium ions (Eu³⁺) provide red emission at 613 nm wavelength. Used in CRT, LCD and plasma displays. |
| Blue Phosphor | Europium ions can also provide blue emission. Used in color TV and fluorescent lamps. |
| Operating Principle | When europium ions receive excitation energy, they emit light at characteristic wavelengths. |
| Advantages | High color purity; Long lifetime; High brightness; Energy efficiency. |
| Application Areas | Television screens; Computer monitors; Mobile phone screens; Energy-saving lighting; LED lighting. |
| Parameter | Specification (6343 - ≥99.99%) | Test Method |
|---|---|---|
| Appearance | White crystalline or powder | Visual |
| Purity (EuF₃) | ≥ 99.99% | AAS / ICP / GDMS |
| Eu₂O₃/TREO | ≥ 99.99% | AAS / ICP |
| TREO (% min.) | ≥ 81% | AAS / ICP |
| Iron (Fe₂O₃) | ppm level | AAS / ICP / GDMS |
| Silicon (SiO₂) | ppm level | AAS / ICP / GDMS |
| Calcium (CaO) | ppm level | AAS / ICP / GDMS |
| Copper (CuO) | ppm level | AAS / ICP / GDMS |
| Nickel (NiO) | ppm level | AAS / ICP / GDMS |
| Zinc (ZnO) | ppm level | AAS / ICP / GDMS |
| Lead (PbO) | ppm level | AAS / ICP / GDMS |
| Chloride (Cl⁻) | ppm level | Ion Chromatography |
| Lanthanum (La₂O₃) | ppm level | ICP / GDMS |
| Cerium (CeO₂) | ppm level | ICP / GDMS |
| Praseodymium (Pr₆O₁₁) | ppm level | ICP / GDMS |
| Neodymium (Nd₂O₃) | ppm level | ICP / GDMS |
| Samarium (Sm₂O₃) | ppm level | ICP / GDMS |
| Other Rare Earths | ppm level | ICP / GDMS |
| Form | Crystalline powder | Visual |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity | Low toxicity |
| Acute Inhalation Toxicity | Dust inhalation may cause irritation |
| Skin Irritation | May be irritating |
| Eye Irritation | May be irritating |
| Chronic Toxicity | Rare earth compounds may show health effects with prolonged exposure |
| Carcinogenicity | Not classified as carcinogenic |
| Mutagenicity | Not classified as mutagenic |
| Target Organs | Respiratory system (dust irritation); Skin; Eyes |
| Special Toxicity Note | Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property |
GHS Classification (in compliance with CLP and UN GHS):
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315 (optional) |
| Eye Irritation | Category 2 | H319 (optional) |
| STOT - SE (Single Exposure) | Category 3 | H335 (optional) |
Note: Generally not classified as hazardous in solid state. Powder form may cause irritation.
Signal Word: WARNING (optional)
Hazard Pictograms: GHS07 (optional)
Hazard Statements (H-Codes) - if classified:
| Code | Statement |
|---|---|
| H315 | Causes skin irritation |
| H319 | Causes serious eye irritation |
| H335 | May cause respiratory irritation |
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only outdoors or in a well-ventilated area |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing |
| P312 | Call a POISON CENTER/doctor if you feel unwell |
| P362+P364 | Take off contaminated clothing and wash it before reuse |
| P403+P233 | Store in a well-ventilated place. Keep container tightly closed |
| P501 | Dispose of contents/container in accordance with local/regional/national/international regulations |
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention. |
| Skin Contact | Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention. |
| Eye Contact | Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention. |
| Ingestion | Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention. |
| Parameter | Information |
|---|---|
| Fire Hazard | Not flammable |
| Hazards During Fire | May release toxic fluoride fumes at high temperatures |
| Suitable Extinguishing Media | Dry chemical powder, CO₂, water spray, alcohol-resistant foam |
| Unsuitable Extinguishing Media | Water jet |
| Special Protective Equipment | Self-contained breathing apparatus (SCBA), full protective clothing |
| Special Precautions | Prevent dust from entering sewers and waterways; Do not inhale fumes |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area; Away from moisture; In closed containers; Keep in original packaging |
| Container Requirements | Airtight containers; Tightly closed due to hygroscopic property |
| Materials to Protect From | Strong acids, oxidizing agents, moisture |
| Shelf Life | 2-3 years (under proper storage conditions) |
| Stability Note | Slightly hygroscopic; Absorbs moisture; Store in closed containers |
| Packaging Type | Quantity | Material |
|---|---|---|
| Plastic Drum | 25-50 kg | HDPE (airtight) |
| Plastic Bucket | 5-25 kg | HDPE (airtight) |
| Glass Bottle | 100 g - 2 kg | Glass (airtight) |
| Plastic Bag | 1-10 kg | PE (sealed) |
| Flexibag | 100-500 kg | PE lined |
| Parameter | Information |
|---|---|
| UN Number | Not regulated (not dangerous) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG Code | Not regulated |
| IATA (Air) | Not regulated |
| Marine Pollutant | No |
| Transport Temperature | Ambient temperature; Protect from moisture |
| Type | Name |
|---|---|
| Turkish Names | Europium Florür, Europium(III) Florür, Europium Triflorür |
| English Names | Europium Fluoride, Europium(III) Fluoride, Europium Trifluoride |
| German Names | Europiumfluorid, Europium(III)-fluorid, Europiumtrifluorid |
| French Names | Fluorure de Europium, Fluorure d'Europium(III), Trifluorure de Europium |
| Spanish Names | Fluoruro de Europio, Fluoruro de Europio(III), Trifluoruro de Europio |
| Chemical Names | Europium Trifluoride; Europium Fluoride |
| CAS Number | 13765-25-8 |
| Chemical Formula | EuF₃ |
| Parameter | Value |
|---|---|
| Product | Europium Fluoride / Europium Fluoride |
| CAS Number | 13765-25-8 |
| Chemical Formula | EuF₃ |
| Molecular Weight | 208.96 g/mol |
| Appearance | White crystalline or powder |
| Solubility | Insoluble in water; Moderately soluble in acids |
| Primary Function | Rare earth fluoride salt; Phosphor activator |
| Main Applications | Display technology, fluorescent lighting, biotechnology, security, quantum technology |
| Shelf Life | 2-3 years |
| GHS Signal Word | WARNING (optional) |
| UN Number | Not regulated |
| Special Features | Hygroscopic; Phosphor activator; Used in red/blue phosphor production |
Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.
Irritant. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.
Insoluble in water. Moderately soluble in strong mineral acids.
Decomposes upon heating and may release toxic fluoride fumes.
Rare earth compound requires special handling and purity considerations.
Phosphor applications require high purity (≥99.99%).
Incompatibilities: Strong acids, oxidizing agents, moisture (long-term).
Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.
9. Display Technology:
Use high-purity (≥99.99%) as phosphor activator in color cathode ray tubes (CRT) and LCD screens.
10. Fluorescent Lighting:
Use in blue phosphor production for color TV, computer screens and fluorescent lamps.
11. Biotechnology:
Use europium fluorescence to study biomolecular interactions in drug discovery studies.
12. Security Applications:
Use in anti-counterfeiting phosphors in Euro banknotes.
13. Quantum Technology:
Use high-purity grade in quantum memory chips. Use in research for data storage systems.
14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.
15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.
16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.
17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers.
18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.
19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.
20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical and phosphor applications.
| Application | Recommended Grade | Explanation |
|---|---|---|
| CRT/LCD/Plasma display phosphor | 6343 (≥99.99%) or 6341 (≥99.999%) | Optical purity is critical |
| Fluorescent lighting | 6343 (≥99.99%) | Color purity required |
| Biotechnology | 6341 (≥99.999%) | High purity required |
| Security applications | 6343 (≥99.99%) | High purity required |
| Quantum technology | 6341 (≥99.999%) | Highest purity required |
| Industrial applications | 6345 (≥99.9%) | Economic solution |
| Parameter | Requirement |
|---|---|
| Storage Temperature | Room temperature (15-25°C) |
| Humidity | <60% relative humidity |
| Container | Airtight containers |
| Location | Cool, dry, well-ventilated area |
The processing of rare earth elements should be carefully managed from an environmental perspective. Waste and residues should be properly disposed of.
The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.