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Cetyl Stearyl Alcohol, Cetearyl Alcohol, Cetostearyl Alcohol, C16-18 Alcohol, 67762-27-0, 8005-44-5, 67762-30-5

Cetyl Stearyl Alcohol, Cetearyl Alcohol, Cetostearyl Alcohol, C16-18 Alcohol, 67762-27-0, 8005-44-5, 67762-30-5

CETEARYL ALCOHOL (CETOSTEARYL ALCOHOL)

1. PRODUCT DEFINITION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name (IUPAC) Hexadecan-1-ol; octadecan-1-ol (mixture)
Common Name (INCI) Cetearyl Alcohol
Other Names Cetostearyl Alcohol, Cetyl-stearyl alcohol, Alcohols (C16-18), Cetyl/stearyl alcohol, C16-18 alcohols
Chemical Class Fatty Alcohol blend
Primary Components Cetyl Alcohol (C₁₆H₃₄O) and Stearyl Alcohol (C₁₈H₃₈O)
Appearance White, waxy flakes, pastilles, or solid mass
Odour Faint, characteristic fatty alcohol odour

2. CAS NUMBER REFERENCE TABLE

CAS Number EC Number Description / Scope
67762-27-0 267-008-6 Most widely used CAS number. Defines the C16-18 fatty alcohol blend (Cetearyl Alcohol / Cetostearyl Alcohol). Listed as the primary identifier by PubChem and ECHA.
8005-44-5 Another valid CAS number commonly used for Cetearyl Alcohol. Listed alongside 67762-27-0 as a primary identifier in PubChem. No official EC counterpart.
67762-30-5 267-009-1 A valid CAS number defining the broader C14-18 fatty alcohol range. Commercially used for Cetearyl Alcohol products.

Important Clarifications:

  • EC number 267-008-6 belongs to CAS 67762-27-0.

  • EC number 267-009-1 belongs to CAS 67762-30-5.

  • All three CAS numbers are valid and accepted identifiers for Cetearyl Alcohol. The scope of 67762-30-5 is slightly broader (C14-18), but it is commercially used to describe standard Cetearyl Alcohol blends.

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value / Description
Physical state (20-25 °C) White, waxy solid (flakes or pastilles)
Colour White to very pale yellow
Melting point 48 – 56 °C (varies with C16:C18 ratio)
Boiling point ~249 °C
Flash point ~132.85 °C
Density ~0.842 g/cm³ (or g/mL)
Solubility in water Insoluble
Solubility in organics Partially soluble in alcohol; soluble in ether, oils, and esters
Refractive Index ~1.46
HLB Value ~15.5 (tends to form oil-in-water emulsions, limited capacity)
Molecular Weight ~512.94 g/mol (representative formula: C₃₄H₇₂O₂)

4. PRODUCT TYPES AND COMPARATIVE TABLE

The final consistency and sensory feel of the product are determined by the ratio of Cetyl (C16) to Stearyl (C18) alcohol.

Type (Cetyl:Stearyl) Composition Characteristic Properties Key Applications
30:70 Type 30% Cetyl (C16), 70% Stearyl (C18) Harder, denser, and more stable emulsions. Stronger thickening and stabilizing effect due to high stearyl alcohol content. Higher melting point. Rich night creams, protective hand creams, ointment bases, firm stick products (deodorant sticks, lip balms). Preferred where high stability and no phase separation are critical.
50:50 Type 50% Cetyl, 50% Stearyl Balanced crystal structure providing homogeneous distribution. Ideal middle ground between the softness of cetyl alcohol and the firmness of stearyl alcohol. The most widely used, "standard" type. Moisturizing creams and lotions, body milks, hair conditioners and masks, shampoos, sunscreens. Suitable for both O/W and W/O emulsions.
70:30 Type 70% Cetyl, 30% Stearyl Softer, creamier, and more velvety skin feel. The moisturizing and emollient effect is more dominant due to the high cetyl alcohol content. Provides sufficient softening to act as a standalone hair conditioning active. Hair conditioners and treatment masks (where a softening effect is paramount), soothing creams for sensitive skin, lip balms, serums. Also used to aid the stability of emulsifiers.

5. FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

  • Co-Emulsifier and Emulsion Stabilizer: Cetearyl alcohol is a non-ionic co-emulsifier. It strengthens the interfacial film formed by the primary emulsifier, preventing droplet coalescence and ensuring long-term emulsion stability. It works effectively in both oil-in-water (O/W) and water-in-oil (W/O) systems.

  • Viscosity Builder / Consistency Modifier: It forms a three-dimensional crystalline gel network (lamellar phases) within the formulation, trapping the emulsion droplets and increasing the viscosity. This provides a rich, creamy texture that is easy to spread and leaves a lasting, luxurious feel on the skin.

  • Emollient and Skin Conditioner: It forms a thin, protective, lipophilic film on the skin and hair surface. This film reduces transepidermal water loss (TEWL), providing moisturization, softness, and a smooth, non-greasy skin feel.

  • Opacifier: In liquid or gel-based formulations, it imparts a desirable matte, creamy, and opaque appearance, enhancing the product's visual aesthetics.

6. SECTORAL APPLICATIONS AND USAGE RATES

Product Type Recommended Usage Rate Notes
Face and Body Creams 1 – 5% Adjust based on desired thickness. The 50:50 type is very common here.
Lotions 1 – 4% Ideal for more fluid formulations.
Hair Conditioners and Masks 2 – 8% Provides noticeable softening and body. The 70:30 or 50:50 types are preferred.
Anhydrous Products (Balms, Sticks, Solid Shampoos) 5 – 25% Used to build the solid structure and adjust hardness. The 30:70 type is particularly well-suited for these applications.
General Cream Formulations 2 – 3% A typical usage level is sufficient to stabilize the emulsion and provide a pleasant texture.

Critical Note: Cetearyl Alcohol is a co-emulsifier and thickener, not a primary emulsifier. It must always be used in combination with a suitable primary emulsifier (see Section 7) to achieve a stable emulsion.

7. RECOMMENDED EMULSIFIER COMBINATIONS (Generic INCI Names)

Cetearyl Alcohol must be paired with a stronger primary emulsifier. The most common combinations are:

Formulation Goal Recommended Emulsifier System (Generic INCI Names)
Natural / Organic products Glyceryl Stearate & Cetearyl Alcohol & Sodium Stearoyl Lactylate blends, or Cetearyl Glucoside & Cetearyl Alcohol blends
Light and fast-absorbing lotions Sucrose Polystearate & Cetearyl Alcohol based systems
High pH stability products (e.g., hair relaxers) Cetearyl Alcohol & Ceteareth-20 combinations, or Cetearyl Glucoside & Cetearyl Alcohol combinations
Luxurious, velvety texture Glyceryl Stearate & Cetearyl Alcohol & Sodium Stearoyl Lactylate based systems (liquid crystal-forming types)
Pharmaceutical / Medical formulations Cetearyl Alcohol & Sodium Lauryl Sulfate & Sodium Cetearyl Sulfate combinations, or PEG-derivative emulsifying waxes

8. REGULATORY STATUS, SAFETY, AND STORAGE

  • GHS Classification: Not classified as a hazardous substance or mixture under CLP (EC 1272/2008).

  • Toxicology: Very low acute oral, dermal, and inhalation toxicity. Not a significant skin or eye irritant at typical use concentrations. Considered to have very low sensitization (allergy) potential. Not carcinogenic, mutagenic, or reprotoxic.

  • Comedogenicity: Generally considered non-comedogenic (low risk of clogging pores), making it suitable for acne-prone skin formulations.

  • Cosmetic Use: Listed as a safe cosmetic ingredient by the Cosmetic Ingredient Review (CIR) panel. Approved without restrictions under EU Cosmetics Regulation (EC 1223/2009).

  • Sustainability: When derived from vegetable sources (coconut or palm oil), it is considered a natural, renewable, and biodegradable ingredient, widely used in natural and organic formulations.

  • Storage: Store in a cool (<25 °C), dry, and well-ventilated area, away from direct sunlight and strong odours. Keep containers tightly closed.

  • Shelf Life: Typically 2-3 years from the date of manufacture under proper storage conditions.

  • Personal Protection: Standard industrial hygiene practices are sufficient (e.g., gloves, safety goggles for handling molten material).

9. FREQUENTLY ASKED QUESTIONS

Q1: What is the difference between Cetyl Alcohol and Cetearyl Alcohol?
Cetyl alcohol (C16) is a single, pure ingredient. Cetearyl alcohol is a blend of both cetyl alcohol (C16) and stearyl alcohol (C18). This blend offers superior emulsifying, stabilizing, and thickening properties compared to either component alone, making it the industry standard.

Q2: Is Cetearyl Alcohol harmful or drying to the skin?
No. Unlike simple, volatile alcohols like ethanol, it is a fatty, waxy alcohol that acts as an emollient. It forms a protective layer that prevents moisture loss, leaving the skin feeling smooth, soft, and conditioned without a greasy residue.

Q3: Is it suitable for natural or vegan formulations?
Yes. It is typically derived from plant-based sources like coconut or palm oil, making it suitable for both natural and vegan-friendly formulations. Always verify the source with your supplier.

Q4: What is its main function in a hair conditioner?
It acts as a thickener, giving the product a luxurious, rich texture. Simultaneously, it coats the hair strands, smoothing the cuticle, reducing static, and providing detangling and softening benefits.

Q5: Why must it be combined with another emulsifier?
Cetearyl alcohol is a co-emulsifier and thickener, not a primary emulsifier. It stabilizes an emulsion formed by a stronger, primary emulsifier. Using it alone will not reliably create a stable cream or lotion.

10. QUICK REFERENCE TABLE

Property Value
Primary CAS 67762-27-0
INCI Name Cetearyl Alcohol
Composition Blend of Cetyl (C16) and Stearyl (C18) alcohols
Appearance White waxy flakes / pastilles
Melting Point 48 – 56 °C
Solubility Insoluble in water; soluble in oils
Main Functions Co-emulsifier, thickener, emollient, opacifier
Key Benefit Provides a smooth, velvety, non-greasy skin feel and excellent emulsion stability

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