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Europium Fluoride, Europium Trifluoride, 13765-25-8

Europium Fluoride, Europium Trifluoride, 13765-25-8

EUROPIUM FLUORIDE (EUROPIUM FLUORIDE / EUROPIUM TRIFLUORIDE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Europium Fluoride / Europium Fluoride
Other Technical Names Europium Trifluoride, Europium(III) Fluoride
CAS Number 13765-25-8
Chemical Formula EuF₃
Molecular Weight 208.96 g/mol
Product Family Rare Earth Fluoride Salt
Appearance White crystalline or powder

CHEMICAL STRUCTURE

    Europium Fluoride (EuF₃)
    
    Europium Ions (Eu³⁺) and Fluoride Ions (F⁻)
    in Crystal Structure
    
         F⁻  Eu³⁺  F⁻
           \    |    /
            F⁻Eu³⁺F⁻
           /    |    \
         F⁻  Eu³⁺  F⁻
    
    Europium Ions (Eu³⁺) with Fluoride Ions (F⁻)
    Rare Earth Fluoride Salt
    White Crystalline Solid
    Used as Phosphor Activator

Molecular Formula: EuF₃
Ionic Structure: Eu³⁺ and F⁻ ions
Oxidation State: +3
Color Provider: Phosphor activator

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Europium Fluoride / Europium Fluoride
Other Technical Names (English) Europium Fluoride, Europium(III) Fluoride, Europium Trifluoride
Other Technical Names (Turkish) Europium Florür, Europium(III) Florür, Europium Triflorür
Other Technical Names (German) Europiumfluorid, Europium(III)-fluorid, Europiumtrifluorid
Other Technical Names (French) Fluorure de Europium, Fluorure d'Europium(III), Trifluorure de Europium
Other Technical Names (Spanish) Fluoruro de Europio, Fluoruro de Europio(III), Trifluoruro de Europio
CAS Number 13765-25-8
Chemical Formula EuF₃
Molecular Weight 208.96 g/mol
Chemical Class Rare Earth Fluoride Salt
Appearance White crystalline or powder
Odor Odorless
Color White
Crystal Structure Crystalline solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White crystalline or powder Visual
Chemical Formula EuF₃ -
Molecular Weight 208.96 g/mol Calculated
Density Not specified -
Melting Point Not specified (decomposes upon heating) -
Solubility Insoluble in water; Moderately soluble in strong mineral acids -
Stability Slightly hygroscopic (absorbs moisture) -
Color White -
Hygroscopicity Slightly hygroscopic -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Rare earth fluoride salt; Derived from europium element; Used as phosphor activator
Stability Slightly hygroscopic (absorbs moisture); Stable under normal conditions; Decomposes upon heating
Reactivity Insoluble in water; Moderately soluble in strong mineral acids; Decomposes at high temperatures
Incompatible Materials Strong acids, oxidizing agents, moisture (long-term)
Thermal Decomposition EuF₃ → heat → EuOF + F₂ (decomposes upon heating)
Solubility in Water Insoluble in water
Acid Solubility Moderately soluble in strong mineral acids
Special Property Used as phosphor activator; Used in display technologies and fluorescent lighting

SECTION 4: RARE EARTH FLUORIDES COMPARISON TABLE

Property Europium Fluoride Terbium Fluoride Gadolinium Fluoride Explanation
Chemical Formula EuF₃ TbF₃ GdF₃ -
CAS Number 13765-25-8 13708-63-9 13765-26-9 -
Appearance White crystalline White crystalline White crystalline -
Solubility Insoluble in water Insoluble in water Insoluble in water All are insoluble in water
Hygroscopic Slightly Slightly Slightly All are hygroscopic
Use Phosphor activator Phosphor activator MRI contrast agent -
Special Feature Red/blue phosphor Green phosphor Magnetic -

SECTION 5: EUROPIUM FLUORIDE GRADES

Product Code Purity (%) Form Application Areas
6341 ≥ 99.999% Crystalline powder High-purity research, quantum technology
6343 ≥ 99.99% Crystalline powder Display technologies, fluorescent lighting
6345 ≥ 99.9% Crystalline powder Industrial applications, research

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Rare Earth Compound Derived from europium element belonging to the lanthanide group. Consists of europium ions (Eu³⁺) and fluoride ions (F⁻).
Optical Properties Used as phosphor activator. Europium ions provide characteristic red (613 nm) and blue emission upon excitation.
Phosphor Activator Used as phosphor activator in CRT, LCD screens and plasma displays. Used in red and blue color production in energy-saving lamps.
Hygroscopic Property Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers.
Solubility Insoluble in water, moderately soluble in strong mineral acids.
Security Applications Used in anti-counterfeiting phosphors in Euro banknotes.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Display Technology Phosphor activator Used as phosphor activator in color cathode ray tubes (CRT) and LCD screens.
Fluorescent Lighting Color production Used in blue phosphor production for color TV, computer screens and fluorescent lamps.
Biotechnology Fluorescence tracking Europium fluorescence is used to study biomolecular interactions in drug discovery studies.
Security Anti-counterfeiting Used in anti-counterfeiting phosphors in Euro banknotes.
Quantum Technology Data storage Researched since 2015 for quantum memory chips, in systems that can store data for days.
LED Technology Phosphor activator Used as phosphor activator in white LED production.

SECTION 8: PHOSPHOR APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Red Phosphor Europium ions (Eu³⁺) provide red emission at 613 nm wavelength. Used in CRT, LCD and plasma displays.
Blue Phosphor Europium ions can also provide blue emission. Used in color TV and fluorescent lamps.
Operating Principle When europium ions receive excitation energy, they emit light at characteristic wavelengths.
Advantages High color purity; Long lifetime; High brightness; Energy efficiency.
Application Areas Television screens; Computer monitors; Mobile phone screens; Energy-saving lighting; LED lighting.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Specification (6343 - ≥99.99%) Test Method
Appearance White crystalline or powder Visual
Purity (EuF₃) ≥ 99.99% AAS / ICP / GDMS
Eu₂O₃/TREO ≥ 99.99% AAS / ICP
TREO (% min.) ≥ 81% AAS / ICP
Iron (Fe₂O₃) ppm level AAS / ICP / GDMS
Silicon (SiO₂) ppm level AAS / ICP / GDMS
Calcium (CaO) ppm level AAS / ICP / GDMS
Copper (CuO) ppm level AAS / ICP / GDMS
Nickel (NiO) ppm level AAS / ICP / GDMS
Zinc (ZnO) ppm level AAS / ICP / GDMS
Lead (PbO) ppm level AAS / ICP / GDMS
Chloride (Cl⁻) ppm level Ion Chromatography
Lanthanum (La₂O₃) ppm level ICP / GDMS
Cerium (CeO₂) ppm level ICP / GDMS
Praseodymium (Pr₆O₁₁) ppm level ICP / GDMS
Neodymium (Nd₂O₃) ppm level ICP / GDMS
Samarium (Sm₂O₃) ppm level ICP / GDMS
Other Rare Earths ppm level ICP / GDMS
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be irritating
Eye Irritation May be irritating
Chronic Toxicity Rare earth compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Special Toxicity Note Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315 (optional)
Eye Irritation Category 2 H319 (optional)
STOT - SE (Single Exposure) Category 3 H335 (optional)

Note: Generally not classified as hazardous in solid state. Powder form may cause irritation.

Signal Word: WARNING (optional)

Hazard Pictograms: GHS07 (optional)

Hazard Statements (H-Codes) - if classified:

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable
Hazards During Fire May release toxic fluoride fumes at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Away from moisture; In closed containers; Keep in original packaging
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong acids, oxidizing agents, moisture
Shelf Life 2-3 years (under proper storage conditions)
Stability Note Slightly hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Europium Florür, Europium(III) Florür, Europium Triflorür
English Names Europium Fluoride, Europium(III) Fluoride, Europium Trifluoride
German Names Europiumfluorid, Europium(III)-fluorid, Europiumtrifluorid
French Names Fluorure de Europium, Fluorure d'Europium(III), Trifluorure de Europium
Spanish Names Fluoruro de Europio, Fluoruro de Europio(III), Trifluoruro de Europio
Chemical Names Europium Trifluoride; Europium Fluoride
CAS Number 13765-25-8
Chemical Formula EuF₃

SECTION 19: SUMMARY TABLE

Parameter Value
Product Europium Fluoride / Europium Fluoride
CAS Number 13765-25-8
Chemical Formula EuF₃
Molecular Weight 208.96 g/mol
Appearance White crystalline or powder
Solubility Insoluble in water; Moderately soluble in acids
Primary Function Rare earth fluoride salt; Phosphor activator
Main Applications Display technology, fluorescent lighting, biotechnology, security, quantum technology
Shelf Life 2-3 years
GHS Signal Word WARNING (optional)
UN Number Not regulated
Special Features Hygroscopic; Phosphor activator; Used in red/blue phosphor production

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  2. Irritant. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.

  3. Insoluble in water. Moderately soluble in strong mineral acids.

  4. Decomposes upon heating and may release toxic fluoride fumes.

  5. Rare earth compound requires special handling and purity considerations.

  6. Phosphor applications require high purity (≥99.99%).

  7. Incompatibilities: Strong acids, oxidizing agents, moisture (long-term).

  8. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

9. Display Technology:
Use high-purity (≥99.99%) as phosphor activator in color cathode ray tubes (CRT) and LCD screens.

10. Fluorescent Lighting:
Use in blue phosphor production for color TV, computer screens and fluorescent lamps.

11. Biotechnology:
Use europium fluorescence to study biomolecular interactions in drug discovery studies.

12. Security Applications:
Use in anti-counterfeiting phosphors in Euro banknotes.

13. Quantum Technology:
Use high-purity grade in quantum memory chips. Use in research for data storage systems.

14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.

16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers.

18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.

20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical and phosphor applications.

EUROPIUM FLUORIDE SELECTION GUIDE:

Application Recommended Grade Explanation
CRT/LCD/Plasma display phosphor 6343 (≥99.99%) or 6341 (≥99.999%) Optical purity is critical
Fluorescent lighting 6343 (≥99.99%) Color purity required
Biotechnology 6341 (≥99.999%) High purity required
Security applications 6343 (≥99.99%) High purity required
Quantum technology 6341 (≥99.999%) Highest purity required
Industrial applications 6345 (≥99.9%) Economic solution

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area

ENVIRONMENTAL NOTE:

The processing of rare earth elements should be carefully managed from an environmental perspective. Waste and residues should be properly disposed of.

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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