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Europium Acetate Hydrate, Europium Triacetate Hydrate, 62667‑64‑5

Europium Acetate Hydrate, Europium Triacetate Hydrate, 62667‑64‑5

EUROPIUM ACETATE HYDRATE (EUROPIUM ACETATE HYDRATE / EUROPIUM TRIACETATE HYDRATE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Europium Acetate Hydrate / Europium Acetate Hydrate
Other Technical Names Europium Triacetate Hydrate, Europium(III) Acetate Hydrate
CAS Number 62667-64-5
Chemical Formula Eu(CH₃COO)₃·xH₂O (typically tetrahydrate form)
Molecular Weight ~347 g/mol (hydrated form)
EC Number
HS Code 291529
Product Family Rare Earth Acetate Salt
Appearance White or slightly pink crystalline solid

CHEMICAL STRUCTURE

    Europium Acetate Hydrate [Eu(CH₃COO)₃·xH₂O]
    
    Europium Ions (Eu³⁺) and Acetate Ions (CH₃COO⁻)
    with Hydrate Molecules
    
         CH₃COO⁻  Eu³⁺  CH₃COO⁻
           \         |         /
            CH₃COO⁻-Eu³⁺-CH₃COO⁻
           /         |         \
         CH₃COO⁻  Eu³⁺  CH₃COO⁻
    
    Europium Ions (Eu³⁺) with Acetate Ions (CH₃COO⁻)
    Surrounded by Water Molecules (H₂O)
    Rare Earth Acetate Salt
    White/Slightly Pink Crystalline Solid
    Used in Red Phosphor and LED Applications

Molecular Formula: Eu(CH₃COO)₃·xH₂O
Ionic Structure: Eu³⁺ and CH₃COO⁻ ions
Hydrate State: x variable (typically tetrahydrate)
Color: White or slightly pink

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Europium Acetate Hydrate / Europium Acetate Hydrate
Other Technical Names (English) Europium Acetate Hydrate, Europium Triacetate Hydrate, Europium(III) Acetate Hydrate
Other Technical Names (Turkish) Europium Asetat Hidrat, Europium Triasetat Hidrat, Europyum(III) Asetat Hidrat
Other Technical Names (German) Europiumacetat Hydrat, Europiumtriacetat Hydrat
Other Technical Names (French) Acétate d'Europium Hydraté, Triacétate d'Europium Hydraté
Other Technical Names (Spanish) Acetato de Europio Hidratado, Triacetato de Europio Hidratado
CAS Number 62667-64-5
EC Number
HS Code 291529
Chemical Formula Eu(CH₃COO)₃·xH₂O
Molecular Weight ~347 g/mol (hydrated form)
Chemical Class Rare Earth Acetate Salt
Appearance White or slightly pink crystalline solid
Odor Slight acetic acid odor
Color White or slightly pink
Crystal Structure Crystalline solid
Hygroscopic Hygroscopic (absorbs moisture)

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White or slightly pink crystalline solid Visual
Chemical Formula Eu(CH₃COO)₃·xH₂O -
Molecular Weight ~347 g/mol (hydrated) Calculated
Density ~2.6-2.8 g/cm³ -
Melting Point Decomposes upon heating -
Solubility Soluble in water; Soluble in acetic acid -
Stability Stable under normal conditions; Protect from moisture and light -
Color White or slightly pink Originates from europium ions
pH Neutral to slightly acidic -
Hygroscopicity Hygroscopic Must be stored in closed containers

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Rare earth acetate salt; Derived from europium element; Critical for red phosphor production; Optical materials
Stability Stable under normal conditions; Protect from moisture and light; Decomposes at high temperatures
Reactivity Soluble in water; Soluble in acetic acid; Reacts with strong bases and reducing agents
Incompatible Materials Strong bases, reducing agents, oxidizing agents, moisture
Thermal Decomposition Eu(CH₃COO)₃·xH₂O → heat → Eu₂O₃ + CO₂ + H₂O (decomposes upon heating)
Solubility in Water Soluble in water; Dissociates into Eu³⁺ and CH₃COO⁻ ions
Acid Solubility Soluble in acetic acid
Special Property Precursor for europium oxide and other europium compounds; Critical for red phosphor production; Used in LEDs and fluorescent lamps

SECTION 4: EUROPIUM ACETATE FORMS

Type Chemical Formula Explanation
Hydrate (General) Eu(CH₃COO)₃·xH₂O Most common commercial form; x typically 3-4
Anhydrous Eu(CH₃COO)₃ Special synthesis

SECTION 5: EUROPIUM ACETATE GRADES

Grade Purity (%) Form Application Areas
EA-1 ≥ 99.99% Crystalline powder High-purity research, optical materials, phosphors
EA-2 ≥ 99.9% Crystalline powder LED and fluorescent applications
EA-3 ≥ 99.0% Crystalline powder Industrial applications, general use

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Rare Earth Salt Derived from europium element belonging to the lanthanide series. Consists of europium ions (Eu³⁺) and acetate ions (CH₃COO⁻).
Red Phosphor Production Europium salts are critical for production of red-emitting phosphors. Eu³⁺ ions provide red emission at 613 nm wavelength.
LED and Fluorescent Lamps Eu³⁺-doped phosphors are used for red light production in LED and fluorescent lamps.
Precursor Material Used as precursor for europium oxide (Eu₂O₃) and other europium compounds.
CRT Screens Used in red phosphor production for cathode ray tube (CRT) displays.
Hygroscopic Property Hygroscopic, can absorb moisture from air. Should be stored in closed containers.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Electronics and Photonics Red phosphor Eu³⁺-doped phosphors, especially red-emitting LED and fluorescent lamps.
Specialty Ceramics and Glass Luminescence Used in luminescent glass and advanced ceramics.
Chemical Synthesis Precursor Precursor for europium oxide and other europium compounds.
Laboratory Reagent Used as a reagent in rare earth chemistry research.
Advanced Materials Research Optical material Used in development of next-generation optical and photonic materials.
Metal / Surface Treatment Coating and alloy Can be used in special alloys and coatings.

SECTION 8: PHOSPHOR AND LED APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Red Phosphor Europium ions (Eu³⁺) provide red emission at 613 nm wavelength.
LED Technology Used as red phosphor in white LED production. Improves color temperature and color quality.
Fluorescent Lamps Used in red color production in energy-saving fluorescent lamps.
Operating Principle When Eu³⁺ ions receive excitation energy, they emit red light at 613 nm wavelength.
Advantages High color purity; Long lifetime; High brightness; Energy efficiency.
Application Areas LED lighting; Television screens; Computer monitors; Fluorescent lamps.

SECTION 9: INDUSTRY SUITABILITY TABLE

Industry / Application Suitability Explanation
Textile No application area
Food Prohibited as food additive or in contact materials
Cosmetics Prohibited in cosmetic formulations under CLP/REACH
Metal / Surface Treatment Can be used in special alloys and coatings
Ceramics / Glass Used in luminescent glass and advanced ceramics
Laboratory / Research Widely used as reagent in rare earth chemistry
Electronics / Optics Critical use in phosphors, LEDs and photonic materials
Construction Chemicals No application area

SECTION 10: QUALITY SPECIFICATIONS

Parameter Specification (EA-1 - ≥99.99%) Test Method
Appearance White or slightly pink crystalline solid Visual
Purity (Eu(CH₃COO)₃·xH₂O) ≥ 99.99% AAS / ICP / GDMS
Europium Oxide (Eu₂O₃) ≥ 40.0% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP / GDMS
Calcium (Ca) ≤ 0.001% AAS / ICP / GDMS
Magnesium (Mg) ≤ 0.001% AAS / ICP / GDMS
Silicon (Si) ≤ 0.001% AAS / ICP / GDMS
Aluminum (Al) ≤ 0.001% AAS / ICP / GDMS
Other Rare Earths ≤ 0.01% ICP / GDMS
Chloride (Cl⁻) ≤ 0.01% Ion Chromatography
Sulfate (SO₄²⁻) ≤ 0.01% Ion Chromatography
Moisture ≤ 0.5% Karl Fischer
Form Crystalline powder Visual

SECTION 11: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be irritating
Eye Irritation May cause serious eye irritation
Chronic Toxicity Rare earth compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Special Toxicity Note Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property

SECTION 12: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315
Serious Eye Damage/Irritation Category 1 H318
STOT - SE (Single Exposure) Category 3 H335 (optional)

Signal Word: DANGER

Hazard Pictograms: GHS05 (Corrosive), GHS07 (Irritant)

Hazard Statements (H-Codes):

Code Statement
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

SECTION 13: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P310 Immediately call a POISON CENTER/doctor
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 14: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. Seek immediate medical attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek immediate medical attention.

SECTION 15: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable. May release toxic fumes at high temperatures.
Hazards During Fire May release europium oxide and organic decomposition products at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 16: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; Protect from moisture and light; In closed containers; Keep in original packaging
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong bases, reducing agents, oxidizing agents, moisture
Shelf Life ~2 years (under proper storage conditions)
Stability Note Hygroscopic; Absorbs moisture; Store in closed containers

SECTION 17: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 18: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Europium Asetat Hidrat, Europium Triasetat Hidrat, Europyum(III) Asetat Hidrat
English Names Europium Acetate Hydrate, Europium Triacetate Hydrate, Europium(III) Acetate Hydrate
German Names Europiumacetat Hydrat, Europiumtriacetat Hydrat
French Names Acétate d'Europium Hydraté, Triacétate d'Europium Hydraté
Spanish Names Acetato de Europio Hidratado, Triacetato de Europio Hidratado
Chemical Names Europium(3+) acetate hydrate; Europium triacetate hydrate
CAS Number 62667-64-5
HS Code 291529
Chemical Formula Eu(CH₃COO)₃·xH₂O

SECTION 20: SUMMARY TABLE

Parameter Value
Product Europium Acetate Hydrate / Europium Acetate Hydrate
CAS Number 62667-64-5
Chemical Formula Eu(CH₃COO)₃·xH₂O
Molecular Weight ~347 g/mol (hydrated)
Appearance White or slightly pink crystalline solid
Solubility Soluble in water; Soluble in acetic acid
Primary Function Rare earth acetate salt; Red phosphor precursor
Main Applications Electronics and photonics (LED, fluorescent), specialty ceramics, laboratory
Shelf Life ~2 years
GHS Signal Word DANGER
UN Number Not regulated
Special Features Hygroscopic; Critical for red phosphor and LED applications

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. May cause serious eye damage. Eye protection is mandatory. Seek immediate medical attention upon contact.

  2. Irritant. May cause irritation to skin and respiratory tract. Use appropriate protective equipment.

  3. Hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  4. Decomposes upon heating and may release organic decomposition products.

  5. Rare earth compound requires special handling and purity considerations.

  6. Phosphor and LED applications require high purity (≥99.99%).

  7. Not approved for food and cosmetics. Prohibited in cosmetic formulations under CLP/REACH.

  8. Incompatibilities: Strong bases, reducing agents, oxidizing agents, moisture.

  9. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

10. Red Phosphor Production:
Use europium acetate for red phosphor production in LEDs, fluorescent lamps and CRT displays. Prefer high-purity (≥99.99%) EA-1 grade.

11. Optical Materials:
Use in Eu³⁺-doped optical materials and luminescent glass production.

12. Chemical Synthesis:
Use as precursor for europium oxide (Eu₂O₃) and other europium compounds.

13. Laboratory:
Use as a reagent in rare earth chemistry research.

14. Advanced Materials Research:
Use in development of next-generation optical and photonic materials.

15. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

16. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, full face shield, protective clothing.

17. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

18. Storage:
Store in cool, dry, well-ventilated area; Protect from moisture and light; Store in closed, airtight containers.

19. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

20. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for rare earth compounds.

EUROPIUM ACETATE SELECTION GUIDE:

Application Recommended Grade Explanation
Red phosphor (LED) EA-1 (≥99.99%) Highest purity required
Fluorescent lamps EA-1 (≥99.99%) Highest purity required
Optical materials EA-1 (≥99.99%) Highest purity required
Chemical synthesis EA-2 (≥99.9%) High purity required
Research EA-1 (≥99.99%) High purity required

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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