We unleash your business potential by maximize the business innovation.
Send EmailThulium Triacetate Hydrate, Thulium Acetate Hydrate, 314041‑04‑8
| Parameter | Information |
|---|---|
| Product Name | Thulium Acetate Hydrate |
| Chemical Name | Thulium(III) Acetate Hydrate |
| Other Names | Thulium Triacetate Hydrate, Thulium Acetate Hydrate |
| CAS Number | 314041-04-8 |
| EC Number | Not available |
| HS Code | 291529 |
| Molecular Formula | Tm(CH₃COO)₃·xH₂O (typically tetrahydrate) |
| Molecular Weight | ~293 g/mol (anhydrous basis) |
| Purity | Greater than or equal to 99 percent (rare earth purity) |
| Appearance | White or slightly pink crystalline solid |
| Odor | Slight acetic acid odor |
| Physical State (20°C) | Solid (crystalline) |
Thulium acetate hydrate is the acetate salt of thulium. Thulium ions (Tm3+) and acetate ions (CH3COO-) are present in a 1:3 ratio. The compound typically exists as a hydrate with variable water content (usually tetrahydrate). It is hygroscopic and readily absorbs moisture from the air.
Structural Formula:
THULIUM ACETATE HYDRATE [Tm(CH3COO)3·xH2O]
|
Tm3+ - CH3COO- Ionic Bonds
|
+----------------+----------------+
| | |
Organic Salt Hygroscopic Acidic
Structure Property Salt
| Parameter | Value |
|---|---|
| Oxidation State | Tm3+ (Thulium +3) |
| Molecular Weight | ~293 g/mol (anhydrous) |
| Water Content | Variable (typically x = 4) |
| Appearance | White or slightly pink crystalline solid |
| Density | ~2.5–2.7 g/cm3 |
| pH (aqueous solution) | Slightly acidic |
| Property | Value | Description |
|---|---|---|
| Appearance | White or slightly pink crystalline solid | - |
| Odor | Slight acetic acid odor | - |
| Chemical Formula | Tm(CH3COO)3·xH2O | - |
| Molecular Weight | ~293 g/mol (anhydrous) | - |
| Density | ~2.5–2.7 g/cm3 | - |
| Melting Point | Decomposes upon heating | - |
| Solubility in Water | Soluble | - |
| Solubility in Acetic Acid | Soluble | - |
| Solubility in Ethanol | Slightly soluble | - |
| Hygroscopicity | High | Absorbs moisture from air |
| Stability | Stable under normal conditions; sensitive to moisture and light | - |
| pH (aqueous solution) | Slightly acidic | - |
| Thermal Decomposition | Decomposes to thulium oxide (Tm2O3) | - |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions |
| Conditions to Avoid | Moisture, high temperature, strong oxidizing agents |
| Incompatible Materials | Strong bases, strong oxidizing agents, reducing agents |
| Hazardous Decomposition Products | Thulium oxide (Tm2O3), carbon dioxide, acetic acid vapors |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | High; absorbs moisture from air |
| Photosensitivity | Moderate |
Thermal Decomposition:
2Tm(CH3COO)3·xH2O → Tm2O3 + 3CO2↑ + 3CH3COCH3↑ + xH2O↑
Reaction with Alkali:
Tm(CH3COO)3 + 3NaOH → Tm(OH)3↓ + 3CH3COONa
| Application | Function | Details |
|---|---|---|
| Laser Crystals | Laser medium | Tm3+ doped laser crystals for 2 micrometer wavelength lasers |
| Optical Amplifiers | Signal amplification | Thulium-doped fiber amplifiers (TDFA) for telecommunications |
| Infrared Emitters | IR source | Thulium-based infrared emitting materials |
| Solid-State Lasers | Laser material | Tm:YAG, Tm:YLF, and other thulium-doped laser crystals |
| Phosphors | Luminescent material | Green-emitting phosphors for display applications |
| Scintillators | Radiation detection | Thulium-doped scintillation materials |
| Application | Function | Details |
|---|---|---|
| Infrared Optics | IR transmission | Thulium-containing glasses for infrared applications |
| Luminescent Materials | Light emission | Thulium-doped luminescent materials |
| Advanced Ceramics | Performance enhancer | Specialty ceramic components |
| Optical Glass | Optical additive | Enhances optical properties |
| Application | Function | Details |
|---|---|---|
| Laboratory Reagent | Rare earth research | Used as a reagent in rare earth chemistry |
| Precursor Compound | Starting material | Synthesis of other thulium compounds |
| Advanced Materials Research | Research material | Development of new materials |
| Catalyst Research | Catalyst precursor | Various catalytic applications |
| Application | Function | Details |
|---|---|---|
| Surface Treatment | Coating material | Specialty coating applications |
| Alloy Additive | Alloy component | Specialty alloy production |
| Precursor | Intermediate | Production of other thulium compounds |
| Sector / Application | Suitability | Description |
|---|---|---|
| Textile | Not Suitable | No application area |
| Food | Not Suitable | Prohibited in food additives or food contact materials |
| Cosmetics | Not Suitable | Prohibited in cosmetic formulations under CLP/REACH |
| Metal / Surface Treatment | Suitable | Can be used in specialty alloys and coatings |
| Ceramics / Glass | Suitable | Used in advanced ceramics and specialty glass production |
| Laboratory / Research | Suitable | Widely used as reagent in rare earth chemistry |
| Electronics / Optics | Suitable | Critical use in laser crystals, optical amplifiers, and photonics |
| Construction Chemicals | Not Suitable | No application area |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Sealed, moisture-proof containers |
| Light Protection | Protect from light |
| Moisture Protection | Store with desiccant; hygroscopic |
| Temperature | Room temperature (15-25 degrees Celsius) |
| Shelf Life | Approximately 2 years under proper conditions |
| Stability Note | Hygroscopic; may absorb moisture if exposed to humid air |
| Packaging Type | Quantity | Material |
|---|---|---|
| Glass Bottle | 10 g, 50 g, 100 g | Amber glass with desiccant |
| Plastic Container | 100 g, 500 g, 1 kg | HDPE container, moisture-proof |
| Fiber Drum | 5 kg, 10 kg, 25 kg | PE-lined, moisture-proof |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | Greater than 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant (H315) |
| Eye Irritation | Mild to severe irritant (H319) |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver effects at high doses |
| Environmental Hazards | Low to moderate toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registration required |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| Food / Cosmetics | Not approved |
Thulium(III) Acetate Hydrate
Thulium Triacetate Hydrate
Thulium Acetate Hydrate
Tm(CH3COO)3·xH2O
| Property | Value |
|---|---|
| CAS Number | 314041-04-8 |
| HS Code | 291529 |
| Molecular Formula | Tm(CH3COO)3·xH2O |
| Molecular Weight | ~293 g/mol (anhydrous) |
| Appearance | White or slightly pink crystalline solid |
| Density | ~2.5–2.7 g/cm3 |
| Water Solubility | Soluble |
| Purity | Greater than or equal to 99 percent |
| Hygroscopicity | High |
| GHS Signal Word | WARNING |
Thulium acetate hydrate is highly hygroscopic. Must be stored in moisture-proof containers with desiccant.
Protect from light to prevent degradation.
Decomposes at high temperatures to thulium oxide.
Causes skin and eye irritation. Use appropriate personal protective equipment.
Dust may cause respiratory irritation. Use in well-ventilated areas.
Primarily used in research, electronics, optics, and photonics applications.
Storage:
Store in a cool, dry, well-ventilated area
Use sealed, moisture-proof containers with desiccant
Protect from light
Store at room temperature (15-25 degrees Celsius)
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Immediately reseal container after use
Waste Management:
Dispose in accordance with local regulations
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Thulium acetate hydrate is a specialty rare earth compound; appropriate precautions must be taken during handling.