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Send EmailEuropium Sulfate, Europium Trisulfate, Europium Sulfate Hydrate, 10031‑54‑6
| Parameter | Information |
|---|---|
| Product Name | Europium Sulfate |
| Chemical Name | Europium(III) Sulfate |
| Other Names | Europium Trisulfate, Europium Sulfate Hydrate |
| CAS Number | 10031-54-6 |
| EC Number (EINECS) | 233-119-7 |
| HS Code | 283429 |
| Molecular Formula | Eu₂(SO₄)₃·xH₂O (typically hydrated form) |
| Molecular Weight | ~632.06 g/mol (anhydrous basis) |
| Purity | ≥ 99% (rare earth purity) |
| Appearance | White to light pink crystalline solid |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline) |
Europium sulfate is the sulfate salt of europium. Europium ions (Eu³⁺) and sulfate ions (SO₄²⁻) are present in a 2:3 ratio. The compound typically exists as a hydrate with variable water content. It is hygroscopic and readily absorbs moisture from the air. Europium salts are characterized by their light pink coloration due to the electronic configuration of the Eu³⁺ ion.
Structural Formula:
EUROPIUM SULFATE [Eu₂(SO₄)₃·xH₂O]
|
Eu³⁺ - SO₄²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Ionic Crystal Hygroscopic Acidic
Structure Property Salt
| Parameter | Value |
|---|---|
| Oxidation State | Eu³⁺ (Europium +3) |
| Molecular Weight | ~632.06 g/mol (anhydrous) |
| Water Content | Variable (typically x = 8) |
| Appearance | White to light pink crystalline solid |
| Density | ~3.7 g/cm³ |
| pH (aqueous solution) | Slightly acidic |
| Color Origin | f-f transitions of Eu³⁺ ion |
| Property | Value | Description |
|---|---|---|
| Appearance | White to light pink crystalline solid | - |
| Odor | Odorless | - |
| Chemical Formula | Eu₂(SO₄)₃·xH₂O | - |
| Molecular Weight | ~632.06 g/mol (anhydrous) | - |
| Density | ~3.7 g/cm³ | - |
| Melting Point | Decomposes upon heating | - |
| Solubility in Water | Soluble | - |
| Solubility in Acids | Soluble | - |
| Solubility in Ethanol | Slightly soluble | - |
| Hygroscopicity | High | Absorbs moisture from air |
| Stability | Stable under normal conditions; sensitive to moisture and light | - |
| pH (aqueous solution) | Slightly acidic | - |
| Thermal Decomposition | Decomposes to europium oxide (Eu₂O₃) | - |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions |
| Conditions to Avoid | Moisture, high temperature, strong oxidizing agents |
| Incompatible Materials | Strong bases, strong oxidizing agents, reducing agents |
| Hazardous Decomposition Products | Europium oxide (Eu₂O₃), sulfur dioxide (SO₂), sulfur trioxide (SO₃) |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | High; absorbs moisture from air |
| Photosensitivity | Moderate |
Thermal Decomposition:
Eu₂(SO₄)₃·xH₂O → Eu₂O₃ + 3SO₃↑ + xH₂O↑
Reaction with Alkali:
Eu₂(SO₄)₃ + 6NaOH → 2Eu(OH)₃↓ + 3Na₂SO₄
Reaction with Phosphate:
Eu₂(SO₄)₃ + 2Na₃PO₄ → 2EuPO₄↓ + 3Na₂SO₄
| Application | Function | Details |
|---|---|---|
| Europium Oxide (Eu₂O₃) Production | Precursor | High-purity europium oxide production |
| Europium Phosphate (EuPO₄) Production | Precursor | Phosphor applications |
| Mixed Rare Earth Compounds | Precursor | Specialty mixed oxides |
| Application | Function | Details |
|---|---|---|
| Red Phosphors | Luminescent material | Eu³⁺ is critical for red emission in phosphors |
| LED Phosphors | Light emission | Europium-doped phosphors for LED lighting |
| Display Phosphors | Display material | Red phosphors for displays and screens |
| Fluorescent Lamps | Lighting | Europium-based red phosphors for fluorescent lighting |
| Scintillators | Radiation detection | Europium-doped scintillation materials |
| Laser Phosphors | Laser medium | Europium-doped laser materials |
| CRT Phosphors | Display material | Red phosphors for cathode ray tubes |
| Application | Function | Details |
|---|---|---|
| Laser Crystals | Laser medium | Eu³⁺ doped laser crystals |
| Optical Devices | Optical component | Europium-based optical materials |
| Solid-State Lasers | Laser material | Europium-doped laser crystals |
| Optical Glass | Optical additive | Enhances optical properties |
| OLED Materials | Luminescent material | Europium-based OLED emitters |
| Application | Function | Details |
|---|---|---|
| Advanced Ceramics | Performance enhancer | Specialty ceramic components |
| Specialty Glass | Optical additive | Infrared and optical glasses |
| Colored Glass | Colorant | Glass coloring for decorative applications |
| Refractory Materials | Heat resistance | High-temperature applications |
| Application | Function | Details |
|---|---|---|
| Laboratory Reagent | Rare earth research | Used as a reagent in rare earth chemistry |
| Precursor Compound | Starting material | Synthesis of other europium compounds |
| Advanced Materials Research | Research material | Development of new materials |
| Standard Preparation | Reference material | Calibration and analysis |
| Sector / Application | Suitability | Description |
|---|---|---|
| Textile | Not Suitable | No application area |
| Food | Not Suitable | Prohibited in food additives or food contact materials |
| Cosmetics | Not Suitable | Prohibited in cosmetic formulations under CLP/REACH |
| Metal / Surface Treatment | Suitable | Can be used in specialty alloys and coatings |
| Ceramics / Glass | Suitable | Used in advanced ceramics and specialty glass production |
| Laboratory / Research | Suitable | Widely used as reagent in rare earth chemistry |
| Electronics / Optics | Suitable | Critical use in phosphors, LEDs, lasers, and photonics |
| Construction Chemicals | Not Suitable | No application area |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Sealed, moisture-proof containers |
| Light Protection | Protect from light |
| Moisture Protection | Store with desiccant; hygroscopic |
| Temperature | Room temperature (15-25°C) |
| Shelf Life | Approximately 2 years under proper conditions |
| Stability Note | Hygroscopic; may absorb moisture if exposed to humid air |
| Packaging Type | Quantity | Material |
|---|---|---|
| Glass Bottle | 10 g, 50 g, 100 g | Amber glass with desiccant |
| Plastic Container | 100 g, 500 g, 1 kg | HDPE container, moisture-proof |
| Fiber Drum | 5 kg, 10 kg, 25 kg | PE-lined, moisture-proof |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant (H315) |
| Eye Irritation | Mild to severe irritant (H319) |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver effects at high doses |
| Environmental Hazards | Low to moderate toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 233-119-7 |
| Food / Cosmetics | Not approved |
Europium(III) Sulfate
Europium Trisulfate
Europium Sulfate Hydrate
Eu₂(SO₄)₃·xH₂O
| Property | Value |
|---|---|
| CAS Number | 10031-54-6 |
| EC Number | 233-119-7 |
| HS Code | 283429 |
| Molecular Formula | Eu₂(SO₄)₃·xH₂O |
| Molecular Weight | ~632.06 g/mol (anhydrous) |
| Appearance | White to light pink crystalline solid |
| Density | ~3.7 g/cm³ |
| Water Solubility | Soluble |
| Purity | ≥ 99% |
| Hygroscopicity | High |
| GHS Signal Word | WARNING |
Europium sulfate is highly hygroscopic. Must be stored in moisture-proof containers with desiccant.
Protect from light to prevent degradation.
Decomposes at high temperatures to europium oxide (Eu₂O₃), releasing sulfur oxides.
Causes skin and eye irritation. Use appropriate personal protective equipment.
Dust may cause respiratory irritation. Use in well-ventilated areas.
Primarily used in research, phosphors, LEDs, lasers, and photonics applications.
Eu³⁺ is critical for red emission in phosphors, LEDs, and displays.
Storage:
Store in a cool, dry, well-ventilated area
Use sealed, moisture-proof containers with desiccant
Protect from light
Store at room temperature (15-25°C)
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Immediately reseal container after use
Waste Management:
Dispose in accordance with local regulations
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Europium sulfate is a specialty rare earth compound; appropriate precautions must be taken during handling