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Erbium Nitrate, Erbium Nitrate Hydrate, Erbium Trinitrate, 10031-51-3

Erbium Nitrate, Erbium Nitrate Hydrate, Erbium Trinitrate, 10031-51-3

ERBIUM NITRATE (ERBIUM NITRATE / ERBIUM NITRATE HYDRATE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Erbium Nitrate / Erbium Nitrate Hydrate
Other Technical Names Erbium Trinitrate, Erbium Nitrate Hydrate, Erbium(III) Nitrate
CAS Number 10031-51-3
Chemical Formula Er(NO₃)₃·xH₂O
Molecular Weight 353.27 g/mol (for anhydrous form)
Product Family Rare Earth Nitrate Salt
Appearance Pink crystalline solid

CHEMICAL STRUCTURE

    Erbium Nitrate Hydrate (Er(NO₃)₃·xH₂O)
    
    Erbium Ions (Er³⁺) and Nitrate Ions (NO₃⁻)
    with Hydrate Molecules in Crystal Structure
    
         NO₃⁻  Er³⁺  NO₃⁻
           \    |    /
            NO₃⁻Er³⁺NO₃⁻
           /    |    \
         NO₃⁻  Er³⁺  NO₃⁻
    
    Erbium Ions (Er³⁺) with Nitrate Ions (NO₃⁻)
    Surrounded by Hydrate Molecules (H₂O)
    Rare Earth Nitrate Salt
    Pink Crystalline Solid

Molecular Formula: Er(NO₃)₃·xH₂O
Ionic Structure: Er³⁺ and NO₃⁻ ions
Hydrate State: x variable (typically 3-6)
Color Provider: Provides pink color

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Erbium Nitrate / Erbium Nitrate Hydrate
Other Technical Names (English) Erbium Nitrate, Erbium(III) Nitrate, Erbium Trinitrate, Erbium Nitrate Hydrate
Other Technical Names (Turkish) Erbiyum Nitrat, Erbiyum(III) Nitrat, Erbiyum Trinitrat, Erbiyum Nitrat Hidrat
Other Technical Names (German) ErbiumNitrat, Erbium(III)-Nitrat, Erbiumtrinitrat
Other Technical Names (French) Nitrate d'Erbium, Nitrate d'Erbium(III), Trinitrate d'Erbium
Other Technical Names (Spanish) Nitrato de Erbio, Nitrato de Erbio(III), Trinitrato de Erbio
CAS Number 10031-51-3
Chemical Formula Er(NO₃)₃·xH₂O
Molecular Weight 353.27 g/mol (for anhydrous form)
Chemical Class Rare Earth Nitrate Salt
Appearance Pink crystalline solid
Odor Odorless
Color Pink
Crystal Structure Crystalline solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Pink crystalline solid Visual
Chemical Formula Er(NO₃)₃·xH₂O -
Molecular Weight 353.27 g/mol (anhydrous) Calculated
Density Not specified (varies with hydrate degree) -
Melting Point Not distinct, decomposes upon heating -
Solubility Soluble in water; High solubility in strong mineral acids -
Stability Slightly hygroscopic (absorbs moisture) -
Color Pink Originates from erbium ions
Oxidizing Property May increase fire risk when in contact with combustible materials -
pH Acidic (when dissolved in water) -
Hygroscopicity Slightly hygroscopic -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Rare earth nitrate salt; Derived from erbium element; Exhibits oxidizing properties; Provides pink color
Stability Slightly hygroscopic (absorbs moisture); Decomposes upon heating; Stable under normal conditions
Reactivity Exhibits oxidizing properties; Increases fire risk when in contact with combustible materials; Soluble in strong acids
Incompatible Materials Combustible materials, reducing agents, organic materials, strong bases
Thermal Decomposition Er(NO₃)₃·xH₂O → heat → Er₂O₃ + NOₓ + H₂O (decomposes upon heating)
Solubility in Water Soluble in water; Dissociates into Er³⁺ and NO₃⁻ ions
Acid Solubility High solubility in strong mineral acids
Special Property Provides pink color in glass and porcelain glazes; Acts as precursor for high-purity erbium oxide production

SECTION 4: RARE EARTH NITRATES COMPARISON TABLE

Property Erbium Nitrate Terbium Nitrate Holmium Nitrate Explanation
Chemical Formula Er(NO₃)₃·xH₂O Tb(NO₃)₃·xH₂O Ho(NO₃)₃·xH₂O -
CAS Number 10031-51-3 57584-27-7 10168-82-8 -
Color Pink Colorless/Yellow Yellow Erbium gives pink color
Solubility Soluble in water Soluble in water Soluble in water All are water soluble
Oxidizing Yes Yes Yes All are oxidizing
Use Glass, fiber optics Phosphors, glass Laser, glass -
Special Feature Critical for fiber optics Magnetic Laser applications -

SECTION 5: ERBIUM NITRATE GRADES

Grade Purity (%) Form Application Areas
EN-1 ≥ 99.99% Crystalline powder Fiber optics, high-purity research
EN-2 ≥ 99.9% Crystalline powder Glass and ceramics, optical applications
EN-3 ≥ 99.5% Crystalline powder Industrial applications, research

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Rare Earth Salt Derived from erbium element. Consists of erbium ions (Er³⁺) and nitrate ions (NO₃⁻).
Oxidizing Property Exhibits oxidizing properties due to nitrate ions. May increase fire risk when in contact with combustible materials.
Color Provider Provides pink color in glass and porcelain glazes. Characteristic color of erbium ions.
Intermediate Compound Used as primary raw material for high-purity erbium oxide (Er₂O₃) production. Converts to oxide through thermal decomposition.
Hygroscopic Property Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers.
Solubility High solubility in water and strong mineral acids. Provides Er³⁺ ions in solution.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Glass Production Coloring and protection Provides pink color and UV blocking properties. Used in specialty glass production.
Porcelain and Ceramics Colorant Used as a colorant in glazes. Provides pink tones.
Optical Fibers Dopant (additive) High-purity erbium nitrate used as a dopant in fiber optic amplifiers.
Telecommunications Signal amplification Plays a critical role as a signal amplifier in fiber optic data transmission.
Research and Industry Precursor material Used as a precursor material for erbium oxide and other erbium compounds.
Optical Coatings Coating material Used as coating material in optical components.
Catalysts Chemical reactions Used as a catalyst in certain chemical reactions.

SECTION 8: FIBER OPTIC APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Application Used as a dopant in erbium-doped fiber amplifiers (EDFA).
Operating Principle Erbium ions (Er³⁺) are excited by laser diode; Provides emission at 1.5 µm wavelength.
Wavelength 1.5 µm (1550 nm) - Ideal for optical communication; Lowest fiber loss region.
Advantages Long-distance signal transmission; Signal amplification; No electronic conversion required.
Application Areas Internet backbone; Submarine communication cables; Satellite communication; Telephone lines.
Importance Fundamental component of modern telecommunication infrastructure.

SECTION 9: QUALITY SPECIFICATIONS (EN-1 GRADE – ≥99.99%)

Parameter Specification Test Method
Appearance Pink crystalline solid Visual
Purity (Er(NO₃)₃) ≥ 99.99% AAS / ICP / GDMS
Erbium Oxide (Er₂O₃) ≥ 39.0% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP / GDMS
Calcium (Ca) ≤ 0.001% AAS / ICP / GDMS
Magnesium (Mg) ≤ 0.001% AAS / ICP / GDMS
Silicon (Si) ≤ 0.001% AAS / ICP / GDMS
Aluminum (Al) ≤ 0.001% AAS / ICP / GDMS
Other Rare Earths ≤ 0.01% ICP / GDMS
Nitrate Content Matches theoretical value Titration
Water of Hydration Varies with degree TGA
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be irritating
Eye Irritation May be irritating
Chronic Toxicity Rare earth compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Special Toxicity Note Irritant; May cause irritation to skin, eyes and respiratory tract; Avoid contact with combustible materials due to oxidizing properties

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Oxidizing Solids Category 2 H272
Skin Irritation Category 2 H315
Eye Irritation Category 2 H319
STOT - SE (Single Exposure) Category 3 H335

Signal Word: WARNING

Hazard Pictograms: GHS03 (Oxidizing), GHS07 (Irritant)

Hazard Statements (H-Codes):

Code Statement
H272 May intensify fire; oxidizer
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P210 Keep away from heat/sparks/open flames/hot surfaces
P220 Keep away from combustible materials
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Oxidizer; May intensify fire when in contact with combustible materials
Hazards During Fire May release toxic nitrogen oxide (NOₓ) fumes at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray (for large fires), alcohol-resistant foam
Unsuitable Extinguishing Media Water jet (may spread molten material)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Isolate fire area; Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Away from combustible materials; In closed containers; Protect from moisture
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Combustible materials, reducing agents, organic materials, strong bases, moisture
Shelf Life 2-3 years (under proper storage conditions)
Stability Note Slightly hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number 1477 (Nitrates, inorganic, n.o.s.)
Hazard Class 5.1 (Oxidizing substances)
Packing Group III
ADR/RID 5.1, PG III
IMDG Code 5.1, PG III
IATA (Air) 5.1, PG III
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture; Keep away from combustible materials

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Erbiyum Nitrat, Erbiyum(III) Nitrat, Erbiyum Trinitrat, Erbiyum Nitrat Hidrat
English Names Erbium Nitrate, Erbium(III) Nitrate, Erbium Trinitrate, Erbium Nitrate Hydrate
German Names ErbiumNitrat, Erbium(III)-Nitrat, Erbiumtrinitrat
French Names Nitrate d'Erbium, Nitrate d'Erbium(III), Trinitrate d'Erbium
Spanish Names Nitrato de Erbio, Nitrato de Erbio(III), Trinitrato de Erbio
Chemical Names Erbium Nitrate Hydrate; Erbium Trinitrate Hydrate
CAS Number 10031-51-3
Chemical Formula Er(NO₃)₃·xH₂O

SECTION 19: SUMMARY TABLE

Parameter Value
Product Erbium Nitrate / Erbium Nitrate Hydrate
CAS Number 10031-51-3
Chemical Formula Er(NO₃)₃·xH₂O
Molecular Weight 353.27 g/mol (anhydrous)
Appearance Pink crystalline solid
Solubility Soluble in water; Soluble in acids
Primary Function Rare earth salt; Colorant; Precursor material
Main Applications Glass production, porcelain/ceramics, optical fibers, telecommunications, research
Shelf Life 2-3 years
GHS Signal Word WARNING
UN Number 1477
Hazard Class 5.1 (Oxidizing)
Special Features Oxidizing; Pink colorant; Hygroscopic

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Oxidizing substance. May intensify fire when in contact with combustible materials. Keep away from combustible materials.

  2. Irritant. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.

  3. Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  4. Decomposes upon heating and may release toxic nitrogen oxide (NOₓ) fumes.

  5. Rare earth salt requires special handling and purity considerations.

  6. Fiber optic applications require high purity (≥99.99%).

  7. Incompatibilities: Combustible materials, reducing agents, organic materials, strong bases.

  8. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

9. Glass Production:
Use erbium nitrate to provide pink color and UV blocking properties. Provide appropriate doping ratios.

10. Porcelain and Ceramics:
Use as a colorant in glazes. Add appropriate amounts to achieve pink tones.

11. Fiber Optic Applications:
Use high-purity (≥99.99%) EN-1 grade for fiber optic amplifiers. Maintain signal quality in long-distance communication lines.

12. Erbium Oxide Production:
Use as primary raw material for high-purity erbium oxide production. Convert to oxide through thermal decomposition.

13. Research Applications:
Select appropriate purity level. Determine quality according to research requirements.

14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.

16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

17. Storage:
Store in cool, dry, well-ventilated area; Keep away from combustible materials; Store in closed, airtight containers.

18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.

20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical and fiber optic applications.

ERBIUM NITRATE SELECTION GUIDE:

Application Recommended Grade Explanation
Fiber optic amplifier EN-1 (≥99.99%) Optical purity is critical
Glass and ceramics EN-2 (≥99.9%) Economic solution
Erbium oxide production EN-1 (≥99.99%) or EN-2 (≥99.9%) Depends on purity requirement
Research EN-1 (≥99.99%) High purity required
Industrial applications EN-3 (≥99.5%) Economic solution

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area; Separate from combustible materials

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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