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Indium Acetate, Indium Triacetate, 25114‑58‑3

Indium Acetate, Indium Triacetate, 25114‑58‑3

INDIUM ACETATE (INDIUM ACETATE / INDIUM TRIACETATE)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Indium Acetate / Indium Acetate
Other Technical Names Indium Triacetate, Indium(III) Acetate
CAS Number 25114-58-3
Chemical Formula In(C₂H₃O₂)₃
Molecular Weight 291.95 g/mol
EC Number
HS Code 291529
Product Family Indium Salt / Acetate Salt
Appearance White crystalline powder

CHEMICAL STRUCTURE

    Indium Acetate [In(C₂H₃O₂)₃]
    
    Indium Ions (In³⁺) and Acetate Ions (C₂H₃O₂⁻)
    in Crystal Structure
    
         C₂H₃O₂⁻  In³⁺  C₂H₃O₂⁻
           \         |         /
            C₂H₃O₂⁻-In³⁺-C₂H₃O₂⁻
           /         |         \
         C₂H₃O₂⁻  In³⁺  C₂H₃O₂⁻
    
    Indium Ions (In³⁺) with Acetate Ions (C₂H₃O₂⁻)
    Indium Salt
    White Crystalline Powder
    Used in Semiconductor and ITO Applications

Molecular Formula: In(C₂H₃O₂)₃
Ionic Structure: In³⁺ and C₂H₃O₂⁻ ions
Oxidation State: +3
Color: White

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Indium Acetate / Indium Acetate
Other Technical Names (English) Indium Acetate, Indium Triacetate, Indium(III) Acetate, Acetic Acid Indium(3+) Salt
Other Technical Names (Turkish) İndiyum Asetat, İndiyum Triasetat, İndiyum(III) Asetat, Asetik Asit İndiyum(3+) Tuzu
Other Technical Names (German) Indiumacetat, Indiumtriacetat, Indium(III)-acetat
Other Technical Names (French) Acétate d'Indium, Triacétate d'Indium, Acétate d'Indium(III)
Other Technical Names (Spanish) Acetato de Indio, Triacetato de Indio, Acetato de Indio(III)
CAS Number 25114-58-3
EC Number
HS Code 291529
Chemical Formula In(C₂H₃O₂)₃
Molecular Weight 291.95 g/mol
Chemical Class Indium Salt / Acetate Salt
Appearance White crystalline powder
Odor Slight acetic acid odor
Color White
Crystal Structure Crystalline powder
Hygroscopic Hygroscopic (absorbs moisture)

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White crystalline powder Visual
Chemical Formula In(C₂H₃O₂)₃ -
Molecular Weight 291.95 g/mol Calculated
Density ~2.7 g/cm³ -
Melting Point ~270°C (decomposes upon heating) -
Solubility Soluble in water; Soluble in mineral acids; Soluble in acetic acid -
Stability Stable under normal conditions; Protect from moisture and light -
Color White -
pH Neutral to slightly acidic -
Hygroscopicity Hygroscopic Must be stored in closed containers

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Indium salt; Acetate salt; Precursor for semiconductors and transparent conductive oxides (ITO)
Stability Stable under normal conditions; Protect from moisture and light; Decomposes at high temperatures
Reactivity Soluble in water; Soluble in mineral acids; Reacts with strong bases and reducing agents
Incompatible Materials Strong bases, reducing agents, oxidizing agents, moisture
Thermal Decomposition In(C₂H₃O₂)₃ → heat → In₂O₃ + CO₂ + H₂O (decomposes upon heating)
Solubility in Water Soluble in water; Dissociates into In³⁺ and C₂H₃O₂⁻ ions
Acid Solubility Soluble in mineral acids and acetic acid
Special Property Precursor for indium oxide (In₂O₃) and ITO (Indium-Tin Oxide); Semiconductor applications

SECTION 4: INDIUM ACETATE GRADES

Grade Purity (%) Form Application Areas
IA-1 ≥ 99.99% Crystalline powder High-purity research, semiconductors, ITO
IA-2 ≥ 99.9% Crystalline powder Industrial applications, catalyst
IA-3 ≥ 99.5% Crystalline powder General use, research

SECTION 5: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Explanation
Precursor Material Critical precursor for indium oxide (In₂O₃) and ITO (Indium-Tin Oxide) production.
Semiconductor Applications Used in production of indium-based semiconductors. Important for optoelectronic devices.
Transparent Conductive Oxides (ITO) Indium acetate is a precursor for ITO coatings. Used in flat panel displays, solar cells and touch screens.
Catalyst Used as catalyst in organic and inorganic synthesis.
Hygroscopic Property Hygroscopic, can absorb moisture from air. Should be stored in closed containers.
Advanced Materials Research Used in nanoelectronics, thin film technologies and advanced materials research.

SECTION 6: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Electronics and Photonics Precursor Transparent conductive oxides (ITO), indium-based semiconductors.
Chemical Synthesis Catalyst Used as catalyst in organic and inorganic synthesis.
Laboratory Reagent Used as a reagent in indium chemistry research.
Advanced Materials Research Precursor Nanoelectronics, thin film technologies.
Metal / Surface Treatment Coating and alloy Can be used in special alloys and coatings.
Ceramics / Glass Additive Used in advanced ceramics and specialty glass production.

SECTION 7: ITO (INDIUM-TIN OXIDE) APPLICATIONS - DETAILED EXPLANATION

Parameter Explanation
Application Indium acetate is a precursor for ITO (Indium-Tin Oxide) production.
Function ITO is a transparent conductive oxide critical for electronic devices.
Operating Principle Indium acetate thermally decomposes to indium oxide (In₂O₃); Alloyed with tin to produce ITO.
Advantages High conductivity; High light transmittance; Good adhesion; Durability.
Application Areas Flat panel displays (LCD, OLED); Touch screens; Solar cells; Smart glass; Optoelectronic devices.

SECTION 8: INDUSTRY SUITABILITY TABLE

Industry / Application Suitability Explanation
Textile No application area
Food Prohibited as food additive or in contact materials
Cosmetics Prohibited in cosmetic formulations under CLP/REACH
Metal / Surface Treatment Can be used in special alloys and coatings
Ceramics / Glass Used in advanced ceramics and specialty glass
Laboratory / Research Widely used as reagent in indium chemistry
Electronics / Optics Critical use in semiconductors, transparent conductive oxides and photonic materials
Construction Chemicals No application area

SECTION 9: QUALITY SPECIFICATIONS

Parameter Specification (IA-1 - ≥99.99%) Test Method
Appearance White crystalline powder Visual
Purity (In(C₂H₃O₂)₃) ≥ 99.99% AAS / ICP / GDMS
Indium Oxide (In₂O₃) ≥ 50.0% AAS / ICP
Iron (Fe) ≤ 0.001% AAS / ICP / GDMS
Calcium (Ca) ≤ 0.001% AAS / ICP / GDMS
Magnesium (Mg) ≤ 0.001% AAS / ICP / GDMS
Silicon (Si) ≤ 0.001% AAS / ICP / GDMS
Aluminum (Al) ≤ 0.001% AAS / ICP / GDMS
Lead (Pb) ≤ 0.001% AAS / ICP / GDMS
Cadmium (Cd) ≤ 0.001% AAS / ICP / GDMS
Chloride (Cl⁻) ≤ 0.01% Ion Chromatography
Sulfate (SO₄²⁻) ≤ 0.01% Ion Chromatography
Moisture ≤ 0.5% Karl Fischer
Form Crystalline powder Visual

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation May be irritating
Eye Irritation May cause serious eye irritation
Chronic Toxicity Indium compounds may show health effects with prolonged exposure
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation); Skin; Eyes
Occupational Exposure Limit (ACGIH/NIOSH TWA) 0.1 mg/m³
Special Toxicity Note Irritant; May cause irritation to skin, eyes and respiratory tract; Protect from moisture due to hygroscopic property

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in compliance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315
Serious Eye Damage/Irritation Category 1 H318
STOT - SE (Single Exposure) Category 3 H335

Signal Word: DANGER

Hazard Pictograms: GHS05 (Corrosive), GHS07 (Irritant)

Hazard Statements (H-Codes):

Code Statement
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing
P310 Immediately call a POISON CENTER/doctor
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Keep at rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Remove contaminated clothing immediately. Wash skin with plenty of soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses. Continue rinsing. Seek immediate medical attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Seek immediate medical attention.

SECTION 14: FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable. May release toxic fumes at high temperatures.
Hazards During Fire May release indium oxide and organic decomposition products at high temperatures
Suitable Extinguishing Media Dry chemical powder, CO₂, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media Water jet
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Room temperature, dry and cool environment; Protect from moisture; In closed containers; Keep in original packaging
Container Requirements Airtight containers; Tightly closed due to hygroscopic property
Materials to Protect From Strong bases, reducing agents, oxidizing agents, moisture
Shelf Life ~2 years (under proper storage conditions)
Stability Note Hygroscopic; Absorbs moisture; Store in closed containers

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Drum 25-50 kg HDPE (airtight)
Plastic Bucket 5-25 kg HDPE (airtight)
Glass Bottle 100 g - 2 kg Glass (airtight)
Plastic Bag 1-10 kg PE (sealed)
Flexibag 100-500 kg PE lined

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (not dangerous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names İndiyum Asetat, İndiyum Triasetat, İndiyum(III) Asetat, Asetik Asit İndiyum(3+) Tuzu
English Names Indium Acetate, Indium Triacetate, Indium(III) Acetate, Acetic Acid Indium(3+) Salt
German Names Indiumacetat, Indiumtriacetat, Indium(III)-acetat
French Names Acétate d'Indium, Triacétate d'Indium, Acétate d'Indium(III)
Spanish Names Acetato de Indio, Triacetato de Indio, Acetato de Indio(III)
Chemical Names Indium(3+) acetate; Indium triacetate
CAS Number 25114-58-3
HS Code 291529
Chemical Formula In(C₂H₃O₂)₃

SECTION 19: SUMMARY TABLE

Parameter Value
Product Indium Acetate / Indium Acetate
CAS Number 25114-58-3
Chemical Formula In(C₂H₃O₂)₃
Molecular Weight 291.95 g/mol
Appearance White crystalline powder
Solubility Soluble in water; Soluble in acids
Primary Function Indium salt; Precursor; Catalyst
Main Applications Electronics (ITO), catalyst, laboratory, advanced materials research
Shelf Life ~2 years
GHS Signal Word DANGER
UN Number Not regulated
Special Features Hygroscopic; Critical for semiconductor and ITO applications

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. May cause serious eye damage. Eye protection is mandatory. Seek immediate medical attention upon contact.

  2. Irritant. May cause irritation to skin and respiratory tract. Use appropriate protective equipment.

  3. Hygroscopic (absorbs moisture). Store in closed containers in dry environment.

  4. Decomposes upon heating and may release organic decomposition products.

  5. Indium compound requires special handling and purity considerations.

  6. ITO and semiconductor applications require high purity (≥99.99%).

  7. Not approved for food and cosmetics. Prohibited in cosmetic formulations under CLP/REACH.

  8. Occupational exposure limit: ACGIH/NIOSH TWA 0.1 mg/m³.

  9. Incompatibilities: Strong bases, reducing agents, oxidizing agents, moisture.

  10. Hygiene Requirement: Wash hands thoroughly after use. Remove contaminated clothing.

BEST PRACTICE RECOMMENDATIONS:

11. ITO (Indium-Tin Oxide) Production:
Use indium acetate for transparent conductive oxide coatings. Prefer high-purity (≥99.99%) IA-1 grade.

12. Semiconductor Applications:
Use in production of indium-based semiconductors. Suitable for optoelectronic devices.

13. Catalyst:
Use as catalyst in organic and inorganic synthesis.

14. Laboratory:
Use as a reagent in indium chemistry research.

15. Advanced Materials Research:
Use in nanoelectronics, thin film technologies and advanced materials research.

16. Use:
Use in well-ventilated areas; Avoid dust formation; Wear protective gloves, safety goggles and appropriate respiratory protection.

17. Personal Protective Equipment:
Use protective gloves (nitrile, neoprene), chemical safety goggles, full face shield, protective clothing.

18. Hygiene:
Do not eat, drink or smoke while using; Wash hands thoroughly after use; Do not take contaminated work clothes home.

19. Storage:
Store at room temperature in dry and cool environment; Protect from moisture; Store in closed, airtight containers.

20. Spill Response:
Avoid dust formation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

21. Disposal:
Dispose in accordance with local, regional and national regulations; Contact licensed waste disposal services for indium compounds.

22. Purity Requirements:
Select the correct purity grade according to the application. High purity (≥99.99%) is required for electronics and semiconductor applications.

INDIUM ACETATE SELECTION GUIDE:

Application Recommended Grade Explanation
ITO production IA-1 (≥99.99%) Highest purity required
Semiconductors IA-1 (≥99.99%) Highest purity required
Catalyst IA-2 (≥99.9%) High purity required
Research IA-1 (≥99.99%) High purity required
Industrial applications IA-3 (≥99.5%) Economic solution

RECOMMENDED STORAGE CONDITIONS:

Parameter Requirement
Storage Temperature Room temperature (15-25°C)
Humidity <60% relative humidity
Container Airtight containers
Location Cool, dry, well-ventilated area

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is provided in good faith; however, since all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, use, handling, disposal and regulatory compliance information, reference should be made to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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