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Send EmailNickel Sulfate, Nickel Sulfate Hexahydrate, Nickel Sulphate Heptahydrate, Nickel Sulphate Anhydrous, 10101‑97‑0, 10101‑98‑1, 7786‑81‑4
| Parameter | Information |
|---|---|
| Product Name | Nickel Sulfate / Nickel Sulfate |
| Other Technical Names | Nickel Sulfate Hexahydrate, Nickel Sulphate Heptahydrate, Nickel Sulphate Anhydrous |
| CAS Numbers | 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous) |
| Chemical Formula | NiSO₄·6H₂O (Hexahydrate); NiSO₄·7H₂O (Heptahydrate); NiSO₄ (Anhydrous) |
| Molecular Weight | 262.84 g/mol (Hexahydrate) |
| EC Number (EINECS) | 232-104-9 |
| Product Family | Nickel Salt / Sulfate Salt |
| Appearance | Green crystals (hydrated); Yellowish (anhydrous) |
Nickel Sulfate Hexahydrate (NiSO₄·6H₂O)
Nickel Ions (Ni²⁺) and Sulfate Ions (SO₄²⁻)
in Hexahydrate Form (with 6 H₂O Molecules)
SO₄²⁻ Ni²⁺ SO₄²⁻
\ | /
SO₄²⁻Ni²⁺SO₄²⁻
/ | \
SO₄²⁻ Ni²⁺ SO₄²⁻
Nickel Ions (Ni²⁺) with Sulfate Ions (SO₄²⁻)
Surrounded by 6 Water Molecules (H₂O)
Nickel Salt
Green Crystalline Solid
Used in Electroplating and Battery Applications
Molecular Formula: NiSO₄·6H₂O
Ionic Structure: Ni²⁺ and SO₄²⁻ ions
Hydrate State: Hexahydrate (6 water molecules)
Color: Green (hydrated); Yellowish (anhydrous)
| Parameter | Information |
|---|---|
| Product Name | Nickel Sulfate / Nickel Sulfate |
| Other Technical Names (English) | Nickel Sulfate Hexahydrate, Nickel(II) Sulfate Hexahydrate, Nickelous Sulfate Hexahydrate, Nickel Sulphate Crystals |
| Other Technical Names (Turkish) | Nikel Sülfat, Nikel(II) Sülfat Hekzahidrat, Nikel Sülfat 6-Hidrat, Yeşil Nikel Sülfat |
| Other Technical Names (German) | Nickelsulfat Hexahydrat, Nickel(II)-sulfat Hexahydrat |
| Other Technical Names (French) | Sulfate de Nickel Hexahydraté, Sulfate de Nickel(II) Hexahydraté |
| Other Technical Names (Spanish) | Sulfato de Níquel Hexahidratado, Sulfato de Níquel(II) Hexahidratado |
| CAS Numbers | 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous) |
| EC Number (EINECS) | 232-104-9 |
| UN Number | 3077 |
| Chemical Formula | NiSO₄·6H₂O (Hexahydrate) |
| Molecular Weight | 262.84 g/mol (Hexahydrate) |
| Chemical Class | Nickel Salt / Sulfate Salt |
| Appearance | Green crystals (hydrated); Yellowish (anhydrous) |
| Odor | Odorless |
| Color | Green (hydrated); Yellowish (anhydrous) |
| Crystal Structure | Crystalline solid |
| Hygroscopic | Slightly hygroscopic (absorbs moisture) |
| Property | Hexahydrate | Heptahydrate | Anhydrous | Note |
|---|---|---|---|---|
| Chemical Formula | NiSO₄·6H₂O | NiSO₄·7H₂O | NiSO₄ | - |
| CAS Number | 10101-97-0 | 10101-98-1 | 7786-81-4 | - |
| Appearance | Green crystals | Green crystals | Yellowish powder | - |
| Molecular Weight | 262.84 g/mol | 280.86 g/mol | 154.76 g/mol | - |
| Density | ~2.07 g/cm³ | ~1.95 g/cm³ | ~3.68 g/cm³ | - |
| Melting Point | 53°C (dehydration) | 53°C (dehydration) | 840°C (decomposes) | - |
| pH (100 g/L, 20°C) | ~4.3-4.7 | ~4.3-4.7 | ~4.3-4.7 | Acidic solution |
| Water Solubility (20°C) | ~625-650 g/L | ~625-650 g/L | ~625-650 g/L | High solubility |
| Hygroscopic | Slight | Slight | High | - |
| Stability | Stable | Stable | Stable | - |
| Parameter | Information |
|---|---|
| Chemical Character | Nickel salt; Sulfate salt; Primary raw material for electroplating and battery applications |
| Stability | Stable under normal conditions; Loses water upon heating; Decomposes at high temperatures |
| Reactivity | Soluble in water; Reacts with acids; Reacts with bases to form nickel hydroxide |
| Incompatible Materials | Strong bases, oxidizing agents, reducing agents, organic materials |
| Thermal Decomposition | NiSO₄·6H₂O → heat → NiSO₄ + 6H₂O (loses water upon heating) |
| Thermal Decomposition (High) | NiSO₄ → heat → NiO + SO₃ (decomposes at high temperature) |
| Solubility in Water | High solubility in water; Dissociates into Ni²⁺ and SO₄²⁻ ions |
| Special Property | Main nickel source in electroplating baths; Used in battery cathode material production |
| Type | Chemical Formula | CAS Number | Explanation |
|---|---|---|---|
| Nickel Sulfate Hexahydrate | NiSO₄·6H₂O | 10101-97-0 | Most common commercial form; Electroplating standard |
| Nickel Sulfate Heptahydrate | NiSO₄·7H₂O | 10101-98-1 | Less common; Some older processes |
| Nickel Sulfate Anhydrous | NiSO₄ | 7786-81-4 | Dried at high temperature; Special synthesis |
| Nickel Sulfamate | Ni(SO₃NH₂)₂ | 13770-89-3 | Derived from nickel sulfate; Sulfamate plating |
| Nickel Sulfate Solution | Aqueous solution | CAS not assigned | Mixture; Liquid form |
| Grade | Purity | Ni Content | Application Areas |
|---|---|---|---|
| Electroplating Grade | ≥ 98% | ~22% | Electroplating baths, bright nickel plating |
| Battery Grade | ≥ 99% | ~22% | NMC (Nickel-Manganese-Cobalt) cathode production |
| Technical Grade | ≥ 97% | ~21% | General chemical production |
| High Purity / Analytical Grade | ≥ 99.5% | ~22.5% | Laboratory, precision applications |
| Property | Explanation |
|---|---|
| Electroplating | Main nickel source in acid sulfate nickel baths. Widely used in bright, pre-sulfamate underlayers. |
| Nickel Source | Can play a role in pre-treatment chemicals for surfaces to be nickel-plated. |
| Chemical Synthesis | Starting material for production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.). |
| Battery Production | Critical raw material in NMC (Nickel-Manganese-Cobalt) cathode material production for lithium-ion batteries. |
| Laboratory Reagent | Standard source salt for nickel salts. Used in analytical chemistry and research. |
| Hygroscopic Property | Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers. |
| Industry / Application | Function | Typical Use |
|---|---|---|
| Electroplating | Nickel plating | Main nickel source in acid sulfate nickel baths. Bright, pre-sulfamate underlayers. |
| Metal Surface Treatment | Pre-treatment | Plays a role in pre-treatment chemicals for nickel-plated surfaces. |
| Battery Production | Cathode material | Critical raw material in NMC (Nickel-Manganese-Cobalt) cathode production. Li-ion battery sector. |
| Chemical Synthesis | Starting material | Production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.). |
| Laboratory | Reagent | Standard source salt for nickel salts. Analytical chemistry and research. |
| Automotive | Electronics and plating | Nickel plating on automotive parts, electronic components. |
| Parameter | Explanation |
|---|---|
| Bath Composition | Nickel sulfate (main salt), nickel chloride (for anode dissolution), boric acid (buffer) |
| Operating Principle | Ni²⁺ ions are reduced at the cathode to form nickel metal plating |
| Advantages | Bright plating; Good corrosion resistance; High wear resistance; Easy processability |
| Application Areas | Automotive parts; Decorative plating; Electronic components; Industrial equipment |
| Parameter | Specification | Test Method |
|---|---|---|
| Appearance | Green crystals | Visual |
| Ni Content | ~22% | AAS / ICP |
| Nickel Sulfate (NiSO₄·6H₂O) | ≥ 98% | AAS / ICP |
| Cobalt (Co) | ≤ 0.01% | AAS / ICP |
| Iron (Fe) | ≤ 0.001% | AAS / ICP |
| Copper (Cu) | ≤ 0.001% | AAS / ICP |
| Zinc (Zn) | ≤ 0.001% | AAS / ICP |
| Lead (Pb) | ≤ 0.001% (N.D.) | AAS / ICP |
| Calcium (Ca) | ≤ 0.01% | AAS / ICP |
| Magnesium (Mg) | ≤ 0.01% | AAS / ICP |
| Sodium (Na) | ≤ 0.02% | AAS / ICP |
| Chloride (Cl⁻) | ≤ 0.005% | Ion Chromatography |
| Insoluble Matter | ≤ 0.01% | Gravimetric |
| pH (100 g/L, 20°C) | 4.3-4.7 | pH Meter |
| Form | Crystalline powder | Visual |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity | Toxic (LD50: ~375 mg/kg) |
| Acute Inhalation Toxicity | Dust inhalation poses serious health risks |
| Skin Irritation | Sensitizer; May cause allergic reactions |
| Eye Irritation | Irritant |
| Chronic Toxicity | Carcinogenic (Category 1A/1B); Respiratory sensitizer; Skin sensitizer |
| Carcinogenicity | Classified as carcinogenic (Nickel compounds) |
| Mutagenicity | Not classified as mutagenic |
| Target Organs | Respiratory system (lungs); Skin; Eyes |
| Occupational Exposure Limit (ACGIH TWA) | 0.1 mg/m³ (nickel compounds) |
| NIOSH IDLH | 10 mg/m³ |
| Special Toxicity Note | Nickel salts may show carcinogenic effects when inhaled; Skin sensitizer; Appropriate protective equipment and ventilation are essential |
GHS Classification (in compliance with CLP and UN GHS):
| Hazard Class | Category | H-Statement |
|---|---|---|
| Carcinogenicity | Category 1A/1B | H350 |
| Respiratory Sensitizer | Category 1 | H334 |
| Skin Sensitizer | Category 1 | H317 |
| Acute Toxicity (Inhalation) | Category 4 | H332 |
| Chronic Aquatic Toxicity | Category 1/2 | H410/H411 |
Signal Word: DANGER
Hazard Pictograms: GHS08 (Health hazard), GHS09 (Environment)
Hazard Statements (H-Codes):
| Code | Statement |
|---|---|
| H350 | May cause cancer (by inhalation) |
| H334 | May cause allergic or asthmatic symptoms or breathing difficulties if inhaled |
| H317 | May cause allergic skin reaction |
| H332 | Harmful if inhaled |
| H410 | Very toxic to aquatic life with long lasting effects |
| Code | Statement |
|---|---|
| P201 | Obtain special instructions before use |
| P202 | Do not handle until all safety precautions have been read and understood |
| P260 | Do not breathe dust/fume/gas/mist/vapors/spray |
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only outdoors or in a well-ventilated area |
| P272 | Contaminated work clothing should not be allowed out of the workplace |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing |
| P308+P313 | IF exposed or concerned: Get medical advice/attention |
| P333+P313 | If skin irritation or rash occurs: Get medical advice/attention |
| P342+P311 | If experiencing respiratory symptoms: Call a POISON CENTER/doctor |
| P362+P364 | Take off contaminated clothing and wash it before reuse |
| P403+P233 | Store in a well-ventilated place. Keep container tightly closed |
| P501 | Dispose of contents/container in accordance with local/regional/national/international regulations |
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. If symptoms develop, get medical attention. |
| Skin Contact | Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation or rash occurs, get medical advice/attention. |
| Eye Contact | Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention. |
| Ingestion | Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek immediate medical attention. |
| Parameter | Information |
|---|---|
| Fire Hazard | Not flammable. May release toxic fumes at high temperatures. |
| Hazards During Fire | May release toxic nickel oxide and sulfur oxide fumes at high temperatures |
| Suitable Extinguishing Media | Dry chemical powder, CO₂, water spray, alcohol-resistant foam |
| Unsuitable Extinguishing Media | Water jet |
| Special Protective Equipment | Self-contained breathing apparatus (SCBA), full protective clothing |
| Special Precautions | Prevent dust from entering sewers and waterways; Do not inhale fumes |
| Parameter | Information |
|---|---|
| Storage Conditions | Between +5°C and +30°C, dry, well-ventilated area; Away from direct sunlight; Away from moisture; In closed containers |
| Container Requirements | Airtight containers; Tightly closed due to hygroscopic property |
| Materials to Protect From | Strong bases, oxidizing agents, moisture, heat |
| Shelf Life | 1-2 years (under proper storage conditions) |
| Stability Note | Slightly hygroscopic; Absorbs moisture; Store in closed containers |
| Packaging Type | Quantity | Material |
|---|---|---|
| Kraft Sack (PE inner) | 25 kg | PE inner + outer kraft sack |
| HDPE Bag | 25 kg | HDPE (airtight) |
| Plastic Drum | 25-50 kg | HDPE (airtight) |
| Plastic Bucket | 5-25 kg | HDPE (airtight) |
| Bigbag | 500-1000 kg | PE lined woven polypropylene |
| Flexibag | 100-500 kg | PE lined |
| Parameter | Information |
|---|---|
| UN Number | 3077 (Environmentally hazardous substance, solid, n.o.s.) |
| Hazard Class | 9 (Environmentally hazardous substances) |
| Packing Group | III |
| ADR/RID | 9, PG III |
| IMDG Code | 9, PG III |
| IATA (Air) | 9, PG III |
| Marine Pollutant | Yes |
| Transport Temperature | Ambient temperature; Protect from moisture; Closed packaging to prevent dust dispersion |
| Type | Name |
|---|---|
| Turkish Names | Nikel Sülfat, Nikel(II) Sülfat Hekzahidrat, Nikel Sülfat 6-Hidrat, Yeşil Nikel Sülfat |
| English Names | Nickel Sulfate, Nickel(II) Sulfate Hexahydrate, Nickelous Sulfate Hexahydrate, Nickel Sulphate Crystals |
| German Names | Nickelsulfat Hexahydrat, Nickel(II)-sulfat Hexahydrat |
| French Names | Sulfate de Nickel Hexahydraté, Sulfate de Nickel(II) Hexahydraté |
| Spanish Names | Sulfato de Níquel Hexahidratado, Sulfato de Níquel(II) Hexahidratado |
| Chemical Names | Sulfuric acid, nickel(2+) salt, hexahydrate; Nickel sulfate (1:1), hexahydrate |
| CAS Numbers | 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous) |
| EC Number | 232-104-9 |
| UN Number | 3077 |
| Abbreviations | NSH, NiSO₄·6H₂O, Ni Sulphate Hexa |
| Parameter | Hexahydrate | Heptahydrate | Anhydrous |
|---|---|---|---|
| Product | Nickel Sulfate Hexahydrate | Nickel Sulfate Heptahydrate | Nickel Sulfate Anhydrous |
| CAS Number | 10101-97-0 | 10101-98-1 | 7786-81-4 |
| Chemical Formula | NiSO₄·6H₂O | NiSO₄·7H₂O | NiSO₄ |
| Molecular Weight | 262.84 g/mol | 280.86 g/mol | 154.76 g/mol |
| Appearance | Green crystals | Green crystals | Yellowish powder |
| Density | ~2.07 g/cm³ | ~1.95 g/cm³ | ~3.68 g/cm³ |
| Melting Point | 53°C (dehydration) | 53°C (dehydration) | 840°C (decomposes) |
| Common Use | Most common form | Less common | Special synthesis |
Carcinogenic. May cause cancer by inhalation. Avoid breathing dust at all costs.
Sensitizer. May cause allergic skin reactions and respiratory sensitivity.
Very toxic to aquatic life. Must not be discharged uncontrolled into wastewater.
Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.
Heavy metal salt. Wastewater treatment and heavy metal removal are critical.
Subject to strict regulations under REACH and RoHS.
Metal impurities such as cobalt, iron, copper, zinc, lead affect plating quality.
Incompatibilities: Strong bases, oxidizing agents, reducing agents, organic materials.
Hygiene Requirement: Wash hands thoroughly after use. Do not take contaminated work clothes home.
10. Electroplating:
Use as main nickel source in acid sulfate nickel baths. Provide optimized bath parameters for bright nickel plating.
11. Battery Production:
Use battery grade nickel sulfate for NMC (Nickel-Manganese-Cobalt) cathode material production. Comply with strict metal impurity limits.
12. Chemical Synthesis:
Use as starting material for production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.).
13. Laboratory:
Use as standard source salt for nickel salts. Preferred in analytical chemistry and research.
14. Use:
Use in well-ventilated areas; Avoid dust formation; Use local exhaust ventilation; Prefer closed systems.
15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, full face shield, protective clothing and NIOSH approved respiratory protection.
16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.
17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers; Protect from direct sunlight.
18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.
19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for heavy metal waste.
20. Environmental Precautions:
Must not be discharged uncontrolled into wastewater. Wastewater treatment and heavy metal removal are essential.
| Application | Recommended Form | Explanation |
|---|---|---|
| Electroplating | Hexahydrate (Electroplating Grade) | Most common use |
| Battery production | Hexahydrate (Battery Grade) | Strict metal impurity limits |
| Chemical synthesis | Hexahydrate or Anhydrous | Depends on application |
| High temperature | Anhydrous | Water-free processes |
| Laboratory | Hexahydrate (Analytical Grade) | High purity |
| Parameter | Requirement |
|---|---|
| Storage Temperature | Between +5°C and +30°C |
| Humidity | <60% relative humidity |
| Container | Airtight containers |
| Location | Dry, well-ventilated area; Away from direct sunlight |
Nickel sulfate is a heavy metal salt. Must not be discharged uncontrolled into wastewater. Wastewater treatment and heavy metal removal should be provided. Nickel ions are toxic to aquatic organisms.
The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.