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Europium Chloride Hexahydrate, Europium Trichloride Hexahydrate, Europium Chloride Hydrate, 13759-92-7

Europium Chloride Hexahydrate, Europium Trichloride Hexahydrate, Europium Chloride Hydrate, 13759-92-7

EUROPIUM CHLORIDE HEXAHYDRATE (EUROPIUM CHLORIDE HEXAHYDRATE / EUROPIUM TRICHLORIDE HEXAHYDRATE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Europium Chloride Hexahydrate / Europium Chloride Hexahydrate
Other Technical Names Europium Chloride Hydrate, Europium Trichloride Hexahydrate, Europium(III) Chloride Hydrate
CAS Number 13759-92-7
Chemical Formula EuCl₃·6H₂O
Molecular Weight 366.41 g/mol
Product Family Rare Earth Chloride Salt
Appearance White crystalline or powder

CHEMICAL STRUCTURE

    Europium Chloride Hexahydrate (EuCl₃·6H₂O)
    
    Europium Ions (Eu³⁺) and Chloride Ions (Cl⁻)
    in Hexahydrate Form (with 6 H₂O Molecules)
    
         Cl⁻  Eu³⁺  Cl⁻
           \    |    /
            Cl⁻Eu³⁺Cl⁻
           /    |    \
         Cl⁻  Eu³⁺  Cl⁻
    
    Europium Ions (Eu³⁺) with Chloride Ions (Cl⁻)
    Surrounded by 6 Water Molecules (H₂O)
    Rare Earth Chloride Salt
    White Crystalline Solid

Molecular Formula: EuCl₃·6H₂O
Ionic Structure: Eu³⁺ and Cl⁻ ions
Hydrate State: Hexahydrate (6 water molecules)
Color Provider: Critical for red and blue phosphor production

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Europium Chloride Hexahydrate / Europium Chloride Hexahydrate
Other Technical Names (English) Europium Chloride Hexahydrate, Europium(III) Chloride Hydrate, Europium Trichloride Hexahydrate
Other Technical Names (Turkish) Europium Klorür Hekzahidrat, Europium Klorür Hidrat, Europium Triklorür Hekzahidrat, Avrupa Klorür
Other Technical Names (German) Europiumchlorid Hexahydrat, Europium(III)-chlorid Hexahydrat
Other Technical Names (French) Chlorure de Europium Hexahydraté, Chlorure d'Europium(III) Hexahydraté
Other Technical Names (Spanish) Cloruro de Europio Hexahidratado, Cloruro de Europio(III) Hexahidratado
CAS Number 13759-92-7
Chemical Formula EuCl₃·6H₂O
Molecular Weight 366.41 g/mol
Chemical Class Rare Earth Chloride Salt
Appearance White crystalline or powder
Odor Odorless
Color White
Crystal Structure Crystalline solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White crystalline or powder Visual
Chemical Formula EuCl₃·6H₂O -
Molecular Weight 366.41 g/mol Calculated
Density Approximately 4.89 g/mL (at 25°C) -
Melting Point Approximately 850°C (close to anhydrous form) -
Solubility Soluble in water; Soluble in mineral acids -
Stability Slightly hygroscopic (absorbs moisture) -
Color White -
pH Neutral to slightly acidic (when dissolved in water) -
Hygroscopicity Slightly hygroscopic -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Rare earth chloride salt; Derived from europium element; Critical for red and blue phosphor production; Exhibits optical properties
Stability Slightly hygroscopic (absorbs moisture); Stable under normal conditions; Converts to anhydrous form upon heating
Reactivity Soluble in water; Soluble in mineral acids; Reacts with bases; Decomposes at high temperatures
Incompatible Materials Strong bases, oxidizing agents, moisture (long-term)
Thermal Decomposition EuCl₃·6H₂O → heat → EuCl₃ + 6H₂O (loses water upon heating)
Solubility in Water Soluble in water; Dissociates into Eu³⁺ and Cl⁻ ions
Acid Solubility High solubility in mineral acids
Special Property Plays a critical role in red and blue phosphor production; Fundamental component in display technologies

SECTION 4: RARE EARTH CHLORIDES COMPARISON TABLE

Property Europium Chloride Terbium Chloride Gadolinium Chloride Explanation
Chemical Formula EuCl₃·6H₂O TbCl₃·6H₂O GdCl₃·6H₂O -
CAS Number 13759-92-7 13798-24-8 13450-84-5 -
Appearance White crystalline Colorless/White White crystalline -
Solubility Soluble in water Soluble in water Soluble in water All are water soluble
Hygroscopic Slightly Slightly Slightly All are hygroscopic
Use Red phosphor Green phosphor MRI contrast agent -
Special Feature Red/blue phosphor Magnetic Magnetic -

SECTION 5: EUROPIUM CHLORIDE GRADES

Grade Purity (%) Form Application Areas
EC-1 ≥ 99.99% Crystalline powder Display technologies, high-purity research
EC-2 ≥ 99.9% Crystalline powder Fluorescent lighting, laser glasses
EC-3 ≥ 99.5% Crystalline powder Industrial applications, research

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Rare Earth Salt Derived from europium element belonging to the lanthanide series. Consists of europium ions (Eu³⁺) and chloride ions (Cl⁻).
Optical Properties Plays a critical role in red and blue phosphor production. Europium ions provide characteristic red (613 nm) and blue emission upon excitation.
Phosphor Production Used in red phosphor production for cathode ray tubes (CRT), LCD screens and plasma displays. Used in red and blue color production in energy-saving lamps.
Hygroscopic Property Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers.
Solubility High solubility in water and mineral acids. Provides Eu³⁺ ions in solution.
Color Provider Fundamental component in red and blue color production. Indispensable for display technologies.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Display Technology Phosphor production Used in red phosphor production for cathode ray tubes (CRT), LCD screens and plasma displays.
Fluorescent Lighting Color production Used in red and blue color production in energy-saving lamps.
Laser Glasses Optical material Used in the production of special laser glasses.
Quantum Memory Data storage Has been considered for use in next-generation data storage research.
Research Reagent Used as a reagent in rare earth chemistry and optical material development.
LED Technology Phosphor production Used as red phosphor in white LED production.

SECTION 8: PHOSPHOR APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Red Phosphor Europium ions (Eu³⁺) provide red emission at 613 nm wavelength. Used in CRT, LCD and plasma displays.
Blue Phosphor Europium ions can also provide blue emission. Used in energy-saving lamps.
Operating Principle When europium ions receive excitation energy, they emit light at characteristic wavelengths.
Advantages High color purity; Long lifetime; High brightness; Energy efficiency.
Application Areas Television screens; Computer monitors; Mobile phone screens; Energy-saving lighting; LED lighting.

SECTION 9: QUALITY SPECIFICATIONS (EC-1 GRADE – ≥99.99%)

Parameter Specification Test Method
Appearance White crystalline or powder Visual
Purity (EuCl₃·6H₂O) ≥ 99.99% AAS / ICP / GDMS
Europium Oxide (Eu₂O₃) ≥ 38.0% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP / GDMS
Calcium (Ca) ≤ 0.001% AAS / ICP / GDMS
Magnesium (Mg) ≤ 0.001% AAS / ICP / GDMS
Silicon (Si) ≤ 0.001% AAS / ICP / GDMS
Aluminum (Al) ≤ 0.001% AAS / ICP / GDMS
Other Rare Earths ≤ 0.01% ICP / GDMS
Chloride Content Matches theoretical value Titration
Water of Crystallization 6 H₂O molecules TGA
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be slightly irritating
Eye Irritation May be slightly irritating
Chronic Toxicity Rare earth compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Special Toxicity Note Slightly irritating; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315 (optional)
Eye Irritation Category 2 H319 (optional)
STOT - SE (Single Exposure) Category 3 H335 (optional)

Note: Generally not classified as hazardous in solid state. Powder form may cause irritation.

Signal Word: WARNING (optional)

Hazard Pictograms: GHS07 (optional)

Hazard Statements (H-Codes) - if classified:

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable
Hazards During Fire May release toxic chloride fumes at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Away from moisture; In closed containers; Keep in original packaging
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong bases, oxidizing agents, moisture
Shelf Life 2-3 years (under proper storage conditions)
Stability Note Slightly hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Europium Klorür Hekzahidrat, Europium Klorür Hidrat, Europium Triklorür Hekzahidrat, Avrupa Klorür
English Names Europium Chloride Hexahydrate, Europium(III) Chloride Hydrate, Europium Trichloride Hexahydrate
German Names Europiumchlorid Hexahydrat, Europium(III)-chlorid Hexahydrat
French Names Chlorure de Europium Hexahydraté, Chlorure d'Europium(III) Hexahydraté
Spanish Names Cloruro de Europio Hexahidratado, Cloruro de Europio(III) Hexahidratado
Chemical Names Europium Trichloride Hexahydrate; Europium Chloride Hydrate
CAS Number 13759-92-7
Chemical Formula EuCl₃·6H₂O

SECTION 19: SUMMARY TABLE

Parameter Value
Product Europium Chloride Hexahydrate
CAS Number 13759-92-7
Chemical Formula EuCl₃·6H₂O
Molecular Weight 366.41 g/mol
Appearance White crystalline or powder
Density Approximately 4.89 g/mL (at 25°C)
Melting Point Approximately 850°C
Solubility Soluble in water; Soluble in acids
Primary Function Rare earth salt; Phosphor production; Colorant
Main Applications Display technology, fluorescent lighting, laser glasses, quantum memory, research
Shelf Life 2-3 years
GHS Signal Word WARNING (optional)
UN Number Not regulated
Special Features Hygroscopic; Critical for red/blue phosphor production

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  2. Slightly irritating. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.

  3. Loses water upon heating and converts to anhydrous form. May release chloride fumes at high temperatures.

  4. Rare earth salt requires special handling and purity considerations.

  5. Display and lighting applications require high purity (≥99.99%).

  6. Incompatibilities: Strong bases, oxidizing agents, moisture (long-term).

  7. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

9. Display Technology:
Use high-purity (≥99.99%) EC-1 grade for red phosphor production in cathode ray tubes (CRT), LCD screens and plasma displays.

10. Fluorescent Lighting:
Select appropriate grade for red and blue color production in energy-saving lamps.

11. Laser Glasses:
Use in the production of special laser glasses. Pay attention to optical purity requirements.

12. Quantum Memory:
Use high-purity grade in next-generation data storage research.

13. Research Applications:
Use as a reagent in rare earth chemistry and optical material development. Select appropriate purity level.

14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.

16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers.

18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.

20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical and display applications.

EUROPIUM CHLORIDE SELECTION GUIDE:

Application Recommended Grade Explanation
CRT/LCD/Plasma display phosphor EC-1 (≥99.99%) Optical purity is critical
Fluorescent lighting EC-1 (≥99.99%) Color purity required
Laser glasses EC-1 (≥99.99%) High purity required
Quantum memory EC-1 (≥99.99%) High purity required
Research EC-1 (≥99.99%) or EC-2 (≥99.9%) Depends on purity requirement
Industrial applications EC-3 (≥99.5%) Economic solution

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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