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Cerium Chloride, Cerous Chloride, 19423-76-8

Cerium Chloride, Cerous Chloride, 19423-76-8

CERIUM CHLORIDE (CERIUM CHLORIDE / CEROUS CHLORIDE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Cerium Chloride / Cerium Chloride
Other Technical Names Cerous Chloride, Cerium(III) Chloride
CAS Number 19423-76-8 (hydrate form)
Chemical Formula CeCl₃·xH₂O
Molecular Weight 246.48 g/mol (anhydrous form)
Product Family Rare Earth Chloride Salt
Appearance White crystalline powder or light yellow solid

CHEMICAL STRUCTURE

    Cerium Chloride (CeCl₃·xH₂O)
    
    Cerium Ions (Ce³⁺) and Chloride Ions (Cl⁻)
    with Hydrate Molecules
    
         Cl⁻  Ce³⁺  Cl⁻
           \    |    /
            Cl⁻Ce³⁺Cl⁻
           /    |    \
         Cl⁻  Ce³⁺  Cl⁻
    
    Cerium Ions (Ce³⁺) with Chloride Ions (Cl⁻)
    Rare Earth Chloride Salt
    White/Light Yellow Crystalline Solid
    Used as Catalyst and in Glass Industry

Molecular Formula: CeCl₃·xH₂O
Ionic Structure: Ce³⁺ and Cl⁻ ions
Hydrate State: x variable
Oxidation State: +3
Color: White or light yellow

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Cerium Chloride / Cerium Chloride
Other Technical Names (English) Cerium Chloride, Cerium(III) Chloride, Cerous Chloride
Other Technical Names (Turkish) Seryum Klorür, Seryum(III) Klorür, Seröz Klorür
Other Technical Names (German) Cerchlorid, Cer(III)-chlorid, Cerouschlorid
Other Technical Names (French) Chlorure de Cérium, Chlorure de Cérium(III), Chlorure Céreux
Other Technical Names (Spanish) Cloruro de Cerio, Cloruro de Cerio(III), Cloruro Ceroso
CAS Number 19423-76-8 (hydrate form)
Chemical Formula CeCl₃·xH₂O
Molecular Weight 246.48 g/mol (anhydrous form)
Chemical Class Rare Earth Chloride Salt
Appearance White crystalline powder or light yellow solid
Odor Odorless
Color White or light yellow
Crystal Structure Crystalline solid

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White crystalline powder or light yellow solid Visual
Chemical Formula CeCl₃·xH₂O -
Molecular Weight 246.48 g/mol (anhydrous) Calculated
Density 3.97 g/cm³ -
Melting Point 817°C -
Solubility Soluble in water; Soluble in mineral acids -
Stability Hygroscopic (absorbs moisture); Stable under normal conditions -
Color White or light yellow -
pH Neutral to slightly acidic (when dissolved in water) -
Hygroscopicity Highly hygroscopic Must be stored in sealed containers

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Rare earth chloride salt; Derived from cerium element; Acts as Lewis acid catalyst in organic synthesis; Hygroscopic
Stability Hygroscopic (absorbs moisture); Stable under normal conditions; Converts to anhydrous form upon heating
Reactivity Reacts readily with acids and moisture; Acts as Lewis acid catalyst in organic synthesis
Incompatible Materials Strong bases, oxidizing agents, moisture
Thermal Decomposition CeCl₃·xH₂O → heat → CeCl₃ + xH₂O (loses water upon heating)
Solubility in Water Soluble in water; Dissociates into Ce³⁺ and Cl⁻ ions
Acid Solubility Soluble in mineral acids
Special Property Lewis acid catalyst for organic synthesis; Glass decolorization; UV blocking

SECTION 4: RARE EARTH CHLORIDES COMPARISON TABLE

Property Cerium Chloride Lanthanum Chloride Neodymium Chloride Explanation
Chemical Formula CeCl₃·xH₂O LaCl₃·xH₂O NdCl₃·xH₂O -
CAS Number 19423-76-8 10099-58-8 10024-93-8 -
Appearance White/light yellow White Pinkish Different colors
Solubility Soluble in water Soluble in water Soluble in water All are water soluble
Hygroscopic High High High All are hygroscopic
Use Catalyst, glass Catalyst Laser, magnetic -
Special Feature UV blocking Catalyst Laser applications -

SECTION 5: CERIUM CHLORIDE GRADES

Grade Purity (%) Form Application Areas
CC-1 ≥ 99.99% Crystalline powder High-purity research, optical applications
CC-2 ≥ 99.9% Crystalline powder Industrial applications, catalyst
CC-3 ≥ 99.5% Crystalline powder Glass production, general use

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Rare Earth Salt Derived from cerium element belonging to the lanthanide series. Consists of cerium ions (Ce³⁺) and chloride ions (Cl⁻).
Catalyst Acts as Lewis acid catalyst in organic synthesis. Used in various organic reactions.
Glass Decolorization In the glass industry, it keeps iron in the ferrous state, decolorizing the glass. Used for decolorization of glass.
UV Blocking Cerium-doped glass blocks ultraviolet light. Used in medical and aerospace glasses.
Polymer Stabilizer Prevents plastics from darkening under sunlight. Acts as UV stabilizer.
Hygroscopic Nature Highly hygroscopic, absorbs moisture from air. Must be stored in closed containers.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Organic Chemistry Catalyst Used as Lewis acid catalyst in various reactions.
Glass Production Decolorization and UV protection Decolorization of glass. Production of special glasses that block UV light (medical and aerospace glasses).
Electronics Color protection Prevents color degradation in television glasses.
Polymer Industry UV stabilizer Prevents plastics from degrading under UV light.
Optics Precision processing Used in precision optical polishing and special glass production.
Research Reagent Used as a reagent in rare earth chemistry studies.

SECTION 8: GLASS INDUSTRY APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Decolorization Iron oxide impurities in glass production cause green color. Cerium chloride keeps iron in the ferrous state, decolorizing the glass.
UV Blocking Cerium-doped glass blocks ultraviolet light. Used in medical and aerospace glasses.
Operating Principle Ce³⁺ ions absorb UV light and convert it to visible light.
Advantages Transparency; UV protection; Color stability; High quality.
Application Areas Eyeglass lenses; Medical glasses; Aerospace glasses; Television glasses.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Specification (CC-1 - ≥99.99%) Test Method
Appearance White/light yellow crystalline powder Visual
Purity (CeCl₃) ≥ 99.99% AAS / ICP / GDMS
Cerium Oxide (Ce₂O₃) ≥ 40.0% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP / GDMS
Calcium (Ca) ≤ 0.001% AAS / ICP / GDMS
Magnesium (Mg) ≤ 0.001% AAS / ICP / GDMS
Silicon (Si) ≤ 0.001% AAS / ICP / GDMS
Aluminum (Al) ≤ 0.001% AAS / ICP / GDMS
Other Rare Earths ≤ 0.01% ICP / GDMS
Chloride Content Matches theoretical value Titration
Water of Hydration Varies with degree TGA
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be irritating
Eye Irritation May be irritating
Chronic Toxicity Rare earth compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Special Toxicity Note Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315 (optional)
Eye Irritation Category 2 H319 (optional)
STOT - SE (Single Exposure) Category 3 H335 (optional)

Note: Generally not classified as hazardous in solid state. Powder form may cause irritation.

Signal Word: WARNING (optional)

Hazard Pictograms: GHS07 (optional)

Hazard Statements (H-Codes) - if classified:

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable
Hazards During Fire May release toxic chloride fumes at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Away from moisture; In closed containers; Keep in original packaging
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong bases, oxidizing agents, moisture
Shelf Life 2-3 years (under proper storage conditions)
Stability Note Highly hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Seryum Klorür, Seryum(III) Klorür, Seröz Klorür
English Names Cerium Chloride, Cerium(III) Chloride, Cerous Chloride
German Names Cerchlorid, Cer(III)-chlorid, Cerouschlorid
French Names Chlorure de Cérium, Chlorure de Cérium(III), Chlorure Céreux
Spanish Names Cloruro de Cerio, Cloruro de Cerio(III), Cloruro Ceroso
Chemical Names Cerium Chloride Hydrate; Cerous Chloride Hydrate
CAS Number 19423-76-8 (hydrate form)
Chemical Formula CeCl₃·xH₂O

SECTION 19: SUMMARY TABLE

Parameter Value
Product Cerium Chloride / Cerium Chloride
CAS Number 19423-76-8 (hydrate form)
Chemical Formula CeCl₃·xH₂O
Molecular Weight 246.48 g/mol (anhydrous)
Appearance White/light yellow crystalline powder
Density 3.97 g/cm³
Melting Point 817°C
Solubility Soluble in water; Soluble in acids
Primary Function Rare earth salt; Catalyst; Glass additive
Main Applications Organic chemistry, glass production, electronics, polymer, optics
Shelf Life 2-3 years
GHS Signal Word WARNING (optional)
UN Number Not regulated
Special Features Highly hygroscopic; Lewis acid catalyst; UV blocking

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Highly hygroscopic (absorbs moisture). Store in closed, airtight containers in dry environment.

  2. Irritant. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.

  3. Loses water upon heating and converts to anhydrous form. May release chloride fumes at high temperatures.

  4. Lewis acid acts as catalyst in organic synthesis. Use under appropriate conditions.

  5. Rare earth compound requires special handling and purity considerations.

  6. Glass and optical applications require high purity (≥99.99%).

  7. Incompatibilities: Strong bases, oxidizing agents, moisture (long-term).

  8. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

9. Organic Chemistry:
Use as Lewis acid catalyst in various reactions. Ensure appropriate reaction conditions.

10. Glass Production:
Use for decolorization of glass and production of special glasses that block UV light. Preferred in medical and aerospace glasses.

11. Electronics:
Use to prevent color degradation in television glasses.

12. Polymer Industry:
Use as UV stabilizer to prevent plastics from degrading under UV light.

13. Optics:
Use in precision optical polishing and special glass production.

14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.

16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers.

18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.

20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical, glass and catalyst applications.

CERIUM CHLORIDE SELECTION GUIDE:

Application Recommended Grade Explanation
Organic synthesis (catalyst) CC-2 (≥99.9%) High purity required
Glass decolorization CC-2 (≥99.9%) High purity required
UV blocking glass CC-1 (≥99.99%) Highest purity required
Optical applications CC-1 (≥99.99%) Highest purity required
Polymer stabilizer CC-2 (≥99.9%) High purity required
Research CC-1 (≥99.99%) or CC-2 (≥99.9%) Depends on application

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area

ENVIRONMENTAL NOTE:

The mining and processing of rare earth elements should be carefully managed from an environmental perspective. Waste and residues should be properly disposed of.

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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