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Send EmailGadolinium Acetate, Gadolinium Acetate Tetrahydrate, Gadolinium Acetate Hydrate, Gadolinium Acetate Anhydrous, 100587‑93‑7, 31298-16-5, 15280-53-2
| Parameter | Information |
|---|---|
| Product Name | Gadolinium Acetate / Gadolinium Acetate |
| Other Technical Names | Gadolinium Acetate Tetrahydrate, Gadolinium Acetate Hydrate, Gadolinium Acetate Anhydrous |
| CAS Numbers | 31298-16-5 (Anhydrous); 15280-53-2 (Tetrahydrate); 100587-93-7 (Hydrate Variant) |
| Chemical Formula | Gd(C₂H₃O₂)₃·4H₂O (Tetrahydrate); Gd(CH₃COO)₃ (Anhydrous) |
| Molecular Weight | ~352.37 g/mol (Tetrahydrate); ~370.53 g/mol (Anhydrous) |
| EC Number (EINECS) | 240-204-9 |
| Product Family | Rare Earth Acetate Salt |
| Appearance | White crystalline solid (Tetrahydrate); White powder (Anhydrous) |
Gadolinium Acetate Tetrahydrate [Gd(C₂H₃O₂)₃·4H₂O]
Gadolinium Ions (Gd³⁺) and Acetate Ions (C₂H₃O₂⁻)
in Tetrahydrate Form (with 4 H₂O Molecules)
C₂H₃O₂⁻ Gd³⁺ C₂H₃O₂⁻
\ | /
C₂H₃O₂⁻-Gd³⁺-C₂H₃O₂⁻
/ | \
C₂H₃O₂⁻ Gd³⁺ C₂H₃O₂⁻
Gadolinium Ions (Gd³⁺) with Acetate Ions (C₂H₃O₂⁻)
Surrounded by 4 Water Molecules (H₂O)
Rare Earth Acetate Salt
White Crystalline Solid
Used in Catalyst and Optical Applications
Molecular Formula: Gd(C₂H₃O₂)₃·4H₂O (Tetrahydrate)
Ionic Structure: Gd³⁺ and C₂H₃O₂⁻ ions
Hydrate State: Tetrahydrate (4 water molecules) or Anhydrous
Color: White
| Parameter | Information |
|---|---|
| Product Name | Gadolinium Acetate / Gadolinium Acetate |
| Other Technical Names (English) | Gadolinium Acetate Tetrahydrate, Gadolinium Acetate Hydrate, Gadolinium Acetate Anhydrous |
| Other Technical Names (Turkish) | Gadolinyum Asetat, Gadolinyum Asetat Tetrahydrat, Gadolinyum Asetat Hidrat, Gadolinyum Asetat Susuz |
| Other Technical Names (German) | Gadoliniumacetat, Gadoliniumacetat Tetrahydrat, Gadoliniumacetat Hydrat |
| Other Technical Names (French) | Acétate de Gadolinium, Acétate de Gadolinium Tétrahydraté, Acétate de Gadolinium Hydraté |
| Other Technical Names (Spanish) | Acetato de Gadolinio, Acetato de Gadolinio Tetrahidratado, Acetato de Gadolinio Hidratado |
| CAS Numbers | 31298-16-5 (Anhydrous); 15280-53-2 (Tetrahydrate); 100587-93-7 (Hydrate Variant) |
| EC Number (EINECS) | 240-204-9 |
| Chemical Formula | Gd(C₂H₃O₂)₃·4H₂O (Tetrahydrate); Gd(CH₃COO)₃ (Anhydrous) |
| Molecular Weight | ~352.37 g/mol (Tetrahydrate); ~370.53 g/mol (Anhydrous) |
| Chemical Class | Rare Earth Acetate Salt |
| Appearance | White crystalline solid (Tetrahydrate); White powder (Anhydrous) |
| Odor | Slight acetic acid odor |
| Color | White |
| Crystal Structure | Crystalline solid |
| Property | Tetrahydrate | Anhydrous | Note |
|---|---|---|---|
| Chemical Formula | Gd(C₂H₃O₂)₃·4H₂O | Gd(CH₃COO)₃ | - |
| CAS Number | 15280-53-2 | 31298-16-5 | - |
| Appearance | White crystalline solid | White powder | - |
| Molecular Weight | ~352.37 g/mol | ~370.53 g/mol | - |
| Density | ~2.5-2.7 g/cm³ | ~2.5-2.7 g/cm³ | - |
| Melting Point | Decomposes upon heating | Decomposes upon heating | - |
| Solubility | Soluble in water; Soluble in acetic acid | Soluble in water; Soluble in acetic acid | - |
| Hygroscopic | Slightly hygroscopic | Slightly hygroscopic | Absorbs moisture |
| pH | Neutral to slightly acidic | Neutral to slightly acidic | - |
| Stability | Stable under normal conditions | Stable under normal conditions | - |
| Parameter | Information |
|---|---|
| Chemical Character | Rare earth acetate salt; Derived from gadolinium element; MRI contrast agent; Catalyst; Optical materials |
| Stability | Stable under normal conditions; Protect from moisture and light; Decomposes at high temperatures |
| Reactivity | Soluble in water; Soluble in acetic acid; Reacts with strong bases and reducing agents |
| Incompatible Materials | Strong bases, reducing agents, oxidizing agents, moisture |
| Thermal Decomposition | Gd(C₂H₃O₂)₃·4H₂O → heat → Gd₂O₃ + CO₂ + H₂O (decomposes upon heating) |
| Solubility in Water | Soluble in water; Dissociates into Gd³⁺ and C₂H₃O₂⁻ ions |
| Acid Solubility | Soluble in acetic acid |
| Special Property | Precursor for gadolinium oxide and other gadolinium compounds; MRI contrast agents; Catalysts; Optical materials |
| Type | Chemical Formula | CAS Number | Explanation |
|---|---|---|---|
| Anhydrous | Gd(CH₃COO)₃ | 31298-16-5 | Anhydrous form; Special synthesis in laboratories |
| Tetrahydrate | Gd(C₂H₃O₂)₃·4H₂O | 15280-53-2 | Most common commercial form; White crystalline structure |
| Hydrate Variant | Gd(C₂H₃O₂)₃·xH₂O | 100587-93-7 | Hydrated form; Sold as "trace metals basis" |
| Grade | Purity (%) | Form | Application Areas |
|---|---|---|---|
| GA-1 | ≥ 99.99% | Crystalline powder | High-purity research, optical materials, MRI contrast |
| GA-2 | ≥ 99.9% | Crystalline powder | Catalyst, ceramics, glass |
| GA-3 | ≥ 99.5% | Crystalline powder | Industrial applications, general use |
| Property | Explanation |
|---|---|
| Rare Earth Salt | Derived from gadolinium element belonging to the lanthanide series. Consists of gadolinium ions (Gd³⁺) and acetate ions (C₂H₃O₂⁻). |
| MRI Contrast Agent | Gadolinium compounds are used as contrast agents in magnetic resonance imaging (MRI). Gd³⁺ ions exhibit paramagnetic properties. |
| Catalyst | Used as catalyst in automotive catalysts and organic synthesis. |
| Optical Materials | Used in Gd³⁺-doped optical materials, phosphors and photonic materials. |
| Precursor Material | Used as precursor for gadolinium oxide (Gd₂O₃) and other gadolinium compounds. |
| Hygroscopic Property | Slightly hygroscopic, can absorb moisture from air. Should be stored in closed containers. |
| Industry / Application | Function | Typical Use |
|---|---|---|
| Medical Imaging | MRI contrast agent | Used as contrast agent in magnetic resonance imaging (MRI). |
| Catalyst Production | Catalyst | Used as catalyst in automotive catalysts and organic synthesis. |
| Optical Materials | Optical dopant | Used in Gd³⁺-doped optical materials, phosphors and photonic materials. |
| Ceramics and Glass | Colorant and polishing | Used in glass polishing and advanced ceramics. |
| Chemical Synthesis | Precursor | Precursor for gadolinium oxide and other gadolinium compounds. |
| Research | Reagent | Used as a reagent in rare earth chemistry research. |
| Parameter | Explanation |
|---|---|
| Application | Used as contrast agent in magnetic resonance imaging (MRI). |
| Operating Principle | Gd³⁺ ions exhibit paramagnetic properties; Shortens T1 relaxation time, increasing image contrast. |
| Advantages | High contrast; Good tolerance; Rapid elimination; Widespread use. |
| Application Areas | Brain imaging; Cardiac imaging; Liver imaging; Oncological imaging. |
| Parameter | Specification (GA-1 - ≥99.99%) | Test Method |
|---|---|---|
| Appearance | White crystalline solid | Visual |
| Purity (Gd(C₂H₃O₂)₃·4H₂O) | ≥ 99.99% | AAS / ICP / GDMS |
| Gadolinium Oxide (Gd₂O₃) | ≥ 40.0% | AAS / ICP |
| Iron (Fe) | ≤ 0.001% | AAS / ICP / GDMS |
| Calcium (Ca) | ≤ 0.001% | AAS / ICP / GDMS |
| Magnesium (Mg) | ≤ 0.001% | AAS / ICP / GDMS |
| Silicon (Si) | ≤ 0.001% | AAS / ICP / GDMS |
| Aluminum (Al) | ≤ 0.001% | AAS / ICP / GDMS |
| Other Rare Earths | ≤ 0.01% | ICP / GDMS |
| Chloride (Cl⁻) | ≤ 0.01% | Ion Chromatography |
| Sulfate (SO₄²⁻) | ≤ 0.01% | Ion Chromatography |
| Moisture | ≤ 0.5% | Karl Fischer |
| Form | Crystalline powder | Visual |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity | Low toxicity |
| Acute Inhalation Toxicity | Dust inhalation may cause irritation |
| Skin Irritation | May be irritating |
| Eye Irritation | May cause serious eye irritation |
| Chronic Toxicity | Rare earth compounds may show health effects with prolonged exposure |
| Carcinogenicity | Not classified as carcinogenic |
| Mutagenicity | Not classified as mutagenic |
| Target Organs | Respiratory system (dust irritation); Skin; Eyes |
| Special Toxicity Note | Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property |
GHS Classification (in compliance with CLP and UN GHS):
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315 |
| Serious Eye Damage/Irritation | Category 1 | H318 |
| STOT - SE (Single Exposure) | Category 3 | H335 (optional) |
Signal Word: DANGER
Hazard Pictograms: GHS05 (Corrosive), GHS07 (Irritant)
Hazard Statements (H-Codes):
| Code | Statement |
|---|---|
| H315 | Causes skin irritation |
| H318 | Causes serious eye damage |
| H335 | May cause respiratory irritation |
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust/fume/gas/mist/vapors/spray |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only outdoors or in a well-ventilated area |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing |
| P310 | Immediately call a POISON CENTER/doctor |
| P312 | Call a POISON CENTER/doctor if you feel unwell |
| P362+P364 | Take off contaminated clothing and wash it before reuse |
| P403+P233 | Store in a well-ventilated place. Keep container tightly closed |
| P501 | Dispose of contents/container in accordance with local/regional/national/international regulations |
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention. |
| Skin Contact | Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention. |
| Eye Contact | Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. Seek immediate medical attention. |
| Ingestion | Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek immediate medical attention. |
| Parameter | Information |
|---|---|
| Fire Hazard | Not flammable. May release toxic fumes at high temperatures. |
| Hazards During Fire | May release gadolinium oxide and organic decomposition products at high temperatures |
| Suitable Extinguishing Media | Dry chemical powder, CO₂, water spray, alcohol-resistant foam |
| Unsuitable Extinguishing Media | Water jet |
| Special Protective Equipment | Self-contained breathing apparatus (SCBA), full protective clothing |
| Special Precautions | Prevent dust from entering sewers and waterways; Do not inhale fumes |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area; Protect from moisture and light; In closed containers; Keep in original packaging |
| Container Requirements | Airtight containers; Tightly closed due to hygroscopic property |
| Materials to Protect From | Strong bases, reducing agents, oxidizing agents, moisture |
| Shelf Life | 2-3 years (under proper storage conditions) |
| Stability Note | Slightly hygroscopic; Absorbs moisture; Store in closed containers |
| Packaging Type | Quantity | Material |
|---|---|---|
| Plastic Drum | 25-50 kg | HDPE (airtight) |
| Plastic Bucket | 5-25 kg | HDPE (airtight) |
| Glass Bottle | 100 g - 2 kg | Glass (airtight) |
| Plastic Bag | 1-10 kg | PE (sealed) |
| Flexibag | 100-500 kg | PE lined |
| Parameter | Information |
|---|---|
| UN Number | Not regulated (not dangerous) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG Code | Not regulated |
| IATA (Air) | Not regulated |
| Marine Pollutant | No |
| Transport Temperature | Ambient temperature; Protect from moisture |
| Type | Name |
|---|---|
| Turkish Names | Gadolinyum Asetat, Gadolinyum Asetat Tetrahydrat, Gadolinyum Asetat Hidrat, Gadolinyum Asetat Susuz |
| English Names | Gadolinium Acetate, Gadolinium Acetate Tetrahydrate, Gadolinium Acetate Hydrate, Gadolinium Acetate Anhydrous |
| German Names | Gadoliniumacetat, Gadoliniumacetat Tetrahydrat, Gadoliniumacetat Hydrat |
| French Names | Acétate de Gadolinium, Acétate de Gadolinium Tétrahydraté, Acétate de Gadolinium Hydraté |
| Spanish Names | Acetato de Gadolinio, Acetato de Gadolinio Tetrahidratado, Acetato de Gadolinio Hidratado |
| Chemical Names | Gadolinium(3+) acetate; Gadolinium triacetate |
| CAS Numbers | 31298-16-5 (Anhydrous); 15280-53-2 (Tetrahydrate); 100587-93-7 (Hydrate Variant) |
| EC Number | 240-204-9 |
| Chemical Formula | Gd(C₂H₃O₂)₃·4H₂O |
| Parameter | Tetrahydrate | Anhydrous |
|---|---|---|
| Product | Gadolinium Acetate Tetrahydrate | Gadolinium Acetate Anhydrous |
| CAS Number | 15280-53-2 | 31298-16-5 |
| Chemical Formula | Gd(C₂H₃O₂)₃·4H₂O | Gd(CH₃COO)₃ |
| Molecular Weight | ~352.37 g/mol | ~370.53 g/mol |
| Appearance | White crystalline solid | White powder |
| Common Use | Most common commercial form | Special synthesis |
| Solubility | Soluble in water | Soluble in water |
May cause serious eye damage. Eye protection is mandatory. Seek immediate medical attention upon contact.
Irritant. May cause irritation to skin and respiratory tract. Use appropriate protective equipment.
Slightly hygroscopic (absorbs moisture). Store in closed containers in dry environment.
Decomposes upon heating and may release organic decomposition products.
Rare earth compound requires special handling and purity considerations.
MRI contrast agent applications require high purity (≥99.99%).
Incompatibilities: Strong bases, reducing agents, oxidizing agents, moisture.
Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.
9. MRI Contrast Agent Production:
Use high-purity (≥99.99%) GA-1 grade for magnetic resonance imaging (MRI).
10. Catalyst Production:
Use as catalyst in automotive catalysts and organic synthesis.
11. Optical Materials:
Use in Gd³⁺-doped optical materials, phosphors and photonic materials.
12. Chemical Synthesis:
Use as precursor for gadolinium oxide and other gadolinium compounds.
13. Research:
Use as a reagent in rare earth chemistry studies.
14. Form Selection:
For common use, prefer tetrahydrate form (15280-53-2). For special synthesis, prefer anhydrous form (31298-16-5).
15. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.
16. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, full face shield, protective clothing.
17. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.
18. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture and light; Store in closed, airtight containers.
19. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.
20. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.
| Application | Recommended Form | Explanation |
|---|---|---|
| MRI contrast agent | Tetrahydrate (≥99.99%) | Highest purity required |
| Catalyst | Tetrahydrate (≥99.9%) | High purity required |
| Optical materials | Tetrahydrate (≥99.99%) | Highest purity required |
| Chemical synthesis | Both forms | Depends on application |
| Research | Tetrahydrate (≥99.99%) | High purity required |
| Parameter | Requirement |
|---|---|
| Storage Temperature | Room temperature (15-25°C) |
| Humidity | <60% relative humidity |
| Container | Airtight containers |
| Location | Cool, dry, well-ventilated area |
The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.