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Send EmailErbium Sulfate, Erbium Sesquisulfate, Dierbium Trisulfate, Erbium Sulfate Octahydrate, 13478‑49‑4
| Parameter | Information |
|---|---|
| Product Name | Erbium Sulfate |
| Chemical Name | Erbium(III) Sulfate |
| Other Names | Erbium Sesquisulfate, Dierbium Trisulfate, Erbium Sulfate Octahydrate |
| CAS Number | 13478-49-4 |
| EC Number (EINECS) | 236-779-0 |
| HS Code | 283429 |
| Molecular Formula | Er₂(SO₄)₃ |
| Molecular Weight | 622.71 g/mol |
| Purity | ≥ 99 – 99.99% (rare earth purity) |
| Appearance | Pink-rose colored crystalline powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline) |
Erbium sulfate is the sulfate salt of erbium. Erbium ions (Er³⁺) and sulfate ions (SO₄²⁻) are present in a 2:3 ratio. The compound typically exists in anhydrous form or as an octahydrate. It is hygroscopic and readily absorbs moisture from the air. Erbium salts are characterized by their pink-rose coloration due to the electronic configuration of the Er³⁺ ion.
Structural Formula:
ERBIUM SULFATE [Er₂(SO₄)₃]
|
Er³⁺ - SO₄²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Ionic Crystal Hygroscopic Acidic
Structure Property Salt
| Parameter | Value |
|---|---|
| Oxidation State | Er³⁺ (Erbium +3) |
| Molecular Weight | 622.71 g/mol (anhydrous) |
| Hydration States | Anhydrous and octahydrate forms exist |
| Appearance | Pink-rose colored crystalline powder |
| Density | ~3.68 g/cm³ |
| pH (aqueous solution) | Slightly acidic |
| Color Origin | f-f transitions of Er³⁺ ion |
| Property | Value | Description |
|---|---|---|
| Appearance | Pink-rose colored crystalline powder | - |
| Odor | Odorless | - |
| Chemical Formula | Er₂(SO₄)₃ | - |
| Molecular Weight | 622.71 g/mol | - |
| Density | ~3.68 g/cm³ | - |
| Melting Point | Decomposes upon heating | - |
| Solubility in Water (20°C) | ~13 g/100 mL (soluble) | - |
| Solubility in Acids | Soluble | - |
| Solubility in Ethanol | Slightly soluble | - |
| Hygroscopicity | High | Absorbs moisture from air |
| Stability | Stable under normal conditions; sensitive to moisture and light | - |
| pH (aqueous solution) | Slightly acidic | - |
| Thermal Decomposition | Decomposes to erbium oxide (Er₂O₃) | - |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions |
| Conditions to Avoid | Moisture, high temperature, strong oxidizing agents |
| Incompatible Materials | Strong bases, strong oxidizing agents, reducing agents |
| Hazardous Decomposition Products | Erbium oxide (Er₂O₃), sulfur dioxide (SO₂), sulfur trioxide (SO₃) |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | High; absorbs moisture from air |
| Photosensitivity | Moderate |
Thermal Decomposition:
Er₂(SO₄)₃ → Er₂O₃ + 3SO₃↑
Reaction with Alkali:
Er₂(SO₄)₃ + 6NaOH → 2Er(OH)₃↓ + 3Na₂SO₄
Reaction with Phosphate:
Er₂(SO₄)₃ + 2Na₃PO₄ → 2ErPO₄↓ + 3Na₂SO₄
| Application | Function | Details |
|---|---|---|
| Erbium Oxide (Er₂O₃) Production | Precursor | High-purity erbium oxide production |
| Erbium Phosphate (ErPO₄) Production | Precursor | Phosphor applications |
| Mixed Rare Earth Compounds | Precursor | Specialty mixed oxides |
| Application | Function | Details |
|---|---|---|
| Fiber Optics | Optical amplifier | Erbium-doped fiber amplifiers (EDFA) for telecommunications |
| Laser Crystals | Laser medium | Er³⁺ doped laser crystals for 1.5 µm and 2.9 µm wavelength lasers |
| Solid-State Lasers | Laser material | Er:YAG and other erbium-doped laser crystals |
| Optical Amplifiers | Signal amplification | Erbium-doped waveguide amplifiers |
| Optical Glass | Optical additive | Enhances optical properties |
| Infrared Optics | IR transmission | Erbium-containing glasses for infrared applications |
| Application | Function | Details |
|---|---|---|
| Advanced Ceramics | Performance enhancer | Specialty ceramic components |
| Specialty Glass | Optical additive | Infrared and optical glasses |
| Colored Glass | Colorant | Pink-rose glass coloring for decorative applications |
| Refractory Materials | Heat resistance | High-temperature applications |
| Application | Function | Details |
|---|---|---|
| Optical Devices | Optical component | Erbium-based optical materials |
| Phosphors | Luminescent material | Erbium-based phosphors |
| Scintillators | Radiation detection | Erbium-doped scintillation materials |
| Upconversion Materials | Light conversion | Erbium-doped upconversion materials for bioimaging and photonics |
| Application | Function | Details |
|---|---|---|
| Laboratory Reagent | Rare earth research | Used as a reagent in rare earth chemistry |
| Precursor Compound | Starting material | Synthesis of other erbium compounds |
| Advanced Materials Research | Research material | Development of new materials |
| Standard Preparation | Reference material | Calibration and analysis |
| Sector / Application | Suitability | Description |
|---|---|---|
| Textile | Not Suitable | No application area |
| Food | Not Suitable | Prohibited in food additives or food contact materials |
| Cosmetics | Not Suitable | Prohibited in cosmetic formulations under CLP/REACH |
| Metal / Surface Treatment | Suitable | Can be used in specialty alloys and coatings |
| Ceramics / Glass | Suitable | Used in advanced ceramics and specialty glass production |
| Laboratory / Research | Suitable | Widely used as reagent in rare earth chemistry |
| Electronics / Optics | Suitable | Critical use in fiber optics, lasers, and photonics |
| Construction Chemicals | Not Suitable | No application area |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Sealed, moisture-proof containers |
| Light Protection | Protect from light |
| Moisture Protection | Store with desiccant; hygroscopic |
| Temperature | Room temperature (15-25°C) |
| Shelf Life | Approximately 2 years under proper conditions |
| Stability Note | Hygroscopic; may absorb moisture if exposed to humid air |
| Packaging Type | Quantity | Material |
|---|---|---|
| Glass Bottle | 10 g, 50 g, 100 g | Amber glass with desiccant |
| Plastic Container | 100 g, 500 g, 1 kg | HDPE container, moisture-proof |
| Fiber Drum | 5 kg, 10 kg, 25 kg | PE-lined, moisture-proof |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant (H315) |
| Eye Irritation | Mild to severe irritant (H319) |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver effects at high doses |
| Environmental Hazards | Low to moderate toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 236-779-0 |
| Food / Cosmetics | Not approved |
Erbium(III) Sulfate
Erbium Sesquisulfate
Dierbium Trisulfate
Erbium Sulfate Octahydrate
Er₂(SO₄)₃
| Property | Value |
|---|---|
| CAS Number | 13478-49-4 |
| EC Number | 236-779-0 |
| HS Code | 283429 |
| Molecular Formula | Er₂(SO₄)₃ |
| Molecular Weight | 622.71 g/mol |
| Appearance | Pink-rose colored crystalline powder |
| Density | ~3.68 g/cm³ |
| Water Solubility (20°C) | ~13 g/100 mL |
| Purity | ≥ 99 – 99.99% |
| Hygroscopicity | High |
| GHS Signal Word | WARNING |
Erbium sulfate is highly hygroscopic. Must be stored in moisture-proof containers with desiccant.
Protect from light to prevent degradation.
Decomposes at high temperatures to erbium oxide (Er₂O₃), releasing sulfur oxides.
Causes skin and eye irritation. Use appropriate personal protective equipment.
Dust may cause respiratory irritation. Use in well-ventilated areas.
Primarily used in research, fiber optics, lasers, and photonics applications.
Erbium-doped fiber amplifiers (EDFA) are critical for telecommunications (1.5 µm wavelength).
Storage:
Store in a cool, dry, well-ventilated area
Use sealed, moisture-proof containers with desiccant
Protect from light
Store at room temperature (15-25°C)
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Immediately reseal container after use
Waste Management:
Dispose in accordance with local regulations
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Erbium sulfate is a specialty rare earth compound; appropriate precautions must be taken during handling.