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Send EmailCetyl Stearyl Alcohol, Cetearyl Alcohol, Cetostearyl Alcohol, C16-18 Alcohol, 67762-27-0, 8005-44-5, 67762-30-5
CETEARYL ALCOHOL (CETOSTEARYL ALCOHOL)
1. PRODUCT DEFINITION AND CHEMICAL IDENTITY
| Parameter | Description |
|---|---|
| Chemical Name (IUPAC) | Hexadecan-1-ol; octadecan-1-ol (mixture) |
| Common Name (INCI) | Cetearyl Alcohol |
| Other Names | Cetostearyl Alcohol, Cetyl-stearyl alcohol, Alcohols (C16-18), Cetyl/stearyl alcohol, C16-18 alcohols |
| Chemical Class | Fatty Alcohol blend |
| Primary Components | Cetyl Alcohol (C₁₆H₃₄O) and Stearyl Alcohol (C₁₈H₃₈O) |
| Appearance | White, waxy flakes, pastilles, or solid mass |
| Odour | Faint, characteristic fatty alcohol odour |
2. CAS NUMBER REFERENCE TABLE
| CAS Number | EC Number | Description / Scope |
|---|---|---|
| 67762-27-0 | 267-008-6 | Most widely used CAS number. Defines the C16-18 fatty alcohol blend (Cetearyl Alcohol / Cetostearyl Alcohol). Listed as the primary identifier by PubChem and ECHA. |
| 8005-44-5 | — | Another valid CAS number commonly used for Cetearyl Alcohol. Listed alongside 67762-27-0 as a primary identifier in PubChem. No official EC counterpart. |
| 67762-30-5 | 267-009-1 | A valid CAS number defining the broader C14-18 fatty alcohol range. Commercially used for Cetearyl Alcohol products. |
Important Clarifications:
EC number 267-008-6 belongs to CAS 67762-27-0.
EC number 267-009-1 belongs to CAS 67762-30-5.
All three CAS numbers are valid and accepted identifiers for Cetearyl Alcohol. The scope of 67762-30-5 is slightly broader (C14-18), but it is commercially used to describe standard Cetearyl Alcohol blends.
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value / Description |
|---|---|
| Physical state (20-25 °C) | White, waxy solid (flakes or pastilles) |
| Colour | White to very pale yellow |
| Melting point | 48 – 56 °C (varies with C16:C18 ratio) |
| Boiling point | ~249 °C |
| Flash point | ~132.85 °C |
| Density | ~0.842 g/cm³ (or g/mL) |
| Solubility in water | Insoluble |
| Solubility in organics | Partially soluble in alcohol; soluble in ether, oils, and esters |
| Refractive Index | ~1.46 |
| HLB Value | ~15.5 (tends to form oil-in-water emulsions, limited capacity) |
| Molecular Weight | ~512.94 g/mol (representative formula: C₃₄H₇₂O₂) |
4. PRODUCT TYPES AND COMPARATIVE TABLE
The final consistency and sensory feel of the product are determined by the ratio of Cetyl (C16) to Stearyl (C18) alcohol.
| Type (Cetyl:Stearyl) | Composition | Characteristic Properties | Key Applications |
|---|---|---|---|
| 30:70 Type | 30% Cetyl (C16), 70% Stearyl (C18) | Harder, denser, and more stable emulsions. Stronger thickening and stabilizing effect due to high stearyl alcohol content. Higher melting point. | Rich night creams, protective hand creams, ointment bases, firm stick products (deodorant sticks, lip balms). Preferred where high stability and no phase separation are critical. |
| 50:50 Type | 50% Cetyl, 50% Stearyl | Balanced crystal structure providing homogeneous distribution. Ideal middle ground between the softness of cetyl alcohol and the firmness of stearyl alcohol. The most widely used, "standard" type. | Moisturizing creams and lotions, body milks, hair conditioners and masks, shampoos, sunscreens. Suitable for both O/W and W/O emulsions. |
| 70:30 Type | 70% Cetyl, 30% Stearyl | Softer, creamier, and more velvety skin feel. The moisturizing and emollient effect is more dominant due to the high cetyl alcohol content. Provides sufficient softening to act as a standalone hair conditioning active. | Hair conditioners and treatment masks (where a softening effect is paramount), soothing creams for sensitive skin, lip balms, serums. Also used to aid the stability of emulsifiers. |
5. FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION
Co-Emulsifier and Emulsion Stabilizer: Cetearyl alcohol is a non-ionic co-emulsifier. It strengthens the interfacial film formed by the primary emulsifier, preventing droplet coalescence and ensuring long-term emulsion stability. It works effectively in both oil-in-water (O/W) and water-in-oil (W/O) systems.
Viscosity Builder / Consistency Modifier: It forms a three-dimensional crystalline gel network (lamellar phases) within the formulation, trapping the emulsion droplets and increasing the viscosity. This provides a rich, creamy texture that is easy to spread and leaves a lasting, luxurious feel on the skin.
Emollient and Skin Conditioner: It forms a thin, protective, lipophilic film on the skin and hair surface. This film reduces transepidermal water loss (TEWL), providing moisturization, softness, and a smooth, non-greasy skin feel.
Opacifier: In liquid or gel-based formulations, it imparts a desirable matte, creamy, and opaque appearance, enhancing the product's visual aesthetics.
6. SECTORAL APPLICATIONS AND USAGE RATES
| Product Type | Recommended Usage Rate | Notes |
|---|---|---|
| Face and Body Creams | 1 – 5% | Adjust based on desired thickness. The 50:50 type is very common here. |
| Lotions | 1 – 4% | Ideal for more fluid formulations. |
| Hair Conditioners and Masks | 2 – 8% | Provides noticeable softening and body. The 70:30 or 50:50 types are preferred. |
| Anhydrous Products (Balms, Sticks, Solid Shampoos) | 5 – 25% | Used to build the solid structure and adjust hardness. The 30:70 type is particularly well-suited for these applications. |
| General Cream Formulations | 2 – 3% | A typical usage level is sufficient to stabilize the emulsion and provide a pleasant texture. |
Critical Note: Cetearyl Alcohol is a co-emulsifier and thickener, not a primary emulsifier. It must always be used in combination with a suitable primary emulsifier (see Section 7) to achieve a stable emulsion.
7. RECOMMENDED EMULSIFIER COMBINATIONS (Generic INCI Names)
Cetearyl Alcohol must be paired with a stronger primary emulsifier. The most common combinations are:
| Formulation Goal | Recommended Emulsifier System (Generic INCI Names) |
|---|---|
| Natural / Organic products | Glyceryl Stearate & Cetearyl Alcohol & Sodium Stearoyl Lactylate blends, or Cetearyl Glucoside & Cetearyl Alcohol blends |
| Light and fast-absorbing lotions | Sucrose Polystearate & Cetearyl Alcohol based systems |
| High pH stability products (e.g., hair relaxers) | Cetearyl Alcohol & Ceteareth-20 combinations, or Cetearyl Glucoside & Cetearyl Alcohol combinations |
| Luxurious, velvety texture | Glyceryl Stearate & Cetearyl Alcohol & Sodium Stearoyl Lactylate based systems (liquid crystal-forming types) |
| Pharmaceutical / Medical formulations | Cetearyl Alcohol & Sodium Lauryl Sulfate & Sodium Cetearyl Sulfate combinations, or PEG-derivative emulsifying waxes |
8. REGULATORY STATUS, SAFETY, AND STORAGE
GHS Classification: Not classified as a hazardous substance or mixture under CLP (EC 1272/2008).
Toxicology: Very low acute oral, dermal, and inhalation toxicity. Not a significant skin or eye irritant at typical use concentrations. Considered to have very low sensitization (allergy) potential. Not carcinogenic, mutagenic, or reprotoxic.
Comedogenicity: Generally considered non-comedogenic (low risk of clogging pores), making it suitable for acne-prone skin formulations.
Cosmetic Use: Listed as a safe cosmetic ingredient by the Cosmetic Ingredient Review (CIR) panel. Approved without restrictions under EU Cosmetics Regulation (EC 1223/2009).
Sustainability: When derived from vegetable sources (coconut or palm oil), it is considered a natural, renewable, and biodegradable ingredient, widely used in natural and organic formulations.
Storage: Store in a cool (<25 °C), dry, and well-ventilated area, away from direct sunlight and strong odours. Keep containers tightly closed.
Shelf Life: Typically 2-3 years from the date of manufacture under proper storage conditions.
Personal Protection: Standard industrial hygiene practices are sufficient (e.g., gloves, safety goggles for handling molten material).
9. FREQUENTLY ASKED QUESTIONS
Q1: What is the difference between Cetyl Alcohol and Cetearyl Alcohol?
Cetyl alcohol (C16) is a single, pure ingredient. Cetearyl alcohol is a blend of both cetyl alcohol (C16) and stearyl alcohol (C18). This blend offers superior emulsifying, stabilizing, and thickening properties compared to either component alone, making it the industry standard.
Q2: Is Cetearyl Alcohol harmful or drying to the skin?
No. Unlike simple, volatile alcohols like ethanol, it is a fatty, waxy alcohol that acts as an emollient. It forms a protective layer that prevents moisture loss, leaving the skin feeling smooth, soft, and conditioned without a greasy residue.
Q3: Is it suitable for natural or vegan formulations?
Yes. It is typically derived from plant-based sources like coconut or palm oil, making it suitable for both natural and vegan-friendly formulations. Always verify the source with your supplier.
Q4: What is its main function in a hair conditioner?
It acts as a thickener, giving the product a luxurious, rich texture. Simultaneously, it coats the hair strands, smoothing the cuticle, reducing static, and providing detangling and softening benefits.
Q5: Why must it be combined with another emulsifier?
Cetearyl alcohol is a co-emulsifier and thickener, not a primary emulsifier. It stabilizes an emulsion formed by a stronger, primary emulsifier. Using it alone will not reliably create a stable cream or lotion.
10. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| Primary CAS | 67762-27-0 |
| INCI Name | Cetearyl Alcohol |
| Composition | Blend of Cetyl (C16) and Stearyl (C18) alcohols |
| Appearance | White waxy flakes / pastilles |
| Melting Point | 48 – 56 °C |
| Solubility | Insoluble in water; soluble in oils |
| Main Functions | Co-emulsifier, thickener, emollient, opacifier |
| Key Benefit | Provides a smooth, velvety, non-greasy skin feel and excellent emulsion stability |