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Send EmailCerium Chloride, Cerous Chloride, 19423-76-8
| Parameter | Information |
|---|---|
| Product Name | Cerium Chloride / Cerium Chloride |
| Other Technical Names | Cerous Chloride, Cerium(III) Chloride |
| CAS Number | 19423-76-8 (hydrate form) |
| Chemical Formula | CeCl₃·xH₂O |
| Molecular Weight | 246.48 g/mol (anhydrous form) |
| Product Family | Rare Earth Chloride Salt |
| Appearance | White crystalline powder or light yellow solid |
Cerium Chloride (CeCl₃·xH₂O)
Cerium Ions (Ce³⁺) and Chloride Ions (Cl⁻)
with Hydrate Molecules
Cl⁻ Ce³⁺ Cl⁻
\ | /
Cl⁻Ce³⁺Cl⁻
/ | \
Cl⁻ Ce³⁺ Cl⁻
Cerium Ions (Ce³⁺) with Chloride Ions (Cl⁻)
Rare Earth Chloride Salt
White/Light Yellow Crystalline Solid
Used as Catalyst and in Glass Industry
Molecular Formula: CeCl₃·xH₂O
Ionic Structure: Ce³⁺ and Cl⁻ ions
Hydrate State: x variable
Oxidation State: +3
Color: White or light yellow
| Parameter | Information |
|---|---|
| Product Name | Cerium Chloride / Cerium Chloride |
| Other Technical Names (English) | Cerium Chloride, Cerium(III) Chloride, Cerous Chloride |
| Other Technical Names (Turkish) | Seryum Klorür, Seryum(III) Klorür, Seröz Klorür |
| Other Technical Names (German) | Cerchlorid, Cer(III)-chlorid, Cerouschlorid |
| Other Technical Names (French) | Chlorure de Cérium, Chlorure de Cérium(III), Chlorure Céreux |
| Other Technical Names (Spanish) | Cloruro de Cerio, Cloruro de Cerio(III), Cloruro Ceroso |
| CAS Number | 19423-76-8 (hydrate form) |
| Chemical Formula | CeCl₃·xH₂O |
| Molecular Weight | 246.48 g/mol (anhydrous form) |
| Chemical Class | Rare Earth Chloride Salt |
| Appearance | White crystalline powder or light yellow solid |
| Odor | Odorless |
| Color | White or light yellow |
| Crystal Structure | Crystalline solid |
| Property | Value | Test Method / Note |
|---|---|---|
| Appearance | White crystalline powder or light yellow solid | Visual |
| Chemical Formula | CeCl₃·xH₂O | - |
| Molecular Weight | 246.48 g/mol (anhydrous) | Calculated |
| Density | 3.97 g/cm³ | - |
| Melting Point | 817°C | - |
| Solubility | Soluble in water; Soluble in mineral acids | - |
| Stability | Hygroscopic (absorbs moisture); Stable under normal conditions | - |
| Color | White or light yellow | - |
| pH | Neutral to slightly acidic (when dissolved in water) | - |
| Hygroscopicity | Highly hygroscopic | Must be stored in sealed containers |
| Parameter | Information |
|---|---|
| Chemical Character | Rare earth chloride salt; Derived from cerium element; Acts as Lewis acid catalyst in organic synthesis; Hygroscopic |
| Stability | Hygroscopic (absorbs moisture); Stable under normal conditions; Converts to anhydrous form upon heating |
| Reactivity | Reacts readily with acids and moisture; Acts as Lewis acid catalyst in organic synthesis |
| Incompatible Materials | Strong bases, oxidizing agents, moisture |
| Thermal Decomposition | CeCl₃·xH₂O → heat → CeCl₃ + xH₂O (loses water upon heating) |
| Solubility in Water | Soluble in water; Dissociates into Ce³⁺ and Cl⁻ ions |
| Acid Solubility | Soluble in mineral acids |
| Special Property | Lewis acid catalyst for organic synthesis; Glass decolorization; UV blocking |
| Property | Cerium Chloride | Lanthanum Chloride | Neodymium Chloride | Explanation |
|---|---|---|---|---|
| Chemical Formula | CeCl₃·xH₂O | LaCl₃·xH₂O | NdCl₃·xH₂O | - |
| CAS Number | 19423-76-8 | 10099-58-8 | 10024-93-8 | - |
| Appearance | White/light yellow | White | Pinkish | Different colors |
| Solubility | Soluble in water | Soluble in water | Soluble in water | All are water soluble |
| Hygroscopic | High | High | High | All are hygroscopic |
| Use | Catalyst, glass | Catalyst | Laser, magnetic | - |
| Special Feature | UV blocking | Catalyst | Laser applications | - |
| Grade | Purity (%) | Form | Application Areas |
|---|---|---|---|
| CC-1 | ≥ 99.99% | Crystalline powder | High-purity research, optical applications |
| CC-2 | ≥ 99.9% | Crystalline powder | Industrial applications, catalyst |
| CC-3 | ≥ 99.5% | Crystalline powder | Glass production, general use |
| Property | Explanation |
|---|---|
| Rare Earth Salt | Derived from cerium element belonging to the lanthanide series. Consists of cerium ions (Ce³⁺) and chloride ions (Cl⁻). |
| Catalyst | Acts as Lewis acid catalyst in organic synthesis. Used in various organic reactions. |
| Glass Decolorization | In the glass industry, it keeps iron in the ferrous state, decolorizing the glass. Used for decolorization of glass. |
| UV Blocking | Cerium-doped glass blocks ultraviolet light. Used in medical and aerospace glasses. |
| Polymer Stabilizer | Prevents plastics from darkening under sunlight. Acts as UV stabilizer. |
| Hygroscopic Nature | Highly hygroscopic, absorbs moisture from air. Must be stored in closed containers. |
| Industry / Application | Function | Typical Use |
|---|---|---|
| Organic Chemistry | Catalyst | Used as Lewis acid catalyst in various reactions. |
| Glass Production | Decolorization and UV protection | Decolorization of glass. Production of special glasses that block UV light (medical and aerospace glasses). |
| Electronics | Color protection | Prevents color degradation in television glasses. |
| Polymer Industry | UV stabilizer | Prevents plastics from degrading under UV light. |
| Optics | Precision processing | Used in precision optical polishing and special glass production. |
| Research | Reagent | Used as a reagent in rare earth chemistry studies. |
| Parameter | Explanation |
|---|---|
| Decolorization | Iron oxide impurities in glass production cause green color. Cerium chloride keeps iron in the ferrous state, decolorizing the glass. |
| UV Blocking | Cerium-doped glass blocks ultraviolet light. Used in medical and aerospace glasses. |
| Operating Principle | Ce³⁺ ions absorb UV light and convert it to visible light. |
| Advantages | Transparency; UV protection; Color stability; High quality. |
| Application Areas | Eyeglass lenses; Medical glasses; Aerospace glasses; Television glasses. |
| Parameter | Specification (CC-1 - ≥99.99%) | Test Method |
|---|---|---|
| Appearance | White/light yellow crystalline powder | Visual |
| Purity (CeCl₃) | ≥ 99.99% | AAS / ICP / GDMS |
| Cerium Oxide (Ce₂O₃) | ≥ 40.0% | AAS / ICP |
| Iron (Fe) | ≤ 0.001% | AAS / ICP / GDMS |
| Calcium (Ca) | ≤ 0.001% | AAS / ICP / GDMS |
| Magnesium (Mg) | ≤ 0.001% | AAS / ICP / GDMS |
| Silicon (Si) | ≤ 0.001% | AAS / ICP / GDMS |
| Aluminum (Al) | ≤ 0.001% | AAS / ICP / GDMS |
| Other Rare Earths | ≤ 0.01% | ICP / GDMS |
| Chloride Content | Matches theoretical value | Titration |
| Water of Hydration | Varies with degree | TGA |
| Form | Crystalline powder | Visual |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity | Low toxicity |
| Acute Inhalation Toxicity | Dust inhalation may cause irritation |
| Skin Irritation | May be irritating |
| Eye Irritation | May be irritating |
| Chronic Toxicity | Rare earth compounds may show health effects with prolonged exposure |
| Carcinogenicity | Not classified as carcinogenic |
| Mutagenicity | Not classified as mutagenic |
| Target Organs | Respiratory system (dust irritation); Skin; Eyes |
| Special Toxicity Note | Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property |
GHS Classification (in compliance with CLP and UN GHS):
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315 (optional) |
| Eye Irritation | Category 2 | H319 (optional) |
| STOT - SE (Single Exposure) | Category 3 | H335 (optional) |
Note: Generally not classified as hazardous in solid state. Powder form may cause irritation.
Signal Word: WARNING (optional)
Hazard Pictograms: GHS07 (optional)
Hazard Statements (H-Codes) - if classified:
| Code | Statement |
|---|---|
| H315 | Causes skin irritation |
| H319 | Causes serious eye irritation |
| H335 | May cause respiratory irritation |
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only outdoors or in a well-ventilated area |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing |
| P312 | Call a POISON CENTER/doctor if you feel unwell |
| P362+P364 | Take off contaminated clothing and wash it before reuse |
| P403+P233 | Store in a well-ventilated place. Keep container tightly closed |
| P501 | Dispose of contents/container in accordance with local/regional/national/international regulations |
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention. |
| Skin Contact | Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention. |
| Eye Contact | Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention. |
| Ingestion | Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. If symptoms develop, get medical attention. |
| Parameter | Information |
|---|---|
| Fire Hazard | Not flammable |
| Hazards During Fire | May release toxic chloride fumes at high temperatures |
| Suitable Extinguishing Media | Dry chemical powder, CO₂, water spray, alcohol-resistant foam |
| Unsuitable Extinguishing Media | Water jet |
| Special Protective Equipment | Self-contained breathing apparatus (SCBA), full protective clothing |
| Special Precautions | Prevent dust from entering sewers and waterways; Do not inhale fumes |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area; Away from moisture; In closed containers; Keep in original packaging |
| Container Requirements | Airtight containers; Tightly closed due to hygroscopic property |
| Materials to Protect From | Strong bases, oxidizing agents, moisture |
| Shelf Life | 2-3 years (under proper storage conditions) |
| Stability Note | Highly hygroscopic; Absorbs moisture; Store in closed containers |
| Packaging Type | Quantity | Material |
|---|---|---|
| Plastic Drum | 25-50 kg | HDPE (airtight) |
| Plastic Bucket | 5-25 kg | HDPE (airtight) |
| Glass Bottle | 100 g - 2 kg | Glass (airtight) |
| Plastic Bag | 1-10 kg | PE (sealed) |
| Flexibag | 100-500 kg | PE lined |
| Parameter | Information |
|---|---|
| UN Number | Not regulated (not dangerous) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG Code | Not regulated |
| IATA (Air) | Not regulated |
| Marine Pollutant | No |
| Transport Temperature | Ambient temperature; Protect from moisture |
| Type | Name |
|---|---|
| Turkish Names | Seryum Klorür, Seryum(III) Klorür, Seröz Klorür |
| English Names | Cerium Chloride, Cerium(III) Chloride, Cerous Chloride |
| German Names | Cerchlorid, Cer(III)-chlorid, Cerouschlorid |
| French Names | Chlorure de Cérium, Chlorure de Cérium(III), Chlorure Céreux |
| Spanish Names | Cloruro de Cerio, Cloruro de Cerio(III), Cloruro Ceroso |
| Chemical Names | Cerium Chloride Hydrate; Cerous Chloride Hydrate |
| CAS Number | 19423-76-8 (hydrate form) |
| Chemical Formula | CeCl₃·xH₂O |
| Parameter | Value |
|---|---|
| Product | Cerium Chloride / Cerium Chloride |
| CAS Number | 19423-76-8 (hydrate form) |
| Chemical Formula | CeCl₃·xH₂O |
| Molecular Weight | 246.48 g/mol (anhydrous) |
| Appearance | White/light yellow crystalline powder |
| Density | 3.97 g/cm³ |
| Melting Point | 817°C |
| Solubility | Soluble in water; Soluble in acids |
| Primary Function | Rare earth salt; Catalyst; Glass additive |
| Main Applications | Organic chemistry, glass production, electronics, polymer, optics |
| Shelf Life | 2-3 years |
| GHS Signal Word | WARNING (optional) |
| UN Number | Not regulated |
| Special Features | Highly hygroscopic; Lewis acid catalyst; UV blocking |
Highly hygroscopic (absorbs moisture). Store in closed, airtight containers in dry environment.
Irritant. May cause irritation to skin, eyes and respiratory tract. Use appropriate protective equipment.
Loses water upon heating and converts to anhydrous form. May release chloride fumes at high temperatures.
Lewis acid acts as catalyst in organic synthesis. Use under appropriate conditions.
Rare earth compound requires special handling and purity considerations.
Glass and optical applications require high purity (≥99.99%).
Incompatibilities: Strong bases, oxidizing agents, moisture (long-term).
Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.
9. Organic Chemistry:
Use as Lewis acid catalyst in various reactions. Ensure appropriate reaction conditions.
10. Glass Production:
Use for decolorization of glass and production of special glasses that block UV light. Preferred in medical and aerospace glasses.
11. Electronics:
Use to prevent color degradation in television glasses.
12. Polymer Industry:
Use as UV stabilizer to prevent plastics from degrading under UV light.
13. Optics:
Use in precision optical polishing and special glass production.
14. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.
15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, protective clothing and NIOSH approved dust mask.
16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.
17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers.
18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.
19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.
20. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for optical, glass and catalyst applications.
| Application | Recommended Grade | Explanation |
|---|---|---|
| Organic synthesis (catalyst) | CC-2 (≥99.9%) | High purity required |
| Glass decolorization | CC-2 (≥99.9%) | High purity required |
| UV blocking glass | CC-1 (≥99.99%) | Highest purity required |
| Optical applications | CC-1 (≥99.99%) | Highest purity required |
| Polymer stabilizer | CC-2 (≥99.9%) | High purity required |
| Research | CC-1 (≥99.99%) or CC-2 (≥99.9%) | Depends on application |
| Parameter | Requirement |
|---|---|
| Storage Temperature | Room temperature (15-25°C) |
| Humidity | <60% relative humidity |
| Container | Airtight containers |
| Location | Cool, dry, well-ventilated area |
The mining and processing of rare earth elements should be carefully managed from an environmental perspective. Waste and residues should be properly disposed of.
The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.