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Nickel Sulfate, Nickel Sulfate Hexahydrate, Nickel Sulphate Heptahydrate, Nickel Sulphate Anhydrous, 10101‑97‑0, 10101‑98‑1, 7786‑81‑4

Nickel Sulfate, Nickel Sulfate Hexahydrate, Nickel Sulphate Heptahydrate, Nickel Sulphate Anhydrous, 10101‑97‑0, 10101‑98‑1, 7786‑81‑4

NICKEL SULFATE (NICKEL SULFATE / NICKEL SULFATE HEXAHYDRATE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Nickel Sulfate / Nickel Sulfate
Other Technical Names Nickel Sulfate Hexahydrate, Nickel Sulphate Heptahydrate, Nickel Sulphate Anhydrous
CAS Numbers 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous)
Chemical Formula NiSO₄·6H₂O (Hexahydrate); NiSO₄·7H₂O (Heptahydrate); NiSO₄ (Anhydrous)
Molecular Weight 262.84 g/mol (Hexahydrate)
EC Number (EINECS) 232-104-9
Product Family Nickel Salt / Sulfate Salt
Appearance Green crystals (hydrated); Yellowish (anhydrous)

CHEMICAL STRUCTURE

    Nickel Sulfate Hexahydrate (NiSO₄·6H₂O)
    
    Nickel Ions (Ni²⁺) and Sulfate Ions (SO₄²⁻)
    in Hexahydrate Form (with 6 H₂O Molecules)
    
         SO₄²⁻  Ni²⁺  SO₄²⁻
           \      |     /
            SO₄²⁻Ni²⁺SO₄²⁻
           /      |     \
         SO₄²⁻  Ni²⁺  SO₄²⁻
    
    Nickel Ions (Ni²⁺) with Sulfate Ions (SO₄²⁻)
    Surrounded by 6 Water Molecules (H₂O)
    Nickel Salt
    Green Crystalline Solid
    Used in Electroplating and Battery Applications

Molecular Formula: NiSO₄·6H₂O
Ionic Structure: Ni²⁺ and SO₄²⁻ ions
Hydrate State: Hexahydrate (6 water molecules)
Color: Green (hydrated); Yellowish (anhydrous)

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Nickel Sulfate / Nickel Sulfate
Other Technical Names (English) Nickel Sulfate Hexahydrate, Nickel(II) Sulfate Hexahydrate, Nickelous Sulfate Hexahydrate, Nickel Sulphate Crystals
Other Technical Names (Turkish) Nikel Sülfat, Nikel(II) Sülfat Hekzahidrat, Nikel Sülfat 6-Hidrat, Yeşil Nikel Sülfat
Other Technical Names (German) Nickelsulfat Hexahydrat, Nickel(II)-sulfat Hexahydrat
Other Technical Names (French) Sulfate de Nickel Hexahydraté, Sulfate de Nickel(II) Hexahydraté
Other Technical Names (Spanish) Sulfato de Níquel Hexahidratado, Sulfato de Níquel(II) Hexahidratado
CAS Numbers 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous)
EC Number (EINECS) 232-104-9
UN Number 3077
Chemical Formula NiSO₄·6H₂O (Hexahydrate)
Molecular Weight 262.84 g/mol (Hexahydrate)
Chemical Class Nickel Salt / Sulfate Salt
Appearance Green crystals (hydrated); Yellowish (anhydrous)
Odor Odorless
Color Green (hydrated); Yellowish (anhydrous)
Crystal Structure Crystalline solid
Hygroscopic Slightly hygroscopic (absorbs moisture)

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Hexahydrate Heptahydrate Anhydrous Note
Chemical Formula NiSO₄·6H₂O NiSO₄·7H₂O NiSO₄ -
CAS Number 10101-97-0 10101-98-1 7786-81-4 -
Appearance Green crystals Green crystals Yellowish powder -
Molecular Weight 262.84 g/mol 280.86 g/mol 154.76 g/mol -
Density ~2.07 g/cm³ ~1.95 g/cm³ ~3.68 g/cm³ -
Melting Point 53°C (dehydration) 53°C (dehydration) 840°C (decomposes) -
pH (100 g/L, 20°C) ~4.3-4.7 ~4.3-4.7 ~4.3-4.7 Acidic solution
Water Solubility (20°C) ~625-650 g/L ~625-650 g/L ~625-650 g/L High solubility
Hygroscopic Slight Slight High -
Stability Stable Stable Stable -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Nickel salt; Sulfate salt; Primary raw material for electroplating and battery applications
Stability Stable under normal conditions; Loses water upon heating; Decomposes at high temperatures
Reactivity Soluble in water; Reacts with acids; Reacts with bases to form nickel hydroxide
Incompatible Materials Strong bases, oxidizing agents, reducing agents, organic materials
Thermal Decomposition NiSO₄·6H₂O → heat → NiSO₄ + 6H₂O (loses water upon heating)
Thermal Decomposition (High) NiSO₄ → heat → NiO + SO₃ (decomposes at high temperature)
Solubility in Water High solubility in water; Dissociates into Ni²⁺ and SO₄²⁻ ions
Special Property Main nickel source in electroplating baths; Used in battery cathode material production

SECTION 4: NICKEL SULFATE TYPES AND CAS NUMBERS

Type Chemical Formula CAS Number Explanation
Nickel Sulfate Hexahydrate NiSO₄·6H₂O 10101-97-0 Most common commercial form; Electroplating standard
Nickel Sulfate Heptahydrate NiSO₄·7H₂O 10101-98-1 Less common; Some older processes
Nickel Sulfate Anhydrous NiSO₄ 7786-81-4 Dried at high temperature; Special synthesis
Nickel Sulfamate Ni(SO₃NH₂)₂ 13770-89-3 Derived from nickel sulfate; Sulfamate plating
Nickel Sulfate Solution Aqueous solution CAS not assigned Mixture; Liquid form

SECTION 5: NICKEL SULFATE GRADES

Grade Purity Ni Content Application Areas
Electroplating Grade ≥ 98% ~22% Electroplating baths, bright nickel plating
Battery Grade ≥ 99% ~22% NMC (Nickel-Manganese-Cobalt) cathode production
Technical Grade ≥ 97% ~21% General chemical production
High Purity / Analytical Grade ≥ 99.5% ~22.5% Laboratory, precision applications

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Electroplating Main nickel source in acid sulfate nickel baths. Widely used in bright, pre-sulfamate underlayers.
Nickel Source Can play a role in pre-treatment chemicals for surfaces to be nickel-plated.
Chemical Synthesis Starting material for production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.).
Battery Production Critical raw material in NMC (Nickel-Manganese-Cobalt) cathode material production for lithium-ion batteries.
Laboratory Reagent Standard source salt for nickel salts. Used in analytical chemistry and research.
Hygroscopic Property Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Electroplating Nickel plating Main nickel source in acid sulfate nickel baths. Bright, pre-sulfamate underlayers.
Metal Surface Treatment Pre-treatment Plays a role in pre-treatment chemicals for nickel-plated surfaces.
Battery Production Cathode material Critical raw material in NMC (Nickel-Manganese-Cobalt) cathode production. Li-ion battery sector.
Chemical Synthesis Starting material Production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.).
Laboratory Reagent Standard source salt for nickel salts. Analytical chemistry and research.
Automotive Electronics and plating Nickel plating on automotive parts, electronic components.

SECTION 8: ELECTROPLATING APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Bath Composition Nickel sulfate (main salt), nickel chloride (for anode dissolution), boric acid (buffer)
Operating Principle Ni²⁺ ions are reduced at the cathode to form nickel metal plating
Advantages Bright plating; Good corrosion resistance; High wear resistance; Easy processability
Application Areas Automotive parts; Decorative plating; Electronic components; Industrial equipment

SECTION 9: QUALITY SPECIFICATIONS (ELECTROPLATING GRADE)

Parameter Specification Test Method
Appearance Green crystals Visual
Ni Content ~22% AAS / ICP
Nickel Sulfate (NiSO₄·6H₂O) ≥ 98% AAS / ICP
Cobalt (Co) ≤ 0.01% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP
Copper (Cu) ≤ 0.001% AAS / ICP
Zinc (Zn) ≤ 0.001% AAS / ICP
Lead (Pb) ≤ 0.001% (N.D.) AAS / ICP
Calcium (Ca) ≤ 0.01% AAS / ICP
Magnesium (Mg) ≤ 0.01% AAS / ICP
Sodium (Na) ≤ 0.02% AAS / ICP
Chloride (Cl⁻) ≤ 0.005% Ion Chromatography
Insoluble Matter ≤ 0.01% Gravimetric
pH (100 g/L, 20°C) 4.3-4.7 pH Meter
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Toxic (LD50: ~375 mg/kg)
Acute Inhalation Toxicity Dust inhalation poses serious health risks
Skin Irritation Sensitizer; May cause allergic reactions
Eye Irritation Irritant
Chronic Toxicity Carcinogenic (Category 1A/1B); Respiratory sensitizer; Skin sensitizer
Carcinogenicity Classified as carcinogenic (Nickel compounds)
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (lungs); Skin; Eyes
Occupational Exposure Limit (ACGIH TWA) 0.1 mg/m³ (nickel compounds)
NIOSH IDLH 10 mg/m³
Special Toxicity Note Nickel salts may show carcinogenic effects when inhaled; Skin sensitizer; Appropriate protective equipment and ventilation are essential

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Carcinogenicity Category 1A/1B H350
Respiratory Sensitizer Category 1 H334
Skin Sensitizer Category 1 H317
Acute Toxicity (Inhalation) Category 4 H332
Chronic Aquatic Toxicity Category 1/2 H410/H411

Signal Word: DANGER

Hazard Pictograms: GHS08 (Health hazard), GHS09 (Environment)

Hazard Statements (H-Codes):

Code Statement
H350 May cause cancer (by inhalation)
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
H317 May cause allergic skin reaction
H332 Harmful if inhaled
H410 Very toxic to aquatic life with long lasting effects

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P308+P313 IF exposed or concerned: Get medical advice/attention
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. If symptoms develop, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation or rash occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek immediate medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable. May release toxic fumes at high temperatures.
Hazards During Fire May release toxic nickel oxide and sulfur oxide fumes at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Between +5°C and +30°C, dry, well-ventilated area; Away from direct sunlight; Away from moisture; In closed containers
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong bases, oxidizing agents, moisture, heat
Shelf Life 1-2 years (under proper storage conditions)
Stability Note Slightly hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Kraft Sack (PE inner) 25 kg PE inner + outer kraft sack
HDPE Bag 25 kg HDPE (airtight)
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Bigbag 500-1000 kg PE lined woven polypropylene
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number 3077 (Environmentally hazardous substance, solid, n.o.s.)
Hazard Class 9 (Environmentally hazardous substances)
Packing Group III
ADR/RID 9, PG III
IMDG Code 9, PG III
IATA (Air) 9, PG III
Marine Pollutant Yes
Transport Temperature Ambient temperature; Protect from moisture; Closed packaging to prevent dust dispersion

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Nikel Sülfat, Nikel(II) Sülfat Hekzahidrat, Nikel Sülfat 6-Hidrat, Yeşil Nikel Sülfat
English Names Nickel Sulfate, Nickel(II) Sulfate Hexahydrate, Nickelous Sulfate Hexahydrate, Nickel Sulphate Crystals
German Names Nickelsulfat Hexahydrat, Nickel(II)-sulfat Hexahydrat
French Names Sulfate de Nickel Hexahydraté, Sulfate de Nickel(II) Hexahydraté
Spanish Names Sulfato de Níquel Hexahidratado, Sulfato de Níquel(II) Hexahidratado
Chemical Names Sulfuric acid, nickel(2+) salt, hexahydrate; Nickel sulfate (1:1), hexahydrate
CAS Numbers 10101-97-0 (Hexahydrate); 10101-98-1 (Heptahydrate); 7786-81-4 (Anhydrous)
EC Number 232-104-9
UN Number 3077
Abbreviations NSH, NiSO₄·6H₂O, Ni Sulphate Hexa

SECTION 19: SUMMARY TABLE

Parameter Hexahydrate Heptahydrate Anhydrous
Product Nickel Sulfate Hexahydrate Nickel Sulfate Heptahydrate Nickel Sulfate Anhydrous
CAS Number 10101-97-0 10101-98-1 7786-81-4
Chemical Formula NiSO₄·6H₂O NiSO₄·7H₂O NiSO₄
Molecular Weight 262.84 g/mol 280.86 g/mol 154.76 g/mol
Appearance Green crystals Green crystals Yellowish powder
Density ~2.07 g/cm³ ~1.95 g/cm³ ~3.68 g/cm³
Melting Point 53°C (dehydration) 53°C (dehydration) 840°C (decomposes)
Common Use Most common form Less common Special synthesis

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. Carcinogenic. May cause cancer by inhalation. Avoid breathing dust at all costs.

  2. Sensitizer. May cause allergic skin reactions and respiratory sensitivity.

  3. Very toxic to aquatic life. Must not be discharged uncontrolled into wastewater.

  4. Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  5. Heavy metal salt. Wastewater treatment and heavy metal removal are critical.

  6. Subject to strict regulations under REACH and RoHS.

  7. Metal impurities such as cobalt, iron, copper, zinc, lead affect plating quality.

  8. Incompatibilities: Strong bases, oxidizing agents, reducing agents, organic materials.

  9. Hygiene Requirement: Wash hands thoroughly after use. Do not take contaminated work clothes home.

BEST PRACTICE RECOMMENDATIONS:

10. Electroplating:
Use as main nickel source in acid sulfate nickel baths. Provide optimized bath parameters for bright nickel plating.

11. Battery Production:
Use battery grade nickel sulfate for NMC (Nickel-Manganese-Cobalt) cathode material production. Comply with strict metal impurity limits.

12. Chemical Synthesis:
Use as starting material for production of other nickel compounds (nickel oxide, nickel hydroxide, nickel acetate, etc.).

13. Laboratory:
Use as standard source salt for nickel salts. Preferred in analytical chemistry and research.

14. Use:
Use in well-ventilated areas; Avoid dust formation; Use local exhaust ventilation; Prefer closed systems.

15. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, full face shield, protective clothing and NIOSH approved respiratory protection.

16. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

17. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture; Store in closed, airtight containers; Protect from direct sunlight.

18. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

19. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for heavy metal waste.

20. Environmental Precautions:
Must not be discharged uncontrolled into wastewater. Wastewater treatment and heavy metal removal are essential.

NICKEL SULFATE SELECTION GUIDE:

Application Recommended Form Explanation
Electroplating Hexahydrate (Electroplating Grade) Most common use
Battery production Hexahydrate (Battery Grade) Strict metal impurity limits
Chemical synthesis Hexahydrate or Anhydrous Depends on application
High temperature Anhydrous Water-free processes
Laboratory Hexahydrate (Analytical Grade) High purity

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Between +5°C and +30°C
Humidity <60% relative humidity
Container Airtight containers
Location Dry, well-ventilated area; Away from direct sunlight

ENVIRONMENTAL NOTE:

Nickel sulfate is a heavy metal salt. Must not be discharged uncontrolled into wastewater. Wastewater treatment and heavy metal removal should be provided. Nickel ions are toxic to aquatic organisms.

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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